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Growth of Polytypic Crystals

  • Conference paper
Growth and Defect Structures

Part of the book series: Crystals ((CRYSTALS,volume 10))

Abstract

Polytypic crystals of semiconductors, dielectrics and magnetic materials attract an increasing attention in science and technology. On one hand, the phenomenon of polytypism is one of the fundamental problems of solid-state physics; its solution would make it possible to elucidate- the problem of the interconnection of different structures and intraatomic forces acting in crystals. On the other hand, the polytypic difference in crystals is most strongly expressed in electro-physical properties, which makes their application promising, mainly in semiconductor electronics. Thus, the difficulties of producing modulated structures in polytypic crystals can be overcome since these crystals form a class of one-dimensional natural superlattices.

The present state of the investigations of growth processes, structural and thermodynamic properties of polytypic crystals of different substances, the nature of polytypism and the physics of phase transitions between polytypic structures is considered in this review. The main thermodynamic and kinetic principles of polytype-crystal synthesis are discussed as well as the major problems in the field of their controlled growth

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  1. Electrical Engineering Institute, 5 Prof. Popor Street, 197022, Leningrad, USSR

    Yu. M. Tairov & V. F. Tsvetkov

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  1. Yu. M. Tairov
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  1. Kristall-Labor der Physikalischen Institute, Lotzestr. 16-18, D-3400, Göttingen, Germany

    H. C. Freyhardt

  2. Institut für Metallphysik der, Universität Göttingen, Hospitalstr. 12, D-3400, Göttingen, Germany

    H. C. Freyhardt

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Tairov, Y.M., Tsvetkov, V.F. (1984). Growth of Polytypic Crystals. In: Freyhardt, H.C., Müller, G. (eds) Growth and Defect Structures. Crystals, vol 10. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-69866-8_1

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