Abstract
The current state of knowledge of the electronic structures of the binary di- and hexaborides is reviewed. New work is presented which allows rationalization of the stability of these materials as well as the metal-deficient and mixed-metal phases. Band structure and density-of-states calculations lead to values of electrical conductivities and Hall coefficients for these materials which agree well with experimental data.
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ARMSTRONG, D.R., BREEZE, A., PERKINS, P.G.: On the electronic structure of some metal hexaborides. J. Phys. (C) 8, 3558–3570 (1975)
ARMSTRONG, D.R., PERKINS, P.G., STEWART, J.J.P.: Calculation of the electronic structure of boranes by the self-consistent molecular orbital method. Parti: B10H14 and some neutral chloroboranes. J. Chem. Soc. Dalton Trans., 3674–3679 (1971)
ARMSTRONG, D.R., PERKINS, P.G., STEWART, J.J.P.: Calculation of the electronic structure of boranes by the self-consistent molecular orbital method. Part II: Highly symmetrical cage anions. J. Chem. Soc., Dalton Trans., 627–632 (1973)
ARONSSON, B.: In: Borides, Silicides and Phosphides. B. Aronsson, R. Lundström and S. Lundquist (eds.). New York: Wiley and Sons, 1965, p. 32
BALLHAUSEN, C.J., GRAY, H.B.: The electronic structure of the vanadyl ion. Inorg. Chem. 1, 111–122 (1962)
BLUM, P., BERTAUT, F.: Contribution à l’étude des borures à teneur élevée en bore. Acta Cryst. 7, 81–86 (1954)
DECKER, R.W., STEBBINS, D.W.: Photoelectric work functions of borides of La, Pr and Nd. J. Appl. Phys. 26, 1004–1006 (1955)
FLEMING, G.S., LIU, S.H., LOUCKS, T.L.: Fermi surfaces for DHCP La, Nd and Pr. Relation to magnetic ordering and crystal structure. Phys. Rev. Lett. 21, 1524–1526 (1968)
HAGENMULLER, P., NASLAIN, R.: An alkali boride: the hexaboride, NaB6. C. R. Acad. Sci. (Paris) 257, 1294–1296 (1963).
HERMAN, F.: Theoretical investigation of the electronic energy band structure of solids. Rev. Mod. Phys. 30, 102–121 (1958)
JOHNSON, R.W., DAANE, A.H.: The lanthanum-boron system. J. Phys. Chem. 65, 909–915 (1961)
JOHNSON, R.W., DAANE, A.H.: Electron requirements of bonds in metal borides. J. Chem. Phys. 38, 425–432 (1963)
JURETSCHKE, H.J., STEINITZ, R.: Hall effect and electrical conductivity of transition metal diborides. J. Phys. Chem. Solids. 4, 118–127 (1958)
KUDINT’SEVA, G.A., TSAREV, B.M.: Radistkh. Elektron 3, 428 (1958)
LAPLACA, S.: Meet. Amer. Cryst. Assoc. Suffern (N.Y.) Feb. 1965
LENK, R.: Czech. J. Phys. 6, 625 (1956)
LEVISON, K.A., PERKINS, P.G.: unpublished
LIPSCOMB, W.N., BRITTON, D.: Valence structure of the higher borides. J. Chem. Phys. 33, 275–280 (1960)
LONGUET-HIGGINS, H.C., ROBERTS, M.D.: The electronic structure of the borides MB6. Proc. Roy. Soc. 224, 336–347 (1954)
LYAKOVSKAYA, I.I., ZIMKINA, T.M., FOMICHEV, V.A.: Boron K spectra from transition metal diborides and LaB6, BaB6 and AsB compounds. Sov. Phys. Solid State 12, 138–143 (1970)
McALOON, B.J., PERKINS, P.G.: Semiempirical LCAOMO theory for infinite systems. J. Chem. Soc. Faraday Trans. II 68, 1121–1126 (1972)
MERCURIO, J.P., ETOURNEAU, J., NASLAIN, R., HAGENMULLER, P., GOODENOUGH, J.B.: J. Solid State Chem. 9, 37 (1974)
MIKHAILOVS’KII, B.I.: Ukr. Fiz. Zhur. 7, 75 (1962)
MUETTERTIES, E.L.: The chemistry of boron and its compounds. New York: Wiley and Sons, 1967
MYRON, H.W., LIU, S.H.: Energy bands for FCC La and Pr. Phys. Rev. B1, 2414–2417 (1970)
PADERNO, Y.B., SAMSONOV, G.V.: Dokl. Akad. Nauk. SSSR 137, 646 (1960)
PEARSON, W.B.: Handbook of lattice spacings and structures for metals and alloys. New York: Pergamon Press, 1958
PERKINS, P.G., WALL, D.H.: Self-consistent molecular orbital calculations on aminoboranes. J. Chem. Soc., 1207–1211 (1966)
SAMSONOV, G.V., GRODSTEIN, A.E.: Zhur. Fiz. Khim. 30, 379 (1956)
STEWART, J.J.P.: personal communication
THOMPSON, R.: The chemistry of metal borides and related compounds. In: Progress in Boron Chemistry. New York: Pergamon Press 2, 173–230 (1970)
WESTBROOK, J.H.: Proc. Int. Symp. High Temp. Technol. New York: McGraw Hill, 1960
YAMAZAKI, M.: Group theoretical treatment of the energy bands in metal borides. J. Phys. Soc. Japan 12, 1–6 (1957)
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Perkins, P.G. (1977). The Electronic Structures of the Hexaborides and the Diborides. In: Matkovich, V.I. (eds) Boron and Refractory Borides. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-66620-9_4
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DOI: https://doi.org/10.1007/978-3-642-66620-9_4
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