Skip to main content

Part of the book series: Springer Series in Chemical Physics ((CHEMICAL,volume 10))

  • 120 Accesses

Abstract

Our concern in this volume is with molecular systems that have been displaced from thermal equilibrium, often to a considerable extent. Lasers and chemical lasers in particular operate because such displacements are feasible and are used, in turn, as means for driving other systems away from equilibrium. The first task is thus to examine those concepts and theoretical constructs of chemical physics that provide the framework for a discussion of disequilibrium on the molecular level. This chapter will center attention on the means for describing the system, means for the characterization of the phenomena in a compact fashion. The need for such a chapter stems from the traditional concern of physical chemistry with the simpler case of systems in thermal equilibrium. When disequilibrium was introduced it was often discussed as a macroscopic phenomenon. An extension of the traditional conceptual machinery is now required. In particular, the two mainstays of physical chemistry, chemical kinetics and chemical thermodynamics, need to be discussed from a molecular or state-to-state point of view.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 84.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. R.D. Levine, R.B. Bernstein: Molecular Reaction Dynamics (Clarendon, Oxford 1974)

    Google Scholar 

  2. A.M.G. Ding, L.J. Kirsch, D.S. Perry, J.C. Polanyi, J.L. Schreiber: Faraday Discuss. Chem. Soc. 55, 252 (1973)

    CAS  Google Scholar 

  3. J.G. Pruett, R.N. Zare: J. Chem. Phys. 64, 1774 (1976)

    CAS  Google Scholar 

  4. P.R. Brooks, E.F. Hayes (eds.): State-to-State Chemistry (ACS Symposium Series 56, Washington 1977)

    Google Scholar 

  5. S.H. Bauer: Chem. Rev. 78, 147 (1978)

    CAS  Google Scholar 

  6. C.B. Moore, P.F. Zittel: Science 182, 541 (1973)

    CAS  Google Scholar 

  7. R.N. Zare, P.J. Dagdigian: Science 185, 739 (1974)

    CAS  Google Scholar 

  8. B.F. Gordietz, A.I. Osipov, E.V. Stupechenko, L.A. Shelepin: Sov. Phys. Usp. 15, 759 (1973)

    Google Scholar 

  9. V.S. Letokhov, A.A. Makarov: J. Photochem. 3, 249 (1974)

    CAS  Google Scholar 

  10. M.J. Berry: Ann. Rev. Phys. Chem. 26, 259 (1975)

    CAS  Google Scholar 

  11. E. Pollak, R.D. Levine, Chem. Phys. Lett. 39, 199 (1976)

    CAS  Google Scholar 

  12. R.D. Levine, J. Manz: J. Chem. Phys. 63, 4280 (1975)

    CAS  Google Scholar 

  13. H. Kaplan, R.D. Levine, J. Manz: Chem. Phys. 12, 447 (1976)

    CAS  Google Scholar 

  14. R.D. Levine, R.B. Bernstein: Accts. Chem. Res. 7, 393 (1974)

