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Lyotrope polymere Flüssigkristalle

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Lyotrope Flüssigkristalle

Zusammenfassung

Seit der Entdeckung des ersten Flüssigkristalls von Reinitzer im Jahre 1888 hat sich die Erforschung des flüssigkristallinen Phasenzustandes zu einem inter-disziplinären Arbeitsgebiet entwickelt, das vielfältige chemische, physikalische, biologische und anwendungsrelevante Forschungsrichtungen einschließt.

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Literatur

  1. Ringsdorf H, Schlarb B, Venzmer J (1988) Moleculare Architektur und Funktion von poly-meren orientierten Systemen-Modelle für das Studium von Organisation, Oberflächen-erkennung und Dynamik bei Biomembranen. Angew Chem 100:117–162

    Article  CAS  Google Scholar 

  2. Laschewsky A (1995) Molecular concepts, self-organisation and properties of polysoaps. Adv Polym Sci 124:1–86

    Article  CAS  Google Scholar 

  3. Hall PJ, Tiddy GJT (1992) Lyotropic side chain polymer liquid crystals. In: Collyer AA (ed) Liquid crystal polymers. From structures to applications. Elsevier London, UK, p 237

    Chapter  Google Scholar 

  4. Fairhurst CE, Fuller S, Gray J, Holmes C, Tiddy GJT (1998) Lyotropic surfactant liquid crystals. In: Demus D, Goodby J, Gray GW, Spiess H-W, Vill V (eds) Handbook of liquid crystals vol 3. Wiley-vch, Weinheim New York Cichester Brisbane Singapore Toronto, p 341

    Google Scholar 

  5. Chu B, Zhou Z (1996) Physical chemistry of POA surfactants. In: Nonionic surfactants, polyoxyalylene block copolymers, ed Marcel Dekker inc, New York Basel Hong Kong Surfactant Sci Ser vol 60, p 67

    Google Scholar 

  6. Northolt MG, Sikkema DJ (1992) Lyotropic main chain liquid crystal polymers. In: Collyer A A (ed) Liquid crystal polymers. From structures to applications. Elsevier, London, UK, p 273

    Chapter  Google Scholar 

  7. Finkelmann H, Lühmann B, Rehage G (1982) Phase behaviour of lyotropic liquid crystalline side chain polymers in aqueous solutions. Colloid Polym Sci 260:56–65

    Article  CAS  Google Scholar 

  8. Lühmann B, Finkelmann H, Rehage G (1985) Phase behaviour and structure of polymer surfactants in aqueous solutions. The occurrence of lyotropic nematic phases. Macromol Chem 186:1059–1073

    Article  Google Scholar 

  9. Walther M, Finkelmann H (1996) Structure formation of liquid crystalline block copolymers. Prog Polym Sci 21: 951–979

    Article  CAS  Google Scholar 

  10. a)Israelachvili JN, Marcelja S, Horn RG (1980) Physical principles of membrane organization. Q Rev Biophys 13: 121–200; b Israelachvili JN in Degiorgio V, Corti M(eds): Physics of amphiphiles: Micelles, Vesicles and Microemulsions, North-Holand Physics Publishing, Amsterdam 1985, p 24

    Article  CAS  Google Scholar 

  11. Mitchell DJ, Tiddy GJT, Warning L, Bostock T, McDonald MP (1983) Phase behaviour of polyoxyethylene surfactants in water. J Chem Soc Faraday Transl 79:975–1000

    Article  CAS  Google Scholar 

  12. a Kratzat K, Finkelmann H (1993) Branched non-ionic oligooxyethylene Y-amphiphiles: effect of molecular geometry on the micellar shape, 1. Liq Cryst 13: 691–699; b Kratzat K, Finkelmann H (1994) Branched Non-ionic oligooxyethylene V-amphiphiles: effect of molecular geometry on LC-phase behaviour, 2. Colloid Polym Sci 272:400-408; c Kratzat K, Schmidt C, Finkelmann H (1994) A doubly branched non-ionic oligooxyethylen V-amphi-phile: effect of molecular geometry on liquid-crystalline phase behaviour, 3. J Colloid Interface Sci 163:190-198; d Kratzat K, Finkelmann H (1996) Asymmetrically branched non-Ionic oligooxyethylene Y-amphiphiles: effect of molecular geometry on liquid-crystalline phase behaviour, 5. J Colloid Interface Sci 181: 542-550

    Article  Google Scholar 

  13. Fromherz P (1981) The surfactant-block structure of micelles, synthesis of the droplet and of the bilayer concept. Ber Bunsenges Phys Chem 85: 891–899

