Advertisement

Selected Examples

  • Richard L. Carlin

Abstract

The discussion in this chapter concerns some additional examples of interesting magnetic compounds that have been examined recently. It will be seen that all of the principles discussed earlier in this book come together here. No attempt is made at a complete literature survey, or even a summary of all the work reported on a given compound. Consonant with the point of view of this book will be the emphasis on results based on specific heat and magnetic susceptibility data, but especially we are trying to lay a firm foundation for a structural basis of magnetochemistry. The examples chosen are some of the best understood or most important ones, a knowledge of which should be had by everyone interested in this subject. Further information and references may be found in earlier sections of the book, as well as in Refs. [1–6].

Keywords

Electron Paramagnetic Resonance Electron Paramagnetic Resonance Spectrum Easy Axis Magnetic Phase Transition Magnetic Phase Diagram 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Ballhausen C.J., (1962) Introduction to Ligand Field Theory, McGraw-Hill, New YorkGoogle Scholar
  2. 2.
    McGarvey B.R., (1966)in: Transition Metal Chemistry, Vol. 3, p. 90, Ed.: Carlin R.L., Marcel Dekker, Inc., New YorkGoogle Scholar
  3. 3.
    Cotton FA. and Wilkinson G., (1980) 4th Ed.: Advanced Inorganic Chemistry, J. Wiley and Sons, New YorkGoogle Scholar
  4. 4.
    Abragam A. and Bleaney B., (1970) Electron Paramagnetic Resonance of Transition Ions, Oxford University Press, OxfordGoogle Scholar
  5. 5.
    Orton J.W., (1968) Electron Paramagnetic Resonance, Iliffe Books, Ltd., LondonGoogle Scholar
  6. 6.
    a) Mabbs F.E. and Machin D.J. (1973) Magnetism and Transition Metal Complexes, Chapman and Hall, London b) Annual reviews of the literature are provided by the Annual Reports of the Chemical Society, London, and by the Specialist Periodical Reports, also published by the Chemical Society, in the series: Electronic Structure and Magnetism of Inorganic CompoundsGoogle Scholar
  7. 7.
    Gmelin: Handbuch Anorg. Chem., Vol. 57, Part B, Sect. 2, p. 553 (Fig. 213 ), Springer (1966) Berlin, Heidelberg, New YorkGoogle Scholar
  8. 8.
    Robinson W.K. and Friedberg S.A., Phys. Rev. 117, 402 (1960)CrossRefGoogle Scholar
  9. 9.
    McElearney J.N., Losee D.B., Merchant S., and Carlin R.L., Phys. Rev. B7, 3314 (1973)CrossRefGoogle Scholar
  10. 10.
    Polgar L.G., Herweijer A, and de Jonge W.J.M., Phys. Rev. B5, 1957 (1972)CrossRefGoogle Scholar
  11. 11.
    Bizette H, Compt. rend. 243, 1295 (1956)Google Scholar
  12. 12.
    Bhatia S.N., Carlin R.L., and Paduan-Filho A., Physica 92 B, 330 (1977)Google Scholar
  13. 13.
    Kopinga K. and de Jonge W.J.M., Phys. Lett. 43A, 415 (1973)CrossRefGoogle Scholar
  14. 14.
    Van Uitert L.G., Wilhams HJ., Sherwood R.C., and Rubin J.J., J. Appl. Phys. 36, 1029 (1965)CrossRefGoogle Scholar
  15. 15.
    Haseda T., Kobayashi H., and Date M., J. Phys. Soc. Japan 14, 1724 (1959)CrossRefGoogle Scholar
  16. 16.
    Mizuno J., J. Phys. Soc. Japan 16, 1574 (1961)CrossRefGoogle Scholar
  17. 17.
    Hamburger A.I. and Friedberg S.A., Physica 69, 67 (1973)CrossRefGoogle Scholar
  18. 18.
    Kleinberg R., J. Chem. Phys. 50, 4690 (1969)CrossRefGoogle Scholar
  19. 19.
    Kleinberg R, J. Appl. Phys. 38, 1453 (1967)CrossRefGoogle Scholar
  20. 20.
    Paduan-Filho A., Becerra C.C., and Oliveira, Jr. N.F., Phys. Lett. 50 A, 51 (1974)Google Scholar
  21. 21.
    Figueiredo W., Salinas S.R., Becerra C.C., Oliveira, Jr. N.F., and Paduan-Filho A., J. Phys. C15, L-115 (1982)Google Scholar
  22. 22.
    Vianna S.S. and Becerra C.C., Phys. Rev. B28, 2816 (1983)CrossRefGoogle Scholar
  23. 23.
    Oliveira, Jr. N.F., Paduan-Filho A., Sahnas S.R., and Becerra C.C., Phys. Rev. B18, 6165 (1978)CrossRefGoogle Scholar
  24. 24.
    Swüste C.H.W., Botterman A.C., Millenaar J., and de Jonge W.J.M., J. Chem. Phys. 66, 5021 (1977)CrossRefGoogle Scholar
  25. 25.
    de Neef T. and de Jonge W.J.M., Phys. Rev. B10, 1059 (1974)Google Scholar
  26. 26.
    Martin R.L. and White A.H., Trans. Met. Chem. 4, 113 (1968)Google Scholar
  27. 27.
    Gütlich P, Struct. Bonding 44, 83 (1981)CrossRefGoogle Scholar
  28. 28.
    Switzer M.E., Wang R., Rettig M.F., and Maki A.H., J. Am. Chem. Soc. 96, 7669 (1974)CrossRefGoogle Scholar
  29. 29.
    Pignolet L.H., Patterson G.S, Weiher J.F., and Holm R.H., Inorg. Chem. 13, 1263 (1974)CrossRefGoogle Scholar
  30. 30.
    Kennedy B.J., Fallon G.D., Gatehouse B.M.K.C., and Murray K.S., Inorg. Chem. 23, 580 (1984); Zarembowitch J. and Kahn O., Inorg. Chem. 23, 589 (1984)Google Scholar
  31. 31.
    Terzis A., Filippakis S., Mentzafos D., Petrouleas V., and Malliaris A., Inorg. Chem. 23, 334 (1984)CrossRefGoogle Scholar
  32. 32.
    Merrithew P.B. and Rasmussen P.G., Inorg. Chem. 11, 325 (1972)CrossRefGoogle Scholar
  33. 33.
    Harris G., Theor. Chim. Acta 5, 379 (1966); ibid., 10, 119 (1968)Google Scholar
  34. 34.
    Hall G.R. and Hendrickson D.N., Inorg. Chem. 15, 607 (1976)CrossRefGoogle Scholar
  35. 35.
    Healy P.C. and Sinn E., Inorg. Chem. 14, 109 (1975); Butcher R.J. and Sinn E., J. Am. Chem. Soc. 98, 2440, 5139 (1976); Sinn E., Inorg. Chem. 15, 369 (1976); Cuckauskas E.J., Deaver B.S., and Sinn E., J. Chem. Phys. 67, 1257 (1977)Google Scholar
  36. 36.
    Malliaris A. and Papaefthimious V., Inorg. Chem. 21, 770 (1982)CrossRefGoogle Scholar
  37. 37.
    Leipoldt J.G. and Coppens P., Inorg. Chem. 12, 2269 (1973)CrossRefGoogle Scholar
  38. 38.
    Hoskins B.F. and Pannan C.D., Inorg. Nucl. Chem. Lett. 11, 409 (1975)CrossRefGoogle Scholar
  39. 39.
    Martin R.L. and White A.H., Inorg. Chem. 6, 712 (1967); Hoskins B.F. and White A.H., J. Chem. Soc. A1970, 1668Google Scholar
  40. 40.
    Healey P.C., White A.H., and Hoskins B.F., J. Chem. Soc. D 1972, 1369Google Scholar
  41. 41.
    Chapps G.E., McCann S.W., Wickman H.H., and Sherwood R.C., J. Chem. Phys. 60, 990 (1974)CrossRefGoogle Scholar
  42. 42.
    DeFotis G.C., Failon B.K., Wells F.V., and Wickman H.H., Phys. Rev. B29, 3795 (1984)CrossRefGoogle Scholar
  43. 43.
    Carlin R.L., Science, 227, 1291 (1985)CrossRefGoogle Scholar
  44. 44.
    Wickman H.H., Klein M.P., and Shirley D.A., J. Chem. Phys. 42, 2113 (1965)CrossRefGoogle Scholar
  45. 45.
    Bracket G.C., Richards P.L., and Caughey W.S., J. Chem. Phys. 54, 4383 (1971)CrossRefGoogle Scholar
  46. 46.
    Wickman H.H. and Merritt F.R., Chem. Phys. Lett. 1, 117 (1967)CrossRefGoogle Scholar
  47. 47.
    Ganguli P., Marathe V.R., and Mitra S., Inorg. Chem. 14, 970 (1975)CrossRefGoogle Scholar
  48. 48.
    DeFotis G.C., Palacio F, and Carlin R.L., Phys. Rev. B20, 2945 (1979)CrossRefGoogle Scholar
  49. 49.
    Mitra S., Figgis B.N., Raston C.L., Skelton B.W., and White A.H., J. Chem. Soc. Dalton 1979, 753Google Scholar
  50. 50.
    Wickman H.H., Trozzolo A.M., Wilhams H.J., Hull G.W, and Merritt F.R., Phys. Rev. 155, 563 (1967); ibid., 163, 526 (1967)Google Scholar
  51. 51.
    Wickman H.H. and Trozzolo A.M., Inorg. Chem. 7, 63 (1968)CrossRefGoogle Scholar
  52. 52.
    Wickman H.H. and Wagner C.F., J. Chem. Phys. 51, 435 (1969); Wickman H.H., J. Chem. Phys. 56, 976 (1972)Google Scholar
  53. 53.
    Arai N., Sorai M., Suga H., and Seki S., J. Phys. Chem. Solids 38, 1341 (1977)CrossRefGoogle Scholar
  54. 54.
    DeFotis G.C. and Cowen J.A., J. Chem. Phys. 73, 2120 (1980)CrossRefGoogle Scholar
  55. 55.
    Decurtins S., Wells F.V., Sun K.C.-P., and Wickman H.H., Chem. Phys. Lett. 89, 79 (1982)CrossRefGoogle Scholar
  56. 56.
    Yoshikawa M., Sorai M., and Suga H., J. Phys. Chem. Solids 45, 753 (1984)CrossRefGoogle Scholar
  57. 57.
    Burlet P., Burlet P., and Bertaut E.F., Solid State Comm. 14, 665 (1974)CrossRefGoogle Scholar
  58. 58.
    Bertaut E.F., Due T.Q., Burlet P., Burlet P., Thomas M., and Moreau J.M., Acta Cryst. B 30, 2234 (1974)Google Scholar
  59. 59.
    Flippen R.B. and Friedberg S.A., Phys. Rev. 121, 1591 (1961)CrossRefGoogle Scholar
  60. 60.
    Schelleng J.H., Raquet C.A., and Friedberg S.A., Phys. Rev. 176, 708 (1968)CrossRefGoogle Scholar
  61. 61.
    Spence R.D., J. Chem. Phys. 62, 3659 (1975)CrossRefGoogle Scholar
  62. 62.
    Schmidt V.A. and Friedberg SA., Phys. Rev. 188, 809 (1969)CrossRefGoogle Scholar
  63. 63.
    Witteveeb H.T., Rutten W.L.C., and Reedijk J., J. Inorg. Nucl. Chem. 37, 913 (1975)Google Scholar
  64. 64.
    Klaaijsen F.W., Thesis, (1974) Leiden; Klaaijsen F.W., Blöte H.W.J., and Dokoupil Z., Solid State Comm.14,607 (1974); Klaaijsen F.W., Dokoupil Z., and Huiskamp W.J., Physica 79 B 547 (1975). Similar studies on the manganese analogs are published by Klaaijsen F.W., Blöte H.W.J., and Dokoupil Z, Physica 81B, 1 (1976)Google Scholar
  65. 65.
    Blöte H.W.J, Physica 79 B, 427 (1975)Google Scholar
  66. 66.
    Berger L. and Friedberg S.A., Phys. Rev. 136, A158 (1964)CrossRefGoogle Scholar
  67. 67.
