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Synergetics pp 152–155Cite as

Thermal Properties of Oscillating Reactions: Two Examples

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Part of the book series: Springer Series in Synergetics ((SSSYN,volume 3))

Abstract

Chemical engineering provides several examples of thermokinetic oscillations which are accounted for by the thermal properties of both the reaction steps and the vessel [1]. On the other hand, non-equilibrium thermodynamics predicts unusual patterns in isothermal chemical systems far from equilibrium [2], and kinetic analysis of reaction schemes shows that periodicity may appear, provided some kind of feedback is involved [3]. Two questions then arise: (i) are such chemical oscillations truly encountered, and (ii) how do these oscillations differ from thermokinetic ones.

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References

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Authors
  1. C. Vidal
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  2. A. Noyau
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Editor information

Editors and Affiliations

  1. Centre de Recherches Paul Pascal, Domaine Universitaire, F-33405, Talence Cédex, France

    Adolphe Pacault  & Christian Vidal  & 

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© 1979 Springer-Verlag Berlin Heidelberg

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Vidal, C., Noyau, A. (1979). Thermal Properties of Oscillating Reactions: Two Examples. In: Pacault, A., Vidal, C. (eds) Synergetics. Springer Series in Synergetics, vol 3. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-67262-0_23

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  • DOI: https://doi.org/10.1007/978-3-642-67262-0_23

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-67264-4

  • Online ISBN: 978-3-642-67262-0

  • eBook Packages: Springer Book Archive

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