Abstract
The direct carbonylation of organomercurials occurs only with great difficulty. However, a number of transition metal reagents promote carbonylation under mild conditions. These reactions can be used to prepare a host of carbonyl-containing products, including carboxylic acids and esters, carbonates, urethanes, ureas and ketones. These reactions are the subject of this chapter.
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Larock, R.C. (1985). Carbonylation. In: Organomercury Compounds in Organic Synthesis. Reactivity and Structure Concepts in Organic Chemistry, vol 22. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-70004-0_8
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DOI: https://doi.org/10.1007/978-3-642-70004-0_8
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