Noise Induced Transitions

Abstract

In this paper I will deal with the effect of external random perturbations, “noise”, on chemical systems and other open nonlinear systems. As a concrete example let us consider a CSTR. This is an open system and as such subject to external constraints, namely the concentrations of the chemical species in the feed streams, the flow rate, the stirring rate, the temperature, and the incident light intensity in the case of a photochemical reaction. These external constraints characterize the state of the environment of the open system and will, in general, fluctuate more or less strongly. Such environmental fluctuations are particularly important for natural systems; here random fluctuations are always present and their amplitude is not necessarily small as in laboratory systems. In the latter systems the experimenter will of course try to minimize the effect of random perturbations, though it is impossible to eliminate noise completely. Clearly, random external noise is ubiquitous in open systems, but this fact by itself would hardly warrant a systematic study of the effects of external fluctuations. The question is whether noise is more than a mere nuisance we have to live with. Is there any hope of finding interesting physics? The intuitive, and wrong, answer would be negative: The system averages out rapid fluctuations and the only trace of external noise would be a certain fuzziness in the state of the system. Of course, if the state of the system becomes unstable, the fluctuations initiate the departure from the unstable state. Then the dynamics of the system take over and the system evolves to a new stable state.