Abstract
The dynamic behaviour of polymerization reactors is very interesting and complex. The possibilities for reactor runaway, multiple steady states, and autonomous oscillations cause both reactor and control system design to be especially difficult. This paper provides a brief survey of the scope of the field and discusses the recent literature. Specific polymerization processes are used to illustrate the key issues.
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References
D.T. Ahlberg, I. Cheyne: Adaptive control of a polymerization reactor. AIChE Symp. Ser. 159, 221 (1976)
A. Ahmad, R.G. Anthony: Polymerization of isoprene in hexane with butyl 1ithium in a CSTR. AIChE Symp. Ser. 160, 61 (1976)
A. Ahmad, M.N. Treybig, R.G. Anthony: Multiple steady state solutions in an isothermal perfectly mixed flow reactor. J. Appl. Polym. Sei. 21, 2021 (1977)
J.A. Biesenberger: Thermal runaway in chain-addition polymerizations and copolymerizations. ACS Symp. Ser. 104, 15 (1979a)
J.A. Biesenberger, R. Capinpin, D.H. Sebastian, J.C. Yang: A study of chain addition polymerizations with temperature variations. Polym. Eng. Sei. 16, 101, 117 (1976)
L.L. Böhm: Reaction model for Ziegler-Natta polymerization processes. Polymer 19, 545 (1978)
J. Boor: Ziegler-Natta Catalysis and Polymeriaztion ( Academic, New York 1979 )
T.C. Bouton, D.C. Chappelear: Continuous polymerization reactions. AIChE Symp. Ser. 160 (1976)
N.F. Brockmeier, J.B. Rogan: Simulation of continuous propylene poly-merization in a backmix reactor using semibatch kinetic data. AIChE Symp. Ser. 160, 28 (1976)
E. Broyer, C.W. Macosko, F.E. Critchfield, L.F. Lawler: Curing and heat transfer in polyurethane reaction molding. Polym. Eng. Sei. 18, 382 (1978)
C. Cozewith, W.W. Graessley, G. Verstrate: Polymer crosslinking in CSTR’s. Chem. Eng. Sei. 34, 245 (1979)
G. Crone, A. Renken: Der Einfluß periodischer Prozeßführung auf radikalische Polymerisationsreaktionen. Chem. Ing. Tech. 51, 42 (1979)
W. Gebert, F. Bandermann: Optimierende Reaktionsführung lebender Polymerer. Angew. Makromol. Chem. 57, 153 (1977)
H. Gerrens: Multiple stationary states and oscillations in polymerization reactors. Proceedings 3rd IFAC PRP Conf. Brussels (1975)
H. Gerrens: Polymerization reactors and polyreactions, a review. Proceedings 4th Intern. Symp. on Chemical Reaction Engineering Heidelberg 1976, p. 585
J.W. Hamer, T. Akramov, W.H. Ray: The dynamic behaviour of bulk and solution polymerization in continuous stirred tank reactors. Chem. Eng. Sei. (submitted for publication 1980 )
J.N. Henderson, T.C. Bouton: Polymerization reactors and processes. ACS Symp. Ser. 104, 1979
A. Husain, A.E. Hamielec: Thermal polymerization of styrene. J. Appl. Polym. Sei. 1207 (1978)
R. Jaisinghani, W.H. Ray: On the dynamic behaviour of a class of homogeneous continuous stirred tank polymerization reactors. Chem. Eng. Sei. 32, 811 (1977)
C. Kiparissides, J.F. MacGregor, A.E. Hamielec: Continuous emulsion polymerization, modelling oscillations in vinyl acetate polymerization. J. Appl. Polym. Sei. 23, 401 (1979)
V.A. Kirillov, W.H. Ray: The mathematical modelling of continuous emulsion polymerization reactors. Chem. Eng. Sei. 33, 1499 (1978)
S. Middelman: Fundamentals of Polymer Processing ( McGraw-Hill, New York 1977 )
K.W. Min, H. I. Gostin: Simulation of semi-batch emulsion polymerization reactors for PVC. Polym. Preprints, April 1979
K.W. Min, W.H. Ray: On the mathematical modelling of emulsion poly-merization reactors. J. Macromol. Sei. Rev. Macromol. Chem. C11, 111 (1974)
