Abstract
Nickel belongs to the transition metal family and shows close chemical similarities with Fe and Co. Even more than these elements, it is concentrated in silicated Fe-Mg minerals by octahedral substitution with Fe2+ ions. Thus, the mean mineral/ matrix partition coefficient of Ni is 14.0,5.0 and 2.6 for basaltic whole rocks, for olivine, and orthopyroxene and clinopyroxene, respectively. The high Ni contents in olivine (3000–4500 ppm), spinel (3000–3500 ppm) and orthopyroxene minerals (650–1000 ppm) emphasize its high affinity for the first formed minerals during fractional crystallization of magmas. This is due to the electronic configuration of the Ni2+ ion: the coordinating octahedron of oxygen atoms is more stable with Ni2+ than with Fe2+ or Mg2+ atoms in the centre (Burns 1970). Ni cannot be defined as a rare element in the universe (in decreasing order of abundance, it takes the 14th place, before Na, K or Mn), but the average crustal content of 75 ppm emphasizes its lowlithophile characteristics. Ni is more abundant in materials of mantellic origin, especially in ultrabasic rocks with a world average content of 1450 ppm; the content being as high as 3000 ppm in dunites (Turekian 1978).
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References
Avias J (1978) L’évolution des idées et des connaissances sur la genèse et sur la nature des minerais de nickel, en particulier latéritiques, de leur découverte à nos jours. Bull BRGM Paris Sect 11:162–165.
Bernardelli AL, Melfi AJ, Oliveira SMB, Trescases JJ (1983) The Carajas nickel deposit. Proe 2nd Int Seminar on Lateritisation Processes, São Paulo 1982. In: Melfi AJ, Carvalho A (eds) Laterisation processes. Instituto Astronômico e Geofisico, Univ São Paulo, Brazil, pp 53–63.
Besset F (1978) Localisations et répartitions successives du nickel au cours de I’altération latéritique des péridotites de Nouvelle-Calédonie.Thèse, U niv Montpellier, 129 pp.
Brindley GW (1978) The structure and chemistry of hydrous nickel-containing silicate and aluminate minerals. Bull BRGM Paris Sect 11:233–245.
Brindley GW, Hang PT (1973) The nature of garnierites I. Clay Min 21:17–40.
Brindley GW, Maksimovicz Z (1974) The nature and nomenclature of hydrous nickel-containing silicates. Clay Min 10:271–277.
Brindley GW, Wan MM (1975) Compositions, structures and thermal behavior of nickel-containing minerals in the lizardite-nepouite series. Am Mineral 60:863–871.
Brindley GW, Bish DL, Wan HM (1979) Compositions, structures, and properties of nickel-containing minerals in the kerolite-pimelite series. Am Mineral 64:615–625.
Burns RG (1970) Mineralogical applications of Crystal Field Theory. Cambridge Univ Press, Cambridge.
Cervelle BD, Maquet M (1982) Cristallochimie des lizardites substituées Mg-Fe-Ni par spectrométrie visible et infra-rouge proche. Clay Min 17:377–392.
Chukrov FV, Gorshov AI, Sivtsov AV, Baresovskaya VV (1983) On the manganese mineralogy, in the latente weathering crusts of ultrabasic rocks. 2nd Int Seminar on Lateritisation Processes, São Paulo. In: Melfi AJ, Carvalho A (eds) Lateritisation processes. Instituto Astronòmico e Geofísico, Univ Säo Paulo, Brazil, pp 147–158.
Colin F (1985) Etude pétrologique des alterations de pyroxénite du gisement nickélifère de Niquelandia (Brésil). Paris Jrav Doe Mém ORSTOM, Paris, 137 pp.
Colin F, Nahon D, Trescases JJ, Melfi AJ (1990) Lateritic weathering of pyroxenites at Niquelandia, Goias, Brazil: the supergene behavior of nickel. Econ Geol 85:1010–1023.
Decarreau A, Colin F, Herbillon A, Manceau A, Nahon D, Paquet H, Trauth-Badaut D, Trescases JJ (1987) Domain segregations in Ni-Fe-Mg smectites. Clays Clay Min 35:1–10.