    CAS  Google Scholar 

  15. L.J. Kirsch, J.C. Polanyi: J. Chem. Phys. 57, 4498 (1972)

    CAS  Google Scholar 

  16. K.L. Kompa, J. Wanner: Chem. Phys. Lett. 12, 560 (1972)

    CAS  Google Scholar 

  17. D.H. Maylotte, J.C. Polanyi, K.B. Woodall: J. Chem. Phys. 57, 1547 (1972)

    CAS  Google Scholar 

  18. D.J. Douglas, J.C. Polanyi, J.J. Sloan: Chem. Phys. 13, 15 (1976)

    CAS  Google Scholar 

  19. K. Bergmann, C.B. Moore: J. Chem. Phys. 63, 643 (1975)

    CAS  Google Scholar 

  20. D.S. Perry, J.C. Polanyi: Chem. Phys. 12, 419 (1976)

    CAS  Google Scholar 

  21. W.F. Calaway, G.E. Ewing: J. Chem. Phys. 63, 2892 (1975)

    Google Scholar 

  22. S.R.J. Brueck, T.F. Deutsch, R.M. Osgood: J. Chem. Phys. 68, 4941 (1978)

    CAS  Google Scholar 

  23. A. Laubereau, W. Kaiser: Ann. Rev. Phys. Chem. 26, 83 (1975)

    CAS  Google Scholar 

  24. Chap. 3 in Chemical and Biochemical Applications of Lasers, Vol. 2, ed. by C.B. Moore (Academic, New York 1977)

    Google Scholar 

  25. S.R.J. Brueck, T.F. Deutsch, R.M. Osgood: Chem. Phys. Lett. 51, 339 (1977);

    CAS  Google Scholar 

  26. S.R.J. Brueck, T.F. Deutsch, R.M. Osgood: Chem. Phys. Lett. 60, 242 (1979)

    CAS  Google Scholar 

  27. R.D. Levine: Chem. Phys. Lett. 39, 205 (1976)

    CAS  Google Scholar 

  28. R.D. Levine, W.C. Gardiner, Jr.: J. Chem. Phys. 68, 4524 (1978)

    Google Scholar 

  29. R.D. Levine: Quantum Mechanics of Molecular Rate Processes (Clarendon, Oxford 1969)

    Google Scholar 

  30. J.C. Light, J. Ross, K.E. Shuler: In Kinetic Processes in Gases and Plasmas, ed. by A.R. Hochstim (Academic, New York 1965)

    Google Scholar 

  31. K.J. Schmatjko, J. Wolfrumr: Ber. Bunsenges. Phys. Chem. 82, 419 (1978)

    CAS  Google Scholar 

  32. E.T. Jaynes: Phys. Rev. 106, 620 (1957)

    Google Scholar 

  33. R.D. Levine, M. Tribus (eds.): The Maximum Entropy Formalism (MIT Press, Cambridge, MA 1979)

    Google Scholar 

  34. R.D. Levine, A. Ben-Shaul: Chemical and. Biochemical Applications of Lasers, Vol. II, ed. by C.B. Moore (Academic, New York 1977) p. 145.

    Google Scholar 

  35. M. Tribus: Thermodynamics and Thermostatics (Van Nostrand, New York 1961)

    Google Scholar 

  36. A. Katz: Introduction to Statistical Mechanics (Freeman, San Francisco 1967)

    Google Scholar 

  37. R. Bairelein: Atoms and Information Theory (Freeman, San Francisco 1971)

    Google Scholar 

  38. R.D. Levine: Ann. Rev. Phys. Chem. 29, 59 (1978)

    CAS  Google Scholar 

  39. R.D. Levine, R.B. Bernstein: Dynamics of Molecular Collisions, ed. by W.H. Miller (Plenum, New York 1976) Part. B, p. 323

