Skip to main content
SpringerLink
Log in

Localized to Itinerant Electronic Transitions in Perovskite-Related Structures

  • Conference paper
Physics and Chemistry of Transition Metal Oxides

Part of the book series: Springer Series in Solid-State Sciences ((SSSOL,volume 125))

Abstract

Experiments on several perovskite-related transition-metal oxides at the cross-over from localized to itinerant electronic behavior reveal strong electron coupling not only to static, but also to dynamic oxygen displacements. A discontinuous change in the mean kinetic energy of the electrons results in a first-order transition at the cross-over and a breakdown of the Brinkman-Rice strong-correlation model before long-range magnetic order is stabilized. The superconductive copper oxides appear to stabilize a distinguishable thermodynamic state below a T ℓ ≈ 300 K where a multicenter polaron gas condenses into a polaron liquid that progressively orders into mobile stripes as the temperature is lowered to Tc. It is suggested that itinerant vibronic states are formed as a result of coupling of itinerant electrons to dynamic oxygen displacements along the Cu-O bond axes in the mobile stripes. Such vibronic states would be responsible for a remarkable transfer of spectral weight to states propagating parallel to the bond axes. The transfer of spectral weight is responsible for the anisotropy of the superconductive gap and an enhancement of the thermoelectric power in the interval Tc < T < T ℓ that is uniquely associated with the high- Tc superconductive phenomenon.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 84.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. R.D. Shannon and C.T. Prewitt, Acta Crystallogr. B25, 725 (1969)

    Google Scholar 

  2. R.D. Shannon and C.T. Prewitt, Acta Crystallogr. B26, 1046 (1970)

    Article  Google Scholar 

  3. J.B. Goodenough, J.A. Kafalas, and J.M. Longo, inPreparative Methods in Solid State Chemistry, P. Hagenmuller, ed. (Academic Press, New York, 1972) Chap. 1

    Google Scholar 

  4. J. Zaanen. G.A. Sawatsky, and J.W. Allen, Phys. Rev. Lett.55, 418 (1985)

    Article  ADS  Google Scholar 

  5. J.B. Goodenough and J.S. Zhou in MRS Symp. Proc.474, (1998)

    Google Scholar 

  6. E.O. Wollan and W.C. Koehler, Phys. Rev.100, 545 (1955)

    Article  ADS  Google Scholar 

  7. J.B. Goodenough, A. Wald, R.J. Arnott, and N. Menyuk, Phys. Rev.124, 373 (1961)

    Article  ADS  Google Scholar 

  8. J. Töpfer and J.B. Goodenough, Eu. J. Solid State & Inorg. Chem.34, 467 (1997)

    Google Scholar 

  9. J.B. Goodenough, J. Appl. Phys.36, 2342 (1965)

    Article  ADS  Google Scholar 

  10. J.B. Goodenough, Appl. Phys.39, 403 (1968)

    Article  Google Scholar 

  11. I.H,. Inoueet al, Phys. Rev. Lett.74, 2539 (1995)

    Article  ADS  Google Scholar 

  12. J.-S. Zhou and J.B. Goodenough, Phys. Rev.B54, 13393 (1996)

    Article  Google Scholar 

  13. Y. Okimotoet al, Phys. Rev.B51, 9581 (1995)

    Article  ADS  Google Scholar 

  14. J.B. Goodenough, Phys. Rev.171. 466 (1968)

    Article  ADS  Google Scholar 

  15. A. Fujimoriet al, Phys. Rev. Lett.69, 1796 (1992)

    Article  ADS  Google Scholar 

  16. J.B. Goodenough and J.-S. Zhou, Chem. Mater. (in press)

    Google Scholar 

  17. Y. Okadaet al, Phys. Rev. B48, 9677 (1993)

    Article  ADS  Google Scholar 

  18. J.B. Goodenough, Prog. Solid State Chem.5, 145 (1971)

    Article  Google Scholar 

  19. K. Kumagaiet al, Phys. Rev. B48, 7636 (1993)

    Article  ADS  Google Scholar 

  20. J.-S. Zhou, W.B. Archibald, and J.B. Goodenough, Phys. Rev. B57, R2017 (1998)

    Article  ADS  Google Scholar 

  21. J.B. Goodenough and P.M. Raccah, J. Appl. Phys.36, 1031 (1965)

    Article  ADS  Google Scholar 

  22. J.B. Torranceet al, Phys. Rev. B45. 8209 (1992)

    ADS  Google Scholar 

  23. X. Obradorset al, Phys. Rev. B47, 12353 (1993); P.C. Cranfield, J.D. Thompson, S.W. Cheong, and L.W. Rupp, Phys. Rev. B47, 12357 (1997)

    Article  Google Scholar 

  24. X. Obradorset al, Phys. Rev. B47, 12353 (1993); P.C. Cranfield, J.D. Thompson, S.W. Cheong, and L.W. Rupp, Phys. Rev. B47, 12357 (1997)

