Skip to main content

Umwandlung von Spurenstoffen und ihre Auswirkungen auf die Atmosphäre

  • Chapter
Handbuch der Umweltveränderungen und Ökotoxikologie
  • 334 Accesses

Zusammenfassung

Die Atmosphäre wird in diesem Kapitel vor allem aus der Perspektive des Transports von Luftmassen und deren Eigenschaften betrachtet. Man hat zwischen physikalischen und chemischen Eigenschaften der Luft zu unterscheiden, die durch Zustandsgrößen wie Temperatur oder Wind auf der einen Seite und Konzentrationen oder Mischungsverhältnissen auf der anderen Seite beschrieben werden. Durch Luftbewegungen transportierte Eigenschaften werden als Flüsse bezeichnet, also Massenfluß, Wärmefluß oder Impulsfluß auf der physikalischen Seite und Spurenstofffluß (etwa Ozonfluß, Wasserdampf-oder Feuchtefluß, CO2-Fluß) auf der chemischen Seite. Diese Flüsse führen bei Spurenstoffen im allgemeinen zu einer Verdünnung, d. h. Konzentrationsabnahme. Das geschieht durch Transport von den Quellen oder Anhäufungsgebieten weg und durch Vermischung mit Luftmassen, die geringere Konzentrationen des transportierten Stoffes aufweisen, ferner durch Transport zu Senkengebieten hin. Ein solches ist die Erdoberfläche für viele Luftbeimengungen, die dort deponiert werden (s. Bd. 1B, Kap. 2). Doch unter gewissen Umständen kann der Transport auch zu Anhäufungen von Schadstoffen führen. Das geschieht, wenn verschmutzte kalte Luft in ein Tal abfließt und sich dort ansammelt. Ein anderes Beispiel, das die beobachtete Ozonverteilung in der Stratosphäre betrifft, ist die Anhäufung von Ozon, das in niedrigen Breiten erzeugt wird, durch konvergenten Ozonmassenfluß in mittleren und höheren Breiten (Fabian 1992).

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 179.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 119.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 129.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literatur

Literatur

  • Allegrini I,Febo A,Perrino C (1994) Role of nitrous acid in the oxidation processes in the Mediterranean area. In: Restelli G,Angeletti G (eds) Physicochemical behaviour of atmospheric pollutants,report EUR 15609/1 EN,vol 1,Luxembourg,pp 293–299

    Google Scholar 

  • Ammann M,Kalberer M,Tabor K,Tobler L,Zellweger C,Weingartner E,Nyeki S,Parrat Y,Li F,Piguet D,Rössler E,Jost DT,Gäggeler HW,Baltensperger U (1997) Heterogeneous interaction of NO2with carbonaceous aerosols at the ppb level: adsorption,conversion to NO and production of HONO. In: 7th European Symposium on physico-chemical behaviour of atmospheric pollutants: the oxidising capacity of the troposphere,pp 683–687

    Google Scholar 

  • Ammann M,Kalberer M,Jost DT,Tobler L,Rössler E,Piguet D,Gäggeler HW,Baltensperger U (1998) Heterogeneous production of nitrous acid on soot in polluted air masses. Nature 395:157–160

    CAS  Google Scholar 

  • Anderson LG,Lanning JA,Barrell R,Miyagishima J,Jones RH,Wolfe P (1996) Sources and sinks of formaldehyde and acetaldehyde: an analysis of Denver’s ambient concentration data. Atmos Environ 30:2113–2123

    CAS  Google Scholar 

  • Andersson-Sköld Y,Grennfelt P,Pleijel K (1992) Photochemical ozone creation potentials: a study of different concepts. J Air Waste Manage Assoc 42:1152–1158

    Google Scholar 

  • Andreani-Aksoyoglu S,Keller J (1995) Estimates of monoterpene and isoprene emissions from the forests in Switzerland. J Atmos Chem 20:71–87

    CAS  Google Scholar 

  • Andrés-Hernández MD,Notholt J,Hjorth J,Schrems O (1996) A DOAS Study on the Origin of Nitrous Acid at Urban and Non-Urban Sites. Atmos Environ 30:175–180

    Google Scholar 

  • Altshuller AP (1988) Some characteristics of ozone formation in the urban plume of St. Louis,MO. Atmos Environ 22:499–510

    CAS  Google Scholar 

  • Arey J,Atkinson R,Aschmann SM (1990) Product study of the gas phase reactions of monoterpenes with the OH radical in the presence of NOS. J Geo Phys Res 95:18539–18546

    CAS  Google Scholar 

  • Arnold F,Bürger V,Droste-Franke B,Grimm F,Krieger A,Schneider J,Stilp T (1997) Acetone in the upper troposphere and lower stratosphere: impact on trace gases and aerosols. Geo Phys Res Lett 24:3017–3020

    CAS  Google Scholar 

  • Aschmann SM,Atkinson R (1994) Formation yields of methyl vinyl ketone and methacrolein from the gas-phase reaction of 03with isoprene. Environ Sci Techn 28:1539–1542

    CAS  Google Scholar 

  • ATAL (1997) Luftschadstoffe im Kanton Zürich,Messbericht Immissionen II/1996,Amt für Technische Anlagen and Lufthygiene des Kantons Zürich,Schweiz

    Google Scholar 

  • Atkinson R (1989) Kinetics and mechanisms of the gas-phase reactions of the hy-droxyl radical with organic compounds. J Phys Chem Ref Data,monograph 1

    Google Scholar 

  • Atkinson R (1994) Gas-phase tropospheric chemistry of organic compounds. J Phys Chem Ref Data,monograph 2

    Google Scholar 

  • Atkinson R (1997a) Gas-phase tropospheric chemistry of volatile organic com-pounds. 1. Alkanes and alkenes. J Phys Chem Ref Data 26:215–290

    CAS  Google Scholar 

  • Atkinson R (1997b) Atmospheric reactions of alkoxy and ß-hydroxyalkoxy radi-cals. Int J Chem Kinet 29:99–111

    CAS  Google Scholar 

  • Atkinson R,Aschmann SM (1993a) OH radical production from the gas-phase reactions of 03with a series of alkenes under atmospheric conditions. Environ Sci Technol 27:1357–1363

    CAS  Google Scholar 

  • Atkinson R,Aschmann SM (1993b) Atmospheric chemistry of the monoterpene reaction products nopinone,camphenilone,and 4-acetyl-1-methylcyclohexene. J Atmos Chem 16:337–348

    CAS  Google Scholar 

  • Atkinson R,Aschmann SM (1994) Products of the gas-phase reactions of aromatic hydrocarbons: effect of NO2concentration. Int J Chem Kinet 26:929–944

    CAS  Google Scholar 

  • Atkinson R,Aschmann SM (1995) Alkoxy radical isomerization products from the gas-phase OH radical-initiated reactions of 2,4-dimethyl-2-pentanol and 3,5-dimethyl-3-hexanol. Environ Sci. Technol. 29:528–536

    CAS  Google Scholar 

  • Atkinson R,Aschmann SM,Arey J,Shorees B (1992) Formation of OH radicals in the gas phase reactions of 03with a series of terpenes. J Geo Phys Res 97:6065–6073

    CAS  Google Scholar 

  • Atkinson R,Baulch DL,Cox RA,Hampson RF Jr,Kerr JA,Rossi MJ,Troe J (1996) Evaluated kinetic and photochemical data for atmospheric chemistry: supplement V. Atmos Environ 30

    Google Scholar 

  • Ayers GP,Penkett SA,Gillett RW,Bandy B,Gallbally IE,Meyer CP,Elsworth CM,Bently ST,Forgan BW (1992) Evidence for photochemical control of ozone concentrations in unpolluted marine air. Nature 360:446–448

    CAS  Google Scholar 

  • Ayers GP,Penkett SA,Gillett RW,Bandy B,Gallbally IE,Meyer CP,Elsworth CM,Bently ST,Forgan BW (1996) The annual cycle of peroxides and ozone in marine air at Cape Grim,Tasmania. J Atmos Chem 23:221–252

    CAS  Google Scholar 

  • Baltensperger U,Gäggeler HW,Jost DT,Lugauer M,Schwikowski M,Weingartner E,Seibert P (1997) Aerosol climatology at the high-alpine site Jungfraujoch,Switzerland. J Geo Phys Res 102:19707–19715

    Google Scholar 

  • Barnes I,Bastian V,Becker KH,Niki H (1987) FTIR spectroscopy studies of the CH3S + NO2reaction under atmospheric conditions. Chem Phys Lett 140:451–457

    CAS  Google Scholar 

  • Barnes I,Bastian V,Becker KH (1988) Kinetics and mechanism of the reaction of OH radicals with dimethyl sulfide. Int J Chem Kinet 20:415–431

    CAS  Google Scholar 

  • Barnes I,Bastian V,Becker KH,Martin D (1989) Fourier transform IR studies of the reactions of dimethyl sulfoxide with OH,NO3and Cl radicals. In: Biogenic sulfur in the environment. ACS Symp Ser 393:476–488

    Google Scholar 

  • Barnes I,Bastian V,Becker KH,Overath RD (1991) Kinetic studies of IO,BrO and C1O with dimethylsulfide. Int. J Chem Kinet 23:579–591

    CAS  Google Scholar 

  • Barnes I,Becker KH,Patroescu I (1994a) The tropospheric oxidation of dimethyl sulfide: a new source of carbonyl sulfide. Geo Phys Res Lett 21:2389–2392

    CAS  Google Scholar 

  • Barnes I,Becker KH,Mihalopoulos N (1994b) An FTIR product study of the photooxidation of dimethyl disulfide. J Atmos Chem 18:267–289

    CAS  Google Scholar 

  • Barnes I,Becker KH,Patroescu I (1995) FT-IR Product study of the OH-initiated oxidation of dimethyl sulphide: observation of carbonyl sulphide and dimethyl sulphoxide. J Atmos Chem 30:1805–1814

    Google Scholar 

  • Barnes I,Becker KH,Klotz B (1996a) A new mechanism for the gas-phase photo-oxidation of aromatic hydrocarbons involving the formation of benzene oxide/ oxepin,In: Borell et al (eds) Transport and transformation of pollutants in the troposphere,vol 2. Computational Mechanics,Southampton,pp 599–605

    Google Scholar 

  • Barnes I,Klotz B,Becker KH (1996b) Aromatic hydrocarbon oxidation mechanisms: new developments,paper 96-RP130A.01 presented at the Air and Waste Management Association,89th annual meeting and exhibition,Nashville,Tenesse,23–28 June

    Google Scholar 

  • Barnes I,Becker KH,Goling BT,Klotz B (1996c) Atmospheric chemistry of benzene oxide/oxepine: a possible intermediate in the photooxidation of aromatic hydrocarbons. Faraday Trans (submitted)

    Google Scholar 

  • Barone SB,Turnipseed AA,Ravishankara AR (1995) Role of adducts in the atmospheric oxidation of dimethyl sulfide. Faraday Discuss 100:39–54

    CAS  Google Scholar 

  • Barrie L,Platt U (1997) Arctic tropospheric chemistry: an overview. Tellus B 49:450–454

    Google Scholar 

  • Bartolotti LJ,Edney EO (1995) Density functional theory derived intermediates from the OH initiated atmospheric oxidation of toluene. Chem Phys Lett 245:119–122

    CAS  Google Scholar 

  • Bates TM,Charlson RJ,Gammom MH (1987) Evidence for the climate role of marine biogenic sulphur. Nature 329:319–321

    CAS  Google Scholar 

  • Baumbauer A,Brantner B,Paige M,Novakov T (1994) Laboratory study of NO2reaction with dispersed and bulk liquid water. Atmos Environ 28:3225–3232

