Abstract
During the oxygen or air oxidation of benzaldehyde catalyzed by cobalt and bromide several measureable parameters oscillate including: redox potential, absorbance at 620 nm, oxygen concentration, rate of benzaldehyde disappearance and free radical concentration. At 55–100°C in a 90/10 acetic acid/water mixture the oscillations will last for many hours[1]. A typical cycle is shown in Figure 1.
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References
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© 1984 Springer-Verlag Berlin Heidelberg
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Jensen, J.H., Roelofs, M.G., Wasserman, E. (1984). The Mechanism of the Oscillating Air Oxidation of Benzaldehyde. In: Vidal, C., Pacault, A. (eds) Non-Equilibrium Dynamics in Chemical Systems. Springer Series in Synergetics, vol 27. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-70196-2_4
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DOI: https://doi.org/10.1007/978-3-642-70196-2_4
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