    Google Scholar 

  40. R.D. Levine, J.L. Kinsey: In Atom-Molecule Collision Theory, ed. by R.B. Bernstein (Plenum, New York 1979)

    Google Scholar 

  41. C.E. Shannon: Bell Syst. Tech. J. 27, 397 (1948)

    Google Scholar 

  42. N. Wienner: Cybernetics (MIT Press, Cambridge, MA 1948)

    Google Scholar 

  43. S. Goldman: Information Theory (Dover, New York 1953)

    Google Scholar 

  44. R. Ash: Information Theory (Interscience, New York 1965)

    Google Scholar 

  45. Y. Alhassid, N. Agmon, R.D. Levine: Chem. Phys. Lett. 53, 22 (1978);

    CAS  Google Scholar 

  46. Y. Alhassid, N. Agmon, R.D. Levine: J. Comput. Phys. 30, 250 (1979) and in Ref. 2.28

    Google Scholar 

  47. J.E. Mayer, M.G. Mayer: Statistical Mechanics (Wiley, New York 1940); see also J.C. Keck: In Ref. 2.28

    Google Scholar 

  48. Y. Alhassid, R.D. Levine: Phys. Rev. A18, 89 (1978); See also R.D. Levine: In Ref. 2.28

    Google Scholar 

  49. J.L. Kinsey, R.D. Levine: Chem. Phys. Lett. 65, 413 (1979)

    CAS  Google Scholar 

  50. A. Ben-Shaul, R.D. Levine, R.B. Bernstein: J. Chem. Phys. 57, 5427 (1972)

    CAS  Google Scholar 

  51. D.J. Bogan, D.W. Setser: J. Chem. Phys. 64, 586 (1976)

    CAS  Google Scholar 

  52. M.J. Berry: J. Chem. Phys. 59, 6229 (1973)

    CAS  Google Scholar 

  53. N. Jonathan, CM. Melliar-Smith, S. Okuda, D.H. Slater, D. Timlin: Mol. Phys. 22, 561 (1971)

    CAS  Google Scholar 

  54. G. Hancock, C. Morley, I.W.M. Smith: Chem. Phys. Lett. 12, 193 (1973)

    Google Scholar 

  55. A. Ben-Shaul: Chem. Phys. 1, 244 (1973)

    CAS  Google Scholar 

  56. D.M. Manos, J.M. Parson: J. Chem. Phys. 63, 3575 (1975)

    CAS  Google Scholar 

  57. U. Dinur, R. Kosloff, R.D. Levine, M.J. Berry: Chem. Phys. Lett. 34, 199 (1975)

    CAS  Google Scholar 

  58. R.G. Shortridge, M.C. Lin: J. Chem. Phys. 64, 4076 (1976)

    CAS  Google Scholar 

  59. C.L. Chalek, J.L. Gole: J. Chem. Phys. 65, 2845 (1976)

    CAS  Google Scholar 

  60. K. Liu, J.M. Parson: J. Chem. Phys. 68, 1794 (1978)

    CAS  Google Scholar 

  61. F. Reif: Statistical and Thermal Physics (McGraw-Hill, New York 1965)

    Google Scholar 

  62. M.E. Umstead, R.G. Shortridge, M.C. Lin: J. Phys. Chem. 82, 1455 (1978)

    CAS  Google Scholar 

  63. A. Ben-Shaul, K.L. Kompa, U. Schmailzl: J. Chem. Phys. 65, 1711 (1976)

    CAS  Google Scholar 

  64. J.C. Polanyi, K.B. Woodall: J. Chem. Phys. 57, 1547 (1972)

    Google Scholar 

  65. W.H. Chang, D.W. Setser: J. Chem. Phys. 55, 2298 (1973)

    Google Scholar 

  66. J.G. Moehlmann, R.G. McDonald: J. Chem. Phys. 62, 3061 (1975) See also 2.19

