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Bildung und Verbleib natürlicher halogenorganischer Verbindungen in Wasser, Böden und Sedimenten

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Zusammenfassung

Organohalogenverbindungen wie Polychlorierte Dibenzodioxine, Polychlorierte Biphenyle, Chlorphenole, chlorierte Ethane und Ethene, Trihalogenmethane, Methyliodid und auch FCKWs, die man lange Zeit nur als anthropogen hergestellte Produkte angesehen hat (→ Kap. 7, 16), sind in den letzten Jahren auch als Syntheseprodukte der Natur identifiziert worden. Viele Publikationen in jüngster Zeit deuten darauf hin, daß die natürliche Chlorchemie immer mehr in den Blickpunkt des Interesses rückt (Gribble 1992, 1994a, 1994b, 1995; 1996; Geckeler u. Eberhardt 1995; Grimvall u. de Leer 1995; Hoekstra u. de Leer 1995; Naumann 1993, 1994). Natürliche Chlorierungsprozesse sind bislang kaum untersucht und wurden bei der Diskussion von Massenbilanzen bisher meist vernachlässigt. Schwierigkeiten bereitet vor allem die eindeutige Zuordnung eines halogenorganischen Moleküls zu einer natürli-chen Quelle, wenn der Mensch das identische Molekül in großem Maßstab herstellt und großflächig verteilt.

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Schöler, H.F., Haiber, G. (1997). Bildung und Verbleib natürlicher halogenorganischer Verbindungen in Wasser, Böden und Sedimenten. In: Geochemie und Umwelt. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-59038-2_8

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  • DOI: https://doi.org/10.1007/978-3-642-59038-2_8

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