Abstract
It is known that during elastic deformation of a solid the accumulated potential energy concentrates near the surfaces formed by a fracture of the solid [l]. This energy transformation is accompanied by considerable changes in the physical and chemical properties of a substance at the surface [2]. This facilitates chemical conversions in a solid at low temperatures when the molecular mobility is absent. These simple considerations were the starting point for the present investigation.
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References
V.R. Regel, A.J. Slutsker, E.E. Tomashevskii. Kinetic nature of strength of solids, Moscow, Nauka, 1974 (in Russian)
N.K. Baramboim. Mechanochemistry of high-molecular compounds. Moscow, Khimiya, 1978 (in Russian)
D.P. Kiryukhin, I.M. Barkalov, V.I. Goldanskii. Khim. Vys. Ener., 11, No 6, 438 (1977)
I.M. Barkalov. Uspekhi Khimii, 49, No 2, 364 (1980)
D.P. Kiryukhin, I.M. Barkalov, V.I. Goldanskii. Doklady Akad. Nauk SSSR, 238, 388 (1978)
D.P. Kiryukhin, I.M. Barkalov, V.I. Goldanskii. J. Ch. Phys., 76, 1013 (1979)
I.M. Barkalov, D.P. Kiryukhin, V.I. Goldanskii, A.M. Zanin. Chem. Phys. Lett., 73, No 2, 273 (1980)
I.M. Barkalov, D.P. Kiryukhin. Vysokom. Soedin., 22A, No 4, 723 (1980)
A.M. Zanin, D.P. Kiryukhin, I.M. Barkalov, V.I. Goldanskii, ZhETF Pis’ma, 33, No 6,. 320 (1981)
A.M.Zanin, D.P.Kiryukhin, V.V.Barelko, I.M.Barkalov, V.I.Goldanskii. Doklady Akad.Nauk SSSR, 260, No 6, 1397 (1981)
A.M. Zanin, D.P. Kiryukhin, I.M. Barkalov, V.I. Goldanskii. Doklady Akad. Nauk SSSR,. 260, No 5, 1171 (1981)
N.N. Semenov. On some problems of chemical kinetics and reactivity, Izd. AN SSSR, 1954
V.V. Barelko, Yu.E. Volodin. Kinetika i kataliz, 17, 683 (1976)
A.M. Zanin, D.P. Kiryukhin, V.V. Barelko, I.M. Barkalov, V.I. Goldanskii, Doklady Akad. Nauk SSSR, 261, No 6, 1367 (1981)
A.M. Zanin, D.P. Kiryukhin, V.V. Barelko, I.M. Barkalov, V.I. Goldanskii. Khimicheskaya fizika, 1, No 2, 265 (1982)
A.M. Zanin, D.P. Kiryukhin, I.M. Barkalov, V.I. Goldanskii. Vysokom. Soedin., 24B, No 4, 243 (1982)
V.V. Barelko, I.M. Barkalov, D.A. Vaganov, A.M. Zanin, D.P. Kiryukhin, Doklady Akad. Nauk SSSR, 264, No 1, 99 (1982)
A.M. Zanin, D.P. Kiryukhin, V.V. Barelko, I.M. Barkalov, V.I. Goldanskii. Doklady Akad. Nauk SSSR, 260, No 6 (1981).
N. Glansdorf, I. Prigogine. Thermodynamic theory of structure, stability and fluctuations, J. Wiley, London, (1971)
A.A. Griffith. Phil. Trans. Roy. Soc., 221, 163 (1921)
C. Lair, G.C. Smith. Philosoph. Mag., 7, No 77, 847 (1962)
W. Doll. Journ. Materials Sci., 10, 935 (1975)
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Barkalov, I.M. (1984). Threshold Effects and Autowave Processes in Low-Temperature Solid-State Chemical Reactions. In: Krinsky, V.I. (eds) Self-Organization Autowaves and Structures Far from Equilibrium. Springer Series in Synergetics, vol 28. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-70210-5_30
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DOI: https://doi.org/10.1007/978-3-642-70210-5_30
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