Abstract
When copolymerizing vinyl type monomers, the number of possible diads, triads and higher sequences, which are distinguishable by NMR, depends on how many comonomers form asymmetric or pseudoasymmetric α-C-atoms during enchainment. For simplicity, in the following the term asymmetric α-C-atom is to include pseudoasymmetric α-C-atoms. Considering only the number of triads in the case of binary copolymers, there are 6 triads possible if none of the two comonomers forms an asymmetric α-C-atom, 10 triads if one of the monomers forms an asymmetric center, and 20 triads if both form an asymmetric α-C-atom.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Jabben, M., Chafik, A., Saupe, A., Klesper, E., Cantow, H. J.: Z. Anal. Chem. 249, 1 (1970).
Schäfer, J.: J. Phys. Chem. 70, 1975 (1966).
Bovey, F. A.: J. Polymer Sci. 62, 197 (1962).
Harwood, H. J., Ritchey, W. M.: J. Polymer Sci., Part B, 3, 419 (1965).
Ito, K., Yamashita, Y.: J. Polymer Sci., Part B, 3, 625 (1965).
—, — J. Polymer Sci., Part B, 3, 631 (1965).
— Iwase, S., Umehara, K., Yamashita, Y.: J. Macromol. Sci., Part A, 1, 891 (1967).
Harwood, H. J., Shah, A. K., Bockrath, R. E., Ritchey, W. M.: Appl. Polym. Symp. 8, 227 (1969).
Klesper, E.: J. Polymer Sci., Part B, 6, 313 (1968).
— J. Polymer Sci., Part B, 6, 663 (1968).
—, Gronski, W.: J. Polymer Sci., Part B, 7, 661 (1969).
—, —, J. Polymer Sci., Part B, 7, 727 (1969).
—, J. Polymer Sci., Part A-1, 8, 1191 (1970).
—, Johnsen, A., Gronski, W.: J. Polymer Sci., Part B, 8, 369 (1970).
— Gronski, W., Barth, V.: in preparation.
Küchler, L.: Polymerisationskinetik, p. 203. Berlin-Göttingen-Heidelberg: Springer 1951.
Ito, K., Yamashita, Y.: J. Polymer Sci., Part A-1, 3, 2165 (1965).
Bovey, F. A., Tiers, G. V. D.: Advan. Polymer Sci. 3, 139 (1963).
De Löcker, W., Smets, G.: J. Polymer Sci. 40, 203 (1959).
Smets, G., De Löcker, W.: J. Polymer Sci. 41, 375 (1959).
—, — Polymer Sci. 45, 461 (1960).
Semen, J., Lando, J. B.: Macromolecules 2, 570 (1969).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1971 Springer-Verlag Berlin Heidelberg
About this paper
Cite this paper
Klesper, E., Gronski, W., Johnsen, A. (1971). Complete Triad Assignment of Methylmethacrylate-Methacrylic Acid Copolymers. In: Diehl, P., Fluck, E., Kosfeld, R. (eds) Natural and Synthetic High Polymers. NMR Basic Principles and Progress / NMR Grundlagen und Fortschritte, vol 4. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-65089-5_3
Download citation
DOI: https://doi.org/10.1007/978-3-642-65089-5_3
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-65091-8
Online ISBN: 978-3-642-65089-5
eBook Packages: Springer Book Archive