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The Group of Permutations and the Exclusion Principle

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Group Theory and Quantum Mechanics

Part of the book series: Grundlehren der mathematischen Wissenschaften ((GL,volume 214))

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Abstract

A stationary state of a pair of electrons, without spin and without interaction, is determined by an eigenfunction of the form

$$ \Psi \left( {{q_1},{q_2}} \right) = {\psi _1}\left( {{q_1}} \right){\psi _2}\left( {{q_2}} \right) $$
(29.1)

in which ψ l and ψ 2 are the normed eigenfunctions of the single electrons. If E 1 and E 2 are their energy values, the energy of the whole system is

$$ E = {E_1} + {E_2} $$

.

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Reference

  1. See W. Heisenberg: Mehrkörperproblem und Resonanz in der Quantenmechanik. Zeitschr. f. Phys. 38, p. 411 (1926).

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  2. W. Heisenberg: Über die Spektra von Atomsystemen mit zwei Elektronen. Zeitschr. f. Physik 39, p. 499 (1926).

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  4. N. W. Bazley: Lower bounds for eigenvalues with application to the Helium atom. Proceedings Nat. Acad. of Sciences 45, p. 850 (1959).

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  5. For the history of the Exclusion Principle see my contribution: Exclusion Principle and Spin in the Pauli Memorial Volume (edited by Fierz and Weisskopf), p. 199. New York: Interscience Publ. 1960.

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  6. E. C. Stoner: The Distribution of Electrons among Atomic Levels. Phil. Mag. 48, p. 719 (1925).

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  7. J. von Neumann and E. Wigner: Zur Erklärung einiger Eigenschaften der Spektren aus der Quantenmechanik des Drehelektrons II and III. Zeitschr. f. Phys. 49, p. 73 and 51, p. 844 (1928).

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© 1974 Springer-Verlag Berlin · Heidelberg

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van der Waerden, B.L. (1974). The Group of Permutations and the Exclusion Principle. In: Group Theory and Quantum Mechanics. Grundlehren der mathematischen Wissenschaften, vol 214. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-65860-0_5

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  • DOI: https://doi.org/10.1007/978-3-642-65860-0_5

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-65862-4

  • Online ISBN: 978-3-642-65860-0

  • eBook Packages: Springer Book Archive

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