Abstract
Molecular level fluorescent sensors can be built up following a two-component approach, i.e. by covalently linking a light-emitting fragment to the receptor suitable for the envisaged analyte. When the analyte is an anion, the recognition process can be based on the rather energetic and directional metal-ligand interaction In this case, the receptor subunit must contain a coordinatively unsaturated metal centre, leaving one or more vacant coordination sites available for anion binding In this perspective, the use of the [ZnII(tren)]2+ platform has been exploited with a special regard to the interaction with the -COO- group Linking appropriate substituents to the tren framework allowed the design of ZnII based sensors which signalled carboxylate recognition through either fluorescence quenching (on/off) or revival (off/on) Finally, the same two-component approach has been utilised for the design of a fluorescent thermometric probe.
This is a preview of subscription content, log in via an institution.
Buying options
Tax calculation will be finalised at checkout
Purchases are for personal use only
Learn about institutional subscriptionsPreview
Unable to display preview. Download preview PDF.
References
de Silva AP, Gunaratne HQN, Gunnlaugsson T, Huxley AJM, McCoy CP, Rademacher JT, Rice TE (1997) Chem Rev 97:1515
Czarnik AW (1994) Chem Biol 2:423
Fabbrizzi L, Poggi A (1995) Chem Soc Rev 24:197
Fabbrizzi L, Licchelli M, Pallavicini P, Perotti A, Taglietti A, Sacchi D (1996) Chem-Eur J 2:167
de Silva AP, de Silva SA (1986) J Chem Soc Chem Commun 1709
Minta A, Kao JPY, Tsien RY (1989) J Biol Chem 264:8171
Schmidtchen FP, Berger M (1997) Chem Rev 97:1609
Dhaenens M, Lehn JM, Vigneron JP (1993) J Chem Soc Perkin Trans 2:1379
(a)Fabbrizzi L, Licchelli M, Pallavicini P, Parodi L, Poggi A, Taglietti A (1996) Anion Sensing based on the metal ligand interactions In: Echegoyen L, Kaifer A (eds) Nato ASI Series, Physical supramolecular chemistry Kluwer Academic Publishers, Dordrecht, 433; (b) Fabbrizzi L, Pallavicini P, Perotti A, Parodi L, Taglietti A (1995) Inorg Chim Acta 238:5
Pallavicini P, Sardone N (unpublished results)
Suppan P ( 1994) Chemistry and light The Royal Society of Chemistry, Cambridge, pp 66–68
(a) Moketakis RJ, Martell AE, Lehn JM, Watanabe EI (1982) Inorg Chem 21:4253; (b) Prue J, Schwarzenbach G (1950) Helv Chim Acta 33:963
De Santis G, Fabbrizzi L, Licchelli M, Poggi A, Taglietti A (1996) Angew Chem Int Ed Engl 35:202
Fabbrizzi L, Licchelli M, Parodi L, Poggi A, Taglietti A (1999) Eur J Inorg Chem 35
Fabbrizzi L, Licchelli M, Parodi L, Poggi A, Taglietti A (1998) J Fluoresc 8:263
George P, Hanani G, Irvine D (1964) J Chem Soc 5689
(a) Coughlin PK, Dewan JC, Lippard SJ, Watanabe EI, Lehn JM (1979) J Am Chem Soc 101:265; (b) Strohkamp KG, Lippard SJ (1982) Acc Chem Res 10:318; (c) Coughlin PK, Martin AE, Dewan JC, Watanabe EI, Bulkowski JE, Lehn JM, Lippard SJ (1984) Inorg Chem 23:1004; (d) Fabbrizzi L, Pallavicini P, Parodi P, Perotti P, Taglietti A (1995) J Chem Soc Chem Comm 2439
Fabbrizzi L, Francese G, Licchelli M, Perotti A, Taglietti A (1997) Chem Commun 581
Fabbrizzi L, Faravelli I, Francese G, Licchelli M, Perotti A, Taglietti A (1998) Chem Commun 971
Czarnik AW (1997) In: Czarnik AW (ed) Chemosensors of ion and molecule recognition. Kluwer Academic Publishers, Dordrecht, p 104
Huston ME, Akkaya EU, Czarnik AW (1989) J Am Chem Soc 111:8735
Fabbrizzi L, Licchelli M, Pallavicini P, Taglietti A (1996) Inorg Chem 35:1733
Fabbrizzi L, Licchelli M, Taglietti A (manuscript in preparation)
Fabbrizzi L, Sabatini L (1979) Inorg Chem 18:438
Engeser M, Fabbrizzi L, Licchelli M, Sacchi D (1999) Chem Commun 1191
De Santis G, Fabbrizzi L, Licchelli M, Sardone N, Velders AH (1996) Chem-Eur J 2:1243
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2001 Springer-Verlag Berlin Heidelberg
About this chapter
Cite this chapter
Fabbrizzi, L., Licchelli, M., Poggi, A., Rabaioli, G., Taglietti, A. (2001). Fluorometric Detection of Anion Activity and Temperature Changes. In: Valeur, B., Brochon, JC. (eds) New Trends in Fluorescence Spectroscopy. Springer Series on Fluorescence, vol 1. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-56853-4_11
Download citation
DOI: https://doi.org/10.1007/978-3-642-56853-4_11
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-63214-3
Online ISBN: 978-3-642-56853-4
eBook Packages: Springer Book Archive