    Google Scholar 

  • Becker KH,Fricke W,Löbel J,Schurath U (1985) Part 1: formation,transport,and control of photochemical oxidants. In: Guderian R (ed) Air pollution by photochemical oxidants. Springer,Berlin Heidelberg New York,pp 3–125

    Google Scholar 

  • Becker KH,Brockmann KJ,Bechara J (1990) Production of hydrogen peroxide in forest air by reaction of ozone with terpenes. Nature 346:256–258

    CAS  Google Scholar 

  • Becker KH,Bechara J,Brockmann KJ (1991) Studies on the formation of H2O2in the ozonolysis of alkenes. Atmos Environ 27:57–61

    Google Scholar 

  • Becker KH (1994) The atmospheric oxidation of aromatic hydrocarbons and its impact on photooxidant chemistry. In: Borrell PM,Borrell P,Cvitas T,Seiler W (eds) EUROTAC symposium ‘84 „transport and transformation of pollutants in the troposphere“,11–15 April 1994,Garmisch-Partenkirchen. SPB Academic,Den Haag,pp 67–74

    Google Scholar 

  • Bedjanian Y,Poulet G,Le Bras G (1996) Kinetic study of the reaction of BrO radicals with dimethylsulfide. Int J Chem Kinet 28:383–389

    CAS  Google Scholar 

  • Bergin MS,Russell AG,Milford JB (1995) Quantification of individual VOC reactivity using a chemically detailed three-dimensional photochemical model. Environ Sci Technol 29:3029–3037

    CAS  Google Scholar 

  • Bierbach A,Barnes I,Becker KH,Wiesen E (1994) Atmospheric chemistry of unsaturated carbonyls: butenedial,4-Oxo-2-pentenal,3-hexene-2,5,-dione,maleic anhydride,3H-furan-2-one,and 5-methyl-3H-furan-2-one. Environ Sci Techn 28:715–729

    CAS  Google Scholar 

  • Borrell P,Builtjies PJH,Grennfelt P,Hoy O (eds) (1997) Photo-oxidants,acidification and tools: policy applications of the EUROTRAC results,transport and chemical transformation of pollutants in the troposphere,vol 10. Springer,Berlin Heidelberg New York

    Google Scholar 

  • Bottenheim JW,Gallant AJ (1986) Measurements of NOyspecies and 03at 82°N latitude. Geo Phys Res Lett 13:113–116

    CAS  Google Scholar 

  • Boutron CF (ed) (1994) Topics in atmospheric and interstellar physics and chemistry,les editions de physique les ulis (ISBN 2–86883–241–5)

    Google Scholar 

  • Brauers T,Aschmutat U,Brandenburger U,Dorn H-P,Hausmann M,Hessling M,Hofzumahaus A,Holland F,Plass-Dülmer C,Ehhalt DH (1996) Intercomparison of tropospheric OH radical measurements by multiple folded long-path laser absorption and laser induced fluorescence. Geo Phys Res Lett 23:2545–2548

    CAS  Google Scholar 

  • Brimblecombe P (1987) The big smoke. Methuen,London

    Google Scholar 

  • Broder B,Gygax HA (1985) The influence of locally induced wind systems on the effectiveness of nocturnal dry deposition of ozone. Atmos Environ 19:1627–1637

    CAS  Google Scholar 

  • Brasseur GP,Cox RA,Hauglustaine D,Isaksen I,Lelieveld J,Lister DH,Sausen R,Schumann U,Wahner A,Wiesen P (1998) European scientific assessment of the atmospheric effects of aircraft emissions. Atmos Environ 32:2329–2418

    CAS  Google Scholar 

  • Brunner D,Staehelin J,Jeker J (1998) Large-scale nitrogen oxide plumes in the tropopause region and implications for ozone. Science 282:1305–1309

    CAS  Google Scholar 

  • Bucher-Renner P (1992) Wasserstoffperoxid in der bodennahen Atmosphäre eines voralpinen Standortes,Inauguraldisseratation,Universität Zürich

    Google Scholar 

  • Butkovskaya NI,Le Bras G (1994) Mechanism of the NO3+DMS reaction by discharge flow mass spectrometry. J Phys Chem 98:2582–2591

    CAS  Google Scholar 

  • BUWAL (1995) Vom Menschen verursachte Luftschadstoff-Emissionen in der Schweiz von 1900 bis 2010,Schriftenreihe Umwelt Nr. 256,Bundesamt für Umwelt,Wald und Landschaft (Bern)

    Google Scholar 

  • Calvert JG,Yarwood G,Dunker AM (1994) An evaluation of the mechanism of nitrous acid formation in the urban atmosphere. Res Chem Intermed 20:463–502

    CAS  Google Scholar 

  • Cape JN,Storeton-West RL,Devine SF,Beatty RN,Murdoch A (1993) The reaction of nitrogen dioxide at low concentrations with natural waters. Atmos Environ 27A:2613–2621

    CAS  Google Scholar 

  • Carter WPL (1994) Development of ozone reactivity scales for volatile organic compounds. J Air Waste Manag Assoc 44:881–899

    CAS  Google Scholar 

  • Carter WPL (1995) Computer modeling of environmental chamber measurements of maximum incremental reactivities of volatile organic compounds. Atmos Environ 29:2513–2527

    CAS  Google Scholar 

  • Carter WPL,Atkinson R (1987a) An experimental study of incremental hydrocarbon reactivity. Environ Sci Technol 21:670–679

    CAS  Google Scholar 

  • Carter WPL,Atkinson R (1987b) Computer modeling study of incremental hydrocarbon reactivity. Environ Sci Technol 23:864–880

    Google Scholar 

  • Carter WPL,Atkinson R (1996) Development and evaluation of a detailed mechanism for the atmospheric reactions of Isoprene and NOR. Int J Chem Kinet 28:497–530

    CAS  Google Scholar 

  • Carter WPL,Atkinson R,Winer AM,Pitts JN Jr (1982) Experimental investiga-tion of chamber-dependent radical source. Int J Chem Kinet 14:1071–1103

    CAS  Google Scholar 

  • Carter WPL,Pierce JA,Luo D,Malkina IL (1995) Environmental chamber study of maximum incremental reactivities of volatile organic compounds. Atmos Environ 29:2499–2511

    CAS  Google Scholar 

  • Chang TY,Rudy SJ (1990) Ozone-forming potential of organic emissions from alternative-fueled vehicles. Atmos Environ 24:2421–2430

    Google Scholar 

  • Chai X,Mohnen VA (1997) Whiteface Mountain ozone and sulfate: an investigation of the background concentrations representative for the northern United States. Atmos Environ (in press)

    Google Scholar 

  • Charlson RJ,Lovelock JE,Andreae MO,Warren SG (1987) Oceanic phytoplankton,atmospheric sulfur,cloud albedo,and climate. Nature 326:655–661

    CAS  Google Scholar 

  • Charlson RJ,Schwarz SE,Hales JM,Cess RD,Coakley JA.Jr,Hansen JE,Hoffman DJ (1992) Climate forcing by anthropogenic aerosols. Science 255:423–430

    CAS  Google Scholar 

  • Chebbi A,Carlier P (1996) Carboxylic acids in the troposphere,occurrence,sources,and sinks: a review. Atmos Environ 30:4233–4249

    CAS  Google Scholar 

  • Coacley JA Jr,Bernstein RL,Durkee PA (1987) Effect of ship-stack effluents on cloud reflectivity. Science 237:1020–1022

    Google Scholar 

  • Cooper DJ (1996) Estimation of hydroxyl radical concentrations in the marine atmospheric boundary layer using a reactive atmospheric tracer. J Atmos Chem 25:97–113

    CAS  Google Scholar 

  • Cox RA,Eggleton AEJ,Derwent RG,Lovelock JE,Pack DH (1975) Long range trans-port of photochemical ozone in north-western Europe. Nature 255:118–121

    CAS  Google Scholar 

  • Criegee R (1975) Mechanismus der Ozonolyse. Angew Chem 87:765–771

    CAS  Google Scholar 

  • DeMore WP,Sander SP,Golden DM,Hampson RF,Kurylo MJ,Howard CJ,Ravishankara AR,Kolb CE,Molina MJ (1997) Chemical kinetics and photochemical data for use in stratospheric modeling. JPL Publication,pp 97–94

    Google Scholar 

  • De Muer D,De Backer H (1992) Revision of 20 years of Dobson total ozone data at Uccle (Belgium): fictitious Dobson total ozone trends induced by sulfur dioxide trends. J Geopys Res 97:5921–5937

    Google Scholar 

  • Derwent RG,Jenkin ME (1991) Hydrocarbons and the long-range transport of ozone and PAN across Europe. Atmos Environ 25A:1661–1678

    CAS  Google Scholar 

  • Derwent RG,Jenkin ME,Saunders SM (1996) Photochemical ozone creation potentials for a large number of reactive hydrocarbons under European conditions. Atmos Environ 30:181–199

    CAS  Google Scholar 

  • Dominé F,Murrells TP,Howard CJ (1990) Kinetics of the reactions of NO2with CH3S,CH3SO,CH3SS and CH3SSO at 297 K and 1 Torr. J Phys Chem 94:5839–5847

    Google Scholar 

  • Dominé F,Ravishankara AR,Howard CJ (1992) Kinetics and mechanisms of the reactions of CH3S,CH3SS,CH3SO and CH3SSO with 03at 300 K and low pressures. J Phys Chem 96:2171–2178

    Google Scholar 

  • Döscher A,Gäggeler HW,Schotterer U,Schwikowski M (1995) A 130 years deposition record of sulfate,nitrate and chloride from a high-alpine Glacier. Water Air Soil Pollut 85:603–609

    Google Scholar 

  • Dorn H-P,Brandenburger U,Brauers T,Hausmann M,Ehhalt DH (1996) In-situ detection of tropospheric OH radicals by folded long-path laser absorption. Results from the POPCORN field campaign in August 1994. Geo Phys Res Lett 23:2537–2540

    CAS  Google Scholar 

  • Emmons LK,Caroll MA,Hauglustaine DA,Brasseur GP,Atherton C,Penner J,Sill-man S,Levy H II,Rohrer F,Wauben WMF,Van Velthoven PFJ,Wang Y,Jacob D,Bakwin P,Dickerson R,Doddridge B,Gerbig C,Honrath R,Hübler G,Jaffe D,Kondo,Y,Munger JW,Torres A,Volz-Thomas A (1997) Climatologies of NO and NOy: a comparison of data and models. Atmos Environ 31:1851–1904

    CAS  Google Scholar 

  • EMPA (1994) Technischer Bericht zum Nationalen Beobachtungsnetz für Luftfremdstoffe (NABEL) 1994. Eidgenössische Materialprüfungs-und Forschungsanstalt,Dübendorf,Schweiz

    Google Scholar 

  • Febo A (1994) Nitrous acid in the oxidation processes in urban areas. In: Restelli G,Angeletti G (eds) Physico-chemical behaviour of atmospheric pollutants,report EUR 15609/1 EN,vol 1. Luxembourg,pp 277–286

    Google Scholar 

  • Febo A,Perrino C,Cortiello M (1993) A denuder technique for the measurement of nitrous acid in urban atmospheres. Atmos Environ 27A:1721–1728

    CAS  Google Scholar 

  • Febo A,Perrino C,Allegrini I (1996) Measurement of nitrous acid in Milan,Italy,by DOAS and diffusion denuders. Atmos Environ 30:3599–3609

    CAS  Google Scholar 

  • Feister W,Warmbt W (1987) Long-term measurements of surface ozone in the German Democratic Republic. J Atmos Chem 5:1–21