    Schmidt V.A. and Friedberg S.A., Phys. Rev. B1, 2250 (1970)CrossRefGoogle Scholar
  68. 68.
    Polgar L.G. and Friedberg S.A., Phys. Rev. B4, 3110 (1971)CrossRefGoogle Scholar
  69. 69.
    Herweijer A. and Friedberg S.A., Phys. Rev. B4, 4009 (1971)CrossRefGoogle Scholar
  70. 70.
    Morosin B. and Haseda T., Acta Cryst. B35, 2856 (1979)CrossRefGoogle Scholar
  71. 71.
    Wada N., Matsumoto K., Amaya K., and Haseda T., J. Phys. Soc. Japan 47, 1061 (1979)CrossRefGoogle Scholar
  72. 72.
    Wada N., J. Phys. Soc. Japan 49,1747 (1980); Wada N. and Haseda T., J. Phys. Soc. Japan 50, 779 (1981); Wada N., Kashima Y., Haseda T., and Morosin B., J. Phys. Soc. Japan 50, 3876 (1981)Google Scholar
  73. 73.
    Salem-Sugui, Jr. S., Ortiz W.A., Paduan-Filho A, and Misseil F.P., J. Appl. Phys. 53, 7945 (1982)Google Scholar
  74. 74.
    Carlin R.L. and de Jongh L.J., Chem. Revs, to be publishedGoogle Scholar
  75. 75.
    van Ingen Schenau A.D., Verschoor G.C., and Romers C., Acta Cryst. B30, 1686 (1974)Google Scholar
  76. 76.
    Bergendahl TJ. and Wood J.S., Inorg. Chem. 14, 338 (1975)CrossRefGoogle Scholar
  77. 77.
    a) Algra H.A., de Jongh LJ., and Carlin R.L., Physica, 93 B, 24 (1978) b) Algra HA., de Jongh L.J., Huiskamp WJ., and Carlin R.L., Physica 83 B, 71 (1976)Google Scholar
  78. 78.
    Carlin R.L., O’Connor C.J., and Bhatia S.N., J. Am. Chem. Soc. 98, 685 (1976)CrossRefGoogle Scholar
  79. 79.
    O’Connor C.J. and Carlin R.L., Inorg. Chem. 14, 291 (1975)CrossRefGoogle Scholar
  80. 80.
    Bartolome J., Algra H.A., de Jongh L.J., and Carlin R.L., Physica B94, 60 (1978)Google Scholar
  81. 81.
    Algra H.A., de Jongh L.J., and Carlin R.L., Physica 93 B, 24 (1978)Google Scholar
  82. 82.
    Reinen D. and Krause S., Solid State Comm. 29, 691 (1979)CrossRefGoogle Scholar
  83. 83.
    Algra H.A., de Jongh L.J., and Carlin R.L., Physica 92 B, 258 (1977)Google Scholar
  84. 84.
    Bos W.G., Klaassen T.O., Poulis N.J., and Carlin R.L., J. Mag. Mag. Mat. 15, 464 (1980)CrossRefGoogle Scholar
  85. 85.
    Mennenga G., de Jongh L.J., Huiskamp W.J., Sinn E., L. Mbrecht A., Burriel R, and Carlin R.L., J. Mag. Mag. Mat. 44, 77 (1984)Google Scholar
  86. 86.
    Carlin R.L., Bhatia S.N, and O’Connor C.J, J. Am. Chem. Soc. 99, 7728 (1977)CrossRefGoogle Scholar
  87. 87.
    O’Connor C.J., Deaver, Jr. B.S, and Sinn E, J. Chem. Phys. 70, 5161 (1979)CrossRefGoogle Scholar
  88. 88.
    Greedan J.E, Hewitt D.C, Faggiani R, and Brown I.D., Acta Cryst. B36, 1927 (1980)Google Scholar
  89. 89.
    Hopkins T.E, Zalkin A, Templeton D.H., and Adamson M.G, Inorg. Chem. 5, 1431 (1966)CrossRefGoogle Scholar
  90. 90.
    Edwards A.J, J. Chem. Soc. Dalton 1972, 816Google Scholar
  91. 91.
    McElearney J.N. and Merchant S, Inorg. Chem. 17, 1207 (1978)CrossRefGoogle Scholar
  92. 92.