    CAS  Google Scholar 

  67. R.D. Levine, B.R. Johnson, R.B. Bernstein: Chem. Phys. Lett. 19, 1 (1973)

    CAS  Google Scholar 

  68. J.A. Silver, W.L. Dimpfl, J.H. Brophy, J.L. Kinsey: J. Chem. Phys. 65, 1811 (1976)

    CAS  Google Scholar 

  69. R.P. Mariella, B. Lantzsch, V.T. Maxson, A.C. Luntz: J. Chem. Phys. 69, 3436 (1978)

    Google Scholar 

  70. R.E. Wyatt: Chem. Phys. Lett. 34, 167 (1975)

    CAS  Google Scholar 

  71. D.C. Clary, R.K. Nesbet: Chem. Phys. Lett. 59, 437 (1978)

    CAS  Google Scholar 

  72. W.S. Struve, J.R. Krenos, D.L. McFadden, D.R. Herschbach: J. Chem. Phys. 62, 404 (1975)

    CAS  Google Scholar 

  73. J.R. Krenos, J.C. Tally: J. Chem. Phys. 62, 420 (1975)

    CAS  Google Scholar 

  74. R.D. Levine: In Electronic Transitions Lasers, ed. by J.I. Steinfeld (MIT Press, Cambridge, MA 1975)

    Google Scholar 

  75. M. Luria, D.J. Eckstrom, S.A. Edelstein, B.E. Perry, S.W. Benson: J. Chem. Phys. 64, 2247 (1976)

    CAS  Google Scholar 

  76. M.B. Faist, R.D. Levine: Chem. Phys. Lett. 47, 5 (1977)

    CAS  Google Scholar 

  77. C.L. Chalek, J.L. Gole: Chem. Phys. 19, 59 (1977)

    CAS  Google Scholar 

  78. M.J. Berry: In Ref. 2.68

    Google Scholar 

  79. R.D. Levine, J. Jortner (eds.): Molecular Energy Transfer (Wiley, New York 1976)

    Google Scholar 

  80. G.A. West, R.E. Weston, Jr., G.W. Flynn: Chem. Phys. 35, 275 (1978); see also

    CAS  Google Scholar 

  81. C.R. Quick, C. Wittig, Chem. Phys. 32, 75 (1978)

    CAS  Google Scholar 

  82. M.J. Berry: J. Chem. Phys. 61, 3114 (1974)

    CAS  Google Scholar 

  83. E. Zamir, R.D. Levine: Chem. Phys. Lett. 67, 237 (1979)

    CAS  Google Scholar 

  84. Aa.S. Sudbø, P.A. Schulz, Y.R. Chenand, Y.T. Lee: J. Chem. Phys. 69, 2312 (1978)

    Google Scholar 

  85. I. Kusunoki, Ch. Ottinger: J. Chem. Phys. 71, 4227 (1979)

    CAS  Google Scholar 

  86. R.D. Levine: In Ref. 2.75

    Google Scholar 

  87. J. Jortner, R.D. Levine, S.A. Rice (eds.): Photos elective Chemistry (Wiley, New York 1980)

    Google Scholar 

  88. C. Lifshitz: Adv. Mass Spectrom. 7A, 3 (1978)

    CAS  Google Scholar 

  89. W.H. Miller (ed.): Dynamics of Molecular Collisions (Plenum, New York 1976)

    Google Scholar 

  90. W. Jost: Kinetics of Gas Reactions, Vol. IV A in Physical Chemistry An Advanced Treatise, ed. by H. Eyring, D. Hendersen, W. Jost (Academic, New York 1974)

    Google Scholar 

  91. A.H. Zewail (ed.): Advances in Laser Chemistry, Springer Series in Chemical Physics, Vol. 3 (Springer, Berlin, Heidelberg, New York 1978)

