Abstract
Short lived NMHC have been detected in the remote atmosphere, and their origin was ascribed to local emissions from the ocean surface [1–4]. Superficial sea water in the ocean appears supersaturated in light non methane hydrocarbons by two or three orders of magnitude and acts as a net source for the atmosphere. Despite the great variability of one order of magnitude in hydrocarbons concentrations, its relative composition remains fairly constant and is characterised by a high proportion of alkenes, mainly ethene and propene. In order to determine the origin of these light hydrocarbons, systematic vertical profiles were undertaken in the Mediterranean in order to follow the seasonal variability of light unsaturated and mono-unsaturated hydrocarbons in connection with biological parameters such as chlorophyll and photosynthetic pigments. Also vertical profiles were performed in the Pacific Ocean near hydrothermal sources in order to investigate the possible origin of acetylene.
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References
Lamontagne R.A., J.W. Swinnerton, W.J. Linnenbom, Hydrocarbons in the North and South pacific, Tellus 26 (1973) 71–77.
Rudolph J., D.H. Ehhalt, Measurements of C2-C5 hydrocarbons over the North Atlantic, J. Geophys. Res. 86 (1981) 11959–11964.
Bonsang B, G. Lambert, Nonmethane hydrocarbons in an oceanic atmosphere, J. Atmos.Chem. 2 (1985) 257–271.
Bonsang B., M. Kanakidou, G. Lambert, P. Montray, The marine source of C2-C6 aliphatic hydrocarbons. J. Atmos.Chem. 6 (1988) 3–20.
Donahue N.M., R.G. Prinn, Non methane hydrocarbons chemistry in the remote marine bounsdary layer, J. Geophys. Res. 95 (1990) 18387–18411.
Greenberg J.P., P.R. Zimmerman, Non methane hydrocarbons in remote troposphere, J. Geophys. Res. 89 (1984) 4767–4778.
Rudolph J., A. Khedim, D. Wegenbach, The seasonal variations of light nonmethane hydocarbons in the antarctic troposphere, J. Geophys. Res. 94 (1989) 13039–13044.
Wilson D.F., J.W. Swinnerton, R.A. Lamontagne, Production of carbon monoxyde and gaseous hydrocarbons in seawater: relation to dissolved organic carbon. Science 168 (1970) 1577–1579.
Donahue N.M., R.G. Prinn, In-situ nonmethane hydrocarbon measurements on SAGA 3, J. Geophys. Res. 98 (1993) 16915–16932.
Bonsang B., M. Kanakidou, G. Lambert, NMHC in marine atmosphere: preliminary results of monitoring at Amsterdam Island., J. Atmos. Chem. 11 (1990) 169–178.
Plass Dülmer C, R. Koppmann, J. Rudolph, Light hydrocarbons in the surface water of the Mid-Atlantic, J. Atmos. Chem. 15 (1992) 235-231.
Bonsang B., D. Martin, G. lambert, M. Kanakidou, J.C. Le Roulley, G. Sennequier, Vertical distribution of non methane hydrocarbons in the remote marine boundary layer. J. Geophys. Res. 96 (1991) 7313–7324.
Kanakidou M., B. Bonsang, J.C. Le Roulley, G. Lambert, D. Martin, G. Sennequier, Marine source of atmospheric acetylene, Nature 333 (1988) 51–52.
Bonsang B., C. Polle, G. lambert, Evidence for marine production of isoprene, Geophys. Res. Lett. 11 (1992) 1129–1132.
Ratte M., Plass Dülmer C., Koppmann R., Rudolph J., Denga J. Production mechanism of C2-C4 hydrocarbons in sea water: field measurements and experiments Global Biogeochemical Cycles 7 (1993) 369–378.
Moore R.M., Oram D.E., Penkett S.A., Production of isoprene by marine phytoplankton cultures. Gephys. Res. Lett. 21 (1994) 2507–2510.
Plass Dülmer C, Koppmann R., Rudolph J., Light non methane hydrocarbons in seawater, Global Biogeochemical Cycles 9 (1995) 79–100.
Kanakidou M., Crutzen P.J., Zimmermann P.H., Bonsang B., A 3 dimensional global study of the photochemistry of ethane and propane in the troposphere: production and transport of organic nitrogen compounds, in: H. Van Dop, G. Kallos (eds), Air Pollution Modeling and its Applications IX, Plenum Press,New York 1992, pp. 415–426.
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Bonsang, B. (2000). Air-Sea Exchanges of Non-Methane Hydrocarbons. In: Larsen, S.E., Fiedler, F., Borrell, P. (eds) Exchange and Transport of Air Pollutants over Complex Terrain and the Sea. Transport and Chemical Transformation of Pollutants in the Troposphere, vol 9. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-57252-4_22
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DOI: https://doi.org/10.1007/978-3-642-57252-4_22
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