    CAS  Google Scholar 

  • Flocke F,Volz-Thomas A,Kley D (1994) The use of alkyl nitrate measurements for the characterization of the ozone balance at TOR station No. 11,Schauinsland. In: Boren et al (eds) Proc Eurotrac Symp 94:243–247

    Google Scholar 

  • Flocke F,Volz-Thomas A,Buers H-J,Pätz W,Garthe H-J,Kley D (1998) Longterm measurements of alkyl nitrates in southern Germany 1. General behavior and seasonal and diurnal variation. J Geo Phys Res 103:5729–5746

    CAS  Google Scholar 

  • Finlayson-Pitts BJ,Pitts JN Jr (1986) Atmospheric chemistry. Wiley,New York

    Google Scholar 

  • Fiori AM,Jacob DJ,Logan JA,Yin JH (1998) Long-term trends in ground level ozone over the contiguous United States,1980–1995 (1998) J Geo Phys Res 103:1471–1480

    Google Scholar 

  • Förderer L,Maly P,Wolf M,Bitter T,Maly P (1996) Trendanalyse schweizerischer Luftschadstoff-Immissionsdaten. Umweltmaterialien 53,Bundesamt für Umwelt,Wald und Landschaft (BUWAL),Bern

    Google Scholar 

  • Forstner HJL,Flagan RC,Seinfeld J (1997) Secondary organic aerosol from the photooxidation of aromatic hydrocarbons: Molecular composition. Environ Sci Techn 31:1345–1358

    CAS  Google Scholar 

  • Fouquart Y,Isaka H (1992) Sulfur emission,CCN,clouds and climate - a review. Ann Geo Phys Atmos Hydro Space Sci 10:462–471

    CAS  Google Scholar 

  • Gab S,Hellpointer E,Turner WV,Korte F (1985) Hydroxymethyl hydroperoxide and bis(hydroxymethyl) peroxide from gas-phase ozonolysis of naturally occurring alkenes. Atmos Environ 18:2401–2407

    Google Scholar 

  • Gäb S,Turner WV,Wolff S,Becker KH,Ruppert L,Brockmann K (1995) Formation of alkyl and hydroxyalkyl hydroperoxides on ozonolysis in water and in air. Atmos Environ 18:2401–2407

    Google Scholar 

  • Gao D,Stockwell WR,Milford JB (1995) First-order sensitivity and uncertainty analysis for a regional-scale gas-phase chemical mechanism. J Geo Phys Res 100:23153–23166

    CAS  Google Scholar 

  • Gerecke A,Thielmann A,Gutzwiller L,Rossi MJ (1998) The chemical kinetics of HONO fornation resulting from heterogenous interaction of NO2with flame soot. Geo Phys Res Lett 25:2453–2456

    CAS  Google Scholar 

  • Glasius M,Calogirou A,Jensen NR,Hjorth J,Nielsen CJ (1997) Kinetic study of gas phase reactions of pinonaldehyde and structurally related compounds. Int J Chem Kinet 29:527–533

    CAS  Google Scholar 

  • Glen WR,Zelenka MP,Graham RC (1996) Relating meteorological variables and trends in motor vehicle emissions to monthly urban carbon monoxide concentrations. Atmos Environ 30:4225–4232

    CAS  Google Scholar 

  • Graedel TE (1978) Chemical compounds in the atmosphere. Academic,New York Graedel TE,Hawkins DT,Claxton LC (1986) Atmospheric chemical compounds. Sources,occurrence,and bioassay. Academic,London

    Google Scholar 

  • Granby K,Christensen CS,Lohse C (1997a) Urban and semi-rural observations of carboxylic acids and carbonyls. Atmos Environ 31:1403–1415

    CAS  Google Scholar 

  • Granby K,Egelov AH,Nielsen T,Lohse C (1997b) Carboxylic acids: seasonal variation and relation to chemical and meteorological parameters. J Atmos Chem 28:195–207

    CAS  Google Scholar 

  • Grosjean E,Grosjean D (1997) Gas phase reaction of alkenes with ozone: formation yields of primary cabonyls and biradicals. Environ Sci Techn 31:2421–2427

    CAS  Google Scholar 

  • Grosjean D,Williams EL,Seinfeld JH (1992) Atmospheric oxidation of selected terpenes and related carbonyls: gas-phase carbonyl products. Environ Sci Technol 26:1526–1533

    CAS  Google Scholar 

  • Grosjean D,Williams EL,Grosjean E (1993a) Peroxyacyl nitrates at Southern California mountain forest locations. Environ Sci Technol 27:110–121

    CAS  Google Scholar 

  • Grosjean D,Williams EL,Grosjean E (1993b) Ambient levels of peroxy-n-butyryl nitrate at Southern California moutain forest smog receptor location. Environ Sci Technol 27:326–331

    CAS  Google Scholar 

  • Grosjean D,Williams EL,Grosjean E (1993c) Atmospheric chemistry of isoprene and of its carbonyl products. Environ Sci Technol 27:830–840

    CAS  Google Scholar 

  • Grosjean D,Williams EL,Grosjean E,Andino JM,Seinfeld JH (1993d) Atmospheric oxidation of biogenic hydrocarbons: reaction of ozone with /3-pinene,A-limonene and trans-caryophyllene. Environ Sci Technol 27:2754–2758

    CAS  Google Scholar 

  • Grosjean E,Grosjean D,Fraser MP,Cass GR (1996a) Air quality model evaluations data for organics. 2. C1–C14 carbonyls in Los Angeles air. Environ Sci Techn 30:2687–2703

    CAS  Google Scholar 

  • Grosjean E,Grosjean D,Fraser MP,Cass GR (1996b) Air quality model evaluations data for organics. 3. Peroxyacetyl nitrate and peroxypropionylnitrate in Los Angeles air. Environ Sci Techn 30:2704–2714

    CAS  Google Scholar 

  • Guderian R,Tingey DT,Rabe R (1985) Effects of photochemical oxidants on plants. In: Guderian R (ed) Air pollution by photochemical oxidants. Springer,Berlin Heidelberg New York

    Google Scholar 

  • Guenther AB,Zimmerman PR,Wildermuth M (1994) Natural volatile organic compound emission rate estimates for US woodland landscapes. Atmos Environ 28:1197–1210

    CAS  Google Scholar 

  • Guenther A,Hewitt CN,Erickson D,Fall R,Geron C,Graedel T,Harley P,Klinger L,Lerdau M,Pierce T,Scholes B,Steinbrecher R,Tallamraju R,Taylor J,Zimmerman P (1995) A global model of natural organic compound emissions. J Geo Phys Res 100:8873–8892

    CAS  Google Scholar 

  • Haagen-Smit AJ (1952) Chemistry and physiology of Los Angeles smog. Ind Eng Chem 44:1342–1346

    CAS  Google Scholar 

  • Haagen-Smit AJ,Darley EF,Zaitlin M,Hull H,Noble W (1952) Investigation of injury of plants from air pollution in the Los Angeles area. Plant Physiol 27:18–34

    CAS  Google Scholar 

  • Hakola H,Shorees B,Arey J,Atkinson R (1993) Product formation from the gas-phase reactions of OH radicals and 03with ß-phellandrene. Environ Sci Technol 27:278–283

    CAS  Google Scholar 

  • Hakola H,Arey J,Aschmann SM,Atkinson R (1994) Product formation from the gas-phase reactions of OH radicals and 03with a series of monoterpenes. J Atmos Chem 18:75–102

    CAS  Google Scholar 

  • Hallquist M,Wängberg I,Ljungström E (1996) Atmospheric chemistry of dicarbonyl products from the atmospheric oxidation of selected terpenes,poster presented at the 7th European symposium on physico-chemical behaviour of atmospheric pollutants,Venice (I),2–4 Oct 1996

    Google Scholar 

  • Hanna SR,Strimaitis DG,Scire JS,Moore GE,Kessler RC (1991) Overview of results of analysis of data from the South-Central Coast Cooperative Aerometric Monitoring program (SCCCAMP). J Appl Met 30:511–533

    Google Scholar 

  • Harris GW,Carter WPL,Winer AM,Pitts JN Jr,Platt U,Perner D (1982) Observations of nitrous acid in the Los Angeles atmosphere and implications for predictions of ozone-precursor relationships. Environ Sci Techn 16:414–418

    CAS  Google Scholar 

  • Harrison RM,Kitto A-MN (1994) Evidence for a surface source of atmospheric nitrous acid. Atmos Environ 28:1089–1094

    CAS  Google Scholar 

  • Harrison RM,Peak JD,Collins GM (1996a) Tropospheric cycle of nitrous acid. J Geo Phys Res 101:14429–14439

    CAS  Google Scholar 

  • Harrison RH,Peak JD,Kaye AD (1996b) Atmospheric aerosol major ion composition and cloud condensation nuclei over the northeast atlantic. J Geo Phys Res 101:4425–4434

    CAS  Google Scholar 

  • Hatakeyama S,Izumi K,Akimoto H (1985) Yield of SO2and formation of aerosol in the photo-oxidation of DMS unter atmospheric conditions. Atmos Environ 19:583–586

    Google Scholar 

  • Hatakeyama S,Izumi K,Fukuyama T,Akimoto H (1989) Reactions of ozone with a-pinene and ß-pinene in air: yields of gaseous and particulate products. J Geo Phys Res 94:13013–13024

    CAS  Google Scholar 

  • Hatakeyama S,Izumi K,Fukuyama T,Akimoto H,Washida N (1991) Reactions of OH with a-pinene and ß-pinene in air: estimate of global CO production from the atmospheric oxidation of terpenes. J Geo Phys Res 96:947–958

    Google Scholar 

  • Hellpointner E,Gäb S (1989) Detection of methyl,hydroxymethyl and hydroxyethyl hydroperoxides in air and precipitation. Nature 337:613–634

    Google Scholar 

  • Hegg DA,Ferek RJ,Hobbs PV (1993) Light scattering and cloud condensation nucleus activity of sulfate aerosol measured over the Northeast Atlantic Ocean. J Geo Phys Res 98:14887–14894

    Google Scholar 

  • Hewitt CN,Kok GL (1991) Formation and occurrence of organic hydroperoxides in the troposphere: laboratory and field observations. J Atmos Chem 12:181–194

    CAS  Google Scholar 

  • Hewitt CN,Street RA (1992) A qualitative assessement of the emission of non-methane hydrocarbon compounds from the biosphere to the atmosphere in the UK: present knowledge and uncertainties. Atmos Environ 26A:3069–3077

    CAS  Google Scholar 

  • Hoekman SK (1992) Speciated measurements and calculated reactivities of vehicle exhaust emissions from conventional and reformulated gasolines. Environ Sci Technol 26:1206–1216

    CAS  Google Scholar 

  • Hofzumahaus A,Aschmutat U,Hessling M,Holland F,Ehhalt DH (1996) The measurement of tropospheric OH radicals by laser induced fluorescence spectroscopy during the POPCORN field campaign. Geo Phys Res Lett 23:25412544

    Google Scholar 

  • Holton JR,Haynes PH,McIntyre ME,Douglass AR,Rood RB,Pfister L (1995) Stratosphere-troposphere exchange. Rev Geo Phys 33:403–439

    Google Scholar 

  • Hu J,Stedman DH (1995) Atmospheric ROXradicals at an urban site: comparison to a simple theoretical model. Environ Sci Technol 29:1655–1659

    CAS  Google Scholar 

  • Hynes AJ,Wine PH (1996) The atmospheric chemistry of dimethyl sulfoxide (DMSO) kinetics and mechanism of the OH+DMSO reaction. J Atmos Chem 24:23–37

    CAS  Google Scholar 

  • Hynes AJ,Wine PH,Semmes DH (1986) Kinetics and mechanism of OH reactions with organic sulfides. J Phys Chem 90:4148–4156

    CAS  Google Scholar 

  • Jacob DJ (1986) Chemistry of OH in remote clouds and its role in production of formic acid and peroxymonosulfate. J Geo Phys Res 91:9807–9812

    CAS  Google Scholar 

  • Jenkin ME,Cox RA,Williams DJ (1988) Laboratory studies of the kinetics of formation of nitrous acid from the thermal reaction of nitrogen dioxide and water vapour. Atmos Environ 22:487–498

    CAS  Google Scholar 

  • Jensen NR,Hjorth J,Lohse C,Skov H,Restelli G (1992) Products and mechanism of the gas phase reactions of NO3with CH3SCH3 CD3SCD3 CH3SH and CH3SSCH3. J Atmos Chem 14:95–108

    CAS  Google Scholar 

  • Jobson BT,Niki H,Yokouchi Y,Bottenheim J,Hopper F,Leaitch R (1994) Measurements of C2–C6 hydrocarbons during the polar sunrise 1992 experiment: evidence for Cl atom and Br atopm chemistry. J Geo Phys Res 99:25355–25368

    Google Scholar 

  • IPCC (1995) Intergovernmental panel on climate change,climate change 1994,radiative forcing of climate change and an evaluation of the IS92 emission scenarios (ed by Houghton et al). University Press, Cambridge

    Google Scholar 

  • Junge (1963) Chemistry and radioactivity. Academic,New York

    Google Scholar 

  • Junkermann W,Ibusuki TT (1992) FTIR spectroscopic measurements of surface bond products of nitrogen oxides on aerosol surfaces - implications for heterogeneous HONO production. Atmos Environ 26A:3099–3103

    CAS  Google Scholar 

  • Kalberer M,Tabor K,Ammann M,Parrat Y,Weingartenr E,Piguet D,Rösseler E,Jost DT,Türler A,Gäggeler HW,Baltensperger U (1996) Heterogeneous chemical processing of13NO2by monodisperse carbon aerosols at very low concentrations. J Phys Chem 100:15487–15493

    CAS  Google Scholar 

  • Kasibhatla PS,Levy II H,Moxim WJ,Chameides WL (1991) The relative impact of stratospheric photochemical production on tropospheric NOy levels: a model study. J Geo Phys Res 96:18631–18646

    Google Scholar 

  • Kesselmeier J,Schäfer L,Ciccioli P,Brancaleoni E,Cecinato A,Frattoni M,Foster P,Jacob V,Denis J,Fugit JL,Dutaur L,Torres L (1996) Emission of monoterpenes and isoprene from a mediterranean oak species quercus ilex L. Measured within the BEMA (Biogenic Emissions in the Mediterranean Area) Project. Atmos Environ 30:1841–1850

    CAS  Google Scholar 

  • Khwaja HA (1995) Atmospheric concentrations of carboxylic acids and related compounds at a semiurban site. Atmos Environ 29:127–139

    CAS  Google Scholar 

  • Killus JP,Whitten GZ (1990) Background reactivity in smog chambers. Int J Chem Kinet 22:547–575

    CAS  Google Scholar 

  • Kirchstetter ThW,Harley RA,Littlejohn D (1996) Measurement of nitrous acid in motor vehicle exhaust. Environ Sci Technol 30:2843–2849

    CAS  Google Scholar 

  • Kleffmann J,Becker KH,Wiesen P (1998) Heterogeneous conversion processes on acid surfaces: possible atmospheric implications. Atmos Environ 32:2721–2729

    CAS  Google Scholar 

  • Kleinman LI (1991) Seasonal dependence of boundary layer peroxide concentra-tion: the low and the high NO regimes. J Geo phys Res 96:20721–20733

    CAS  Google Scholar 

  • Kleinman LI (1994) Low and the high NO tropospheric photochemsitry. J Geo Phys Res 99:16831–16838

    CAS  Google Scholar 

  • Kleiman L,Lee Y-N,Springston SR,Nunnermacker L,Zhou X,Brown R,Hallock K,Klotz P,Leahy D,Lee JH,Newman L (1994) Ozone formation at a rural site in the southeastern United States. J Geo Phys Res 99:3469–3482

    Google Scholar 

  • Klemm O,Ziomas IC,Balis D,Suppan P,Slemr J,Romero R,Vyras LG (1998) A summer air-pollution study in Athens,Greece. Atmos Environ 32:2071–2078

    CAS  Google Scholar 

  • Klemp D,Kley D,Kramp F,Buers HJ,Pilwat G,Flocke F,Pätz HW,Volz-Thomas A (1997) Long-term measurements of light hydrocarbons (C2-05) at the Schauinsland (Black Forest). J Atmos Chem 28:135–171

    CAS  Google Scholar 

  • Klotz B,Barnes I,Becker KH,Golding BT (1997) Atmospheric chemistry of benzene oxide/oxepin. J Chem Soc Faraday Trans 93:1507–1516

    CAS  Google Scholar 

  • Klotz B,Sorensen S,Barnes I,Becker KH,Etzkorn T,Volkamer R,Platt U,Wirtz K,Martin-Revifjo M (1998) Atmospheric oxidation of toluene in a large volume outor photoreactor: In situ determination of ring-retaining product yileds. J Phys Chem (in press)

    Google Scholar 

  • Knispel R,Koch R,Siese M,Zetzsch C (1990) Adduct formation of OH radicals with benzene,toluene,and phenol and consecutive reactions of the adducts with NO,,and 02. Ber Bunsenges Phys Chem 94:1375–1379

    CAS  Google Scholar 

  • Kley D,Volz A,Mülheims F (1988) Ozone measurements in historic perspective. In: Isaksen ISA (ed) Tropospheric ozone. Reidel,Dodrecht,pp 63–73

    Google Scholar 

  • Kourtidis KA,Fabian P,Zerefos C,Rappenglück B (1993) Peroxyacetyl nitrate (PAN),peroxypropionyl nitrate (PPN) and PAN/ozone ratio measurements at three sites in Germany. Tellus 45B:442–457

    CAS  Google Scholar 

  • Kramp F,Volz-Thomas A (1997) On the budget of OH radicals and ozone in an urban plume from the decay of C5-C8hydrocarbons and NO R J Atmos Chem 28:263–282

    CAS  Google Scholar 

  • Kreher K,Johnston PV,Wood SW,Nardi B,Platt U (1997) Ground-based measurement of tropospheric and stratospheric BrO at Arrival Heights,Antarctica. Geo Phys Res Lett 24:3021–3024

    CAS  Google Scholar 

  • Kuchler W (1997) Jahresbericht der Immissionssituation im Freiland Sachsen,Jahresbericht 1996

    Google Scholar 

  • Kumar N,Kulshrestha UC,Khare P,Saxena A,Kumari KM,Srivastava SS (1996) Measurements of formic and acetic acid levels in the vapour phase at Dayalbagh,Agra,India. Atmos Environ 30:3545–3550

    CAS  Google Scholar 

  • Kwok ESC,Atkinson R,Arey J (1995) Observation of hydroxycarbonyls from the OH radical-initiated reaction of isoprene. Environ Sci Technol 29:2467–2469

    CAS  Google Scholar 

  • Lacis AA,Wuebbles DJ,Logan JA (1990) Radiative forcing of climate by changes in the vertical distribution of ozone. J Geo Phys Res 95:9971–9981

    Google Scholar 

  • Langner J,Rohde H,Crutzen PJ,Zimmermann P (1992) Anthropogenic influence on the distribution of tropopspheric sulphate aerosol. Nature 359:712–716

    CAS  Google Scholar 

  • Lamb BK,Guenther AB,Gay D,Westberg HH (1987) A national inventory of biogenic hydrocarbon emissions. Atmos Environ 21:1695–1705

    CAS  Google Scholar 

  • Lammel G (1988) Salpetrige Säure und Nitrit im Mehrphasensystem der belasteten Atmosphäre. Dissertation,Universität Mainz

    Google Scholar 

  • Lammel G,Cape JN (1996) Nitrous acid and nitrite in the atmosphere. Chem Soc Rev 25:361–369

    CAS  Google Scholar 

  • Lawrence JE,Koutrakis P (1994) Meaurement of atmospheric formic and acetic acids: methods evaluation and results from field studies. Environ Sci Technol 28: 957–964

    CAS  Google Scholar 

  • Le Bras G,Platt U (1995) A possible mechanism for combined chlorine and bromine catalyzed destruction of tropospheric ozone in the arctic. Geo Phys Res Lett 22:599–602

    Google Scholar 

  • Lee Y-N,Schwartz SE (1981) Reaction kinetics of nitrogen dioxide with liquid water at low partial pressure. J Phys Chem 85:840–848

    CAS  Google Scholar 

  • Lee J H,Leahy DF,Tang IN,Newman L (1993) Measurement and speciation of gas phase peroxides in the atmosphere. J Geo Phys Res 98:2911–2915

    Google Scholar 

  • Lee Y-N,Zhou X,Hallok K (1995) Atmospheric carbonyl compounds at a rural southeastern United State site. J Geo Phys Res 100(25):933–25944

    Google Scholar 

  • Lee SH,Akimoto H,Nakane H,Kurnosenko S,Kinjo Y (1998) Lower tropospheric ozone trend observed in 1989–1997 at Okinawa,Japan. Geo Phys Res Lett 25:1637–1640

    CAS  Google Scholar 

  • Lehning M (1996) Transport processes and regional pollutant budget over topography of varying complexity. PhD thesis,ETHZ,no 11991

    Google Scholar 

  • Lehning M (1998) The regional pollutant budget of the atmospheric boundary layer: Concept,interpretations and observational results. Meteorol Z NF 7:112–119

    Google Scholar 

  • Lehning M,Richner H,Kok GL,Neininger B (1998) Vertical exchange and regional budgets of air pollutants over densely populated areas. Atmos Environ 32:1353–1363

    CAS  Google Scholar 

  • Lemmerich J (1990) Die Entdeckung des Ozons and die ersten 100 Jahre Ozonforschung,Berliner Beiträge zur Geschichte der Naturwissenschaften and der Technik. Sigma-Verlag,Berlin

    Google Scholar 

  • Leone JA,Flagan RC,Grosjean D,Seinfield JH (1985) An outdoor smog chamber and modelling study of toluene-NOx photooxidation. Int J Chem Kinet 17:177–216

    CAS  Google Scholar 

  • Levy H Jr (1971) Normal atmosphere: large radical and formaldehyde concentrations predicted. Science 173:141–143

    CAS  Google Scholar 

  • Li S-M (1994) Equilibrium of particle nitrite with gas phase HONO: tropospheric measurements in the high arctic during polar sunrise. J Geo Phys Res 99: 25469–25478

    Google Scholar 

  • Lightfoot PD,Cox RA,Crowley JN,Destriau M,Hayman GD,Jenkin ME,Moortgat GK,Zabel F (1992) Organic peroxy radicals: kinetics,spectroscopy and tropospheric chemistry. Atmos Environ 26A:1806–1961

    Google Scholar 

  • Lin X,Chameides WL (1993) CCN Formation from DMS oxidation without SO2acting as an intermediate. Geo Phys Res Lett 20:579–582

    CAS  Google Scholar 

  • Lin X,Chameides WL,Kiang CS,Stelson AW,Berresheim H (1992) A model study of the formation of clould condensation nuclei in remote marine areas. J Geo Phys Res 97:18161–18171

    Google Scholar 

  • Littmann FE,Ford HW,Endow N (1956) Formation of ozone in the Los Angeles Atmosphere. Ind Eng Chem 48:1492–1497

    Google Scholar 

  • Liu SC,Trainer M,Fehsenfeld FC,Parrish DD,Williams EJ,Fahey DW,Hubler G,Murphy PC (1987) Ozone production in the rural troposphere and its implications for regional and global ozone distributions. J Geo Phys Res 92:4194–4207

    Google Scholar 

  • Locher R,Pfister H (1996) Ambient VOC in the centre of Zürich. In: Environmental Documentation 47. Federal Office of Environment,Forests and Landscape (FOEFL),Bern Switzerland,pp 119–122

    Google Scholar 

  • Lowi A Jr,Carter WPL (1990) A method for evaluating the atmospheric ozone impact of actual vehicle emissions. SAE technical paper series,paper no 900–710

    Google Scholar 

  • Lugauer M,Baltensperger U,Furger M,Gäggeler HW,Jost DT,Schwikowski M,Wanner H (1998) Aerosol transport to the high Alpine sites Jungfraujoch (3454) and Colle Gnifetti (4452). Tellus 50B:76–92

    Google Scholar 

  • Mage D,Ozolins G,Peterson P,Webster A,Orthofer R,Vandeweerd V,Gwynne M (1996) Urban air pollution in megacities of the world. Atmos Environ 30:681–686

    CAS  Google Scholar 

  • McConnell JC,Henderson GS,Barrie L,Bottenheim J,Niki H,Langford CH,Templeton EMJ (1992) Photochemical bromine production implicated in Arctic boundary layer ozone depletion. Nature 355:150–152

    CAS  Google Scholar 

  • Meijer GM (1976) Methode voor de bepaling van Peroxybenzoylnitraat (PBzN) in buitenlucht en enkele resultaten. Centraal laboratorium tno delft/Rapport-no CL 76/2

    Google Scholar 

  • Meijer GM,Nieboer H (1977) Determination of peroxybenzoyl nitrate (PBzN) in ambient air. VDI-Ber 270:55–56

    Google Scholar 

  • Mertes S,Wahner A (1995) Uptake of nitrogen dioxide and nitrous acid on aqueous surfaces. J Phys Chem 99:14000–14006

    CAS  Google Scholar 

  • Milford JB,Russell AG,McRae GJ (1989) A new approach to photochemical pollution control: implications of spatial patterns in pollution responses to reductions in nitrogen oxides and reactive organic gas emissions. Environ Sci Techn 23:1290–1301

    CAS  Google Scholar 

  • Milford JB,Gao D,Sillman S,Blossey P,Russell AG (1994) Total reactive nitrogen (NOy) as an indicator of the sensitivity of ozone to reductions in hydrocarbon and NO emissions. J Geo Phys Res 99:3533–3542

    CAS  Google Scholar 

  • Miyoshi A,Hatakeyama S,Washida N (1994) OH Radical-initiated photooxidation of isoprene: an estimate of global CO production. J Geo Phys Res 99:18779–18787

    Google Scholar 

  • Montzka SA,Trainer M,Angevine WA,Fehsenfeld FC (1995) Measurements of 3-methyl furan,methyl vinyl ketone,and methacrolein at a rural forested site in the southeastern United States. J Geo Phys Res 100:11393–11401

    CAS  Google Scholar 

  • Moortgat GK (ed) (1996) Laboratory studies on the tropospheric degradation mechanism of biogenic VOCs: isoprene and DMS,EC-Project EV5V-CT91–0038,final report

    Google Scholar 

  • Müller JF (1992) Geographical distribution and seasonal variation of surface emissions and deposition velocities of atmospheric trace gases. J Geo Phys Res 97:3787–3804

    Google Scholar 

  • Neftel A,Blatter A,Hesterberg R,Staffelbach T (1996) Measurement of concentration gradients of HNO2and HNO3over a seminatural ecosystem. Atmos Environ 30:3017–3025

    CAS  Google Scholar 

  • Neininger B (1994) Flugzeugmessdaten Berlin 1994. Ein Auftrag der Länder Berlin und Brandenburg vertreten durch die Fachhochschule Wildau. MetAir,Illnau,Schweiz

    Google Scholar 

  • Neininger B,Dommen J (1996) POLLUMET,Luftverschmutzung und Meteorologie in der Schweiz. Bundesamt für Umwelt Wald und Landschaft,Bern,Schweiz (Umwelt-Materialien Nr 63)

    Google Scholar 

  • Notholt J,Hjorth J,Raes F (1992) Formation of HNO2on aerosol surfaces during foggy periods in the presence of NO and NO2. Atmos Environ 26A:211–217

    CAS  Google Scholar 

  • NRC (National Research Concil) (1991) Rethingking of the ozone problem in urban and regional air pollution. National Academy Press,Washington

    Google Scholar 

  • Olszyna KJ,Bailey EM,Simonaitis R,Meagher JF (1994) 03and NOyrelationships at a rural site. J Geo Phys Res 99:14557–14563

    Google Scholar 

  • Paulson SE,Flagan RC,Seinfeld JH (1992) Atmospheric photooxidation of isoprene,part II: the ozone-isoprene reaction. Int J Chem Kinet 24:103–125

    CAS  Google Scholar 

  • Penner JE,Charlson RJ,Hales JM,Laulainen N,Leifer R,Novakov T,Ogren J,Radke LF,Schwartz S,Travis L (1994) Quantifying and minimizing unceratinty of climate forcing by anthropogenic aerosols. Bull Am Meteorol Soc 75:375–400

    Google Scholar 

  • Penkett SA,Brice KA (1986) The spring maximum of photo-oxidants in the Northern hemisphere. Nature 319:655–657

    CAS  Google Scholar 

  • Perner D,Kessler C,Platt U (1987) HNO2 NO2and NO measurements in automobile engine exhaust by optical absorption. In: Grisar R et al (eds) Monitoring of gaseous pollutants by tunable diode lasers. Reidel,Dordrecht,pp 116–119

    Google Scholar 

  • Pilling MJ,Seakins PW (1995) Reaction kinetics. Oxford Science,Oxford

    Google Scholar 

  • Piccot SD,Watson JJ,Jones JW (1992) A global inventory of volatile organic corn-pound emissions from anthropogenic sources. J Geo Phys Res 97:9897–9912

    CAS  Google Scholar 

  • Pinto JP,Stevens RK,Willis RD,Kellogg R,Mamane Y,Novak J,Santroch J,Benes I,Lenicek J,Bures V (1998) Czech air quality monitoring and receptor modeling study. Environ Sci Techn 32:843–854

    Google Scholar 

  • Pitts JN Jr,Biermann H,Winer AM,Tuazon EC (1984) Spectroscopic identification and measurement of gaseous nitrous acid in dilute auto exhaust. Atmos Environ 18:847–854

    Google Scholar 

  • Plane JMC (1995) Comment made at Faraday discussion 100. Faraday Disc 100:201 Palss-Dülmer C,Brauers T,Rudolph J (1998) POPCORN: a field study of photochemistry in North-Eastern Germany. J Atmos Chem 31:5–31

    Google Scholar 

  • Platt U,Perner D,Winer AM,Harris GW,Pitts JN Jr (1980) Detection of NO3in the polluted troposphere by differential optical absorption. Geo Phys Res Lett 7:89–92

    CAS  Google Scholar 

  • Platt U,Perner D,Schröder J,Kessler C,Toenissen A (1981) The diurnal variation of NO3. J Geo Phys Res 86:11965–11970

    CAS  Google Scholar 

  • Prévôt ASH (1994) Photooxidantien und Primärluftschadstoffe in der plantearen Grenzschicht in der Schweiz nördlich und südlich der Alpen. Dissertation ETH,Nr 10956

    Google Scholar 

  • Prévôt ASH,Staehelin J,Richner H,Griesser T (1993) A thermally driven system influencing concentrations of ozone precursors and photo-oxidants at a receptor site in the Alpine foothills Meteorol Z NF 2:167–177

    Google Scholar 

  • Prévôt ASH,Staehelin J,Kok GL,Schillawski RD,Neiniger B,Staffelbach T,Neftel A,Wernli H,Dommen J (1997) The Milan photooxidant plume. J Geo Phys Res 102:23375–23388

    Google Scholar 

  • Piringer M,Ober E,Puxbaum H,Kromp-Kolb H (1997) Occurrence of nitric acid and related compounds in the northern Vienna basign during summertime anticyclonic conditions. Atmos Environ 31:1049–1057

    CAS  Google Scholar 

  • Pszenny AAP,Keen WC,Jacob DJ,Fan S,Maben JR,Zetwo MP,Springer-Young M,Galloway JN (1993) Evidence of inorganic chlorine gases other than hydrogen chloride in marine surface air. Geo Phys Res Lett 20:699–702

    CAS  Google Scholar 

  • Raes F,Vandingenen R (1992) Simulations of condensation and clould condensation nuclei from biogenic SO2in the remote marine boundary layer. J Geo Phys Res 97:12901–12912

    CAS  Google Scholar 

  • Raga GB,Le Moyne L (1996) On the nature of air pollution dynamics in the Mixico City - I. Nonlinear analysis. Atmos Environ 30:1049–1057

    Google Scholar 

  • Ramacher B,Rudolph J,Koppermann R (1997) Hydrocarbon measurements in the spring Arctic Troposphere during the ARCTOC95 campaign. Tellus B 49:466–485

    Google Scholar 

  • Ray A,Vassalli I,Laverdet G,Le Bras G (1996) Kinetics of the thermal decomposition of the CH3SO2radical and its reaction with NO2at 1 Torr and 298 K. J Phys Chem 100:8895–8900

    CAS  Google Scholar 

  • Reimann,S,Grob K,Frank H (1996) Chloroacetic acids in rainwater. Environ Sci Technol 30:2340–2344

    CAS  Google Scholar 

  • Reiner T,Arnold F (1993) Laboratory flow reactor measurements of the reaction SO3+ H2O +M -* H2SO4+ M,implication for gaseous H2SO4and aerosol formation in the plumes of jet aircraft. Geo Phys Res Lett 20:2659–2662

    CAS  Google Scholar 

  • Roemer M (1996) Trends of tropospheric ozone over Europe,PhD thesis,University of Utrecht,The Netherlands

    Google Scholar 

  • Rubino RA,Bruckmann L,Magyar J (1976) Ozone transport. J Air Pollut Contr Assoc 26:972–975

    Google Scholar 

  • Rudd HJ (1995) Emissions of VOC from stationary sources in UK: speciation. Report AEA/CS/16419033/REMA-029,Harwell,UK

    Google Scholar 

  • Rudolph J,Koppmann R,Plass-Dülmer C (1996) The budgets of ethane and tetrachloroethene: is there evidence for an impact of reactions with chlorine atoms in thetroposphere? Atmos Environ 30:1887–1894

    CAS  Google Scholar 

  • Rudolph J,Ramacher R,Plass-Dülmer C,Müller K-P,Koppmann R (1997) The indirect determination of chlorine atom concentration in the troposphere from changes in patterns of non-methane hydrocarbons. Tellus B 49:592–601

    Google Scholar 

  • Ruppert L (1996) Abbaumechanismen biogener Kohlenwasserstoffe in der Troposphäre - Laboruntersuchungen am Beispiel des Isopren,PhD thesis,Bergische Universität/Gesamthochschule Wuppertal

    Google Scholar 

  • Ruppert L,Barnes I,Becker KH (1995) Tropospheric reactions of isoprene and oxidation products: Kinetic and mechanistic studies. In: Becker KH (ed) Tropospheric oxidation mechanisms. Proceedings of the joint EC/EUROTRAC/ GDCh workshop LACTOZ-HALIPP,Leipzig (D),20–22 Sept 1994,pp 91–102 (European Commission,Luxembourg,1995)

    Google Scholar 

  • Ruppert L,Barnes I,Becker KH (1996) New features from the isoprene+OH-reaction. In: Mirabel P (ed) Homogeneous and heterogenous chemical processes in the troposphere. Proceedings of the EC/EUROTRAC Workshop LACTOZ-HALIPP,Straßburg,25–26 Sept 1995,pp 218–224,European Comission Report EUR 16766 EN,Brüssel

    Google Scholar 

  • Russell AG,Milford JB,Bergin MS,McBride S,McNair L,Yang Y,Stockwell WR,Croes B (1995) Urban ozone control and atmospheric reactivity of organic gases. Science 269:491–495

    CAS  Google Scholar 

  • Salawitch RJ,Wofsy SC,Wennberg PO,Cohen RC,Anderson JG,Fahey DW,Gao RS,Keim ER,Woodbridge EL,Stimpfle RM,Koplow JP,Kohn DW,Webster CR,May RD,Pfister L,Gottlieb EW,Michelsen HA,Yue GK,Prather MJ,Wilson JC,Brock CA,Jonsson HH,Dye JE,Baumgardner D,Proffit MH,Loewenstein M,Podolske JR,Elkins JW,Dutton GS,Hintsa EJ,Dessler AE,Weinstock EM,Kelly KK,Boering KA,Daube BC,Chan KR,Bowen SW (1994) The diurnal variation of hydrogen,nitrogen,and chlorine radicals: implication for heterogeneous production of HNO2. Geo Phys Res Lett 21:2551–2554

    CAS  Google Scholar 

  • Sakamaki F,Akimoto H (1988) HONO formation as unknown radical source in photochemical smog chambers. Int J Chem Kinet 20:111–116

    CAS  Google Scholar 

  • Sakamaki F,Hatakeyama S,Akimoto H (1983) Formation of nitrous acid and nitric oxide in the heterogeneous dark reaction of nitrogen dioxide and water vapour in a smog chamber. Int J Chem Kinet 15:1013–1029

    CAS  Google Scholar 

  • Sakugawa H,Kaplan IR (1989) H2O2and 03in the atmosphere of Los Angeles and its vicinity: factors controlling their formation and their role as oxidants of SO2. J Geo Phys Res 94:12957–12973

    CAS  Google Scholar 

  • Saunders SM,Jenkin ME,Derwent RG,Piling MJ (1997) Report summary. Wold Wide Web site of master chemical mechanism (MCM) for use in tropospheric chemistry models. Atmos Environ 31:1249

    CAS  Google Scholar 

  • SCAG (1991) Southern California Association of Governments,South Coast Air Quality Management District,1991,Air Quality Management Plan,Sacramento,California

    Google Scholar 

  • Schäfer C,Neeb P,Sauer F,Horie O,Moortgat GK (1996) Influence of water vapour on the product formation in the ozonolysis of selected C3-C6alkenes. In: Mirabel P (ed) Homogeneous and heterogenous chemical processes in the troposphere. Proceedings of the EC/EUROTRAC Workshop LACTOZ-HALIPP,Straßburg,25–26 Sept 1995,pp 296–304,European Comission Report EUR 16766 EN,Brüssel

    Google Scholar 

  • Schumann U (1997) The impact of nitrogen oxides emissions from aircraft upon the atmosphere at flight altitudes - results from the AERONOX project. Atmos Environ 31:1723–1733

    CAS  Google Scholar 

  • Scire JS,Chang J (1991) Analysis of historical ozone episodes in the SCCCAMP region and comparison with SCCCAMP 1985 field study data. J Appl Met 30:551–584

    Google Scholar 

  • Seinfeld JH (1986) Air pollution. Wiley,New York

    Google Scholar 

  • Seinfeld JH,Pandis SN (1998) Atmospheric chemistry and physics. Wiley,New York

    Google Scholar 

  • Sempéré R,Kawamura K (1996) Low molecular weight dicarboxylic acids and related polar compounds in the remote marine rain samples collected from western pacific. Atmos Environ 30:1609–1619

    Google Scholar 

  • Sexton K,Westberg H (1980) Elevated ozone concentrations measured downwind of the Chicago-Gary urban complex. J Air Pollut Contr Assoc 30:911–914

    CAS  Google Scholar 

  • Siese M,Koch R,Fittschen C,Zetzsch C (1994) Cycling of OH in the reaction systems toluene/O2/NO and acetylene/02and the addition of OH to isoprene. In: Borell PM,Borrell P,Cvitas T,Seiler W (eds) EUROTRAC symposium ‘84 „Transport and transformation of pollutants in the troposphere,11–15 Apr 1994,SPB Academic,Den Haag,Niederlande,S 115–119

    Google Scholar 

  • Simpson D,Guenther A,Hewitt CN,Steinbrecher R (1995) Biogenic emissions in Europe 1. Estimates and uncertainties. J Geo Phys Res 100:22875–22890

    CAS  Google Scholar 

  • Singh HB,Thakur AN,Chen YE,Kanakidou M (1996) Tetrachloroethylene as an indicator of low Cl atom concentrations in the troposphere. Geo Phys Res Lett 23:1529–1532

    CAS  Google Scholar 

  • Sillman S (1999) The relation between ozone,NO and hydrocarbons in urban and polluted rural environments. Atmos Environ 33:1821–1845

    CAS  Google Scholar 

  • Sillman S,Logan JA,Wofsy SC (1990) The sensitivity of ozone to nitrogen oxides and hydrocarbons in regional ozone episodes. J Geo Phys Res 95:1837–1851

    Google Scholar 

  • Sillman S (1995) The use of NOT H2O2 and HNO3as indicators for ozone-NOXhydrocarbon sensitivity in urban locations. J Geo Phys Res 100:14175–14188

    Google Scholar 

  • Simonaitis R,Olszyna KJ,Meagher JF (1991) Production of hydrogen peroxide and organic peroxides in the gas phase reaction of ozone with natural alkenes. Geo Phys Res Lett 18:9–12

    CAS  Google Scholar 

  • Singh HB,Salas LJ,Viezee W (1986) Global distribution of peroxyacetyl nitrate. Nature 321:588–592

    CAS  Google Scholar 

  • Skov H,Hjorth J,Jensen NR,Restelli G (1992) Products and mechanisms of the reactions of the nitrate radical (NO3) with isoprene,1,3-butadiene and 2,3-dimethyl-1,3-butadiene in air. Atmos Environ 26A:2771–2783

    CAS  Google Scholar 

  • Slemr J,Junkermann W,Volz-Thomas A (1996) Temporal variations in formaldehyde,acetaldehyde and acetone and budget of formaldehyde at a rural site in Southern Germany. Atmos Environ 30:3667–3676

    CAS  Google Scholar 

  • Solberg S,Dye C,Schmidbauer N,Herzog A,Gehrig R (1996) Carbonyls and nonmethane hydrocarbons at rural sites from the Mediterranean to the Arctic. J Atmos Chem 25:33–66

    CAS  Google Scholar 

  • Sorensen S,Falbe-Hansen H,Mangoni M,Hjorth J,Jensen NR (1996) Observation of DMSO and CH3S(0)OH from the gas phase reaction between DMS and OH. J Atmos Chem 24:299–315

    CAS  Google Scholar 

  • Spicer CW (1982) Nitrogen oxide reactions in the urban plume of Boston. Science 215:1095–1097

    CAS  Google Scholar 

  • Staehelin J,Thudium J,Bühler R,Volz-Thomas A,Graber W (1994) Trends in surface ozone concentrations at Arosa (Switzerland). Atmos Environ 28:75–87

    CAS  Google Scholar 

  • Staehelin J,Kegel R,Harris NRP (1998) Trend analysis of the homogenised total ozone series of Arosa (Switzerland),1926–1996. J Geo Phys Res 103:8389–8399

    CAS  Google Scholar 

  • Staffelbach T,Neftel A,Blatter A,Gut A,Fahrni M,Staehelin J,Prévt A,Hering A,Lehning M,Neiniger B,Bäumle M,Kok GL,Dommen J,Hutterli M,Anklin M (1997a) Photochemical oxidant formation over Southern Switzerland,part I: results from summer 1994. J Geo Phys Res (in press)

    Google Scholar 

  • Staffelbach T,Neftel A,Horowitz LW (1997b) Photochemical oxidant formation over Southern Switzerland,part II: model results. J Geo Phys Res (in press)

    Google Scholar 

  • Stickel RE,Nicovich JM,Wang S,Zhao Z,Wine PH (1992) Kinetic and mechanistic study of the reaction of atomic chlorine with dimethyl sulfide. J Phys Chem 96:9875–9883

    CAS  Google Scholar 

  • Stickel RE,Zhao Z,Wine PH (1993) Branching ratios for hydrogen tranfer in the reactions of OD radicals with CH3SCH3and CH3SC2H5. Chem Phys Lett 212:312–318

    CAS  Google Scholar 

  • Streit GE,Guzman F (1996) Mexiko city air quality: progress of an international collaborative project to define air quality management options. Atmos Environ 30:723–733

    CAS  Google Scholar 

  • Stull RB (1988) An introduction to boundary layer climatology. Atmospheric Sciences Library. Kluwer Academic,Dodrecht

    Google Scholar 

  • Suppan P,Fabian P,Vyras LG,Gryning SE (1998) The bevaviour of ozone and peroxyacetyl nitrate concentrations for different wind regimes during the MEDCAPHOT-trace campaign in the greater area of Athens,Greece. Atmos Environ 32:2089–2102

    CAS  Google Scholar 

  • Svensson R,Ljungström E,Lindqvist O (1987) Kinetics of the reaction between nitrogen dioxide and water vapour. Atmos Environ 21:1529–1539

    CAS  Google Scholar 

  • Temple PJ,Taylor OC (1983) World-wide ambient measurements of peroxyacetyl nitrate (PAN) and implications for plant injury. Atmos Environ 17:1583–1587

    CAS  Google Scholar 

  • Toumi R (1994) BrO as a possible sink for dimethylsulfide in the marine atmosphere. Geo Phys Res Lett 21:117–120

    CAS  Google Scholar 

  • Thomm J,Wolff S,Turner WV,Gäb S,Thomas W,Zabel F,Fink EH,Becker KH (1996) Proof of the formation of hydroperoxmethyl formate in the ozonolysis of ethene: synthesis of FT-IR spectra of the compound. Chem Phys Lett 258:155–158

    Google Scholar 

  • Toumi R (1994) BrO as a possible sink for dimethylsulfide in the marine atmosphere. Geo Phys Res Lett 21:117–120

    CAS  Google Scholar 

  • Trainer M,Williams EJ,Parish DD,Buhr MP,Allwine EJ,Westberg HH,Fehsenfeld FC,Liu SC (1987) Models and observations of the impact of the natural hydrocarbons on rural ozone. Nature 322:705–707

    Google Scholar 

  • Trainer M,Parrish DD,Buhr MP,Norton RB,Fehsenfeld FC,Anlauf KG,Botten-heim JW,Tang YZ,Wiebe HA,Roberts JM,Tanner RL,Newman L,Bowersox VC,Meagher JF,Olszyna KJ,Rodgers MO,Wang T,Berresheim H,Demerjian KL,Roychowdhury UK (1993) Correlation of ozone with NOyin photochemically aged air. J Geo Phys Res 98:2917–2925

    CAS  Google Scholar 

  • Trainer M,Ridley BA,Buhr MP,Kok G,Walega J,Hübler G,Parrish DD,Fehsenfeld FC (1995) Regional ozone and urban plumes in the southeastern United States: Birmingham,a case study. J Geo Phys Res 100:18823–18834

    Google Scholar 

  • Tsalkani N,Perros P,Dutot AL,Toupance G (1991) One-year measurements of PAN in the Paris basign: effect of meteorological parameters. Atmos Environ 25A:1941–1949

    CAS  Google Scholar 

  • Tuazon EC,Atkinson R (1990) A product study of the gas-phase reaction of isoprene with the OH radical in the presence of NOX. Int J Chem Kinet 22:1221–1236

    CAS  Google Scholar 

  • Tuazon EC,Winer AM,Pitts IN Jr (1981) Trace pollutant concentrations in a multiday smog epsiode in the California South coast air basin by long path length Fourier transform infrared spectroscopy. Environ Sci Techn 15:1232–1237

    CAS  Google Scholar 

  • Turnipseed AA,Barone SB,Ravishankara AR (1992) Observation of CH3S addition to 02in the gas phase. J Phys Chem 96:7502–7505

    CAS  Google Scholar 

  • Turnipseed AA,Barone SB,Ravishankara AR (1996) Reaction of OH with di-methyl sulfide. 2. Products and mechanisms. J Phys Chem 100:14703–14713

    CAS  Google Scholar 

  • Van Dingenen R,Jensen NR,Hjorth J,Raes F (1994) Peroxynitrate formation during the night-time oxidation of dimethylsulfide: its role as a reservoir species for aerosol formation. J Atmos Chem 18:211–237

    Google Scholar 

  • Varey RH,Ball DJ,Crane AJ,Laxen DPH,Sandalls Ft (1988) Ozone formation in the London plume. Atmos Environ 22:1335–1346

    CAS  Google Scholar 

  • Vogel B,Fiedler F,Vogel H (1995) Influence of topography and biogenic volatile organic compound emission in the State of Baden-Württemberg on ozone concentrations during episodes of high air temperatures. J Geo Phys Res 100:22907–22928

    CAS  Google Scholar 

  • Vogt R,Crutzen Pl,Sander R (1996) A mechanism for halogen release from sea salt aerosol in the remote marine boundary layer. Nature 383:327–330

    CAS  Google Scholar 

  • Volz-Thomas A (1993) Trends in photo-oxidant concentrations. In: Borell PM,Borell P,Cvitas T,Seiler W (eds) The proceedings of EUROTRAC symposium ‘82. SPB Academic,The Hague,The Netherlands,pp 59–64

    Google Scholar 

  • Volz A,Kley D (1988) Evaluation of the Montsouris series of ozone measurements made in the nineteenth century. Nature 332:240–242

    CAS  Google Scholar 

  • Volz-Thomas A,Flocke F,Garthe HJ,Geiss H,Gilge S,Heil T,Kley D,Klemp D,Kramp F,Milehcic D,Pätz HW,Schultz M,Su Y (1993) Photooxidants and precursors at Schauinsland,Black Forrest. In: Borell et al (eds) Proc Eurotrac Symp 92. SPB Academic,The Hague,pp 98–103

    Google Scholar 

  • Wallington TJ,Ellermann T,Nielsen OJ (1993) Atmospheric chemistry of di-methyl sulfide: UV spectra and self-reaction kinetics of CH3SCH2and CH3SCH2O2radicals and kinetics of the reactions CH3SCH2+ 02—> CH3SCH2O2and CH3SCH2O2+ NO —* CH3SCH2O + NO2. J Phys Chem 97:8442–8449

    CAS  Google Scholar 

  • Wängberg I,Barnes I,Becker KH (1997) Product and mechanistic study of the reaction of NO3radicals with a-pinene. Environ Sci Techn 31:2130–2135

    Google Scholar 

  • Warneck P (1988) Chemistry of the natural atmosphere. Academic,London (International geophysics series,vol 41)

    Google Scholar 

  • Wayne RP (1988) Principles and applications of photochemistry,2nd edn. Oxford University Press,New York

    Google Scholar 

  • Wayne RP,Barnes I,Biggs P,Burrows JP,Canosa-Mas CE,Hjorth J,Le Bras G,Moortgat GK,Perner D,Poulet G,Restelli G,Sidebottom H (1991) The nitrate radical: physics,chemistry,and the atmosphere. Atmos Environ 25A:1–206

    CAS  Google Scholar 

  • Wennberg PO,Hanisco TF,Jaeglé L,Jacob DJ,Hinsta EJ,Lanzendorf EJ,Anderson JG,Gao R-S,Keim ER,Donelly SG,Del Negro LA,Fahey DW,McKeen SA,Salawitch RJ,Webster CR,May RD,Herman RL,Proffitt RJ,Margitan JJ,Atlas EL,Schauffler SM,Flocke F,McElroy CT,Bui TP (1998) Hydrogen radicals,nitrogen radicals,and the production of 03in the upper troposphere. Nature 279:49–53

    CAS  Google Scholar 

  • Wernli H (1995) Lagrangian perspective of extratropical cyclones. Diss ETH Nr 11 016,ETH-Zürich

    Google Scholar 

  • White WH,Anderson JA,Blumenthal DL,Husar RB,Gillani NV,Husar JD,Wilson WE Jr (1976) Formation and transport of secondary air pollutants: Ozone and aerosols in the St Louis Urban plume. Science 194:187–189

    CAS  Google Scholar 

  • Wiesen P,Kleffmann J,Kurtenbach R,Becker KH (1995) Mechanistic study of the heterogeneous conversion of NO2into HONO on acid surfaces. Faraday Discuss 100:121–127

    CAS  Google Scholar 

  • Williams EL Jr,Grosjean D (1990) Southern California air quality study: peroxyacetyl nitrate. Atmos Environ 9:2369–2377

    Google Scholar 

  • Williams EL Jr,Grosjean D (1991) Peroxypropinyl nitrate at a Southern California mountain forest site. Environ Sci Technol 25:653–659

    CAS  Google Scholar 

  • Williams EL Jr,Grosjean E,Grosjean D (1993) Ambient levels of the peroxyacyl nitrates PAN,PPN and MPAN in Atlanta,Georgia. J Air Waste Manage Assoc 43:873–879

    CAS  Google Scholar 

  • Williams J,Roberst JM,Fehsenfeld FC,Bertman SB,Buhr MP,Goldan PD,Hübler G,Kuster WC,Reyerson TB,Trainer M,Young V (1997) Regional ozone from biogenic hydrocarbons deduced from airborne measurements of PAN,PPN and MPAN. Geo Phys Res Lett 24:1099–1102

    CAS  Google Scholar 

  • Winer AM,Biermann HW (1994) Long pathlength differential optical absorption spectroscopy (DOAS) measurements of gaseous HONO,NO2and HCHO in the California South Coast Air Bassin. Res Chem Intermed 20:423–445

    CAS  Google Scholar 

  • Wunderli S,Gehrig R (1991) Influence of temperature on formation and stability of surface PAN and ozone. A two year field study in Switzerland. Atmos Environ 25A:1599–1608

    CAS  Google Scholar 

  • Yin F,Grosjean D,Seinfeld JH (1990) Photooxidation of DMS and DMDS I: Mechanism Development. J Atmos Chem 11:309–364

    CAS  Google Scholar 

  • Yu J,Jeffries HE (1997) Atmospheric photooxidation of Alkylbenzenes - II. Evidence of formation of epoxide entermediates. Atm Env 31:2281–2287

    CAS  Google Scholar 

  • Zabel F (1995) Unimolecular decomposition of peroxynitrates. Zeitschrift f. Phys Chemie 188,119–142

    CAS  Google Scholar 

  • Zaveri RA,Saylor RD,Peters LK,McNider R,Song A (1995) A model investigation of summertime diurnal ozone behavior in rural mountainous locations. Atm Env 29:1043–1065

    CAS  Google Scholar 

Literatur

  • Bates DR,Nicolet M (1950) The photochemistry of atmospheric water vapour. J Geophys Res 55:301

    CAS  Google Scholar 

  • Bekki S,Pyle JA (1994) A two-dimensional modelling study of the volcanic eruption of Mt. Pinatubo. J Geophys Res 99:18861–18869

    Google Scholar 

  • Bojkov RD,Zerefos CS,Balis DS,Ziomas IC,Bair AF (1993) Record low total ozone during northern winters of 1992 and 1993. Geophys Res Lett 20:1351–1354

    CAS  Google Scholar 

  • Bojkov RD,Bishop L,Fioletov VE (1995 a) Total ozone trends from quality controlled ground based data (1964–1994). J Geophys Res 100:25867–25876

    Google Scholar 

  • Bojkov RD,Fioletov VE (1997) Changes of the lower stratospheric ozone over Europe and Canada. J Geophys Res 102:1327–1347

    Google Scholar 

  • Brasseur G,Solomon S (1984) Aeronomy of the middle atmosphere. Reidel,Dordrecht

    Google Scholar 

  • Brasseur G,Granier C (1992) Mt. Pinatubo aerosols,chlorofluorocarbons and ozone depletion. Science 257:1239–1242

    CAS  Google Scholar 

  • Browell EV,Butler CF,Ismail S,Robinett PA,Carter AF,Higdon NS,Toon OB,Schoeberl MR,Tuck AF (1990) Lidar observations in the wintertime Arctic stratosphere: polar stratospheric clouds. Geophys Res Lett 17:385–388

    Google Scholar 

  • Burrows JP et al (1999) The Global Ozone Monitoring Experiment (GOME) - mission concept and first scientific results. J Atmos Sci 56:151–175

    Google Scholar 

  • Carslaw KS,Luo BP,Clegg SL,Peter T,Brimblecombe P,Crutzen PJ (1994) Stratospheric aerosol growth and HNO3gas phase depletion from coupled HNO3and H2O uptake by liquid particles. Geophys Res Lett 21:2479–2482

    CAS  Google Scholar 

  • Carslaw KS,Klegg SL,Brimblecomb P (1995) A thermodynamic model of the system HC1-HNO3-H25O4-H2O,including solubilities of HBr from 328 K to 200 K. J Phys Chem 99:11557–11574

    Google Scholar 

  • Carslaw KS,Peter T,Clegg SL (1997) Modelling the composition of liquid stratospheric aerosols. Rev Geophys 35:125–154

    CAS  Google Scholar 

  • Chapman S (1930) A theory of upper atmosphere ozone. Mem R Meteorol Soc 3:103

    Google Scholar 

  • Crutzen PJ (1971) Ozone production rates in an oxygen-hydrogen-nitrogen oxide atmosphere. J Geophys Res 76:7311

    CAS  Google Scholar 

  • Crutzen PJ. (1976) The possible importance of COS for the sulfate layer of the stratosphere. Geophys Res Lett 3:73–76

    CAS  Google Scholar 

  • Dameris M,Grewe V (1994) Three-dimensional description of the stratospheric polar vortex. Beitr Phys Atmos 67:157–160

    Google Scholar 

  • Danckwerts PV (1970) Gas-liquid reactions. McGraw-Hill,New York

    Google Scholar 

  • DeMore WB,Sander SP,Golden DM,Hampson RF,Kurylo MJ,Howard CJ,Ravishankara AR,Kolb CE,Molina MI (1997) Chemical kinetics and photochemical data for use in stratospheric modelling. NASA-JPL publ 97/4

    Google Scholar 

  • Dütsch HU (1980) Vertical ozone distribution and tropospheric ozone. Proc NATO Adv Study Inst Atmospheric Ozone,FAA-EE-80–20:7

    Google Scholar 

  • Dunkerton T (1978) On the mean meridional mass motion of the stratosphere and mesosphere. J Atmos Sci 35:2325–2333

    Google Scholar 

  • Ehhalt DH,Tonnisson A (1980) Hydrogen and carbon compounds in the stratosphere. In: Nicolet M,Aikin AC (eds) Proceedings of the NATO ASI series on atmospheric ozone. US Department of Transportation,Washington DC,pp 129–151

    Google Scholar 

  • Ehhalt DH (1999) In: Zellner R (ed) Global aspects of atmospheric chemistry. Steinkopff,Darmstadt

    Google Scholar 

  • Fahey DW,Kelly KK,Ferry GV,Poole LR,Wilson JC,Murphy DM,Loewenstein R,Chan KR (1989) In situ measurements of total reactive nitrogen,total water and aerosol in a polar stratospheric cloud in Antarctica. J Geophys Res 94:11299–11315

    CAS  Google Scholar 

  • Farman JC,Gardiner BJ,Shanklin DD (1985) Large losses of total ozone in Antarctica reveal seasonal ClOX/NOXinteraction. Nature 315:207–210

    CAS  Google Scholar 

  • Fioletov VE,Kerr JB,Wardle DI,Davies J,Hare EW,McElroy CT,Taranick DW (1997) Long-term ozone decline over the Canadian Arctic to early 1997 from ground-based and balloon oberservations. Geophys Res Lett 24:2705–2708

    CAS  Google Scholar 

  • Gable CM,Betz HF,Maron SH (1950) Phase equilibria of the system sulphur trioxide-water. J Am Chem Soc 72:1445–1448

    CAS  Google Scholar 

  • Hamill P,Turco RP,Toon OB (1988) On the growth of nitric acid and sulfuric acid aerosol particles under stratospheric conditions. J Atmos Chem 7:287–315

    CAS  Google Scholar 

  • Hanson DR,Ravishankara AR,Solomon S (1994) Heterogeneous reactions in sulfuric acid aerosols: a framework for model calculations. J Geophys Res 99:3615–3629

    CAS  Google Scholar 

  • Hofmann DJ,Oltmans SJ,Lathrop JA,Harris JM,Vömel H (1994b) Record low ozone at the South Pole in the spring of 1993. Geophys Res Lett 21:421–424

    CAS  Google Scholar 

  • Holton JR,Haynes PH,McIntyre ME,Douglas AR,Rood RB,Pfister L (1995) Stratosphere-troposphere exchange. Rev Geophys 33:403–439

    Google Scholar 

  • IPCC (1995) Climate change 1994,report of the intergovernmental panel on climate change. Cambridge University Press, Cambridge

    Google Scholar 

  • Jäger H,Deshler T,Homberg F,Freuenthaler V (1997) Five years of lidar observations of the Pinatubo eruption cloud. Proc Int Laser Radar Conf,Springer

    Google Scholar 

  • JGR (1993) Articles by Rind et al, Chu et al, McCormick et al, Chiou et al, Pruost et al, Larsen et al. In: J Geophys Res 98(D3):4835–4917

    Google Scholar 

  • Johnston HS (1971) Reduction of stratospheric ozone by nitrogen oxide catalysts from supersonic transport exhaust. Science 173:517–522

    CAS  Google Scholar 

  • Junge CE,Chagnon CW,Manson JE (1961) Stratospheric aerosols. J Meteorol 18:81–108

    Google Scholar 

  • Kawa SR,Fahey DW,Heidt LE,Pollock WH,Solomon S,Anderson DE,Loewenstein M,Profitt MH,Margitan JJ,Chan KR (1992) Photochemical partitioning of the reactive nitrogen and chlorine reservoirs in the high-latitude stratosphere. J Geophys Res 97:7905–7923

    CAS  Google Scholar 

  • Kelly KK,Tuck AF,Heidt LE (1990) A comparison of ER-2 measurements of stratospheric water vapor between the 1987 Antarctic and 1989 Arctic airborn missions. Geophys Res Lett 17:465–468

    Google Scholar 

  • Khalil MAK,Rasmussen RA,Gunawardena R (1993) Atmospheric methyl bromide: trends and global mass balance. J Geophys Res 98:2887–2896

    CAS  Google Scholar 

  • Koop T,Carslaw K (1996) Melting of H2SO4-H2O particles upon cooling: implications for polar stratospheric clouds. Science 272:1638–1641

    CAS  Google Scholar 

  • Manney GL,Zurek RW,O’Neill A,Swinbank R (1994 a) On the motion of air through the stratospheric polar vortex. J Atmos Sci 51:2973–2994

    Google Scholar 

  • McElroy MB,Salawitch RJ,Wofsy SC,Logan JA (1986) Reduction of Antarctic ozone due to synergistic interactions of chlorine and bromine. Nature 321: 759–762

    CAS  Google Scholar 

  • Molina LT,Molina MJ (1987) Production of C12O2from the self-reaction of the C1O radical. J Phys Chem 91:433–436

    CAS  Google Scholar 

  • Molina MJ,Rowland FS (1974) Stratospheric sink for chlorofluoromethanes. Chlorine atom catalyzed destruction of ozone. Nature 249:810

    CAS  Google Scholar 

  • Montzka SA,Butler JA,Myers RC,Thompson TM,Swanson TH,Clarke AD,Lock LT,Elkins JW (1996) Decline in the tropospheric abundance of halogen from halocarbons: implications for stratospheric ozone depletion. Science 272:1318–1322

    CAS  Google Scholar 

  • Naujokat B,Pyle JA (1997) In: European research on the stratosphere. European Commission,Brussels,pp 39–60

    Google Scholar 

  • Newman PA,Lait LR,Schoeberl MR,Nash ER,Kelly KK,Fahey DW,Nagatani RM,Toohey DW,Avallone LM,Anderson JG (1993) Stratospheric meteorological conditions in the Arctic polar vortex 1991 to 1992. Science 261:1143–1146

    CAS  Google Scholar 

  • Newman PA,Gleason JF,McPeters RD,Stolarski RS (1997) Anomalously low ozone over the Arctic. Geophys Res Lett 24:2689–2692

    CAS  Google Scholar 

  • Norton W,Chipperfield M (1995) Quantification of the transport of chemically activated air from the northern hemisphere polar vortex. J Geophys Res 199:25817–25840

    Google Scholar 

  • O’Neill,A,Grose WL,Pope VD,MacLean H,Swinbank R (1994) Evolution of the stratosphere during northern winter 1991/1992 as diagnosed from the UK Meteorological Office Analyzer. J Atmos Sci 51:2800–2817

    Google Scholar 

  • Oltmans SJ,Hofmann DJ (1995) Increase in lower stratospheric water vapour at a mid-latitude Northern Hemisphere site from 1981–1993. Nature 374:146–149

    Google Scholar 

  • Pawson S,Labitzke K,Lenshow R,Naujokat B,Rajenski B,Wiesner M,Wohlfahrt RC (1993) Climatology of the northern hemispheric stratosphere derived from Berlin analysis,part 1: monthly means. Meteorol Abhandl Ser A,vol 7,3

    Google Scholar 

  • Pawson S,Naujokat B,Labitzke K (1995) On the polar stratospheric cloud forma-tion potential of the northern stratosphere. J Geophys Res 100:23215–23225

    Google Scholar 

  • Schiller C,Engel A,Schmidt U,Borchers R,Ovarlez J (1996) The partioning of hydrogen species in the Arctic winter stratosphere: implications for micro-physical parameters. J Geophys Res 101:14489–14493

    CAS  Google Scholar 

  • Schoeberl MR,Lait LR,Newman PA,Rosenfield JE (1992) The structure of the polar vortex. J Geophys Res 97:7859–7882

    Google Scholar 

  • Schwartz SE (1986) Chemistry of mulitphase atmospheric systems. NATO ASI series. Springer,Berlin Heidelberg New York

    Google Scholar 

  • Seinfeld JL,Pandis SN (1998) Atmospheric chemistry and physics. Wiley,New York

    Google Scholar 

  • Solomon S,Garcia RR,Ravishankara AR (1994) On the role of iodine in ozone depletion. J Geophys Res 99:20491–20499

    Google Scholar 

  • Solomon S,Portmann RW,Garcia RR,Thomason LW,Poole LR,McCormick MP (1996) The role of aerosol variations in anthropogenic ozone depletion at northern mid-latitudes. J Geophys Res 101:6713–6727

    CAS  Google Scholar 

  • Steele HM,Hamill P (1981) Effects of temperature and humidity on the growths and optical properties of sulfuric acid-water droplets in the stratosphere. J Aerosol Sci 12:517–528

    CAS  Google Scholar 

  • Stolarski RS,Cicerone RJ (1974) Stratospheric chlorine: a possible sink for ozone. Can J Chem 52:1610

    CAS  Google Scholar 

  • Tabazadeh A,Turco RP (1993) A model for heterogeneous chemical processes on the surface of ice and nitric acid trihydrate particles. J Geophys Res 98:12727–12740

    Google Scholar 

  • Trepte CR,Veiga RE,McCormick MP (1993) The poleward dispersion of Mount Pinatubo volcanic aerosols. J Geophys Res 98:18563–18573

    Google Scholar 

  • Wahner A,Schiller C (1992) Twiligth variation of vertical column abundances of OC1O and BrO in the north polar region. J Geophys Res 97:8047–8055

    CAS  Google Scholar 

  • Warneck P (1999) In: Zellner R (ed). Global aspects of atmospheric chemistry. Steinkopff,Darmstadt

    Google Scholar 

  • Warneck P (1988) Chemistry of the natural atmosphere. Academic,San Diego

    Google Scholar 

  • WMO (1986)Atmospheric ozone 1985. World Meteorological Organization,Global Ozone Research and Monitoring Project,report no 16,Geneva

    Google Scholar 

  • WMO (1989) Report of the International Ozone Trends Panel,1988. World Meteorological Organization,Global Ozone Research and Monitoring Project,report no 18,Geneva

    Google Scholar 

  • WMO (1992) Scientific assessment of ozone depletion: 1991,World Meteorological Organization,Global Ozone Research and Monitoring Project,report no 25,Geneva

    Google Scholar 

  • WMO (1995) Scientific assessment of ozone depletion: 1994,World Meteorogical Organization,Global Ozone Research and Monitoring Project,report no 37,Geneva

    Google Scholar 

  • WMO (1998) Scientific assessment of ozone depletion 1997. World Meteorological Organization,Global Ozone Research and Monitoring Project,report no 44,Geneva

    Google Scholar 

  • Wofsy SC,McElroy MB,Yung YC (1975) The chemistry of atmospheric bromine. Geophys Res Lett 2:215–218

    CAS  Google Scholar 

  • Zenner R (1986) Chemistry of free radicals in the atmosphere. Oxid Comm 9:255–300

    Google Scholar 

  • Zellner R (1999) In: Zellner R (ed) Global aspects of atmospheric chemistry. Steinkopff,Darmstadt

    Google Scholar 

  • Zerefos CS (1997) WMO Ozone Mapping Center,Thessaloniki,private communication

    Google Scholar 

Download references

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2000 Springer-Verlag Berlin Heidelberg

About this chapter

Cite this chapter

Ebel, A., Staehelin, J., Prévôt, A.S.H., Barnes, I., Zellner, R. (2000). Umwandlung von Spurenstoffen und ihre Auswirkungen auf die Atmosphäre. In: Guderian, R. (eds) Handbuch der Umweltveränderungen und Ökotoxikologie. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-57087-2_3

Download citation

  • DOI: https://doi.org/10.1007/978-3-642-57087-2_3

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-63037-8

  • Online ISBN: 978-3-642-57087-2

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics