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Photocontrol of Ion Extraction and Ion Transport by Photofunctional Crown Ethers

  • Seiji Shinkai
  • Osamu Manabe

Abstract

Photoresponsive systems are ubiquitously seen in nature: photosynthesis, vision, phototropism, and phototaxis are typical examples. In these systems, light is used as a trigger to cause subsequent life processes. We have been interested in the application of the phenomena to biomimetic systems. To imitate the fundamental functions of such photoresponsive systems, one has to combine within a molecule a photoantenna to capture a photon with a functional group to mediate a subsequent event. Host molecules have drawn attention as simplified enzyme model systems. We assumed that the photocontrol of host molecules, as well as that of enzymes 1–3) might provide a somewhat new field of chemistry.

Keywords

Crown Ether Alkali Metal Cation Alkaline Earth Metal Cation Thermal Isomerization Azobenzene Moiety 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer-Verlag, Berlin, Heidelberg 1985

Authors and Affiliations

  • Seiji Shinkai
    • 1
  • Osamu Manabe
    • 1
  1. 1.Department of Industrial Chemistry, Faculty of EngineeringNagasaki UniversityNagasaki 852Japan

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