Abstract
Polymers are highly complex multicomponent materials. Properties typically considered important to polymer performance in products may be very diverse and can be divided into simple and distributed properties. Simple properties are the total weight of polymer present, the residual monomer or oligomer content, total weight of microgels or aggregates, and properties that depend only on these measures, such as conversion in the polymerization reaction, monomer composition and average copolymer composition. For other properties different molecules in the same polymer will have different values of the property. These properties are termed distributed properties, the most important of them in polymer chemistry being the molar mass distribution, the distribution of compositions, the distribution of sequence lengths and the distribution of functionality.
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References
Balke ST (1991) Characterization of Complex Polymers by Size Exclusion Chromatography and High-Performance Liquid Chromatography. In: BARTH HG, MAYS JW (eds) Modern Methods of Polymer Characterization, Chapter 1. Wiley-Interscience, New York.
Elias GH (1984) Macromolecules, Chapter 9. Plenum Press, New York.
Entelis SG, Evreinov VV, Gorshkov AV (1986) Adv Polym Sci 76:129.
Schröder E, Müller G, Arndt K-F (1982) Leitfaden der Polymercharakterisierung. Akademie-Verlag, Berlin.
Janca J (ed) (1984) Steric Size Exclusion Chromatography of Polymers. Dekker, New York.
Glöckner G (1987) Polymer Characterization by Liquid Chromatography. Elsevier, Amsterdam.
Balke ST (1984) Quantitative Column Liquid Chromatography: A Survey of Chemometric Methods. Elsevier, Amsterdam.
Kilz P, Krüger R-P, Much H, Schulz G (1995) ACS Adv Chem 247:223.
Glöckner G (1991) Gradient HPLC of Copolymers and Chromatographic Cross-Fractionation, Chapter 2. Springer, Berlin Heidelberg New York.
Entelis SG, Evreinov VV, Kuzaev AI (1985) Reactive Oligomers. Khimiya, Moscow.
Kuhn W (1936) Kolloid-Z 76:258, (1939) Kolloid-Z 78:3.
Kratky O, Porod G (1949) Rec Trav Chim (Belgium) 68:1106.
Peterlin A (1960) J Polymer Sci 47:403.
Heine S, Kratky O, Porod G (1961) Makromol Chem 44-46:682.
Brandrup J, Immergut, EH (Eds) (1989) Polymer Handbook. Wiley, New York.
Yamakawa H (1971) Modern Theory of Polymer Solutions. Harper & Row, New York.
Bohdanecky M, Kovar J (1982) Viscosity of Polymer Solutions. Elsevier, Amsterdam.
Elias HG (1984) Macromolecules. Plenum Press, New York, p 314.
Glöckner G (1991) Gradient HPLC of Copolymers and Chromatographic Cross-Fractionation. Springer, Berlin Heidelberg New York, pp 28–31.
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Pasch, H., Trathnigg, B. (1999). Introduction. In: HPLC of Polymers. Springer Desktop Editions in Chemistry. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-58265-3_1
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DOI: https://doi.org/10.1007/978-3-642-58265-3_1
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