    Article  CAS  Google Scholar 

  14. Fontell K (1990) Cubic phases in surfactant and surfactant-like lipid systems. Colloid Polym Sci 268: 264–285

    Article  CAS  Google Scholar 

  15. Tenford C (1980) The hydophobic Effect, 2nd edn. Wiley, New York

    Google Scholar 

  16. Owenson B, Pratt LR (1984) Molecular statistical thermodynamics of model micellar aggregates. J Phys Chem 88: 2905–2915

    Article  CAS  Google Scholar 

  17. Cabane B, Duplessix R, Zemb T (1985) J Physique 46: 2161

    Article  CAS  Google Scholar 

  18. Bekutov EA, Bakanova ZK (1986) Synthetic water-soluble polymers in solution, ed Hüthig und Wepf, Basel 1986

    Google Scholar 

  19. Löfflör R (1990) Synthese von Monomeren und Polymeren Amphiphilen und deren Charak-terisierung in wässrigen Lösungen: Chem. Dissertation, Universität Freiburg

    Google Scholar 

  20. Strauss UP (1989) Hydrophobic polyelektrolytes. In Glass JE (ed) Polymers in aqueous media. Adv Chem Ser 223, Am Chem Soc, Washington DC, p 317

    Chapter  Google Scholar 

  21. Kammer U, Eolias HG (1972) Kolloid Z u Z Polymere 250: 344

    Article  CAS  Google Scholar 

  22. Anton P, Köberle P, Laschewsky A (1993) Recent developments in the field of micellar polymers. Macromol Chem 194:1–27

    Article  CAS  Google Scholar 

  23. Jahns E, Finkelmann H (1987) Lyotropic liquid crystalline phase behavior of a polymeric amphiphile polymerized via their hydrophilic ends. Colloid Polym Sci 265(4): 304–311

    Article  CAS  Google Scholar 

  24. Yu G, Yang Z, Ameri M, Attwood D, Collett JH, Price C, Booth C (1997) Diblock copolymers of ethylene oxide and 1,2-butylene oxide in aqueous solution. Effect of E-block-length distribution on self-assoziation properties. J Phys Chem B 101:4394–4401

    Article  CAS  Google Scholar 

  25. Zhou Z, Chu B (1996) Phase behavior and assoziation properties of PEP triblock copolymer in aqueous solution. Macromolecules 27:2025–2033

    Article  Google Scholar 

  26. Yu G-E, Garrett CA, Mai S-M, Altinok H, Attwood D, Price C, Booth C (1998) Effect of cyclisa-tion on the association behavior of block copolymers in aqueous solution. Langmuir 14: 2278–2285

    Article  CAS  Google Scholar 

  27. Yang Z, Pickard S, Deng N-J, Barlow RJ, Attwood D, Booth C (1994) Effect of block structure on the micellisation and gelation of aqueous solutions of copolymers of ethylene oxide and butylene oxide. Macromolecules 27: 2371–2379

    Article  CAS  Google Scholar 

  28. Finkelmann H, Schafheutle MA (1986) Lyotropic liquid crystalline phase behavior of a mono-meric and a polymeric monosaccharide amphiphile in aqueous solution. Colloid Polym Sci 264: 786–790

    Article  CAS  Google Scholar 

  29. Hall C, Tiddy GJT, Pfannemüller B (1991) Lyotropic liquid crystal phase formation in l-(alka-noylmethyl amino) l-deoxy-D-glucitols. Liq Cryst 9: 527–537

    Article  CAS  Google Scholar 

  30. Gallot B, Revilla J, Charreyre MT, Pichot C (1994) Liquid-crystalline propertis of comb-like-polymers prepared by homo and copolymerisation with styrene of liposaccharidic monomers. In: Carfagna C (Ed) Liquid crystalline polymers. Pergamon, Oxford p 1–23

    Google Scholar 

  31. Thundathil R, Stoffer JO, Friberg SE (1980) Polymerisation in lyotropic liquid crystals. Change of structure during polymerisation. J Polym Sci 18: 2629–2640

    CAS  Google Scholar 

  32. McGrath KM (1996) Polymerisation of liquid crystalline phases in binary surfactant/water systems. Colloid Polym Sci 274: 499–512

    Article  CAS  Google Scholar 

  33. Gallot B, Douy A (1987) Comb copolymers with thermotropic and lyotropic properties synthesis and structural study. Mol Cryst Liq Cryst 153: 367–373

    CAS  Google Scholar 

  34. Gallot B, Marchin B (1989) Liquid-crystalline copolymers with lipoamino acid side chains. Synthesis and structure study Liq Cryst 5(6): 1719–1727

    CAS  Google Scholar 

  35. Okahata Y, Tanamachi S, Nagai M, Kunitake T (1981) Synthetic bilayer membranes prepared from dialkyl amphiphiles with nonionic and zwitterionic head groups. J Colloid Interface Sci 82(2): 401–417

