Zusammenfassung
Die Atmosphäre wird in diesem Kapitel vor allem aus der Perspektive des Transports von Luftmassen und deren Eigenschaften betrachtet. Man hat zwischen physikalischen und chemischen Eigenschaften der Luft zu unterscheiden, die durch Zustandsgrößen wie Temperatur oder Wind auf der einen Seite und Konzentrationen oder Mischungsverhältnissen auf der anderen Seite beschrieben werden. Durch Luftbewegungen transportierte Eigenschaften werden als Flüsse bezeichnet, also Massenfluß, Wärmefluß oder Impulsfluß auf der physikalischen Seite und Spurenstofffluß (etwa Ozonfluß, Wasserdampf-oder Feuchtefluß, CO2-Fluß) auf der chemischen Seite. Diese Flüsse führen bei Spurenstoffen im allgemeinen zu einer Verdünnung, d. h. Konzentrationsabnahme. Das geschieht durch Transport von den Quellen oder Anhäufungsgebieten weg und durch Vermischung mit Luftmassen, die geringere Konzentrationen des transportierten Stoffes aufweisen, ferner durch Transport zu Senkengebieten hin. Ein solches ist die Erdoberfläche für viele Luftbeimengungen, die dort deponiert werden (s. Bd. 1B, Kap. 2). Doch unter gewissen Umständen kann der Transport auch zu Anhäufungen von Schadstoffen führen. Das geschieht, wenn verschmutzte kalte Luft in ein Tal abfließt und sich dort ansammelt. Ein anderes Beispiel, das die beobachtete Ozonverteilung in der Stratosphäre betrifft, ist die Anhäufung von Ozon, das in niedrigen Breiten erzeugt wird, durch konvergenten Ozonmassenfluß in mittleren und höheren Breiten (Fabian 1992).
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
Literatur
Literatur
Allegrini I,Febo A,Perrino C (1994) Role of nitrous acid in the oxidation processes in the Mediterranean area. In: Restelli G,Angeletti G (eds) Physicochemical behaviour of atmospheric pollutants,report EUR 15609/1 EN,vol 1,Luxembourg,pp 293–299
Ammann M,Kalberer M,Tabor K,Tobler L,Zellweger C,Weingartner E,Nyeki S,Parrat Y,Li F,Piguet D,Rössler E,Jost DT,Gäggeler HW,Baltensperger U (1997) Heterogeneous interaction of NO2with carbonaceous aerosols at the ppb level: adsorption,conversion to NO and production of HONO. In: 7th European Symposium on physico-chemical behaviour of atmospheric pollutants: the oxidising capacity of the troposphere,pp 683–687
Ammann M,Kalberer M,Jost DT,Tobler L,Rössler E,Piguet D,Gäggeler HW,Baltensperger U (1998) Heterogeneous production of nitrous acid on soot in polluted air masses. Nature 395:157–160
Anderson LG,Lanning JA,Barrell R,Miyagishima J,Jones RH,Wolfe P (1996) Sources and sinks of formaldehyde and acetaldehyde: an analysis of Denver’s ambient concentration data. Atmos Environ 30:2113–2123
Andersson-Sköld Y,Grennfelt P,Pleijel K (1992) Photochemical ozone creation potentials: a study of different concepts. J Air Waste Manage Assoc 42:1152–1158
Andreani-Aksoyoglu S,Keller J (1995) Estimates of monoterpene and isoprene emissions from the forests in Switzerland. J Atmos Chem 20:71–87
Andrés-Hernández MD,Notholt J,Hjorth J,Schrems O (1996) A DOAS Study on the Origin of Nitrous Acid at Urban and Non-Urban Sites. Atmos Environ 30:175–180
Altshuller AP (1988) Some characteristics of ozone formation in the urban plume of St. Louis,MO. Atmos Environ 22:499–510
Arey J,Atkinson R,Aschmann SM (1990) Product study of the gas phase reactions of monoterpenes with the OH radical in the presence of NOS. J Geo Phys Res 95:18539–18546
Arnold F,Bürger V,Droste-Franke B,Grimm F,Krieger A,Schneider J,Stilp T (1997) Acetone in the upper troposphere and lower stratosphere: impact on trace gases and aerosols. Geo Phys Res Lett 24:3017–3020
Aschmann SM,Atkinson R (1994) Formation yields of methyl vinyl ketone and methacrolein from the gas-phase reaction of 03with isoprene. Environ Sci Techn 28:1539–1542
ATAL (1997) Luftschadstoffe im Kanton Zürich,Messbericht Immissionen II/1996,Amt für Technische Anlagen and Lufthygiene des Kantons Zürich,Schweiz
Atkinson R (1989) Kinetics and mechanisms of the gas-phase reactions of the hy-droxyl radical with organic compounds. J Phys Chem Ref Data,monograph 1
Atkinson R (1994) Gas-phase tropospheric chemistry of organic compounds. J Phys Chem Ref Data,monograph 2
Atkinson R (1997a) Gas-phase tropospheric chemistry of volatile organic com-pounds. 1. Alkanes and alkenes. J Phys Chem Ref Data 26:215–290
Atkinson R (1997b) Atmospheric reactions of alkoxy and ß-hydroxyalkoxy radi-cals. Int J Chem Kinet 29:99–111
Atkinson R,Aschmann SM (1993a) OH radical production from the gas-phase reactions of 03with a series of alkenes under atmospheric conditions. Environ Sci Technol 27:1357–1363
Atkinson R,Aschmann SM (1993b) Atmospheric chemistry of the monoterpene reaction products nopinone,camphenilone,and 4-acetyl-1-methylcyclohexene. J Atmos Chem 16:337–348
Atkinson R,Aschmann SM (1994) Products of the gas-phase reactions of aromatic hydrocarbons: effect of NO2concentration. Int J Chem Kinet 26:929–944
Atkinson R,Aschmann SM (1995) Alkoxy radical isomerization products from the gas-phase OH radical-initiated reactions of 2,4-dimethyl-2-pentanol and 3,5-dimethyl-3-hexanol. Environ Sci. Technol. 29:528–536
Atkinson R,Aschmann SM,Arey J,Shorees B (1992) Formation of OH radicals in the gas phase reactions of 03with a series of terpenes. J Geo Phys Res 97:6065–6073
Atkinson R,Baulch DL,Cox RA,Hampson RF Jr,Kerr JA,Rossi MJ,Troe J (1996) Evaluated kinetic and photochemical data for atmospheric chemistry: supplement V. Atmos Environ 30
Ayers GP,Penkett SA,Gillett RW,Bandy B,Gallbally IE,Meyer CP,Elsworth CM,Bently ST,Forgan BW (1992) Evidence for photochemical control of ozone concentrations in unpolluted marine air. Nature 360:446–448
Ayers GP,Penkett SA,Gillett RW,Bandy B,Gallbally IE,Meyer CP,Elsworth CM,Bently ST,Forgan BW (1996) The annual cycle of peroxides and ozone in marine air at Cape Grim,Tasmania. J Atmos Chem 23:221–252
Baltensperger U,Gäggeler HW,Jost DT,Lugauer M,Schwikowski M,Weingartner E,Seibert P (1997) Aerosol climatology at the high-alpine site Jungfraujoch,Switzerland. J Geo Phys Res 102:19707–19715
Barnes I,Bastian V,Becker KH,Niki H (1987) FTIR spectroscopy studies of the CH3S + NO2reaction under atmospheric conditions. Chem Phys Lett 140:451–457
Barnes I,Bastian V,Becker KH (1988) Kinetics and mechanism of the reaction of OH radicals with dimethyl sulfide. Int J Chem Kinet 20:415–431
Barnes I,Bastian V,Becker KH,Martin D (1989) Fourier transform IR studies of the reactions of dimethyl sulfoxide with OH,NO3and Cl radicals. In: Biogenic sulfur in the environment. ACS Symp Ser 393:476–488
Barnes I,Bastian V,Becker KH,Overath RD (1991) Kinetic studies of IO,BrO and C1O with dimethylsulfide. Int. J Chem Kinet 23:579–591
Barnes I,Becker KH,Patroescu I (1994a) The tropospheric oxidation of dimethyl sulfide: a new source of carbonyl sulfide. Geo Phys Res Lett 21:2389–2392
Barnes I,Becker KH,Mihalopoulos N (1994b) An FTIR product study of the photooxidation of dimethyl disulfide. J Atmos Chem 18:267–289
Barnes I,Becker KH,Patroescu I (1995) FT-IR Product study of the OH-initiated oxidation of dimethyl sulphide: observation of carbonyl sulphide and dimethyl sulphoxide. J Atmos Chem 30:1805–1814
Barnes I,Becker KH,Klotz B (1996a) A new mechanism for the gas-phase photo-oxidation of aromatic hydrocarbons involving the formation of benzene oxide/ oxepin,In: Borell et al (eds) Transport and transformation of pollutants in the troposphere,vol 2. Computational Mechanics,Southampton,pp 599–605
Barnes I,Klotz B,Becker KH (1996b) Aromatic hydrocarbon oxidation mechanisms: new developments,paper 96-RP130A.01 presented at the Air and Waste Management Association,89th annual meeting and exhibition,Nashville,Tenesse,23–28 June
Barnes I,Becker KH,Goling BT,Klotz B (1996c) Atmospheric chemistry of benzene oxide/oxepine: a possible intermediate in the photooxidation of aromatic hydrocarbons. Faraday Trans (submitted)
Barone SB,Turnipseed AA,Ravishankara AR (1995) Role of adducts in the atmospheric oxidation of dimethyl sulfide. Faraday Discuss 100:39–54
Barrie L,Platt U (1997) Arctic tropospheric chemistry: an overview. Tellus B 49:450–454
Bartolotti LJ,Edney EO (1995) Density functional theory derived intermediates from the OH initiated atmospheric oxidation of toluene. Chem Phys Lett 245:119–122
Bates TM,Charlson RJ,Gammom MH (1987) Evidence for the climate role of marine biogenic sulphur. Nature 329:319–321
Baumbauer A,Brantner B,Paige M,Novakov T (1994) Laboratory study of NO2reaction with dispersed and bulk liquid water. Atmos Environ 28:3225–3232
Becker KH,Fricke W,Löbel J,Schurath U (1985) Part 1: formation,transport,and control of photochemical oxidants. In: Guderian R (ed) Air pollution by photochemical oxidants. Springer,Berlin Heidelberg New York,pp 3–125
Becker KH,Brockmann KJ,Bechara J (1990) Production of hydrogen peroxide in forest air by reaction of ozone with terpenes. Nature 346:256–258
Becker KH,Bechara J,Brockmann KJ (1991) Studies on the formation of H2O2in the ozonolysis of alkenes. Atmos Environ 27:57–61
Becker KH (1994) The atmospheric oxidation of aromatic hydrocarbons and its impact on photooxidant chemistry. In: Borrell PM,Borrell P,Cvitas T,Seiler W (eds) EUROTAC symposium ‘84 „transport and transformation of pollutants in the troposphere“,11–15 April 1994,Garmisch-Partenkirchen. SPB Academic,Den Haag,pp 67–74
Bedjanian Y,Poulet G,Le Bras G (1996) Kinetic study of the reaction of BrO radicals with dimethylsulfide. Int J Chem Kinet 28:383–389
Bergin MS,Russell AG,Milford JB (1995) Quantification of individual VOC reactivity using a chemically detailed three-dimensional photochemical model. Environ Sci Technol 29:3029–3037
Bierbach A,Barnes I,Becker KH,Wiesen E (1994) Atmospheric chemistry of unsaturated carbonyls: butenedial,4-Oxo-2-pentenal,3-hexene-2,5,-dione,maleic anhydride,3H-furan-2-one,and 5-methyl-3H-furan-2-one. Environ Sci Techn 28:715–729
Borrell P,Builtjies PJH,Grennfelt P,Hoy O (eds) (1997) Photo-oxidants,acidification and tools: policy applications of the EUROTRAC results,transport and chemical transformation of pollutants in the troposphere,vol 10. Springer,Berlin Heidelberg New York
Bottenheim JW,Gallant AJ (1986) Measurements of NOyspecies and 03at 82°N latitude. Geo Phys Res Lett 13:113–116
Boutron CF (ed) (1994) Topics in atmospheric and interstellar physics and chemistry,les editions de physique les ulis (ISBN 2–86883–241–5)
Brauers T,Aschmutat U,Brandenburger U,Dorn H-P,Hausmann M,Hessling M,Hofzumahaus A,Holland F,Plass-Dülmer C,Ehhalt DH (1996) Intercomparison of tropospheric OH radical measurements by multiple folded long-path laser absorption and laser induced fluorescence. Geo Phys Res Lett 23:2545–2548
Brimblecombe P (1987) The big smoke. Methuen,London
Broder B,Gygax HA (1985) The influence of locally induced wind systems on the effectiveness of nocturnal dry deposition of ozone. Atmos Environ 19:1627–1637
Brasseur GP,Cox RA,Hauglustaine D,Isaksen I,Lelieveld J,Lister DH,Sausen R,Schumann U,Wahner A,Wiesen P (1998) European scientific assessment of the atmospheric effects of aircraft emissions. Atmos Environ 32:2329–2418
Brunner D,Staehelin J,Jeker J (1998) Large-scale nitrogen oxide plumes in the tropopause region and implications for ozone. Science 282:1305–1309
Bucher-Renner P (1992) Wasserstoffperoxid in der bodennahen Atmosphäre eines voralpinen Standortes,Inauguraldisseratation,Universität Zürich
Butkovskaya NI,Le Bras G (1994) Mechanism of the NO3+DMS reaction by discharge flow mass spectrometry. J Phys Chem 98:2582–2591
BUWAL (1995) Vom Menschen verursachte Luftschadstoff-Emissionen in der Schweiz von 1900 bis 2010,Schriftenreihe Umwelt Nr. 256,Bundesamt für Umwelt,Wald und Landschaft (Bern)
Calvert JG,Yarwood G,Dunker AM (1994) An evaluation of the mechanism of nitrous acid formation in the urban atmosphere. Res Chem Intermed 20:463–502
Cape JN,Storeton-West RL,Devine SF,Beatty RN,Murdoch A (1993) The reaction of nitrogen dioxide at low concentrations with natural waters. Atmos Environ 27A:2613–2621
Carter WPL (1994) Development of ozone reactivity scales for volatile organic compounds. J Air Waste Manag Assoc 44:881–899
Carter WPL (1995) Computer modeling of environmental chamber measurements of maximum incremental reactivities of volatile organic compounds. Atmos Environ 29:2513–2527
Carter WPL,Atkinson R (1987a) An experimental study of incremental hydrocarbon reactivity. Environ Sci Technol 21:670–679
Carter WPL,Atkinson R (1987b) Computer modeling study of incremental hydrocarbon reactivity. Environ Sci Technol 23:864–880
Carter WPL,Atkinson R (1996) Development and evaluation of a detailed mechanism for the atmospheric reactions of Isoprene and NOR. Int J Chem Kinet 28:497–530
Carter WPL,Atkinson R,Winer AM,Pitts JN Jr (1982) Experimental investiga-tion of chamber-dependent radical source. Int J Chem Kinet 14:1071–1103
Carter WPL,Pierce JA,Luo D,Malkina IL (1995) Environmental chamber study of maximum incremental reactivities of volatile organic compounds. Atmos Environ 29:2499–2511
Chang TY,Rudy SJ (1990) Ozone-forming potential of organic emissions from alternative-fueled vehicles. Atmos Environ 24:2421–2430
Chai X,Mohnen VA (1997) Whiteface Mountain ozone and sulfate: an investigation of the background concentrations representative for the northern United States. Atmos Environ (in press)
Charlson RJ,Lovelock JE,Andreae MO,Warren SG (1987) Oceanic phytoplankton,atmospheric sulfur,cloud albedo,and climate. Nature 326:655–661
Charlson RJ,Schwarz SE,Hales JM,Cess RD,Coakley JA.Jr,Hansen JE,Hoffman DJ (1992) Climate forcing by anthropogenic aerosols. Science 255:423–430
Chebbi A,Carlier P (1996) Carboxylic acids in the troposphere,occurrence,sources,and sinks: a review. Atmos Environ 30:4233–4249
Coacley JA Jr,Bernstein RL,Durkee PA (1987) Effect of ship-stack effluents on cloud reflectivity. Science 237:1020–1022
Cooper DJ (1996) Estimation of hydroxyl radical concentrations in the marine atmospheric boundary layer using a reactive atmospheric tracer. J Atmos Chem 25:97–113
Cox RA,Eggleton AEJ,Derwent RG,Lovelock JE,Pack DH (1975) Long range trans-port of photochemical ozone in north-western Europe. Nature 255:118–121
Criegee R (1975) Mechanismus der Ozonolyse. Angew Chem 87:765–771
DeMore WP,Sander SP,Golden DM,Hampson RF,Kurylo MJ,Howard CJ,Ravishankara AR,Kolb CE,Molina MJ (1997) Chemical kinetics and photochemical data for use in stratospheric modeling. JPL Publication,pp 97–94
De Muer D,De Backer H (1992) Revision of 20 years of Dobson total ozone data at Uccle (Belgium): fictitious Dobson total ozone trends induced by sulfur dioxide trends. J Geopys Res 97:5921–5937
Derwent RG,Jenkin ME (1991) Hydrocarbons and the long-range transport of ozone and PAN across Europe. Atmos Environ 25A:1661–1678
Derwent RG,Jenkin ME,Saunders SM (1996) Photochemical ozone creation potentials for a large number of reactive hydrocarbons under European conditions. Atmos Environ 30:181–199
Dominé F,Murrells TP,Howard CJ (1990) Kinetics of the reactions of NO2with CH3S,CH3SO,CH3SS and CH3SSO at 297 K and 1 Torr. J Phys Chem 94:5839–5847
Dominé F,Ravishankara AR,Howard CJ (1992) Kinetics and mechanisms of the reactions of CH3S,CH3SS,CH3SO and CH3SSO with 03at 300 K and low pressures. J Phys Chem 96:2171–2178
Döscher A,Gäggeler HW,Schotterer U,Schwikowski M (1995) A 130 years deposition record of sulfate,nitrate and chloride from a high-alpine Glacier. Water Air Soil Pollut 85:603–609
Dorn H-P,Brandenburger U,Brauers T,Hausmann M,Ehhalt DH (1996) In-situ detection of tropospheric OH radicals by folded long-path laser absorption. Results from the POPCORN field campaign in August 1994. Geo Phys Res Lett 23:2537–2540
Emmons LK,Caroll MA,Hauglustaine DA,Brasseur GP,Atherton C,Penner J,Sill-man S,Levy H II,Rohrer F,Wauben WMF,Van Velthoven PFJ,Wang Y,Jacob D,Bakwin P,Dickerson R,Doddridge B,Gerbig C,Honrath R,Hübler G,Jaffe D,Kondo,Y,Munger JW,Torres A,Volz-Thomas A (1997) Climatologies of NO and NOy: a comparison of data and models. Atmos Environ 31:1851–1904
EMPA (1994) Technischer Bericht zum Nationalen Beobachtungsnetz für Luftfremdstoffe (NABEL) 1994. Eidgenössische Materialprüfungs-und Forschungsanstalt,Dübendorf,Schweiz
Febo A (1994) Nitrous acid in the oxidation processes in urban areas. In: Restelli G,Angeletti G (eds) Physico-chemical behaviour of atmospheric pollutants,report EUR 15609/1 EN,vol 1. Luxembourg,pp 277–286
Febo A,Perrino C,Cortiello M (1993) A denuder technique for the measurement of nitrous acid in urban atmospheres. Atmos Environ 27A:1721–1728
Febo A,Perrino C,Allegrini I (1996) Measurement of nitrous acid in Milan,Italy,by DOAS and diffusion denuders. Atmos Environ 30:3599–3609
