Abstract
Since the use of platinum in car catalysts, Pt is enriched in the environment (Zereini et al. 1993; Alt et al. 1993; Schramel et al. 1995; Schierl and Fruhmann 1996; Moens et al. 1995). Estimation of Pt-bioavailability has become important, as many Pt compounds are potent sensitizers (Rosner and Merget 1990; Bolm-Audorff et al. 1992). The car-emitted platinum is mainly deposited onto the soil near the motorway. The interaction of the soil with Pt is therefore decisive for further migration steps, i.e. immobilisation or formation of bioavailable species and their translocation into the foodchain.
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References
Alt F, Bambauer A, Hoppstock K; Mergler B (1993) Platinum traces in airborne particulate matter. Determination of whole content, particle size distribution and soluble platinum. Fresenius J Anal Chem 346: 693–696
Bolm-Audorff U, Bienfait HG, Burkhard J, Bury AH, Merget R, Pressel G, Schulze-Weminghaus G (1992) Prevalence of respiratory allergy in a platinum rafinery. Int Arch Ocupp Environ Health 64: 257–260
Ehrenstorfer-Schäfers E, Haiti H, Beck W (1988) Bildung wasserlöslicher Histidin-Platin - Komplexe aus metallischem Platin und Histidin. Z Naturforsch 43b: 499
Huheey JE (1983) Inorganic Chemistry 3rd Ed. Harper & Row New York
Iakovidis A, Hadjiliadis N (1994) Complex compounds of platinum (II) and (IV) with amino acids, peptides and their derivates. Coord Chem Rev 135/136: 17–63
Lustig S, Zang S, Michalke B, Schramel P, Beck W (1996) Transformation behaviour of different platinum compounds in clay - like soil: speciation investigations. Sei Tot Environment 188: 195–204
Lustig S, Zang S, Michalke B, Schramel P, Beck W (1997) Platinum determination in nutrient plants by inductively coupled plasma mass spectrometry with special respect to the hafnium oxide interference. Fresenius J Anal Chem 357: 1157–1163
Lustig S, Michalke B, Beck W, Schramel P (1998) Platinum speciation with hyphenated techniques: high performance liquid chromatography and capillary electrophoresis online coupled to an inductively coupled plasma mass spectrometer - application to aqueous extracts from a platinum treated soil. Fresenius J Anal Chem 360: 18–25
Lustig S, deKimpe J, Cornelis R, Schramel P, Michalke B (1999) Platinum speciation in clinical and environmental samples: Scrutiny of data obtained by using electrophoresis techniques (flatbed and capillary). Electrophoresis, in press
Messerschmidt J, Alt F, Tölg G (1994) Platinum species analysis in plant material by gel permeation chromatography. Anal Chim Acta 274: 161–167
Michalke B, Schramel P (1996) Hyphenation of capillary electrophoresis to inductively coupled plasma mass spectrometry as an element - specific detection method for metal speciation. J Chromat A 750: 51–62
Michalke B, Schramel P (1997) Coupling of capillary electrophoresis with ICP-MS for metal speciation investigations. Fresenius J Anal Chem 357: 594–599
Michalke B, Lustig S, Schramel P (1997) Analysis for the stability of platinum containing species in soil samples using capillary electrophoresis interfaced on-line with inductively coupled plasma mass spectrometry. Electrophoresis 18: 196–201
Moens L, Vanhaecke F, Riondato J, Dams R (1995) Some figures of merrit of a new double focusing inductively coupled plasma mass spectrometer. JAAS 10: 569–574
Nachtigall D, Kock H, Artelt S, Levsen K, Wünsch G (1996) Platinum solubility of a substance designed as a model for emissions of automobile catalytic converters. Fresenius J Anal Chem 354: 742–746
Olesik JW, Kinzer JA, Olesik SV (1995) Capillary electrophoresis inductively coupled plasma mass spectrometry for rapid elemental speciation. Anal Chem 67/1: 1–12
Rosner G, Merget R (1990) Immunotox metals and immunotox allergenic potential of platinum compounds. Immunotox Plenum Press New York
Schierl R, Fruhmann G (1996) Airborne platinum concentrations in Munich city buses. Sei Tot Environment 182: 21–23
Schramel P, Wendler I, Lustig S (1995) Capability of ICP-MS (pneumatic nebulization and ETV) for Pt - analysis in different matrices at ecological relevant concentrations. Fresenius J Anal Chem 353: 115–118
Schramel P, Lustig S (1997) Immissions - Situation fur Platin (Vorkommen von Platin in der Luft, Boden, Wasser, Futtermitteln, Lebensmitteln) Abschlußpräsentation Forschungsverbund Edelmetallemissionen BMBF, GSF München
Tschöpel P, Kotz L, Schulz W, Veber M, Tölg G (1980) Zur Ursache und Vermeidung systematischer Fehler bei Elementbestimmungen in wäßrigen Lösungen im ng/ml und pg/ml - Bereich. Fresenius Z Anal Chem 302: 1–6
Wei C, Morrison GM (1994) Platinum analysis and speciation in urban gullypots. Anal Chim Acta 284: 587–592
Wilkinson G, Gillard RD, McCleverty JA (1987) The synthesis, reactions, properties and applications of coordination compounds. Comprehensive Coordination Chemistry Wheaton & Co Ltd, New York
Zereini F, Zientek C, Urban H (1993) Konzentration und Verteilung von Platingruppenelementen (PGE) in Böden. Z Umweltchem Ökotox 5/3: 130–134
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Michalke, B., Schramel, P. (2000). Platinum speciation using on-line hyphenation of capillary electrophoresis to ICP-MS. In: Zereini, F., Alt, F. (eds) Anthropogenic Platinum-Group Element Emissions. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-59678-0_17
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DOI: https://doi.org/10.1007/978-3-642-59678-0_17
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