    Google Scholar 

  92. R.B. Bernstein (ed.): Atom-Molecule Collision Theory (Plenum, New York 1979)

    Google Scholar 

  93. J.C. Polanyi, J.L. Schreiber: In Ref. 2.78

    Google Scholar 

  94. R.N. Porter, L.M. Raff: In Ref. 2.77

    Google Scholar 

  95. P.J. Kuntz: In Refs. 2.77 and 2.80

    Google Scholar 

  96. J.T. Muckerman, D.G. Truhlar: In Ref. 2.80

    Google Scholar 

  97. D.L. Thompson: Acc. Chem. Res. 9, 338 (1976)

    CAS  Google Scholar 

  98. I.W.M. Smith: In Ref. 2.68

    Google Scholar 

  99. J. Wolfrum: Ber. Bunsenges. Phys. Chem. 81, 114 (1977)

    CAS  Google Scholar 

  100. H.F. Schäfer, III: In Ref. 2.80

    Google Scholar 

  101. G.G. Balint-Kurti: Adv. Chem. Phys. 30, 137 (1975)

    CAS  Google Scholar 

  102. H.S. Johnston: Gas Phase Reaction Rate Theory (Ronald Press, New York 1966)

    Google Scholar 

  103. M.J. Berry, O. Kafri: Faraday Discuss. Chem. Soc. 62, 127 (1977)

    Google Scholar 

  104. R.A. Marcus: J. Phys. Chem. 72, 891 (1968)

    CAS  Google Scholar 

  105. G.S. Hammond: J. Am. Chem. Soc. 77, 334 (1955)

    CAS  Google Scholar 

  106. N. Agmon, R.D. Levine: J. Chem. Phys. 71, 3034 (1979)

    CAS  Google Scholar 

  107. M.J. Berry: Chem. Phys. Lett. 27, 73 (1974);

    CAS  Google Scholar 

  108. M.J. Berry: Chem. Phys. Lett. 29, 323 (1974)

    CAS  Google Scholar 

  109. A. Kafri, E. Pollak, R. Kosloff, R.D. Levine: Chem. Phys. Lett. 33, 202 (1975)

    Google Scholar 

  110. G.C. Schatz, J. Ross: J. Chem. Phys. 66, 1037 (1977)

    CAS  Google Scholar 

  111. P.J. Robinson, K.A. Hoibrook: Unimolecular Reactions (Wiley, New York 1972)

    Google Scholar 

  112. W.L. Hase: In Ref. 2.77

    Google Scholar 

  113. W. Forst: Theory of Unimoleoular Reactions (Academic, New York 1973)

    Google Scholar 

  114. C.C. Jensen, J.I. Steinfeld, R.D. Levine: J. Chem. Phys. 69, 1432 (1978)

    CAS  Google Scholar 

  115. J.D. Rynbrandt, B.S. Rabinovitch: J. Phys. Chem. 75, 2164 (1971)

    Google Scholar 

  116. I. Oref, B.S. Rabinovitch: Acc. Chem. Res. 12, 166 (1979)

    CAS  Google Scholar 

  117. I. Oref, N. Gordon: J. Phys. Chem. 82, 2035 (1978)

    CAS  Google Scholar 

  118. G.W. Flynn: In Chemical and Biochemical Applications of Lasers, Vol. 1, ed. by C.B. Moore (Academic, New York 1974) p. 163

    Google Scholar 

  119. J.I. Steinfeld, R.G. Gordon: In Ref. 2.68

    Google Scholar 

  120. M. Quack, J. Troe: In Gas Kinetics and Energy Transfer, Vol. II (Chemical Society, London 1977) p. 175

    Google Scholar 

  121. G.E. Ewing: J. Chem. Phys. 71, 3143 (1979);

    CAS  Google Scholar 

  122. see also J.A. Beswick, J. Jortner: In Ref. 2.75

    Google Scholar 

  123. J. Ford: Adv. Chem. Phys. 24, 155 (1973);

    CAS  Google Scholar 

  124. in Lectures in Statistical Physics, Lecture Notes in Physics, Vol. 28, ed. by W.C. Schieve, J.S. Turner (Springer, Berlin, Heidelberg, New York 1974)