De Waal SA (1971) South African nickeliferous serpentinites. Min Sci Eng Pretoria 3 (2):32–45.
Deyoung JR, Sutphin DM, Werner ABT, Foose MP (1985) International strategic minerals inventory: sumary report. Nickel Denver, CO, US Geol Surv,62 pp (circular, 930-D).
Elias M, Ronaldson MJ, Giorgetta N (1981) Geology, mineralogy and chemistry of lateritic Ni-Co deposits near Karlgoorlie, Western Australia. Econ Geol 76:1675–1683.
Faust GT (1966) The hydrous nickel-magnesium silicates.The gamierite group. Am Mineral 51:279–298.
Garnier J (1867) Essai sur la géologie et les ressources minérales de la Nouvelle- Calédonie. Ann Mines Paris 6:1–92.
Gerth J (1990) Unit-cell dimensions of pure and trace metal associated goethites. Geochim CosmochimActa 54 (2):363–371.
Golightly JP (1981) Nickeliferous laterite deposits. Econ Geol 75:710–735.
Kuhnel RA, Roorda HJ, Steensma JJ (1978) Distribution and partitioning of elements in nickeliferous latentes. Bull BRGM Paris Sect 11:191–206.
Lelong F, Tardy Y, Grandin G, Trescases JJ, Boulangé B (1976) Pedogenesis, chemical weathering, and processes of formation of some supergene ore deposits. In: Wolf KH (ed) Handbook of stratabound and stratiform ore deposits, vol 3. Elsevier, Amsterdam, pp 93–173.
Maksimovic Z (1966) B-kerolite-pimelite series from Goles Mountain, Yougoslavia.Proc 2nd Int Clay Conf, Jerusalem, 1966, pp 97–105.
Maksimovic Z (1975) The isomorphous series lizardite-nepouite. Int Geol Rev 17:1035–1040.
Manceau A, Calas G (1986) Nickel-bearing clay minerals 2. X-ray absorption study of Ni-Mg distribution. Clay Min 21:341–360.
Manceau A, Calas G, Decarreau A (1985) Nickel-bearing clay minerals. I. Optical study of nickel crystal chemistry. Clay Min 20:367–387.
Manceau A, Llorca S, Calas G (1987) Crystal chemistry of Co and Ni in lithiophorite and asbolane from New Caledonia. Geochim Cosmochim Acta 51:105–113.
Maquet M, Cervelle BD, Gouet G (1981) Signatures of Ni2 and Fe3 in the optical spectra of limonitic ore from New Caledonia: application to the determination of the nickel content. Miner Deposita 16:357–373.
Melfi AJ Trescases JJ, Oliveira SMB (1980) Les latentes nickélifères du Brésil. Cahi ORSTOM Sér Géol 11:15–42.
Melfi AJ, Trescases JJ, Carvalho A, Oliveira SMB, Ribeiro Riho E, Formoso ML (1988) The lateritic ore deposits of Brazil. Sci Géol Bull (Strasb) 41:5–36.
Millot G (1964) Géologie des argiles. Masson, Paris, 499 pp.
Millot G (1982) Weathering sequences“.Climatic”planations.Leveled surfaces and paleosurfaces. Proc 7th Int Clay Conf AIPEA, Bologne-Pavia. Dev Sedimentol 35:585–593.
Millot G, Bonifas M (1955) Transformations isovolumétriques dans les phénomènes de latéritisation et bauxitisation. Bull Serv Carte Géol Als Lorr (Strasb) 8:3–20.
Nahon D (1985) Evolution of iron crusts in tropical landscapes. In: Colman M, Dethiver X (eds) Rates of chemical weathering of rocks and minerals.Academic Press, New York, pp 168–191.
Nahon D (1987) Microgeochemical environments in lateritic weathering. In: Rodriguez-Clemente RJardy Y (eds) Geochemistry and mineral formation in the earth Surface. Consejo Superior de Investigaciones Científicas, Madrid, pp 141–156.
Oliveira SMB, Trescases JJ (1980) Geoquimica da alteração supergena das rochas uitramaficas de Santa Fé (Goias-Brazil). Revista Brasileira de Geociências, São Paulo 15:243–257.
Oliveira SMB, Trescases JJ (1985) O deposito de niquel de Jacupiranga (SP):evolução mineralogica e geoqumica. Revista Brasileira de Geociências, São Paulo 15:249–254.
Oliveira SMB, Trescases JJ, Melfi AJ (1992) Lateritic nickel deposits of Brazil. Miner Deposita 27:137–146.
Ouangrawa M (1990) Etude des composés du fer dans I’altération latéritique de roches ultrabasiques. Exemples de Nouvelle-Calédonie et du Burkina Faso (Ton-Brédié). Thèse Univ Poitiers, 148 pp.
Ouangrawa M, Trescases JJ, Ambrosi JP (1996) Evolution des oxydes de fer au cours de I’altération supergène de roche ultrabasique de Nouvelle Calédonie. CR Acad Sci Paris 323(lla):243–249.
Paquet H, Colin F, Duplay J, Nahon D, MillotG (1987) Ni, Mn, Zn, Cr-smectites, early and effective traps for transition elements in supergene ore deposits. In: Rodriguez-Clemente R, Jardy Y (eds) Geochemistry and mineral formation in the Earth surface. Consejo Superior de Investigaciones Científicas. Madrid, pp 221–229.
Schellmann W (1978) Behavior of nickel, cobalt and chromium in ferruginous lateritic nickel ores. Bull BRGM Paris Sect 11:275–282.
Schellmann W (1983) Geochemical principles of lateritic nickel ore formation. 2nd Int Seminar of Lateritisation Processes, São Paulo. In: Melfi AJ, Carvalho A (eds) Lateritisation processes. Instituto Astronômico e Geofisico, Univ Säo Paulo, Brazil, pp 119–135.
Schwertmann U, Latham M (1986) Properties of iron oxides in some New Caledonian oxisols. Geoderma 39:105–123.
Tardy Y (1969) Géochimie des altérations.Etude des arènes et des eaux de quelques massifs cristallins d’Europe et d’Afrique. Mém Serv Carte Géol Als Lorr (Strasb) 31:199.
Tardy Y, Nahon D (1985) Stability of Al-goethite, Al-Hematite, Fe3-kaolinite-kaolinite in bauxites, ferricretes and latentes. An approach of the mechanism of the concretion formation. Am J Sci 285:865–903.
Trescases JJ (1975) L’évolution supergène des roches ultrabasiques en zone tropicale. Mém ORSTOM Paris 78:259 pp.
Trescases JJ (1979) Remplacement progressif des silicates par les hydroxydes de fer et de nickel dans les, profils d’altération tropicale des roches ultrabasiques Accumulation résiduelle et épigénie. Sci Géol Bull (Strasb) 32:181–188.
Trescases JJ, Dino R, Oliveira SMB (1987) Un gisement de nickel supergène en zone semi-aride:São Joãodo Piaui (Brésil).53: Rodriguez-Clemente R, Jardy Y (eds) Geochemistry and mineral formation in the earth surface. Consejo Superior de Investigaciones Cientificas, Madrid, pp 273–288.
Troly G, Esterle M, Pelletier B, Reibeil W (1979) Nickel deposits in New Caledonia:some factors influencing their formation. Proc Int Symp on Lateritisation Processes, New-Orleans, 1979, pp 81–119.
Turekian KK (1978) Nickel (section B-0).In:Wedepohl KH (ed) Handbook of geochemistry.Springer, Berlin Heidelberg NewYork, p 37.
Zeissink HE (1969) The mineralogy and geochemistry of a nickeliferous laterite profile (Greenvale, Queensland, Australia). Miner Deposita Berlin 4:132–152.
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Trescases, JJ. (1997). The Lateritic Nickel-Ore Deposits. In: Soils and Sediments. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-60525-3_6
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