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Organometallic Compounds

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Free Radicals in Organic Synthesis

Part of the book series: Reactivity and Structure: Concepts in Organic Chemistry ((REACTIVITY,volume 7))

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Abstract

Free radical addition and substitution reactions which have proved so useful in organic synthesis have received less attention in the synthesis of organometallic compounds. The majority of these studies have involved the main group elements and have concentrated on addition reactions. Initially particular reference was made to the addition of silanes, germanes, and various phosphorus compounds to carbon-carbon double and triple bonds [1]. More recently, reactions with more varied substrates have been studied. These include the addition of silanes to halogenated alkenes and alkynes [2, 3], e.g.

the substitution of unsaturater amines by susequent addition, elimination, e.g. [4]

addition to diphyenyldiazomethane [5] with loss of nitrogen,

and the reaction of silanes with nitroarenes to afford nitroxides, e.g. [6],

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Authors and Affiliations

  1. Department of Chemistry, University of London King’s College, Strand London, WC2R 2LS, England

    David Ian Davies

  2. Department of Chemistry, Institute of Science and Technology, University of Manchester, P.O. Box 88, Manchester, M60 1QD, England

    Maxwell James Parrott

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  1. David Ian Davies
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Davies, D.I., Parrott, M.J. (1978). Organometallic Compounds. In: Free Radicals in Organic Synthesis. Reactivity and Structure: Concepts in Organic Chemistry, vol 7. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-66922-4_11

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  • DOI: https://doi.org/10.1007/978-3-642-66922-4_11

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