Feister W,Warmbt W (1987) Long-term measurements of surface ozone in the German Democratic Republic. J Atmos Chem 5:1–21
Flocke F,Volz-Thomas A,Kley D (1994) The use of alkyl nitrate measurements for the characterization of the ozone balance at TOR station No. 11,Schauinsland. In: Boren et al (eds) Proc Eurotrac Symp 94:243–247
Flocke F,Volz-Thomas A,Buers H-J,Pätz W,Garthe H-J,Kley D (1998) Longterm measurements of alkyl nitrates in southern Germany 1. General behavior and seasonal and diurnal variation. J Geo Phys Res 103:5729–5746
Finlayson-Pitts BJ,Pitts JN Jr (1986) Atmospheric chemistry. Wiley,New York
Fiori AM,Jacob DJ,Logan JA,Yin JH (1998) Long-term trends in ground level ozone over the contiguous United States,1980–1995 (1998) J Geo Phys Res 103:1471–1480
Förderer L,Maly P,Wolf M,Bitter T,Maly P (1996) Trendanalyse schweizerischer Luftschadstoff-Immissionsdaten. Umweltmaterialien 53,Bundesamt für Umwelt,Wald und Landschaft (BUWAL),Bern
Forstner HJL,Flagan RC,Seinfeld J (1997) Secondary organic aerosol from the photooxidation of aromatic hydrocarbons: Molecular composition. Environ Sci Techn 31:1345–1358
Fouquart Y,Isaka H (1992) Sulfur emission,CCN,clouds and climate - a review. Ann Geo Phys Atmos Hydro Space Sci 10:462–471
Gab S,Hellpointer E,Turner WV,Korte F (1985) Hydroxymethyl hydroperoxide and bis(hydroxymethyl) peroxide from gas-phase ozonolysis of naturally occurring alkenes. Atmos Environ 18:2401–2407
Gäb S,Turner WV,Wolff S,Becker KH,Ruppert L,Brockmann K (1995) Formation of alkyl and hydroxyalkyl hydroperoxides on ozonolysis in water and in air. Atmos Environ 18:2401–2407
Gao D,Stockwell WR,Milford JB (1995) First-order sensitivity and uncertainty analysis for a regional-scale gas-phase chemical mechanism. J Geo Phys Res 100:23153–23166
Gerecke A,Thielmann A,Gutzwiller L,Rossi MJ (1998) The chemical kinetics of HONO fornation resulting from heterogenous interaction of NO2with flame soot. Geo Phys Res Lett 25:2453–2456
Glasius M,Calogirou A,Jensen NR,Hjorth J,Nielsen CJ (1997) Kinetic study of gas phase reactions of pinonaldehyde and structurally related compounds. Int J Chem Kinet 29:527–533
Glen WR,Zelenka MP,Graham RC (1996) Relating meteorological variables and trends in motor vehicle emissions to monthly urban carbon monoxide concentrations. Atmos Environ 30:4225–4232
Graedel TE (1978) Chemical compounds in the atmosphere. Academic,New York Graedel TE,Hawkins DT,Claxton LC (1986) Atmospheric chemical compounds. Sources,occurrence,and bioassay. Academic,London
Granby K,Christensen CS,Lohse C (1997a) Urban and semi-rural observations of carboxylic acids and carbonyls. Atmos Environ 31:1403–1415
Granby K,Egelov AH,Nielsen T,Lohse C (1997b) Carboxylic acids: seasonal variation and relation to chemical and meteorological parameters. J Atmos Chem 28:195–207
Grosjean E,Grosjean D (1997) Gas phase reaction of alkenes with ozone: formation yields of primary cabonyls and biradicals. Environ Sci Techn 31:2421–2427
Grosjean D,Williams EL,Seinfeld JH (1992) Atmospheric oxidation of selected terpenes and related carbonyls: gas-phase carbonyl products. Environ Sci Technol 26:1526–1533
Grosjean D,Williams EL,Grosjean E (1993a) Peroxyacyl nitrates at Southern California mountain forest locations. Environ Sci Technol 27:110–121
Grosjean D,Williams EL,Grosjean E (1993b) Ambient levels of peroxy-n-butyryl nitrate at Southern California moutain forest smog receptor location. Environ Sci Technol 27:326–331
Grosjean D,Williams EL,Grosjean E (1993c) Atmospheric chemistry of isoprene and of its carbonyl products. Environ Sci Technol 27:830–840
Grosjean D,Williams EL,Grosjean E,Andino JM,Seinfeld JH (1993d) Atmospheric oxidation of biogenic hydrocarbons: reaction of ozone with /3-pinene,A-limonene and trans-caryophyllene. Environ Sci Technol 27:2754–2758
Grosjean E,Grosjean D,Fraser MP,Cass GR (1996a) Air quality model evaluations data for organics. 2. C1–C14 carbonyls in Los Angeles air. Environ Sci Techn 30:2687–2703
Grosjean E,Grosjean D,Fraser MP,Cass GR (1996b) Air quality model evaluations data for organics. 3. Peroxyacetyl nitrate and peroxypropionylnitrate in Los Angeles air. Environ Sci Techn 30:2704–2714
Guderian R,Tingey DT,Rabe R (1985) Effects of photochemical oxidants on plants. In: Guderian R (ed) Air pollution by photochemical oxidants. Springer,Berlin Heidelberg New York
Guenther AB,Zimmerman PR,Wildermuth M (1994) Natural volatile organic compound emission rate estimates for US woodland landscapes. Atmos Environ 28:1197–1210
Guenther A,Hewitt CN,Erickson D,Fall R,Geron C,Graedel T,Harley P,Klinger L,Lerdau M,Pierce T,Scholes B,Steinbrecher R,Tallamraju R,Taylor J,Zimmerman P (1995) A global model of natural organic compound emissions. J Geo Phys Res 100:8873–8892
Haagen-Smit AJ (1952) Chemistry and physiology of Los Angeles smog. Ind Eng Chem 44:1342–1346
Haagen-Smit AJ,Darley EF,Zaitlin M,Hull H,Noble W (1952) Investigation of injury of plants from air pollution in the Los Angeles area. Plant Physiol 27:18–34
Hakola H,Shorees B,Arey J,Atkinson R (1993) Product formation from the gas-phase reactions of OH radicals and 03with ß-phellandrene. Environ Sci Technol 27:278–283
Hakola H,Arey J,Aschmann SM,Atkinson R (1994) Product formation from the gas-phase reactions of OH radicals and 03with a series of monoterpenes. J Atmos Chem 18:75–102
Hallquist M,Wängberg I,Ljungström E (1996) Atmospheric chemistry of dicarbonyl products from the atmospheric oxidation of selected terpenes,poster presented at the 7th European symposium on physico-chemical behaviour of atmospheric pollutants,Venice (I),2–4 Oct 1996
Hanna SR,Strimaitis DG,Scire JS,Moore GE,Kessler RC (1991) Overview of results of analysis of data from the South-Central Coast Cooperative Aerometric Monitoring program (SCCCAMP). J Appl Met 30:511–533
Harris GW,Carter WPL,Winer AM,Pitts JN Jr,Platt U,Perner D (1982) Observations of nitrous acid in the Los Angeles atmosphere and implications for predictions of ozone-precursor relationships. Environ Sci Techn 16:414–418
Harrison RM,Kitto A-MN (1994) Evidence for a surface source of atmospheric nitrous acid. Atmos Environ 28:1089–1094
Harrison RM,Peak JD,Collins GM (1996a) Tropospheric cycle of nitrous acid. J Geo Phys Res 101:14429–14439
Harrison RH,Peak JD,Kaye AD (1996b) Atmospheric aerosol major ion composition and cloud condensation nuclei over the northeast atlantic. J Geo Phys Res 101:4425–4434
Hatakeyama S,Izumi K,Akimoto H (1985) Yield of SO2and formation of aerosol in the photo-oxidation of DMS unter atmospheric conditions. Atmos Environ 19:583–586
Hatakeyama S,Izumi K,Fukuyama T,Akimoto H (1989) Reactions of ozone with a-pinene and ß-pinene in air: yields of gaseous and particulate products. J Geo Phys Res 94:13013–13024
Hatakeyama S,Izumi K,Fukuyama T,Akimoto H,Washida N (1991) Reactions of OH with a-pinene and ß-pinene in air: estimate of global CO production from the atmospheric oxidation of terpenes. J Geo Phys Res 96:947–958
Hellpointner E,Gäb S (1989) Detection of methyl,hydroxymethyl and hydroxyethyl hydroperoxides in air and precipitation. Nature 337:613–634
Hegg DA,Ferek RJ,Hobbs PV (1993) Light scattering and cloud condensation nucleus activity of sulfate aerosol measured over the Northeast Atlantic Ocean. J Geo Phys Res 98:14887–14894
Hewitt CN,Kok GL (1991) Formation and occurrence of organic hydroperoxides in the troposphere: laboratory and field observations. J Atmos Chem 12:181–194
Hewitt CN,Street RA (1992) A qualitative assessement of the emission of non-methane hydrocarbon compounds from the biosphere to the atmosphere in the UK: present knowledge and uncertainties. Atmos Environ 26A:3069–3077
Hoekman SK (1992) Speciated measurements and calculated reactivities of vehicle exhaust emissions from conventional and reformulated gasolines. Environ Sci Technol 26:1206–1216
Hofzumahaus A,Aschmutat U,Hessling M,Holland F,Ehhalt DH (1996) The measurement of tropospheric OH radicals by laser induced fluorescence spectroscopy during the POPCORN field campaign. Geo Phys Res Lett 23:25412544
Holton JR,Haynes PH,McIntyre ME,Douglass AR,Rood RB,Pfister L (1995) Stratosphere-troposphere exchange. Rev Geo Phys 33:403–439
Hu J,Stedman DH (1995) Atmospheric ROXradicals at an urban site: comparison to a simple theoretical model. Environ Sci Technol 29:1655–1659
