Penultimate Effects in Radical Copolymerization I-Kinetical Study

  • J. Guillot
Conference paper
Part of the NMR Basic Principles and Progress / NMR Grundlagen und Fortschritte book series (NMR, volume 4)

Abstract

From kinetical statement, penultimate effects correspond to the influence of units preceding the radical unit on the reactivity of the growing radical. In a more precise way, one speaks about penultimate effect if there is an influence of the unit immediately before the radical unit, and pen-penultimate effect if there is an influence of the unit preceding this last one…

Keywords

Pyrolysis Vinyl Styrene Methacrylate Triad 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Arlam, E. J.: J. Polymer Sci. 17, 375 (1955).CrossRefGoogle Scholar
  2. 2.
    Atherton, J. N., North, A. M.: Trans. Faraday Soc. 58, 2049 (1962).CrossRefGoogle Scholar
  3. 3.
    Ham, G. E., Fordyge, R. G.: J. Am. Chem. Soc. 73, 1186 (1951).CrossRefGoogle Scholar
  4. 4.
    — J. Polymer Sci. 15, 87 (1954).Google Scholar
  5. 5.
    — J. Polymer Sci. 24, 349 (1957).CrossRefGoogle Scholar
  6. 6.
    Merz, E., Alfrey, T., Goldfinger, G.: J. Polymer Sci. 1, 75 (1946).CrossRefGoogle Scholar
  7. 7.
    Ham, G. E., in: Copolymerization, Chap. 1. New York: Interscienee Publishers 1964.Google Scholar
  8. 8.
    Price, F. P.: J. Chem. Phys. 36 (1), 209 (1962).CrossRefGoogle Scholar
  9. 9.
    Guyot, A., Blanc, C., Daniel, J. C, Trambouze, Y.: Compt. Rend. 253, 1795 (1961).Google Scholar
  10. 10.
    Guillot, J.: Ann. Chim. 3 (5), 441 (1968).Google Scholar
  11. 11.
    Barb, W. G.: J. Polymer Sci. 11, 117 (1953).CrossRefGoogle Scholar
  12. 12.
    Mayo, F. R., Lewis, F. M.: J. Am. Chem. Soc. 66, 1594 (1944).CrossRefGoogle Scholar
  13. 13.
    Fineman, M., Ross, S. D.: J. Polymer Sci. 5, 259 (1950).CrossRefGoogle Scholar
  14. 14.
    Guyot, A., Guillot, J.: J. Macromol. Sci., Part A, 2 (5), 889 (1968).CrossRefGoogle Scholar
  15. 15.
    — — J. Macromol. Sci., Part A, 1 (5), 793 (1967).Google Scholar
  16. 16.
    Miller, R. L., Nielsen, L. E.: J. Polymer Sci. 44, 303 (1960).CrossRefGoogle Scholar
  17. 17.
    Berger, M., Kuntz, I.: J. Polymer Sci., Part A, 2, 1687 (1964).Google Scholar
  18. 18.
    Harwood, H. J.: Am. Chem. Soc. Div. Polymer Chem. Preprints 8 (1), 199 (1967).Google Scholar
  19. 19.
    Guillot, J., Guyot, A., Pham Quang Tho: J. Macromol. Sci., Part A, 2, 1303 (1968).CrossRefGoogle Scholar
  20. 20.
    Galin, M., Guillot, J., Guyot, A.: J. Macromol. Sci., Part A, 4, 19 (1970).CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 1971

Authors and Affiliations

  • J. Guillot
    • 1
  1. 1.Chargé de Recherches au Centre National de la Recherche ScientifiqueInstitut de Recherches sur la CatalyseVilleurbanneFrance

Personalised recommendations