    Puertolas J.A, Navarro R, Palacio F, Bartolome J, Gonzalez D, and Carlin R.L, Phys. Rev. B26, 395 (1982)CrossRefGoogle Scholar
  93. 93.
    Puertolas J.A, Navarro R, Palacio F, Bartolome J, Gonzalez D, and Carlin R.L, Phys. Rev. B31, 516 (1985)CrossRefGoogle Scholar
  94. 94.
    Carlin R.L. and O’Connor C.J, Chem. Phys. Lett. 78, 528 (1981)CrossRefGoogle Scholar
  95. 95.
    Carlin R.L. and Burriel R, Phys. Rev. B27, 3012 (1983)CrossRefGoogle Scholar
  96. 96.
    Smith T. and Friedberg S.A., Phys. Rev. 177, 1012 (1969)CrossRefGoogle Scholar
  97. 97.
    Paduan-Filho A, Palacio F, and Carlin R.L, J. Phys. (Paris) 39, L-279 (1978)Google Scholar
  98. 98.
    Puertolas JA, Navarro R, Palacio F, Bartolome J, Gonzalez D, and Carlin R.L, J. Mag. Mag. Mat. 31-34, 1243 (1983)CrossRefGoogle Scholar
  99. 99.
    Palacio F, Paduan-Filho A, and Carlin R.L, Phys. Rev. B21, 296 (1980)CrossRefGoogle Scholar
  100. 100.
    Carlin R.L, Burriel R, Rojo J, and Palacio F, Inorg. Chem. 23, 2213 (1984), and to be publishedGoogle Scholar
  101. 101.
    Oguchi T, Phys. Rev. 133, A1098 (1964)CrossRefGoogle Scholar
  102. 102.
    Carlin R.L. and Palacio F, Coord. Chem. Revs. 65, 141 (1985)CrossRefGoogle Scholar
  103. 103.
    de Jongh LJ., Proceedings of the European Physical Society Summer School on “Magnetic Phase Transitions,” Ettore Majorana Centre, Erice, Italy, July, 1983. Elliott RJ. and Ausloos M, Springer-Verlag, N.Y, 1983Google Scholar
  104. 104.
    Breed DJ, Gilijamse K, Sterkenburg J.W.E, and Miedema A.R, Physica 68, 303 (1973)CrossRefGoogle Scholar
  105. 105.
    Algra H.A., de Jongh L.J, Huiskamp W.J, and Reedijk J, Physica B 86-88,737 (1977); Algra H.A., de Jongh LJ., and Reedijk J, Phys. Rev. Lett. 42, 606 (1979)Google Scholar
  106. 106.
    Mennenga G, Thesis (1983) Leiden; Mennenga G, de Jongh LJ., Huiskamp WJ, and Reedijk J, J. Mag. Mag. Mat, 43, 3, 13 (1981)Google Scholar
  107. 107.
    Carlin R.L, Lambrecht A, and Burriel R, unpublishedGoogle Scholar
  108. 108.
    Lagendijk E. and Huiskamp WJ., Physica 62, 444 (1972)CrossRefGoogle Scholar
  109. 109.
    Bartolome J, Algra H.A., de Jongh LJ., and Huiskamp WJ., Physica B86-88, 707 (1977)Google Scholar
  110. 110.
    Bevaart L, Frikkee E, Lebesque J.V, and de Jongh L.J, Phys. Rev. B18, 3376. (1978)CrossRefGoogle Scholar
  111. 111.
    DeFotis G.C, Pohl C, Pugh S.A., and Sinn E, J. Chem. Phys. 80, 2079 (1984)CrossRefGoogle Scholar
  112. 112.
    Westphal C.H. and Becerra C.C, J. Phys. C13, L 527 (1980)Google Scholar
  113. 113.
    Geoghegan K.F, Holmquist B, Spilburg C.A, and Vallee B.L, Biochemistry 22, 1847 (1983)CrossRefGoogle Scholar
  114. 114.
    Geoghegan K.F, Galdes A, Martineiii R.A, Holmquist B, Auld D.S., and Vallee B.L, Biochemistry 22, 2255 (1983)CrossRefGoogle Scholar
  115. 115.