    Google Scholar 

  125. S.A. Rice: In Ref. 2.79

    Google Scholar 

  126. J.D. McDonald, R.A. Marcus: J. Chem. Phys. 65, 2180 (1976)

    CAS  Google Scholar 

  127. P. Brumer: In Refs. 2.75 and 2.79

    Google Scholar 

  128. I.C. Percival: Adv. Chem. Phys. 36, 1 (1977)

    CAS  Google Scholar 

  129. B.R. Henry: Acc. Chem. Res. 10, 207 (1977)

    CAS  Google Scholar 

  130. M.L. Elert, P. Stannard, W.M. Gelbart: J. Chem. Phys. 67, 5395 (1977)

    CAS  Google Scholar 

  131. A. Albrect: In Ref. 2.79

    Google Scholar 

  132. K.V. Reddy, R.G. Bray, M.J. Berry: In Ref. 2.79

    Google Scholar 

  133. D.F. Heller, S. Mukamel: J. Chem. Phys. 70, 463 (1979)

    CAS  Google Scholar 

  134. D.D. Smith, A.H. Zewail: J. Chem. Phys. 71, 540 (1979)

    CAS  Google Scholar 

  135. M. Rubinson, J.I. Steinfeld: Chem. Phys. 4, 467 (1974)

    CAS  Google Scholar 

  136. I. Procaccia, R.D. Levine: J. Chem. Phys. 63, 4261 (1975)

    CAS  Google Scholar 

  137. C. Ennen, Ch. Ottinger: Chem. Phys. 3, 404 (1974)

    CAS  Google Scholar 

  138. J.F. Bott, N. Cohen: J. Chem. Phys. 58, 4539 (1973)

    CAS  Google Scholar 

  139. I. Procaccia, R.D. Levine: J. Chem. Phys. 65, 495 (1976);

    CAS  Google Scholar 

  140. I. Procaccia, R.D. Levine: Phys. Rev. 14A, 1569 (1976)

    Google Scholar 

  141. C.B. Moore: J. Chem. Phys. 43, 2979 (1965)

    CAS  Google Scholar 

  142. E. Sirkin, Ph.D. Thesis: University of California Berkeley (1980); see also

    Google Scholar 

  143. J.H. Smith, D.W. Robinson: J. Chem. Phys. 68, 5474 (1978);

    CAS  Google Scholar 

  144. J.H. Smith, D.W. Robinson: J. Chem. Phys. 71, 271 (1979)

    CAS  Google Scholar 

  145. E. Cuellar, G.C. Pimentel: J. Chem. Phys. 71, 1385 (1979)

    CAS  Google Scholar 

  146. D.C. Tardy, B.S. Rabinovitch: Chem. Rev. 77, 369 (1977)

    CAS  Google Scholar 

  147. K.F. Hertzfeld, T.A. Litovitz: Absorption and. dispersion of Ultrasonic Waves (Academic, New York 1959)

    Google Scholar 

  148. D. Rapp, T. Kassal: Chem. Rev. 61, 61 (1968)

    Google Scholar 

  149. R.D. Levine, R.B. Bernstein: J. Chem. Phys. 56, 228 (1972)

    Google Scholar 

  150. J.F. Bott: J. Chem. Phys. 63, 2253 (1975)

    CAS  Google Scholar 

  151. J.E. Dove, H. Teitelbaum: Chem. Phys. 6, 431 (1974)

    CAS  Google Scholar 

  152. R.V. Steele, C.B. Moore: J. Chem. Phys. 60, 2794 (1974)

    CAS  Google Scholar 

  153. D.J. Seery: J. Chem. Phys. 56, 1796 (1973)

    Google Scholar 

  154. P.F. Zittel, C.B. Moore: J. Chem. Phys. 59, 6636 (1973)

    CAS  Google Scholar 

  155. R.A. Lucht, T.A. Cool: J. Chem. Phys. 63, 3962 (1975)

    CAS  Google Scholar 

  156. J.F. Bott, N. Cohen: J. Chem. Phys. 58, 934 (1973)

    CAS  Google Scholar 

  157. R.D. Levine, B.R. Johnson: Chem. Phys. Lett. 14, 132 (1972)

    CAS  Google Scholar 

  158. R. Bersohn: In Ref. 2.68

    Google Scholar 

  159. A.P.M. Baede: Adv. Chem. Phys. 30, 463 (1975)

    CAS  Google Scholar 

  160. E. Bauer, E.R. Fisher, F.R. Gilmore: J. Chem. Phys. 51, 4173 (1969)

    CAS  Google Scholar 

  161. R. Olsen, F.T. Smith, E. Bauer: Appl. Opt. 10, 1848 (1971)

    Google Scholar 

  162. R. Grice, D.R. Hersehbach: Mol. Phys. 27, 159 (1974)

    CAS  Google Scholar 

  163. M.B. Faist, R.D. Levine: J. Chem. Phys. 64, 2953.(1976)

    CAS  Google Scholar 

  164. A.M.C. Moutinho, J.A. Aten, J. Los: Physica 53, 471 (1971)

