Zusammenfassung
Durch Kopplung des klassischen Anodic-Stripping-Verfahrens mit der Elektrokatalyse ergibt sich eine neue Möglichkeit zur Steigerung der Empfindlichkeit und Selektivität in der Elektroanalyse. Das unter solchen Bedingungen erhaltene Stripping-Voltammogramm von Kupfer zeigt einen sehr ungewöhnlichen kathodischen Peak, der die Identifizierung von Kupferspuren mit hoher Spezifltät gestattet.
Summary
A new way to enhance the sensitivity and the selectivity of electroanalysis is provided by coupling classical anodic stripping with electrocatalysis. The stripping voltammogram of copper obtained under such conditions presents a very unusual cathodic peak which confers a high specificity to the identification of copper traces.
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References
Birke RL, Marzluff WF (1969) J Am Chem Soc 91:3481
Brdicka R, Wiesner K (1947) Collect Czechoslov Chem Commun 12:138
Buess P, Gierst L, Garcia de Alvarez O (1980) J Electroanal Chem 108:317
Florence TM (1970) J Electroanal Chem 27:273
Frumkin AN (1933) Z Physik Chem 167A:121
Gierst L, Vandenberghen L, Nicolas E (1966) J Electroanal Chem 12:462
Koutecky J (1953) Collect Czechoslov Chem Commun 18:311
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Dedicated to Prof. Dr. W. Fresenius on the occasion of his 70th birthday
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© 1984 Springer-Verlag
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Reignier, M., Buess-Herman, C. (1984). On the Coupling of Anodic Stripping with Electrocatalysis: Application to the Determination of Copper Traces. In: Fresenius, W., Lüderwald, I. (eds) Environmental Research and Protection. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-69777-7_13
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DOI: https://doi.org/10.1007/978-3-642-69777-7_13
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