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Adsorbed PF3 on Ru(001) — Quantum Gear Problem?

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Elementary Processes in Excitations and Reactions on Solid Surfaces

Part of the book series: Springer Series in Solid-State Sciences ((SSSOL,volume 121))

Abstract

According to the recent ESDIAD experiment PF3 molecules adsorbed on Ru(001) show interesting coverage- and temperature-dependent rotational hindrance. A model is constructed that the molecules sit on the atop site, having short ranged interactions. The analysis is made by using Monte Carlo simulation. On the obtained distributions, rotational motions of isolated adsorbates and adsorbate clusters are discussed quantum-mechanically. A possible quantum gear like situation is found for the adsorbate clusters.

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Author information

Authors and Affiliations

  1. Department of Electronic Engineering, Okayama University of Science, 1-1 Ridaicho, Okayama, 700, Japan

    K. Kakitani, H. Kaji & A. Yoshimori

Authors
  1. K. Kakitani
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  2. H. Kaji
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  3. A. Yoshimori
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Editor information

Editors and Affiliations

  1. Department of Applied Physics, Osaka University, 2-1 Yamadaoka, Suita, Osaka, 565, Japan

    Ayao Okiji  & Hideaki Kasai  & 

  2. Faculty of Science, Himeji Institute of Technology, Kamigori-cho, Ako-gun, Hyogo, 678-12, Japan

    Kenji Makoshi

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© 1996 Springer-Verlag Berlin Heidelberg

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Kakitani, K., Kaji, H., Yoshimori, A. (1996). Adsorbed PF3 on Ru(001) — Quantum Gear Problem?. In: Okiji, A., Kasai, H., Makoshi, K. (eds) Elementary Processes in Excitations and Reactions on Solid Surfaces. Springer Series in Solid-State Sciences, vol 121. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-61185-8_25

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  • DOI: https://doi.org/10.1007/978-3-642-61185-8_25

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-64738-3

  • Online ISBN: 978-3-642-61185-8

  • eBook Packages: Springer Book Archive

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