    CAS  Google Scholar 

  165. J.C. Tully: In Ref. 2.77

    Google Scholar 

  166. A.B. Petersen, C. Wittig, S.R. Leone: Appl. Phys. Lett. 27, 305 (1975);

    CAS  Google Scholar 

  167. A.B. Petersen, C. Wittig, S.R. Leone: J. Appl. Phys. 47, 1051 (1976)

    CAS  Google Scholar 

  168. W.R. Green, J. Lukasik, J.R. Wilson, M.D. Wright, J.F. Young, S.E. Harris: Phys. Rev. Lett. 42, 970 (1979)

    CAS  Google Scholar 

  169. T.F. George, I.H. Zimmermann, J.M. Yuan, J.R. Laing, P.L. De Vries: Acc. Chem. Res. 10, 449 (1977)

    CAS  Google Scholar 

  170. J.M. Yuan, T.F. George: J. Chem. Phys. 70, 990 (1979)

    CAS  Google Scholar 

  171. A.M.F. Lau, CK. Rhodes: Phys. Rev. 15, 1570 (1977)

    CAS  Google Scholar 

  172. S. Mukamel, J. Jortner: In Ref. 2.68

    Google Scholar 

  173. K.F. Freed: Top. Appl. Phys. 15, 1 (1976)

    Google Scholar 

  174. W. Siebrand: In Ref. 2.77

    Google Scholar 

  175. P. Avouris, W.M. Gelbart, M.A. El-Sayed: Chem. Rev. 77, 793 (1977)

    CAS  Google Scholar 

  176. I. Oppenheim, K.E. Shuler, G.H. Weiss: Stochastic Processes in Chemical Physics: The Master Equation (MIT Press, Cambridge, MA 1977)

    Google Scholar 

  177. E.W. Montroll, K.E. Shuler: J. Chem. Phys. 26, 454 (1957)

    CAS  Google Scholar 

  178. J.C. Polanyi, K.B. Woodall: J. Chem. Phys. 56, 1563 (1972)

    CAS  Google Scholar 

  179. A.M.G. Ding, J.C. Polanyi: Chem. Phys. 10, 39 (1975)

    CAS  Google Scholar 

  180. I. Procaccia, Y. Shimoni, R.D. Levine: J. Chem. Phys. 63, 3181 (1975)

    CAS  Google Scholar 

  181. N.C. Lang, J.C. Polanyi, J. Wanner: Chem. Phys. 24, 219 (1977)

    CAS  Google Scholar 

  182. J.J. Hinchen, R.M. Hobbs: J. Chem. Phys. 65, 2732 (1975);

    Google Scholar 

  183. See also L.H. Sentman: J. Chem. Phys. 67, 966 (1977)

    CAS  Google Scholar 

  184. T. Feldmann, A. Ben-Shaul: Chem. Phys. Lett. 64, 286 (1979)

    CAS  Google Scholar 

  185. S.D. Rockwood, E.S. Brau, W.A. Proctor, G.H. Canavan: IEEE, J. QE-9, 120 (1973) and references cited therein; See also

    Google Scholar 

  186. W.Q. Jeffers, J.D. Kelley: Chem. Phys. 55, 4433 (1971)

    CAS  Google Scholar 

  187. H.T. Powell: J. Chem. Phys. 63, 2635 (1975)

    CAS  Google Scholar 

  188. M.R. Verter, H. Rabitz: J.Chem. Phys. 64, 2939 (1976)

    CAS  Google Scholar 

  189. M. Tabor, R.D. Levine, A. Ben-Shaul, J.I. Steinfeld: Mol. Phys. 37, 141 (1979)

    CAS  Google Scholar 

  190. For the use of (2.4.17); see also H. Pummer, D. Proch, U. Schmailzl, K.L. Kompa: Opt. Commun. 19, 273 (1976)

    CAS  Google Scholar 

  191. CE. Treanor, J.W. Rich, R.G. Rehm: J. Chem. Phys. 48, 1798 (1968)

    CAS  Google Scholar 

  192. S. Tsuchiya, N. Nielsen, S.H. Bauer: J. Phys. Chem. 77, 2455 (1973); see also

    CAS  Google Scholar 

  193. Y.S. Liu, R.A. McFarlane, G.J. Wolga: J. Chem. Phys. 63, 235 (1975)

    CAS  Google Scholar 

  194. K.E. Shuler: J. Chem. Phys. 32, 1692 (1960)

    CAS  Google Scholar 

  195. E. Weitz, G.W. Flynn: In Ref. 2.75

    Google Scholar 

  196. R.E. McNair, S.F. Fulghum, G.W. Flynn, M.S. Feld: Chem. Phys. Lett. 48, 24 (1977)

    Google Scholar 

  197. I. Shamah, G.W. Flynn: J. Am. Chem. Soc. 99, 319 (1977)

    Google Scholar 

  198. A. Ben-Shaul, K.L. Kompa: Chem. Phys. Lett. 55, 560 (1978);

    CAS  Google Scholar 

  199. see also R.K. Huddleston, E. Weitz: J. Chem. Phys. 66, 1740 (1977)

