Rates of Reactions

  • Manfred T. Reetz
Part of the Reactivity and Structure: Concepts in Organic Chemistry book series (REACTIVITY, volume 24)


Inspite of the fact that many organotitanium compounds are well characterized, the number of kinetic studies is limited. This chapter deals primarily with such efforts directed toward elucidating the intricacies of carbonyl addition of CH3Ti(OCHMe2)3. Various other kinetic processes are also briefly discussed (Section 4.2).


Carbonyl Compound Solvent Ether Titanium Reagent Ligand Exchange Process Methyl Exchange 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


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  1. 1.a)
    Smith, S. G., Charbonneau, L. F., Novak, D. P., Brown, T. L.: J. Am. Chem. Soc. 94, 7059 (1972)CrossRefGoogle Scholar
  2. b).
    Al-Aseer, M. A., Smith, S. G.: J. Org. Chem. 49, 2608 (1984), and lit. cited therein.CrossRefGoogle Scholar
  3. 2.a)
    Ashby, E. C., Laemmle, S., Neumann, H. M.: Acc. Chem. Res. 7, 272 (1974)CrossRefGoogle Scholar
  4. b).
    Ashby, E. C.: Pure Appl. Chem. 52, 545 (1980)CrossRefGoogle Scholar
  5. 3.a)
    Holm, T.: Acta Chem. Scand. 23, 1829 (1969)CrossRefGoogle Scholar
  6. b).
    Holm, T.: Acta Chem. Scand. 25, 833 (1971)CrossRefGoogle Scholar
  7. c).
    Holm, T.: Acta Chem. Scand. B 37, 567 (1983)CrossRefGoogle Scholar
  8. 4.
    Kühlein, K., Clauss, K.: Makromol. Chem. 155, 145 (1972).CrossRefGoogle Scholar
  9. 5.a)
    Maus, S.: Diplomarbeit, Univ. Marburg 1983Google Scholar
  10. b).
    Maus, S.: projected Dissertation, Univ. Marburg 1986.Google Scholar
  11. 6.
    Reichardt, C.: “Solvent Effects in Organic Chemistry”, Verlag Chemie, Weinheim 1979.Google Scholar
  12. 7.
    Toullec, J., Mladenova, M., Gaudemar-Bardone, F., Blagoev, B.: Tetrahedron Lett. 24, 589 (1983).CrossRefGoogle Scholar
  13. 8.
    Reichardt, C.: Liebigs Ann. Chem. 752, 64 (1971).CrossRefGoogle Scholar
  14. 9.
    Reetz, M. T.: Top. Curr. Chem. 106, 1 (1982).Google Scholar
  15. 10.
    Lozach, D., Molle, H., Bauer, P., Dubois, J. E.: Tetrahedron Lett. 24, 4213 (1984).CrossRefGoogle Scholar
  16. 11.
    Westermann, J.: Dissertation, Univ. Marburg 1982.Google Scholar
  17. 12.
    Reetz, M. T., Westermann, J., Steinbach, R., Wenderoth, B., Peter, R., Ostarek, R., Maus, S.: Chem. Ber. 118, 1421 (1985).CrossRefGoogle Scholar
  18. 13.
    Reetz, M. T., Steinbach, R., Westermann, J., Urz, R., Wenderoth, B., Peter, R.: Angew. Chem. 94, 133 (1982)CrossRefGoogle Scholar
  19. Reetz, M. T., Angew. Chem., Int. Ed. Engl. 27, 135 (1982)CrossRefGoogle Scholar
  20. Reetz, M. T., Angew. Chem. Supplement 1982, 257.Google Scholar
  21. 14.
    Reetz, M. T., Kyung, S. H., Hüllmann, M.: Tetrahedron, in press.Google Scholar
  22. 15.
    Reetz, M. T., Kyung, S. H., Westermann, J.: Organometallics 3, 1716 (1984).CrossRefGoogle Scholar
  23. 16.
    Kükenhöhner, T.: Diplomarbeit, Univ. Marburg 1983.Google Scholar
  24. 17.
    Steinbach, R.: Dissertation, Univ. Marburg 1982Google Scholar
  25. Reetz, M. T., et al., unpublished.Google Scholar
  26. 19.
    Erskine, G. J., Hunter, B. K., McCowan, J. D.: Tetrahedron Lett. 26, 1371 (1985).CrossRefGoogle Scholar
  27. 20.
    For example, see the data assembled in: Gmelin Handbuch, “Titan-Organische Verbindungen”, Part 1 (1977); Part 2 (1980), Part 3 (1984), Part 4 (1984), Springer- Verlag, Berlin.Google Scholar
  28. 21.
    Weingarten, H., Van Wazer, J. R: J. Am. Chem. Soc. 88, 2700 (1966).CrossRefGoogle Scholar
  29. 22.
    Weingarten, H., Van Wazer, J. R.: J. Am. Chem. Soc. 87, 724 (1965).CrossRefGoogle Scholar
  30. 23.
    Moedritzer, K.: Adv. Organomet. Chem. 6, 171 (1968).CrossRefGoogle Scholar
  31. 24.
    Druce, P. M., Kingston, B. M., Läppert, M. F., Spalding, T. R., Srivastava, R. C.: J. Chem. Soc. A 1969, 2106.Google Scholar
  32. 25.
    Hanlan, J. F., McCowan, J. D.: Can. J. Chem. 50, 747 (1972).CrossRefGoogle Scholar
  33. 26.
    Yamamoto, T., Yamamoto, A.: J. Organomet. Chem. 57, 127 (1973).CrossRefGoogle Scholar
  34. 27.
    Thiele, K. H., Grahlert, W.: Wiss. Z. Techn. Hochschule Magdeburg 13, 177 (1969).Google Scholar
  35. 28.
    D’yachkovskii, F. S., Khrushch, N. E.: J. Gen. Chem. USSR 41, 1787 (1971).Google Scholar
  36. 29.
    Lee, J. B., Ott, K. C., Grubbs, R. H.: J. Am. Chem. Soc. 104, 7491 (1982).CrossRefGoogle Scholar
  37. 30.
    Calderon, J. L., Cotton, F. A., Takats, J.: J. Am. Chem. Soc. 93, 3587 (1971).CrossRefGoogle Scholar
  38. 31.a)
    Fay, R. C., Lindmark, A. F.: J. Am. Chem. Soc.105, 2118 (1983)CrossRefGoogle Scholar
  39. b).
    see also Chapter 2 (Section 2.5.2.).Google Scholar
  40. 32.
    Puddephatt, R. J., Stalteri, M. A.: Organometallics 2, 1400 (1983).CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 1986

Authors and Affiliations

  • Manfred T. Reetz
    • 1
  1. 1.Fachbereich Chemie der Universität MarburgMarburgGermany

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