Hynes AJ,Wine PH (1996) The atmospheric chemistry of dimethyl sulfoxide (DMSO) kinetics and mechanism of the OH+DMSO reaction. J Atmos Chem 24:23–37
Hynes AJ,Wine PH,Semmes DH (1986) Kinetics and mechanism of OH reactions with organic sulfides. J Phys Chem 90:4148–4156
Jacob DJ (1986) Chemistry of OH in remote clouds and its role in production of formic acid and peroxymonosulfate. J Geo Phys Res 91:9807–9812
Jenkin ME,Cox RA,Williams DJ (1988) Laboratory studies of the kinetics of formation of nitrous acid from the thermal reaction of nitrogen dioxide and water vapour. Atmos Environ 22:487–498
Jensen NR,Hjorth J,Lohse C,Skov H,Restelli G (1992) Products and mechanism of the gas phase reactions of NO3with CH3SCH3 CD3SCD3 CH3SH and CH3SSCH3. J Atmos Chem 14:95–108
Jobson BT,Niki H,Yokouchi Y,Bottenheim J,Hopper F,Leaitch R (1994) Measurements of C2–C6 hydrocarbons during the polar sunrise 1992 experiment: evidence for Cl atom and Br atopm chemistry. J Geo Phys Res 99:25355–25368
IPCC (1995) Intergovernmental panel on climate change,climate change 1994,radiative forcing of climate change and an evaluation of the IS92 emission scenarios (ed by Houghton et al). University Press, Cambridge
Junge (1963) Chemistry and radioactivity. Academic,New York
Junkermann W,Ibusuki TT (1992) FTIR spectroscopic measurements of surface bond products of nitrogen oxides on aerosol surfaces - implications for heterogeneous HONO production. Atmos Environ 26A:3099–3103
Kalberer M,Tabor K,Ammann M,Parrat Y,Weingartenr E,Piguet D,Rösseler E,Jost DT,Türler A,Gäggeler HW,Baltensperger U (1996) Heterogeneous chemical processing of13NO2by monodisperse carbon aerosols at very low concentrations. J Phys Chem 100:15487–15493
Kasibhatla PS,Levy II H,Moxim WJ,Chameides WL (1991) The relative impact of stratospheric photochemical production on tropospheric NOy levels: a model study. J Geo Phys Res 96:18631–18646
Kesselmeier J,Schäfer L,Ciccioli P,Brancaleoni E,Cecinato A,Frattoni M,Foster P,Jacob V,Denis J,Fugit JL,Dutaur L,Torres L (1996) Emission of monoterpenes and isoprene from a mediterranean oak species quercus ilex L. Measured within the BEMA (Biogenic Emissions in the Mediterranean Area) Project. Atmos Environ 30:1841–1850
Khwaja HA (1995) Atmospheric concentrations of carboxylic acids and related compounds at a semiurban site. Atmos Environ 29:127–139
Killus JP,Whitten GZ (1990) Background reactivity in smog chambers. Int J Chem Kinet 22:547–575
Kirchstetter ThW,Harley RA,Littlejohn D (1996) Measurement of nitrous acid in motor vehicle exhaust. Environ Sci Technol 30:2843–2849
Kleffmann J,Becker KH,Wiesen P (1998) Heterogeneous conversion processes on acid surfaces: possible atmospheric implications. Atmos Environ 32:2721–2729
Kleinman LI (1991) Seasonal dependence of boundary layer peroxide concentra-tion: the low and the high NO regimes. J Geo phys Res 96:20721–20733
Kleinman LI (1994) Low and the high NO tropospheric photochemsitry. J Geo Phys Res 99:16831–16838
Kleiman L,Lee Y-N,Springston SR,Nunnermacker L,Zhou X,Brown R,Hallock K,Klotz P,Leahy D,Lee JH,Newman L (1994) Ozone formation at a rural site in the southeastern United States. J Geo Phys Res 99:3469–3482
Klemm O,Ziomas IC,Balis D,Suppan P,Slemr J,Romero R,Vyras LG (1998) A summer air-pollution study in Athens,Greece. Atmos Environ 32:2071–2078
Klemp D,Kley D,Kramp F,Buers HJ,Pilwat G,Flocke F,Pätz HW,Volz-Thomas A (1997) Long-term measurements of light hydrocarbons (C2-05) at the Schauinsland (Black Forest). J Atmos Chem 28:135–171
Klotz B,Barnes I,Becker KH,Golding BT (1997) Atmospheric chemistry of benzene oxide/oxepin. J Chem Soc Faraday Trans 93:1507–1516
Klotz B,Sorensen S,Barnes I,Becker KH,Etzkorn T,Volkamer R,Platt U,Wirtz K,Martin-Revifjo M (1998) Atmospheric oxidation of toluene in a large volume outor photoreactor: In situ determination of ring-retaining product yileds. J Phys Chem (in press)
Knispel R,Koch R,Siese M,Zetzsch C (1990) Adduct formation of OH radicals with benzene,toluene,and phenol and consecutive reactions of the adducts with NO,,and 02. Ber Bunsenges Phys Chem 94:1375–1379
Kley D,Volz A,Mülheims F (1988) Ozone measurements in historic perspective. In: Isaksen ISA (ed) Tropospheric ozone. Reidel,Dodrecht,pp 63–73
Kourtidis KA,Fabian P,Zerefos C,Rappenglück B (1993) Peroxyacetyl nitrate (PAN),peroxypropionyl nitrate (PPN) and PAN/ozone ratio measurements at three sites in Germany. Tellus 45B:442–457
Kramp F,Volz-Thomas A (1997) On the budget of OH radicals and ozone in an urban plume from the decay of C5-C8hydrocarbons and NO R J Atmos Chem 28:263–282
Kreher K,Johnston PV,Wood SW,Nardi B,Platt U (1997) Ground-based measurement of tropospheric and stratospheric BrO at Arrival Heights,Antarctica. Geo Phys Res Lett 24:3021–3024
Kuchler W (1997) Jahresbericht der Immissionssituation im Freiland Sachsen,Jahresbericht 1996
Kumar N,Kulshrestha UC,Khare P,Saxena A,Kumari KM,Srivastava SS (1996) Measurements of formic and acetic acid levels in the vapour phase at Dayalbagh,Agra,India. Atmos Environ 30:3545–3550
Kwok ESC,Atkinson R,Arey J (1995) Observation of hydroxycarbonyls from the OH radical-initiated reaction of isoprene. Environ Sci Technol 29:2467–2469
Lacis AA,Wuebbles DJ,Logan JA (1990) Radiative forcing of climate by changes in the vertical distribution of ozone. J Geo Phys Res 95:9971–9981
Langner J,Rohde H,Crutzen PJ,Zimmermann P (1992) Anthropogenic influence on the distribution of tropopspheric sulphate aerosol. Nature 359:712–716
Lamb BK,Guenther AB,Gay D,Westberg HH (1987) A national inventory of biogenic hydrocarbon emissions. Atmos Environ 21:1695–1705
Lammel G (1988) Salpetrige Säure und Nitrit im Mehrphasensystem der belasteten Atmosphäre. Dissertation,Universität Mainz
Lammel G,Cape JN (1996) Nitrous acid and nitrite in the atmosphere. Chem Soc Rev 25:361–369
Lawrence JE,Koutrakis P (1994) Meaurement of atmospheric formic and acetic acids: methods evaluation and results from field studies. Environ Sci Technol 28: 957–964
Le Bras G,Platt U (1995) A possible mechanism for combined chlorine and bromine catalyzed destruction of tropospheric ozone in the arctic. Geo Phys Res Lett 22:599–602
Lee Y-N,Schwartz SE (1981) Reaction kinetics of nitrogen dioxide with liquid water at low partial pressure. J Phys Chem 85:840–848
Lee J H,Leahy DF,Tang IN,Newman L (1993) Measurement and speciation of gas phase peroxides in the atmosphere. J Geo Phys Res 98:2911–2915
Lee Y-N,Zhou X,Hallok K (1995) Atmospheric carbonyl compounds at a rural southeastern United State site. J Geo Phys Res 100(25):933–25944
Lee SH,Akimoto H,Nakane H,Kurnosenko S,Kinjo Y (1998) Lower tropospheric ozone trend observed in 1989–1997 at Okinawa,Japan. Geo Phys Res Lett 25:1637–1640
Lehning M (1996) Transport processes and regional pollutant budget over topography of varying complexity. PhD thesis,ETHZ,no 11991
Lehning M (1998) The regional pollutant budget of the atmospheric boundary layer: Concept,interpretations and observational results. Meteorol Z NF 7:112–119
Lehning M,Richner H,Kok GL,Neininger B (1998) Vertical exchange and regional budgets of air pollutants over densely populated areas. Atmos Environ 32:1353–1363
Lemmerich J (1990) Die Entdeckung des Ozons and die ersten 100 Jahre Ozonforschung,Berliner Beiträge zur Geschichte der Naturwissenschaften and der Technik. Sigma-Verlag,Berlin
Leone JA,Flagan RC,Grosjean D,Seinfield JH (1985) An outdoor smog chamber and modelling study of toluene-NOx photooxidation. Int J Chem Kinet 17:177–216
Levy H Jr (1971) Normal atmosphere: large radical and formaldehyde concentrations predicted. Science 173:141–143
Li S-M (1994) Equilibrium of particle nitrite with gas phase HONO: tropospheric measurements in the high arctic during polar sunrise. J Geo Phys Res 99: 25469–25478
Lightfoot PD,Cox RA,Crowley JN,Destriau M,Hayman GD,Jenkin ME,Moortgat GK,Zabel F (1992) Organic peroxy radicals: kinetics,spectroscopy and tropospheric chemistry. Atmos Environ 26A:1806–1961
Lin X,Chameides WL (1993) CCN Formation from DMS oxidation without SO2acting as an intermediate. Geo Phys Res Lett 20:579–582
Lin X,Chameides WL,Kiang CS,Stelson AW,Berresheim H (1992) A model study of the formation of clould condensation nuclei in remote marine areas. J Geo Phys Res 97:18161–18171
Littmann FE,Ford HW,Endow N (1956) Formation of ozone in the Los Angeles Atmosphere. Ind Eng Chem 48:1492–1497
Liu SC,Trainer M,Fehsenfeld FC,Parrish DD,Williams EJ,Fahey DW,Hubler G,Murphy PC (1987) Ozone production in the rural troposphere and its implications for regional and global ozone distributions. J Geo Phys Res 92:4194–4207
Locher R,Pfister H (1996) Ambient VOC in the centre of Zürich. In: Environmental Documentation 47. Federal Office of Environment,Forests and Landscape (FOEFL),Bern Switzerland,pp 119–122
Lowi A Jr,Carter WPL (1990) A method for evaluating the atmospheric ozone impact of actual vehicle emissions. SAE technical paper series,paper no 900–710
Lugauer M,Baltensperger U,Furger M,Gäggeler HW,Jost DT,Schwikowski M,Wanner H (1998) Aerosol transport to the high Alpine sites Jungfraujoch (3454) and Colle Gnifetti (4452). Tellus 50B:76–92
Mage D,Ozolins G,Peterson P,Webster A,Orthofer R,Vandeweerd V,Gwynne M (1996) Urban air pollution in megacities of the world. Atmos Environ 30:681–686
McConnell JC,Henderson GS,Barrie L,Bottenheim J,Niki H,Langford CH,Templeton EMJ (1992) Photochemical bromine production implicated in Arctic boundary layer ozone depletion. Nature 355:150–152
Meijer GM (1976) Methode voor de bepaling van Peroxybenzoylnitraat (PBzN) in buitenlucht en enkele resultaten. Centraal laboratorium tno delft/Rapport-no CL 76/2
Meijer GM,Nieboer H (1977) Determination of peroxybenzoyl nitrate (PBzN) in ambient air. VDI-Ber 270:55–56
Mertes S,Wahner A (1995) Uptake of nitrogen dioxide and nitrous acid on aqueous surfaces. J Phys Chem 99:14000–14006
Milford JB,Russell AG,McRae GJ (1989) A new approach to photochemical pollution control: implications of spatial patterns in pollution responses to reductions in nitrogen oxides and reactive organic gas emissions. Environ Sci Techn 23:1290–1301
Milford JB,Gao D,Sillman S,Blossey P,Russell AG (1994) Total reactive nitrogen (NOy) as an indicator of the sensitivity of ozone to reductions in hydrocarbon and NO emissions. J Geo Phys Res 99:3533–3542
Miyoshi A,Hatakeyama S,Washida N (1994) OH Radical-initiated photooxidation of isoprene: an estimate of global CO production. J Geo Phys Res 99:18779–18787
Montzka SA,Trainer M,Angevine WA,Fehsenfeld FC (1995) Measurements of 3-methyl furan,methyl vinyl ketone,and methacrolein at a rural forested site in the southeastern United States. J Geo Phys Res 100:11393–11401
Moortgat GK (ed) (1996) Laboratory studies on the tropospheric degradation mechanism of biogenic VOCs: isoprene and DMS,EC-Project EV5V-CT91–0038,final report
Müller JF (1992) Geographical distribution and seasonal variation of surface emissions and deposition velocities of atmospheric trace gases. J Geo Phys Res 97:3787–3804
Neftel A,Blatter A,Hesterberg R,Staffelbach T (1996) Measurement of concentration gradients of HNO2and HNO3over a seminatural ecosystem. Atmos Environ 30:3017–3025
Neininger B (1994) Flugzeugmessdaten Berlin 1994. Ein Auftrag der Länder Berlin und Brandenburg vertreten durch die Fachhochschule Wildau. MetAir,Illnau,Schweiz
Neininger B,Dommen J (1996) POLLUMET,Luftverschmutzung und Meteorologie in der Schweiz. Bundesamt für Umwelt Wald und Landschaft,Bern,Schweiz (Umwelt-Materialien Nr 63)
Notholt J,Hjorth J,Raes F (1992) Formation of HNO2on aerosol surfaces during foggy periods in the presence of NO and NO2. Atmos Environ 26A:211–217
NRC (National Research Concil) (1991) Rethingking of the ozone problem in urban and regional air pollution. National Academy Press,Washington
Olszyna KJ,Bailey EM,Simonaitis R,Meagher JF (1994) 03and NOyrelationships at a rural site. J Geo Phys Res 99:14557–14563
Paulson SE,Flagan RC,Seinfeld JH (1992) Atmospheric photooxidation of isoprene,part II: the ozone-isoprene reaction. Int J Chem Kinet 24:103–125
Penner JE,Charlson RJ,Hales JM,Laulainen N,Leifer R,Novakov T,Ogren J,Radke LF,Schwartz S,Travis L (1994) Quantifying and minimizing unceratinty of climate forcing by anthropogenic aerosols. Bull Am Meteorol Soc 75:375–400
Penkett SA,Brice KA (1986) The spring maximum of photo-oxidants in the Northern hemisphere. Nature 319:655–657
Perner D,Kessler C,Platt U (1987) HNO2 NO2and NO measurements in automobile engine exhaust by optical absorption. In: Grisar R et al (eds) Monitoring of gaseous pollutants by tunable diode lasers. Reidel,Dordrecht,pp 116–119
Pilling MJ,Seakins PW (1995) Reaction kinetics. Oxford Science,Oxford
Piccot SD,Watson JJ,Jones JW (1992) A global inventory of volatile organic corn-pound emissions from anthropogenic sources. J Geo Phys Res 97:9897–9912
Pinto JP,Stevens RK,Willis RD,Kellogg R,Mamane Y,Novak J,Santroch J,Benes I,Lenicek J,Bures V (1998) Czech air quality monitoring and receptor modeling study. Environ Sci Techn 32:843–854
Pitts JN Jr,Biermann H,Winer AM,Tuazon EC (1984) Spectroscopic identification and measurement of gaseous nitrous acid in dilute auto exhaust. Atmos Environ 18:847–854
Plane JMC (1995) Comment made at Faraday discussion 100. Faraday Disc 100:201 Palss-Dülmer C,Brauers T,Rudolph J (1998) POPCORN: a field study of photochemistry in North-Eastern Germany. J Atmos Chem 31:5–31
Platt U,Perner D,Winer AM,Harris GW,Pitts JN Jr (1980) Detection of NO3in the polluted troposphere by differential optical absorption. Geo Phys Res Lett 7:89–92
Platt U,Perner D,Schröder J,Kessler C,Toenissen A (1981) The diurnal variation of NO3. J Geo Phys Res 86:11965–11970
Prévôt ASH (1994) Photooxidantien und Primärluftschadstoffe in der plantearen Grenzschicht in der Schweiz nördlich und südlich der Alpen. Dissertation ETH,Nr 10956
Prévôt ASH,Staehelin J,Richner H,Griesser T (1993) A thermally driven system influencing concentrations of ozone precursors and photo-oxidants at a receptor site in the Alpine foothills Meteorol Z NF 2:167–177
Prévôt ASH,Staehelin J,Kok GL,Schillawski RD,Neiniger B,Staffelbach T,Neftel A,Wernli H,Dommen J (1997) The Milan photooxidant plume. J Geo Phys Res 102:23375–23388
Piringer M,Ober E,Puxbaum H,Kromp-Kolb H (1997) Occurrence of nitric acid and related compounds in the northern Vienna basign during summertime anticyclonic conditions. Atmos Environ 31:1049–1057
Pszenny AAP,Keen WC,Jacob DJ,Fan S,Maben JR,Zetwo MP,Springer-Young M,Galloway JN (1993) Evidence of inorganic chlorine gases other than hydrogen chloride in marine surface air. Geo Phys Res Lett 20:699–702
Raes F,Vandingenen R (1992) Simulations of condensation and clould condensation nuclei from biogenic SO2in the remote marine boundary layer. J Geo Phys Res 97:12901–12912
Raga GB,Le Moyne L (1996) On the nature of air pollution dynamics in the Mixico City - I. Nonlinear analysis. Atmos Environ 30:1049–1057
Ramacher B,Rudolph J,Koppermann R (1997) Hydrocarbon measurements in the spring Arctic Troposphere during the ARCTOC95 campaign. Tellus B 49:466–485
Ray A,Vassalli I,Laverdet G,Le Bras G (1996) Kinetics of the thermal decomposition of the CH3SO2radical and its reaction with NO2at 1 Torr and 298 K. J Phys Chem 100:8895–8900
Reimann,S,Grob K,Frank H (1996) Chloroacetic acids in rainwater. Environ Sci Technol 30:2340–2344
Reiner T,Arnold F (1993) Laboratory flow reactor measurements of the reaction SO3+ H2O +M -* H2SO4+ M,implication for gaseous H2SO4and aerosol formation in the plumes of jet aircraft. Geo Phys Res Lett 20:2659–2662
Roemer M (1996) Trends of tropospheric ozone over Europe,PhD thesis,University of Utrecht,The Netherlands
Rubino RA,Bruckmann L,Magyar J (1976) Ozone transport. J Air Pollut Contr Assoc 26:972–975
Rudd HJ (1995) Emissions of VOC from stationary sources in UK: speciation. Report AEA/CS/16419033/REMA-029,Harwell,UK
Rudolph J,Koppmann R,Plass-Dülmer C (1996) The budgets of ethane and tetrachloroethene: is there evidence for an impact of reactions with chlorine atoms in thetroposphere? Atmos Environ 30:1887–1894
Rudolph J,Ramacher R,Plass-Dülmer C,Müller K-P,Koppmann R (1997) The indirect determination of chlorine atom concentration in the troposphere from changes in patterns of non-methane hydrocarbons. Tellus B 49:592–601
Ruppert L (1996) Abbaumechanismen biogener Kohlenwasserstoffe in der Troposphäre - Laboruntersuchungen am Beispiel des Isopren,PhD thesis,Bergische Universität/Gesamthochschule Wuppertal
Ruppert L,Barnes I,Becker KH (1995) Tropospheric reactions of isoprene and oxidation products: Kinetic and mechanistic studies. In: Becker KH (ed) Tropospheric oxidation mechanisms. Proceedings of the joint EC/EUROTRAC/ GDCh workshop LACTOZ-HALIPP,Leipzig (D),20–22 Sept 1994,pp 91–102 (European Commission,Luxembourg,1995)
Ruppert L,Barnes I,Becker KH (1996) New features from the isoprene+OH-reaction. In: Mirabel P (ed) Homogeneous and heterogenous chemical processes in the troposphere. Proceedings of the EC/EUROTRAC Workshop LACTOZ-HALIPP,Straßburg,25–26 Sept 1995,pp 218–224,European Comission Report EUR 16766 EN,Brüssel
Russell AG,Milford JB,Bergin MS,McBride S,McNair L,Yang Y,Stockwell WR,Croes B (1995) Urban ozone control and atmospheric reactivity of organic gases. Science 269:491–495
Salawitch RJ,Wofsy SC,Wennberg PO,Cohen RC,Anderson JG,Fahey DW,Gao RS,Keim ER,Woodbridge EL,Stimpfle RM,Koplow JP,Kohn DW,Webster CR,May RD,Pfister L,Gottlieb EW,Michelsen HA,Yue GK,Prather MJ,Wilson JC,Brock CA,Jonsson HH,Dye JE,Baumgardner D,Proffit MH,Loewenstein M,Podolske JR,Elkins JW,Dutton GS,Hintsa EJ,Dessler AE,Weinstock EM,Kelly KK,Boering KA,Daube BC,Chan KR,Bowen SW (1994) The diurnal variation of hydrogen,nitrogen,and chlorine radicals: implication for heterogeneous production of HNO2. Geo Phys Res Lett 21:2551–2554
Sakamaki F,Akimoto H (1988) HONO formation as unknown radical source in photochemical smog chambers. Int J Chem Kinet 20:111–116
Sakamaki F,Hatakeyama S,Akimoto H (1983) Formation of nitrous acid and nitric oxide in the heterogeneous dark reaction of nitrogen dioxide and water vapour in a smog chamber. Int J Chem Kinet 15:1013–1029
Sakugawa H,Kaplan IR (1989) H2O2and 03in the atmosphere of Los Angeles and its vicinity: factors controlling their formation and their role as oxidants of SO2. J Geo Phys Res 94:12957–12973
Saunders SM,Jenkin ME,Derwent RG,Piling MJ (1997) Report summary. Wold Wide Web site of master chemical mechanism (MCM) for use in tropospheric chemistry models. Atmos Environ 31:1249
SCAG (1991) Southern California Association of Governments,South Coast Air Quality Management District,1991,Air Quality Management Plan,Sacramento,California
Schäfer C,Neeb P,Sauer F,Horie O,Moortgat GK (1996) Influence of water vapour on the product formation in the ozonolysis of selected C3-C6alkenes. In: Mirabel P (ed) Homogeneous and heterogenous chemical processes in the troposphere. Proceedings of the EC/EUROTRAC Workshop LACTOZ-HALIPP,Straßburg,25–26 Sept 1995,pp 296–304,European Comission Report EUR 16766 EN,Brüssel
Schumann U (1997) The impact of nitrogen oxides emissions from aircraft upon the atmosphere at flight altitudes - results from the AERONOX project. Atmos Environ 31:1723–1733
Scire JS,Chang J (1991) Analysis of historical ozone episodes in the SCCCAMP region and comparison with SCCCAMP 1985 field study data. J Appl Met 30:551–584
Seinfeld JH (1986) Air pollution. Wiley,New York
Seinfeld JH,Pandis SN (1998) Atmospheric chemistry and physics. Wiley,New York
Sempéré R,Kawamura K (1996) Low molecular weight dicarboxylic acids and related polar compounds in the remote marine rain samples collected from western pacific. Atmos Environ 30:1609–1619
Sexton K,Westberg H (1980) Elevated ozone concentrations measured downwind of the Chicago-Gary urban complex. J Air Pollut Contr Assoc 30:911–914
Siese M,Koch R,Fittschen C,Zetzsch C (1994) Cycling of OH in the reaction systems toluene/O2/NO and acetylene/02and the addition of OH to isoprene. In: Borell PM,Borrell P,Cvitas T,Seiler W (eds) EUROTRAC symposium ‘84 „Transport and transformation of pollutants in the troposphere,11–15 Apr 1994,SPB Academic,Den Haag,Niederlande,S 115–119
Simpson D,Guenther A,Hewitt CN,Steinbrecher R (1995) Biogenic emissions in Europe 1. Estimates and uncertainties. J Geo Phys Res 100:22875–22890
Singh HB,Thakur AN,Chen YE,Kanakidou M (1996) Tetrachloroethylene as an indicator of low Cl atom concentrations in the troposphere. Geo Phys Res Lett 23:1529–1532
Sillman S (1999) The relation between ozone,NO and hydrocarbons in urban and polluted rural environments. Atmos Environ 33:1821–1845
Sillman S,Logan JA,Wofsy SC (1990) The sensitivity of ozone to nitrogen oxides and hydrocarbons in regional ozone episodes. J Geo Phys Res 95:1837–1851
Sillman S (1995) The use of NOT H2O2 and HNO3as indicators for ozone-NOXhydrocarbon sensitivity in urban locations. J Geo Phys Res 100:14175–14188
Simonaitis R,Olszyna KJ,Meagher JF (1991) Production of hydrogen peroxide and organic peroxides in the gas phase reaction of ozone with natural alkenes. Geo Phys Res Lett 18:9–12
Singh HB,Salas LJ,Viezee W (1986) Global distribution of peroxyacetyl nitrate. Nature 321:588–592
Skov H,Hjorth J,Jensen NR,Restelli G (1992) Products and mechanisms of the reactions of the nitrate radical (NO3) with isoprene,1,3-butadiene and 2,3-dimethyl-1,3-butadiene in air. Atmos Environ 26A:2771–2783
Slemr J,Junkermann W,Volz-Thomas A (1996) Temporal variations in formaldehyde,acetaldehyde and acetone and budget of formaldehyde at a rural site in Southern Germany. Atmos Environ 30:3667–3676
Solberg S,Dye C,Schmidbauer N,Herzog A,Gehrig R (1996) Carbonyls and nonmethane hydrocarbons at rural sites from the Mediterranean to the Arctic. J Atmos Chem 25:33–66
Sorensen S,Falbe-Hansen H,Mangoni M,Hjorth J,Jensen NR (1996) Observation of DMSO and CH3S(0)OH from the gas phase reaction between DMS and OH. J Atmos Chem 24:299–315
Spicer CW (1982) Nitrogen oxide reactions in the urban plume of Boston. Science 215:1095–1097
Staehelin J,Thudium J,Bühler R,Volz-Thomas A,Graber W (1994) Trends in surface ozone concentrations at Arosa (Switzerland). Atmos Environ 28:75–87
Staehelin J,Kegel R,Harris NRP (1998) Trend analysis of the homogenised total ozone series of Arosa (Switzerland),1926–1996. J Geo Phys Res 103:8389–8399
Staffelbach T,Neftel A,Blatter A,Gut A,Fahrni M,Staehelin J,Prévt A,Hering A,Lehning M,Neiniger B,Bäumle M,Kok GL,Dommen J,Hutterli M,Anklin M (1997a) Photochemical oxidant formation over Southern Switzerland,part I: results from summer 1994. J Geo Phys Res (in press)
Staffelbach T,Neftel A,Horowitz LW (1997b) Photochemical oxidant formation over Southern Switzerland,part II: model results. J Geo Phys Res (in press)
Stickel RE,Nicovich JM,Wang S,Zhao Z,Wine PH (1992) Kinetic and mechanistic study of the reaction of atomic chlorine with dimethyl sulfide. J Phys Chem 96:9875–9883
Stickel RE,Zhao Z,Wine PH (1993) Branching ratios for hydrogen tranfer in the reactions of OD radicals with CH3SCH3and CH3SC2H5. Chem Phys Lett 212:312–318
Streit GE,Guzman F (1996) Mexiko city air quality: progress of an international collaborative project to define air quality management options. Atmos Environ 30:723–733
Stull RB (1988) An introduction to boundary layer climatology. Atmospheric Sciences Library. Kluwer Academic,Dodrecht
Suppan P,Fabian P,Vyras LG,Gryning SE (1998) The bevaviour of ozone and peroxyacetyl nitrate concentrations for different wind regimes during the MEDCAPHOT-trace campaign in the greater area of Athens,Greece. Atmos Environ 32:2089–2102
Svensson R,Ljungström E,Lindqvist O (1987) Kinetics of the reaction between nitrogen dioxide and water vapour. Atmos Environ 21:1529–1539
Temple PJ,Taylor OC (1983) World-wide ambient measurements of peroxyacetyl nitrate (PAN) and implications for plant injury. Atmos Environ 17:1583–1587
Toumi R (1994) BrO as a possible sink for dimethylsulfide in the marine atmosphere. Geo Phys Res Lett 21:117–120
Thomm J,Wolff S,Turner WV,Gäb S,Thomas W,Zabel F,Fink EH,Becker KH (1996) Proof of the formation of hydroperoxmethyl formate in the ozonolysis of ethene: synthesis of FT-IR spectra of the compound. Chem Phys Lett 258:155–158
Toumi R (1994) BrO as a possible sink for dimethylsulfide in the marine atmosphere. Geo Phys Res Lett 21:117–120
Trainer M,Williams EJ,Parish DD,Buhr MP,Allwine EJ,Westberg HH,Fehsenfeld FC,Liu SC (1987) Models and observations of the impact of the natural hydrocarbons on rural ozone. Nature 322:705–707
Trainer M,Parrish DD,Buhr MP,Norton RB,Fehsenfeld FC,Anlauf KG,Botten-heim JW,Tang YZ,Wiebe HA,Roberts JM,Tanner RL,Newman L,Bowersox VC,Meagher JF,Olszyna KJ,Rodgers MO,Wang T,Berresheim H,Demerjian KL,Roychowdhury UK (1993) Correlation of ozone with NOyin photochemically aged air. J Geo Phys Res 98:2917–2925
Trainer M,Ridley BA,Buhr MP,Kok G,Walega J,Hübler G,Parrish DD,Fehsenfeld FC (1995) Regional ozone and urban plumes in the southeastern United States: Birmingham,a case study. J Geo Phys Res 100:18823–18834
Tsalkani N,Perros P,Dutot AL,Toupance G (1991) One-year measurements of PAN in the Paris basign: effect of meteorological parameters. Atmos Environ 25A:1941–1949
Tuazon EC,Atkinson R (1990) A product study of the gas-phase reaction of isoprene with the OH radical in the presence of NOX. Int J Chem Kinet 22:1221–1236
Tuazon EC,Winer AM,Pitts IN Jr (1981) Trace pollutant concentrations in a multiday smog epsiode in the California South coast air basin by long path length Fourier transform infrared spectroscopy. Environ Sci Techn 15:1232–1237
Turnipseed AA,Barone SB,Ravishankara AR (1992) Observation of CH3S addition to 02in the gas phase. J Phys Chem 96:7502–7505
Turnipseed AA,Barone SB,Ravishankara AR (1996) Reaction of OH with di-methyl sulfide. 2. Products and mechanisms. J Phys Chem 100:14703–14713
Van Dingenen R,Jensen NR,Hjorth J,Raes F (1994) Peroxynitrate formation during the night-time oxidation of dimethylsulfide: its role as a reservoir species for aerosol formation. J Atmos Chem 18:211–237
Varey RH,Ball DJ,Crane AJ,Laxen DPH,Sandalls Ft (1988) Ozone formation in the London plume. Atmos Environ 22:1335–1346
Vogel B,Fiedler F,Vogel H (1995) Influence of topography and biogenic volatile organic compound emission in the State of Baden-Württemberg on ozone concentrations during episodes of high air temperatures. J Geo Phys Res 100:22907–22928
Vogt R,Crutzen Pl,Sander R (1996) A mechanism for halogen release from sea salt aerosol in the remote marine boundary layer. Nature 383:327–330
Volz-Thomas A (1993) Trends in photo-oxidant concentrations. In: Borell PM,Borell P,Cvitas T,Seiler W (eds) The proceedings of EUROTRAC symposium ‘82. SPB Academic,The Hague,The Netherlands,pp 59–64
Volz A,Kley D (1988) Evaluation of the Montsouris series of ozone measurements made in the nineteenth century. Nature 332:240–242
Volz-Thomas A,Flocke F,Garthe HJ,Geiss H,Gilge S,Heil T,Kley D,Klemp D,Kramp F,Milehcic D,Pätz HW,Schultz M,Su Y (1993) Photooxidants and precursors at Schauinsland,Black Forrest. In: Borell et al (eds) Proc Eurotrac Symp 92. SPB Academic,The Hague,pp 98–103
Wallington TJ,Ellermann T,Nielsen OJ (1993) Atmospheric chemistry of di-methyl sulfide: UV spectra and self-reaction kinetics of CH3SCH2and CH3SCH2O2radicals and kinetics of the reactions CH3SCH2+ 02—> CH3SCH2O2and CH3SCH2O2+ NO —* CH3SCH2O + NO2. J Phys Chem 97:8442–8449
Wängberg I,Barnes I,Becker KH (1997) Product and mechanistic study of the reaction of NO3radicals with a-pinene. Environ Sci Techn 31:2130–2135
Warneck P (1988) Chemistry of the natural atmosphere. Academic,London (International geophysics series,vol 41)
Wayne RP (1988) Principles and applications of photochemistry,2nd edn. Oxford University Press,New York
Wayne RP,Barnes I,Biggs P,Burrows JP,Canosa-Mas CE,Hjorth J,Le Bras G,Moortgat GK,Perner D,Poulet G,Restelli G,Sidebottom H (1991) The nitrate radical: physics,chemistry,and the atmosphere. Atmos Environ 25A:1–206
Wennberg PO,Hanisco TF,Jaeglé L,Jacob DJ,Hinsta EJ,Lanzendorf EJ,Anderson JG,Gao R-S,Keim ER,Donelly SG,Del Negro LA,Fahey DW,McKeen SA,Salawitch RJ,Webster CR,May RD,Herman RL,Proffitt RJ,Margitan JJ,Atlas EL,Schauffler SM,Flocke F,McElroy CT,Bui TP (1998) Hydrogen radicals,nitrogen radicals,and the production of 03in the upper troposphere. Nature 279:49–53
Wernli H (1995) Lagrangian perspective of extratropical cyclones. Diss ETH Nr 11 016,ETH-Zürich
White WH,Anderson JA,Blumenthal DL,Husar RB,Gillani NV,Husar JD,Wilson WE Jr (1976) Formation and transport of secondary air pollutants: Ozone and aerosols in the St Louis Urban plume. Science 194:187–189
Wiesen P,Kleffmann J,Kurtenbach R,Becker KH (1995) Mechanistic study of the heterogeneous conversion of NO2into HONO on acid surfaces. Faraday Discuss 100:121–127
Williams EL Jr,Grosjean D (1990) Southern California air quality study: peroxyacetyl nitrate. Atmos Environ 9:2369–2377
Williams EL Jr,Grosjean D (1991) Peroxypropinyl nitrate at a Southern California mountain forest site. Environ Sci Technol 25:653–659
Williams EL Jr,Grosjean E,Grosjean D (1993) Ambient levels of the peroxyacyl nitrates PAN,PPN and MPAN in Atlanta,Georgia. J Air Waste Manage Assoc 43:873–879
Williams J,Roberst JM,Fehsenfeld FC,Bertman SB,Buhr MP,Goldan PD,Hübler G,Kuster WC,Reyerson TB,Trainer M,Young V (1997) Regional ozone from biogenic hydrocarbons deduced from airborne measurements of PAN,PPN and MPAN. Geo Phys Res Lett 24:1099–1102
Winer AM,Biermann HW (1994) Long pathlength differential optical absorption spectroscopy (DOAS) measurements of gaseous HONO,NO2and HCHO in the California South Coast Air Bassin. Res Chem Intermed 20:423–445
Wunderli S,Gehrig R (1991) Influence of temperature on formation and stability of surface PAN and ozone. A two year field study in Switzerland. Atmos Environ 25A:1599–1608
Yin F,Grosjean D,Seinfeld JH (1990) Photooxidation of DMS and DMDS I: Mechanism Development. J Atmos Chem 11:309–364
Yu J,Jeffries HE (1997) Atmospheric photooxidation of Alkylbenzenes - II. Evidence of formation of epoxide entermediates. Atm Env 31:2281–2287
Zabel F (1995) Unimolecular decomposition of peroxynitrates. Zeitschrift f. Phys Chemie 188,119–142
Zaveri RA,Saylor RD,Peters LK,McNider R,Song A (1995) A model investigation of summertime diurnal ozone behavior in rural mountainous locations. Atm Env 29:1043–1065
Literatur
Bates DR,Nicolet M (1950) The photochemistry of atmospheric water vapour. J Geophys Res 55:301
Bekki S,Pyle JA (1994) A two-dimensional modelling study of the volcanic eruption of Mt. Pinatubo. J Geophys Res 99:18861–18869
Bojkov RD,Zerefos CS,Balis DS,Ziomas IC,Bair AF (1993) Record low total ozone during northern winters of 1992 and 1993. Geophys Res Lett 20:1351–1354
Bojkov RD,Bishop L,Fioletov VE (1995 a) Total ozone trends from quality controlled ground based data (1964–1994). J Geophys Res 100:25867–25876
Bojkov RD,Fioletov VE (1997) Changes of the lower stratospheric ozone over Europe and Canada. J Geophys Res 102:1327–1347
Brasseur G,Solomon S (1984) Aeronomy of the middle atmosphere. Reidel,Dordrecht
Brasseur G,Granier C (1992) Mt. Pinatubo aerosols,chlorofluorocarbons and ozone depletion. Science 257:1239–1242
Browell EV,Butler CF,Ismail S,Robinett PA,Carter AF,Higdon NS,Toon OB,Schoeberl MR,Tuck AF (1990) Lidar observations in the wintertime Arctic stratosphere: polar stratospheric clouds. Geophys Res Lett 17:385–388
Burrows JP et al (1999) The Global Ozone Monitoring Experiment (GOME) - mission concept and first scientific results. J Atmos Sci 56:151–175
Carslaw KS,Luo BP,Clegg SL,Peter T,Brimblecombe P,Crutzen PJ (1994) Stratospheric aerosol growth and HNO3gas phase depletion from coupled HNO3and H2O uptake by liquid particles. Geophys Res Lett 21:2479–2482
Carslaw KS,Klegg SL,Brimblecomb P (1995) A thermodynamic model of the system HC1-HNO3-H25O4-H2O,including solubilities of HBr from 328 K to 200 K. J Phys Chem 99:11557–11574
Carslaw KS,Peter T,Clegg SL (1997) Modelling the composition of liquid stratospheric aerosols. Rev Geophys 35:125–154
Chapman S (1930) A theory of upper atmosphere ozone. Mem R Meteorol Soc 3:103
Crutzen PJ (1971) Ozone production rates in an oxygen-hydrogen-nitrogen oxide atmosphere. J Geophys Res 76:7311
Crutzen PJ. (1976) The possible importance of COS for the sulfate layer of the stratosphere. Geophys Res Lett 3:73–76
Dameris M,Grewe V (1994) Three-dimensional description of the stratospheric polar vortex. Beitr Phys Atmos 67:157–160
Danckwerts PV (1970) Gas-liquid reactions. McGraw-Hill,New York
DeMore WB,Sander SP,Golden DM,Hampson RF,Kurylo MJ,Howard CJ,Ravishankara AR,Kolb CE,Molina MI (1997) Chemical kinetics and photochemical data for use in stratospheric modelling. NASA-JPL publ 97/4
Dütsch HU (1980) Vertical ozone distribution and tropospheric ozone. Proc NATO Adv Study Inst Atmospheric Ozone,FAA-EE-80–20:7
Dunkerton T (1978) On the mean meridional mass motion of the stratosphere and mesosphere. J Atmos Sci 35:2325–2333
Ehhalt DH,Tonnisson A (1980) Hydrogen and carbon compounds in the stratosphere. In: Nicolet M,Aikin AC (eds) Proceedings of the NATO ASI series on atmospheric ozone. US Department of Transportation,Washington DC,pp 129–151
Ehhalt DH (1999) In: Zellner R (ed) Global aspects of atmospheric chemistry. Steinkopff,Darmstadt
Fahey DW,Kelly KK,Ferry GV,Poole LR,Wilson JC,Murphy DM,Loewenstein R,Chan KR (1989) In situ measurements of total reactive nitrogen,total water and aerosol in a polar stratospheric cloud in Antarctica. J Geophys Res 94:11299–11315
Farman JC,Gardiner BJ,Shanklin DD (1985) Large losses of total ozone in Antarctica reveal seasonal ClOX/NOXinteraction. Nature 315:207–210
Fioletov VE,Kerr JB,Wardle DI,Davies J,Hare EW,McElroy CT,Taranick DW (1997) Long-term ozone decline over the Canadian Arctic to early 1997 from ground-based and balloon oberservations. Geophys Res Lett 24:2705–2708
Gable CM,Betz HF,Maron SH (1950) Phase equilibria of the system sulphur trioxide-water. J Am Chem Soc 72:1445–1448
Hamill P,Turco RP,Toon OB (1988) On the growth of nitric acid and sulfuric acid aerosol particles under stratospheric conditions. J Atmos Chem 7:287–315
Hanson DR,Ravishankara AR,Solomon S (1994) Heterogeneous reactions in sulfuric acid aerosols: a framework for model calculations. J Geophys Res 99:3615–3629
Hofmann DJ,Oltmans SJ,Lathrop JA,Harris JM,Vömel H (1994b) Record low ozone at the South Pole in the spring of 1993. Geophys Res Lett 21:421–424
Holton JR,Haynes PH,McIntyre ME,Douglas AR,Rood RB,Pfister L (1995) Stratosphere-troposphere exchange. Rev Geophys 33:403–439
IPCC (1995) Climate change 1994,report of the intergovernmental panel on climate change. Cambridge University Press, Cambridge
Jäger H,Deshler T,Homberg F,Freuenthaler V (1997) Five years of lidar observations of the Pinatubo eruption cloud. Proc Int Laser Radar Conf,Springer
JGR (1993) Articles by Rind et al, Chu et al, McCormick et al, Chiou et al, Pruost et al, Larsen et al. In: J Geophys Res 98(D3):4835–4917
Johnston HS (1971) Reduction of stratospheric ozone by nitrogen oxide catalysts from supersonic transport exhaust. Science 173:517–522
Junge CE,Chagnon CW,Manson JE (1961) Stratospheric aerosols. J Meteorol 18:81–108
Kawa SR,Fahey DW,Heidt LE,Pollock WH,Solomon S,Anderson DE,Loewenstein M,Profitt MH,Margitan JJ,Chan KR (1992) Photochemical partitioning of the reactive nitrogen and chlorine reservoirs in the high-latitude stratosphere. J Geophys Res 97:7905–7923
Kelly KK,Tuck AF,Heidt LE (1990) A comparison of ER-2 measurements of stratospheric water vapor between the 1987 Antarctic and 1989 Arctic airborn missions. Geophys Res Lett 17:465–468
Khalil MAK,Rasmussen RA,Gunawardena R (1993) Atmospheric methyl bromide: trends and global mass balance. J Geophys Res 98:2887–2896
Koop T,Carslaw K (1996) Melting of H2SO4-H2O particles upon cooling: implications for polar stratospheric clouds. Science 272:1638–1641
Manney GL,Zurek RW,O’Neill A,Swinbank R (1994 a) On the motion of air through the stratospheric polar vortex. J Atmos Sci 51:2973–2994
McElroy MB,Salawitch RJ,Wofsy SC,Logan JA (1986) Reduction of Antarctic ozone due to synergistic interactions of chlorine and bromine. Nature 321: 759–762
Molina LT,Molina MJ (1987) Production of C12O2from the self-reaction of the C1O radical. J Phys Chem 91:433–436
Molina MJ,Rowland FS (1974) Stratospheric sink for chlorofluoromethanes. Chlorine atom catalyzed destruction of ozone. Nature 249:810
Montzka SA,Butler JA,Myers RC,Thompson TM,Swanson TH,Clarke AD,Lock LT,Elkins JW (1996) Decline in the tropospheric abundance of halogen from halocarbons: implications for stratospheric ozone depletion. Science 272:1318–1322
Naujokat B,Pyle JA (1997) In: European research on the stratosphere. European Commission,Brussels,pp 39–60
Newman PA,Lait LR,Schoeberl MR,Nash ER,Kelly KK,Fahey DW,Nagatani RM,Toohey DW,Avallone LM,Anderson JG (1993) Stratospheric meteorological conditions in the Arctic polar vortex 1991 to 1992. Science 261:1143–1146
Newman PA,Gleason JF,McPeters RD,Stolarski RS (1997) Anomalously low ozone over the Arctic. Geophys Res Lett 24:2689–2692
Norton W,Chipperfield M (1995) Quantification of the transport of chemically activated air from the northern hemisphere polar vortex. J Geophys Res 199:25817–25840
O’Neill,A,Grose WL,Pope VD,MacLean H,Swinbank R (1994) Evolution of the stratosphere during northern winter 1991/1992 as diagnosed from the UK Meteorological Office Analyzer. J Atmos Sci 51:2800–2817
Oltmans SJ,Hofmann DJ (1995) Increase in lower stratospheric water vapour at a mid-latitude Northern Hemisphere site from 1981–1993. Nature 374:146–149
Pawson S,Labitzke K,Lenshow R,Naujokat B,Rajenski B,Wiesner M,Wohlfahrt RC (1993) Climatology of the northern hemispheric stratosphere derived from Berlin analysis,part 1: monthly means. Meteorol Abhandl Ser A,vol 7,3
Pawson S,Naujokat B,Labitzke K (1995) On the polar stratospheric cloud forma-tion potential of the northern stratosphere. J Geophys Res 100:23215–23225
Schiller C,Engel A,Schmidt U,Borchers R,Ovarlez J (1996) The partioning of hydrogen species in the Arctic winter stratosphere: implications for micro-physical parameters. J Geophys Res 101:14489–14493
Schoeberl MR,Lait LR,Newman PA,Rosenfield JE (1992) The structure of the polar vortex. J Geophys Res 97:7859–7882
Schwartz SE (1986) Chemistry of mulitphase atmospheric systems. NATO ASI series. Springer,Berlin Heidelberg New York
Seinfeld JL,Pandis SN (1998) Atmospheric chemistry and physics. Wiley,New York
Solomon S,Garcia RR,Ravishankara AR (1994) On the role of iodine in ozone depletion. J Geophys Res 99:20491–20499
Solomon S,Portmann RW,Garcia RR,Thomason LW,Poole LR,McCormick MP (1996) The role of aerosol variations in anthropogenic ozone depletion at northern mid-latitudes. J Geophys Res 101:6713–6727
Steele HM,Hamill P (1981) Effects of temperature and humidity on the growths and optical properties of sulfuric acid-water droplets in the stratosphere. J Aerosol Sci 12:517–528
Stolarski RS,Cicerone RJ (1974) Stratospheric chlorine: a possible sink for ozone. Can J Chem 52:1610
Tabazadeh A,Turco RP (1993) A model for heterogeneous chemical processes on the surface of ice and nitric acid trihydrate particles. J Geophys Res 98:12727–12740
Trepte CR,Veiga RE,McCormick MP (1993) The poleward dispersion of Mount Pinatubo volcanic aerosols. J Geophys Res 98:18563–18573
Wahner A,Schiller C (1992) Twiligth variation of vertical column abundances of OC1O and BrO in the north polar region. J Geophys Res 97:8047–8055
Warneck P (1999) In: Zellner R (ed). Global aspects of atmospheric chemistry. Steinkopff,Darmstadt
Warneck P (1988) Chemistry of the natural atmosphere. Academic,San Diego
WMO (1986)Atmospheric ozone 1985. World Meteorological Organization,Global Ozone Research and Monitoring Project,report no 16,Geneva
WMO (1989) Report of the International Ozone Trends Panel,1988. World Meteorological Organization,Global Ozone Research and Monitoring Project,report no 18,Geneva
WMO (1992) Scientific assessment of ozone depletion: 1991,World Meteorological Organization,Global Ozone Research and Monitoring Project,report no 25,Geneva
WMO (1995) Scientific assessment of ozone depletion: 1994,World Meteorogical Organization,Global Ozone Research and Monitoring Project,report no 37,Geneva
WMO (1998) Scientific assessment of ozone depletion 1997. World Meteorological Organization,Global Ozone Research and Monitoring Project,report no 44,Geneva
Wofsy SC,McElroy MB,Yung YC (1975) The chemistry of atmospheric bromine. Geophys Res Lett 2:215–218
Zenner R (1986) Chemistry of free radicals in the atmosphere. Oxid Comm 9:255–300
Zellner R (1999) In: Zellner R (ed) Global aspects of atmospheric chemistry. Steinkopff,Darmstadt
Zerefos CS (1997) WMO Ozone Mapping Center,Thessaloniki,private communication
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2000 Springer-Verlag Berlin Heidelberg
About this chapter
Cite this chapter
Ebel, A., Staehelin, J., Prévôt, A.S.H., Barnes, I., Zellner, R. (2000). Umwandlung von Spurenstoffen und ihre Auswirkungen auf die Atmosphäre. In: Guderian, R. (eds) Handbuch der Umweltveränderungen und Ökotoxikologie. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-57087-2_3
Download citation
DOI: https://doi.org/10.1007/978-3-642-57087-2_3
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-63037-8
Online ISBN: 978-3-642-57087-2
eBook Packages: Springer Book Archive