    Google Scholar 

  25. J.L. García-Muñoz, P. Lacorre, and R. Cywinski, Phys. Rev. B51, 15197 (1995); J. Rodríguez-Carvajalet al, Phys. Rev. B57, 456 (1998)

    Article  Google Scholar 

  26. J.L. García-Muñoz, P. Lacorre, and R. Cywinski, Phys. Rev. B51, 15197 (1995); J. Rodríguez-Carvajalet al, Phys. Rev. B57, 456 (1998)

    Article  ADS  Google Scholar 

  27. J.B. Goodenough, J. Solid State Chem.127, 126 (1996)

    Article  ADS  Google Scholar 

  28. M. Medardeet al, Phys. Rev. Lett,80, 2397 (1998)

    Article  ADS  Google Scholar 

  29. G.M. Zhao, K. Konder, H. Keller, and K.A. Müller, Nature381, 676 (1996)

    Article  ADS  Google Scholar 

  30. J.-S. Zhou and J.B. Goodenough, Phys. Rev. Lett.80, 2665 (1998)

    Article  ADS  Google Scholar 

  31. J.B. Goodenough, Ferroelectrics130, 77 (1992)

    Article  Google Scholar 

  32. J.-S. Zhou, H. Chen, and J.B. Goodenough, Phys. Rev. B49, 9084 (1994)

    Article  ADS  Google Scholar 

  33. J.C. Grenieret al, Physica C202, 209 (1992)

    Article  Google Scholar 

  34. G.I. Bersuker and J.B. Goodenough, Physica C274, 267 (1997)

    Article  ADS  Google Scholar 

  35. J.B. Goodenough, J.-S. Zhou, and J. Chan, Phys. Rev. B47, 5275 (1993)

    Article  ADS  Google Scholar 

  36. G.S. Baebingeret al, Phys. Rev. Lett.77, 5427 (1996)

    ADS  Google Scholar 

  37. J.B. Goodenough and J.-S. Zhou, Phys. Rev. B49, 4251 (1994); Phys. Rev. Lett.76, 3412 (1996); Phys

    ADS  Google Scholar 

  38. A. Bianconiet al, Phys. Rev. Lett.76, 3412 (1996); Phys. Rev. B54, 4310, 12018 (1996)

    Article  ADS  Google Scholar 

  39. A. Bianconiet al, Phys. Rev. Lett.76, 3412 (1996); Phys. Rev. B54, 4310, 12018 (1996)

    Google Scholar 

  40. J.M. Tranquadaet al, Nature375, 561 (1995); Phys. Rev. B54. 7489 (1996)

    Article  ADS  Google Scholar 

  41. J.M. Tranquadaet al, Nature375, 561 (1995); Phys. Rev. B54. 7489 (1996)

    Article  ADS  Google Scholar 

  42. J.-S. Zhou and J.B. Goodenough, Phys. Rev. B56, 6288 (1997)

    Article  ADS  Google Scholar 

  43. J.-S. Zhou and J.B. Goodenough, Phys. Rev. B51, 3104 (1995); Phys. Rev. Lett.77, 151 1190 (1996)

    ADS  Google Scholar 

  44. J.-S. Zhou and J.B. Goodenough, Phys. Rev. B51, 3104 (1995); Phys. Rev. Lett.77, 151 1190 (1996)

    Article  ADS  Google Scholar 

  45. M.R. Normanet al, Nature392, 157 (1998)

    Article  ADS  Google Scholar 

  46. P. Coleman, Nature392, 134 (1998)

    Article  ADS  Google Scholar 

  47. D.S. Dessauet al, Phys. Rev. Lett71, 2781 (1993)

    Article  ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Texas Materials Institute, ETC 9.102, University of Texas at Austin, 78712-1063, Austin, TX, USA

    J. B. Goodenough & J.-S. Zhou

Authors
  1. J. B. Goodenough
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. J.-S. Zhou
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. Department of Physics, The University of Tokyo, Tokyo, 113, Japan

    Hidetoshi Fukuyama

  2. Department of Applied Physics, The University of Tokyo, Tokyo, 113, Japan

    Naoto Nagaosa

Rights and permissions

Reprints and permissions

Copyright information

© 1999 Springer-Verlag Berlin Heidelberg

About this paper

Cite this paper

Goodenough, J.B., Zhou, JS. (1999). Localized to Itinerant Electronic Transitions in Perovskite-Related Structures. In: Fukuyama, H., Nagaosa, N. (eds) Physics and Chemistry of Transition Metal Oxides. Springer Series in Solid-State Sciences, vol 125. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-60041-8_2

Download citation

  • DOI: https://doi.org/10.1007/978-3-642-60041-8_2

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-64231-9

  • Online ISBN: 978-3-642-60041-8

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation