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Open-chained Equivalents of Crown Ethers

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Macrocyclic Polyether Syntheses

Part of the book series: Reactivity and Structure Concepts in Organic Chemistry ((REACTIVITY,volume 13))

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Abstract

With the discovery of the crowns45 and related species, it was inevitable that a search would begin for simpler and simpler relatives which might be useful in similar applications. Perhaps these compounds would be easier and more economical to prepare and ultimately, of course, better in one respect or another than the molecules which inspired the research. In particular, the collateral developments of crown ether chemistry and phase transfer catalysis65,76 fostered an interest in utilizing the readily available polyethylene glycol mono- or dimethyl ethers as catalysts for such reactions. Although there is considerable literature in this area, much of it relates to the use of simple polyethylene glycols in phase transfer processes. Since our main concern in this monograph is with novel structures, we will discuss these simple examples further only briefly, below.

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Authors and Affiliations

  1. Department of Chemistry, University of Maryland, 20742, College Park, MD, USA

    Professor George W. Gokel

  2. Chemicals and Pigments Department, Jacson Laboratory, E. I. Du Pont de Nemours Co., Inc., 08023, Deepwater, New Jersey, USA

    Dr. Stephen H. Korzeniowski

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  1. Professor George W. Gokel
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  2. Dr. Stephen H. Korzeniowski
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Gokel, G.W., Korzeniowski, S.H. (1982). Open-chained Equivalents of Crown Ethers. In: Macrocyclic Polyether Syntheses. Reactivity and Structure Concepts in Organic Chemistry, vol 13. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-68451-7_7

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  • DOI: https://doi.org/10.1007/978-3-642-68451-7_7

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