K.W. Min, W.H. Ray: The computer simulation of batch emulsion poly-merization reactors through a detailed mathematical model. J. Appl. Polym. Sei. 22, 89 (1978)
J.G. Moore, M.R. West, J.R. Brooks: The anionic polution polymerization of butadiene in a CSTR. ACS Symp. Ser. 104, 281 (1979)
E.J. Nagel, V.A. Kirillov, W.H. Ray: The prediction of molecular weight distributions for high-density polyolefins. I(AMP)EC Product Dev. 19, 372 (1980)
M. Nomura, S. Sasaki, K. Fujita, M. Harada, W. Eguchi: Continuous emulsion polymerization of vinyl acetate. Proceedings San Francisco ACS meeting, 1980
J.A. Noronha, M.R. Juba, H.M. Low, E.J. Schiffhauer: High temperature free-radical polymerization in viscous systems. ACS Symp. Ser. 104, 339 (1979)
I. Piirma, J.L. Gardon: Emulsion polymerization. ACS Symp. Ser. 24 (1976)
G.W. Poehlein, D.J. Dougherty: Continuous emulsion polymerization. J. Rubber Chem. Tech. 50, 601 (1977)
W.H. Ray: On the mathematical modelling of polymerization reactors. J. Macromol. Sei. - Rev. Macromol. Chem. CS, 1 (1972)
W.H. Ray, S.K. Jain, R. Salovey: On the modelling of bulk PVC reactors. J. Appl. Polym. Sei. 19, 1297 (1975)
W.H. Ray, R.L. Laurence: “Polymerization reactor engineering”, in Chemical Reactor Theory, ed. by L. Lapidus, N.R. Amundson (1977)
E.G. Richter, C.W. Macosko: Kinetics of fast (RIM) urethane polymeriz-ation. Polymer. Eng. Sei. 18, 1012 (1978)
C.E. Schildknecht, I. Skeist: Polymerization Processes ( Wiley Inter-science, New York 1977 )
A.D. Schmidt, W.H. Ray: Isothermal multiplicities for solution poly-merization in a CSTR. Chem. Eng. Sei. (submitted for publication, 1980 )
F.J. Schork, G. Chu, W.H. Ray: Multiple steady states and dynamics of a CSTR for emulsion polymerization. Presented at 1980 Annual AIChE meeting, Chicago, 111. (1980)
H. Schuler: An observer for the chain length distribution in polymeriz-ation systems. Proceedings 1978 CHISA, Czechoslovakia 1978
D.H. Sebastian, J.A. Biesenberger: Thermal ignition phenomena in chain- addition copolymerizations. J, Appl. Polym. Sei. 23, 661 (1979b)
J.J. Spitz, R.L. Laurence, D.C. Chappelear: An experimental study of a polymerization reactor in periodic operation. AIChE Symp. Ser. 160, 86 (1976)
T. Tanlak, A. Ahmad, M.N. Treybig, R.G. Anthony: Polymerization of styrene with n-butyllithium in a batch reactor. J. Appl. Polym. Sei. 22, 315 (1978)
M. Tirrell, K. Gromley: Composition control of batch copolymerization reactors. Chem. Eng. Sei. (in press 1980)
M. Tirrell, J.J. Ly, C.W. Macosko: Conversion and composition profiles in polyurethane reaction molding ACS Symp. Ser. 104, 149 (1979)
T.N. Treybig, R.G. Anthony: Anionic styrene polymerization in a CSTR. ACS Symp. Ser. 104, 295 (1979)
K. Wisseroth: Die Gasphasen-polymerisation der Olefine — Rückblick auf eine Entwicklung. Chem. Z. 101, 271 (1977)
H. Yokoyama, T. Sano, T. Chijiiwa, R. Kajiya: A simulation method for ethylene glycol terephthalate polycondensation process. J. Jpn. Petrol. Inst. 21, 271 (1976)
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Ray, W.H. (1981). Dynamic Behaviour of Polymerization Reactors. In: Ebert, K.H., Deuflhard, P., Jäger, W. (eds) Modelling of Chemical Reaction Systems. Springer Series in Chemical Physics, vol 18. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-68220-9_25
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DOI: https://doi.org/10.1007/978-3-642-68220-9_25
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