Abstract
Studies of flow-induced deformation of isolated chains in solution [1] confirm the theoretical prediction of the coil-stretch transition in elongational flow [2]. Although there are still several unresolved issues related to the scaling of the critical strain rate with molecular weight [3,4], it is believed that the basic physics of the coil-stretch transition in a single polymer chain is well-understood.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Frank FC, Keller A, Mackley MR (1971) Polymer 12: 467
de Gennes P-G (1974) J Chem Phys 60: 751
Keller A, Odell JA (1985) Coll & Polym SCi 263: 181
Nguyen TQ, Yu G, Rausch H-H (1995) Macromolecules 28: 4851
Rabin Y, Alexander S (1990) Europhys Lett 13: 49
Klein J, Perhia D, Warburg S (1991) Nature 352: 143
Alexander S, Rabin Y (1990) J Phys: Condens Matter 2: SA313
Rabin Y, Samulski ET (1992) Macromolecules Commun 25: 2985
de Gennes P-G (1979) Scaling methods in polymer physics. Cornell University Press, Ithaca
Bird RB, Armstrong RC, Hassager O (1977) Dynamics of polymeric liquids, vol 1. Wiley, New York
Brochard-Wyart F (1993) Europhys Lett 23: 105
Kume T, Hashimoto T (1995) In: Nakatani AI, Dadmun MD (eds) Flow-induced structure in polymers. ACS Symposium Series 597: 35
Migler K, Liu C-H, Pine DJ (1996) Phys Rev Lett 29: 1422
Chow A, Keller A, Müller AJ, Odell JA (1988) Macromolecules 21: 250
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1999 Springer-Verlag Berlin Heidelberg
About this chapter
Cite this chapter
Rabin, Y., Alexander, S. (1999). Osmotic Pressure in Solutions of Stretched Polymers. In: Nguyen, T.Q., Kausch, HH. (eds) Flexible Polymer Chains in Elongational Flow. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-58252-3_4
Download citation
DOI: https://doi.org/10.1007/978-3-642-58252-3_4
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-63515-1
Online ISBN: 978-3-642-58252-3
eBook Packages: Springer Book Archive