    Article  CAS  Google Scholar 

  36. Barlow DJ, Ma G, Lawrence MJ, Webster JRP, Penfold J (1995) Neutron reflectance studies of a novel nonionic surfactant and molecular modeling of the surfactant vesicles. Langmuir 11: 3737–3741

    Article  CAS  Google Scholar 

  37. Kratzat K, nicht veröffentlichten Resultate

    Google Scholar 

  38. Schafheutle MA, Finkelmann H (1988) Shapes of micelles and molecular geometry. Synthesis and studis on the phase behaviour, surface tension and rheology of rigid rod-like surfactants in aqeous solution. Liq Crystals 3(10): 1369–1386

    Article  CAS  Google Scholar 

  39. a Pietschmann N, Lunow A, Brezesinski G, Tschierske C, Kuschel F, Zaschke H (1991) The first liquid crystalline diol compound which exhibits nematic, smectic A+, and smectic C+ meso-phases in the presence of water. Colloid Polym Sci 269: 636–639; b) Tschierske C, Lunow A, Joachimi D, Hentrich F, Girdziunaite D, Zaschke H, Mädicke A, Brezesinski G, Kuschel F (1991) Amphiphilic propane-1,2-diol derivatives incorporating calamitic structural units. Liq Crystals 9: 821-829

    Article  Google Scholar 

  40. Boden N, Bushby RJ, Jolley KW, Holmes MC, Sixl F (1987) Molec Crystals Liq Crystals 152:37

    CAS  Google Scholar 

  41. Keller-Griffith R, Ringsdorf H, Vierengel A (1986) Structural variations in amphiphiles: Discoidal multivalent cations. Colloid Polym Sci 264: 924–935

    Article  CAS  Google Scholar 

  42. Lühmann B, Finkelmann H (1987) Lyotropic liquid crystalline phase behavior of amphiphilic monomers and polymers having a rod-like hydrophobic moiety. Colloid Polym Sci 265: 506–516

    Article  Google Scholar 

  43. Pietschmann N, Brezesinski G, Tschierske C, Zaschke H, Kuschel F (1989) Phase behavior of amphiphilic side-chain polymers. Liq Cryst 5(6): 1697–1709

    Article  CAS  Google Scholar 

  44. Schwarzwälder C, Meier W (1997) New nonionic head type polysoaps: a way to reversed liquid crystalline phases. Macromolecules 30(16): 4601–4607

    Article  Google Scholar 

  45. Fendler JH (1992) Vesicles. In: Membrane mimetic chemistry, Wiley, New York, p 113

    Google Scholar 

  46. Sisson TM, Lamparski HG, Kölchens S, Elayadi A, O’Brien DF (1996) Cross-linking polymerisations in two-dimensional assemblies. Macromolecules 29:8321–8329

    Article  CAS  Google Scholar 

  47. Naitoh K, Ishii Y, Tsujii K (1991) Iridescent phenomena and polymerisation behavior of amphiphilic monomers in lamellar liquid crystalline phase. J Phys Chem 95: 7915–7918

    Article  CAS  Google Scholar 

  48. Srisiri W, Benedicto A, O’Brien DF, Trouard TP, Orädd G, Persson S, Lindblom G (1998) Stabilization of a bicontinuous cubic phase from polymerizable monoacylgycerol and diacylgycerol. Langmuir 14:1921–1926

    Article  CAS  Google Scholar 

  49. Lee Y-S, Yang J, Sisson TM, Frankel DA, Gleeson JT, Aksay E, Keller SL, Gruner SM, O’Brien DF (1995) Polymerisation of nonlamellar lipid assemblies. J Am Chem Soc 117:5573–5578

    Article  CAS  Google Scholar 

  50. Srisiri W, Sisson TM, O’Brien DF, McGrath KM, Han Y, Gruner SM (1997) Polymerisation of the inverted hexagonal phase. J Am Chem Soc 119:4866–4873

    Article  CAS  Google Scholar 

  51. Dorn K, Klingbiel RT, Specht DP, Tyminski PN, Ringsdorf H, O’Brien DF (1984) Permeability characteristics of polymeric bilayer membranes of methacryloyl and butadiene lipids. J Am Chem Soc 106:1627–1633

    Article  CAS  Google Scholar 

  52. Meier C (1989) Lyotrop Flüssigkristalline Copolymere aus nichtamphiphilen Monomeren: Chem. Dissertation, Universität Freiburg

    Google Scholar 

  53. Glatter O, Scherf G, Schillén K, Brown W (1994) Characterisation of a poly(ethylene oxide)-poly(propylene oxide) triblock copolymer (EO27 PO39 EO27) in aqueous solution. Macromolecules 27: 6046–6054

    Article  CAS  Google Scholar 

  54. Mortensen K, Pedersen JK (1993) Structural study on the micelle formation of poly(ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide) triblock copolymer in aqueous solution. Macromolecules 26: 805–812

    Article  CAS  Google Scholar 

  55. Wanka G, Hoffmann H, Ulbricht W (1994) Phase diagrams and aggregation behaviour of EPE triblock copolymers in aqueous solution. Macromolecules 27:4145–4159

    Article  CAS  Google Scholar 

  56. Alexandridis P, Zhou D, Khan A (1996) Lyotropic liquid crystallinity in amphiphilic block copolymers: temperature effects on phase behaviour and structure for PEO-PPO-PEO copolymers of different composition. Langmuir 12:2690–2700

    Article  CAS  Google Scholar 

  57. Zhang K, Khan A (1995) Phase behavior of poly(ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide) triblock copolymers in water. Macromolecules 28: 3807–3812

    Article  CAS  Google Scholar 

  58. Alexandridis P, Olsson U, Lindman B (1998) A record nine different phases in a ternary isothermal system of an amphiphilic block copolymer and selective solvents. Langmuir 14: 2627–2638

    Article  CAS  Google Scholar 

  59. Mortensen K, Brown W, Jorgensen E (1994) Phase behavior of PEP triblock copolymer melt and aqueous solutions. Macromolecules 27: 5654–5666

    Article  CAS  Google Scholar 

  60. Mortensen K (1997) Cubic phase in a connected micellar network of poly(propylene oxide)-poly(ethylene oxide)-poly(propylene oxide) triblock copolymers in water. Macromolecules 30:503–507

    Article  CAS  Google Scholar 

  61. Alexandridis P, Olsson U, Lindman B (1996) Phase behavior of amphiphilic block copolymers in water-oil mixtures: the pluronik 25R4-water-xylene system. J Phys Chem 100:280–288

    Article  CAS  Google Scholar 

  62. Alexandridis P, Olsson U, Lindman B (1997) Structural polymorphism of amphiphilic copolymers: six lyotropic liquid crystalline and two solution phases in a poly(oxybutylene)-b-poly(oxyethylene)-water-xylene system. Langmuir 13:23–34

    Article  CAS  Google Scholar 

  63. Yang J, Wegner G (1992) Polymerisation in lyotropic liquid crystals. 1. Phase behavior of photo-cross-linkable ethylene oxide (PEO)-dimethylsiloxane (PDMS) triblock copolymers PEO-PDMS-PEO in aqueous solution. Macromolecules 25:1786–1790

    Article  CAS  Google Scholar 

  64. Hill RM, He M, Lin Z, Davis HT, Scriven LE (1993) Lyotropic liquid crystal phase behavior of polymeric siloxane surfactants. Langmuir 9:2789–2798

    Article  CAS  Google Scholar 

  65. Löffler R, Finkelmann H (1990) Amphiphilic liquid-crystalline elastomers. Makromol Chem Rapid Commun 11:321–328

    Article  Google Scholar 

  66. Fischer P, Schmidt C, Finkelmann H (1995) Amphiphilic liquid-crystalline networks-phase behavior and alignment by chemical fields. Makromol Rapid Commun 16: 435-447

    Google Scholar 

  67. Fischer P, Schmidt C, Finkelmann H (1995) Amphiphilic liquid-crystalline networks-phase behavior and alignment by chemical fields. Makromol Rapid Commun 16:435–447

    Article  CAS  Google Scholar 

  68. Albrecht H (1997) Verzweigte Amphiphile mit hoher Polarisierbarkeitsanisotropie. Synthese und Eigenschaften von Monomeren, Polymeren und Elastomeren: Chem. Dissertation, Uni-versität Freiburg

    Google Scholar 

  69. Fischer P, Finkelmann H (1998) Lyotropic liquid-crystalline elastomers. Progr Colloid Polym Sci 111: 127–134

    Article  CAS  Google Scholar 

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Authors
  1. K. Kratzat
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Editors and Affiliations

  1. Institut für Physikalische Chemie, Universität Paderborn, 33095, Paderborn, Deutschland

    Horst Stegemeyer

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Kratzat, K. (1999). Lyotrope polymere Flüssigkristalle. In: Stegemeyer, H. (eds) Lyotrope Flüssigkristalle. Steinkopff, Heidelberg. https://doi.org/10.1007/978-3-642-58712-2_3

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  • DOI: https://doi.org/10.1007/978-3-642-58712-2_3

  • Publisher Name: Steinkopff, Heidelberg

  • Print ISBN: 978-3-642-63695-0

  • Online ISBN: 978-3-642-58712-2

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