    Dickinson L.C. and Chien J.C.W, J. Am. Chem. Soc. 105, 6481 (1983)CrossRefGoogle Scholar
  116. 116.
    Yachandra V, Powers L, and Spiro T.G, J. Am. Chem. Soc. 105, 6596 (1983)CrossRefGoogle Scholar
  117. 117.
    Hardman K.F. and Lipscomb W.N., J. Am. Chem. Soc. 106, 463 (1984)CrossRefGoogle Scholar
  118. 118.
    Bertini I. and Luchinat C., Acc. Chem. Res. 16, 272 (1983)CrossRefGoogle Scholar
  119. 119.
    Banci L., Bencini A., Benelli C., Gatteschi D., and Zanchini C., Struct. Bond. 52, 37 (1982). See also the related review: Bencini A. and Gatteschi D., Trans. Met. Chem. (N.Y.)8, 1 (1982)Google Scholar
  120. 120.
    Vallee B.L., Riordan J.F., Johansen J.T., and Livingston D.M., Cold Spring Harbor Symp. Quant. Biol. 36, 517 (1971)Google Scholar
  121. 121.
    Haffiier P.H. and Coleman J.E., J. Biol. Chem. 248, 6630 (1973)Google Scholar
  122. 122.
    Rosenberg R.C., Root C.A., and Gray H.B., J. Am. Chem. Soc. 97, 21 (1975)CrossRefGoogle Scholar
  123. 123.
    Solomon E.I., Wang R.-H., McMillin D.R., and Gray H.B., Biochem. Biophys. Res. Comm. 69, 1039 (1976)CrossRefGoogle Scholar
  124. 124.
    Bertini I., Canti G., Luchinat C., and Mani F., Inorg. Chem. 20, 1670 (1981)CrossRefGoogle Scholar
  125. 125.
    Brown R.S., Salmon D., Curtis NJ., and Kusuma S., J. Am. Chem. Soc. 104, 3188 (1982)CrossRefGoogle Scholar
  126. 126.
    Benelli C., Bertini I., DiVaira M., and Mani F., Inorg. Chem. 23, 1422 (1984)CrossRefGoogle Scholar
  127. 127.
    Yim M.B., Kuo L.C., and Makinen M.W., J. Magn. Res. 46, 247 (1982)CrossRefGoogle Scholar
  128. 128.
    Makinen M.W. and Yim M.B., Proc. Natl. Acad. Sci. USA 78, 6221 (1981)CrossRefGoogle Scholar
  129. 129.
    Kuo L.C. and Makinen M.W., J. Biol. Chem. 257, 24 (1982)Google Scholar
  130. 130.
    Makinen M.W., Kuo L.C., Yim M.P., Wells G.B., Fukuyama J.M., and Kim J.E., J. Am. Chem. Soc. 107, 5245 (1985)CrossRefGoogle Scholar
  131. 131.
    Horrocks, Jr. W. De W., Ishley J.N., Holmquist B., and Thompson J.S., J. Inorg. Biochem. 12, 131 (1980)CrossRefGoogle Scholar
  132. 132.
    Horrocks, Jr. W. De W, Ishley J.N., and Whittle R.R., Inorg. Chem. 21, 3265 (1982)CrossRefGoogle Scholar
  133. 133.
    Horrocks, Jr. W. De W., Ishley J.N., and Whittle R.R., Inorg. Chem. 21, 3270 (1982)CrossRefGoogle Scholar
  134. 134.
    Bencini A., Benelli C., Gatteschi D., and Zanchini C., Inorg. Chem. 19, 3839 (1980)CrossRefGoogle Scholar
  135. 135.
    Dori Z., Eisenberg R., and Gray H.B., Inorg. Chem. 6, 483 (1967)CrossRefGoogle Scholar
  136. 136.
    Cini R. and Orioli P., J. Inorg. Biochem. 14, 95 (1981); Orioli P., Cini R., Donati D., and Mangani S., J. Am. Chem. Soc. 103, 4446 (1981)CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 1986

Authors and Affiliations

  • Richard L. Carlin
    • 1
  1. 1.Department of ChemistryUniversity of Illinois at ChicagoChicagoUSA

Personalised recommendations