    CAS  Google Scholar 

  200. R.M. Osgood, P.B. Sacket, Jr., A. Javan: J. Chem. Phys. 60, 1464 (1974)

    CAS  Google Scholar 

  201. I. Procaccia, Y. Shimoni, R.D. Levine: J. Chem. Phys. 65, 3284 (1976)

    Google Scholar 

  202. R.D. Levine, M. Berrondo: Chem. Phys. Lett. 47, 399 (1977)

    CAS  Google Scholar 

  203. I. Procaccia, R.D. Levine: J. Chem. Phys. 65, 3357 (1976)

    CAS  Google Scholar 

  204. R.D. Levine: J. Chem. Phys. 65, 3302 (1976)

    CAS  Google Scholar 

  205. R.D. Levine, O. Kafri: Chem. Phys. Lett. 27, 175 (1974);

    CAS  Google Scholar 

  206. R.D. Levine, O. Kafri: Chem. Phys. 8, 426 (1975)

    Google Scholar 

  207. O. Kafri, R.D. Levine: Isr. J. Chem. 16, 342 (1977)

    CAS  Google Scholar 

  208. A. Ben-Shaul, O. Kafri, R.D. Levine: Chem. Phys. 16, 342 (1977);

    Google Scholar 

  209. A. Ben-Shaul, O. Kafri, R.D. Levine: Chem. Phys. 36, 307 (1979)

    CAS  Google Scholar 

  210. For reviews see A. Ben-Shaul: In Ref. 2.75;

    Google Scholar 

  211. R.D. Levine: In Proceedings of the 12th Symposium on Shock Tubes and Waves, Jerusalem, 1979, ed. by A. Lifshitz (Magnes Press, Jerusalem 1979)

    Google Scholar 

  212. R.A. Marcus, O.K. Rice: J. Phys. Colloid Chem. 55, 894 (1951)

    CAS  Google Scholar 

  213. G.Z. Whitten, B.S. Rabinovitch: J. Chem. Phys. 38, 2466 (1963)

    CAS  Google Scholar 

  214. R.D. Levine: J. Phys. Chem. 83, 159 (1979)

    CAS  Google Scholar 

  215. P. Pechukas: In Ref. 2.77

    Google Scholar 

  216. R.B. Bernstein, A. Dalgarno, H.S.W. Massey, I.C. Percival: Proc. R. Soc. London A 274, 427 (1963)

    Google Scholar 

  217. P. Pechukas, J.C. Light: J. Chem. Phys. 42, 328 (1965)

    Google Scholar 

  218. A. Ben-Shaul: Chem. Phys. 22, 341 (1977)

    CAS  Google Scholar 

  219. M. Quack, J. Troe: Ber. Bunsenges. Phys. Chem. 80, 1140 (1976)

    CAS  Google Scholar 

  220. R.A. Marcus: J. Chem. Phys. 62, 1372 (1975)

    CAS  Google Scholar 

  221. J.C. Keck: Adv. Chem. Phys. 13, 85 (1967)

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

Copyright information

© 1981 Springer-Verlag Berlin Heidelberg

About this chapter

Cite this chapter

Ben-Shaul, A., Haas, Y., Levine, R.D., Kompa, K.L. (1981). Disequilibrium. In: Lasers and Chemical Change. Springer Series in Chemical Physics, vol 10. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-67826-4_2

Download citation

  • DOI: https://doi.org/10.1007/978-3-642-67826-4_2

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-67828-8

  • Online ISBN: 978-3-642-67826-4

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics