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Atomic and Molecular Beams pp 555–578Cite as

High Resolution Translational Spectroscopic Studies of Elementary Chemical Processes

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Abstract

Nascent product quantum state distribution in chemical reactions can now be measured routinely using many laser-based techniques such as laser-induced fluorescence (LIF), resonance-enhanced multiphoton ionization (REMPI) etc. For example, in the O(1D) + H2 → OH(2II) + H reaction, the OH radical products are frequently detected using LIF through the A←X transition. Quantum state distribution of nascent chemical products, however, only carries part of the product information in a molecular beam experiment. Information on the angular distributions of reaction products is at least as important to the understanding of the whole picture of reactions. In reality, quantum state resolved differential cross section measurements could provide the most detailed mechanistic information on a chemical reaction, and also the most stringent test for a quantitatively accurate theoretical picture for this process.

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Authors and Affiliations

  1. Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei, Taiwan

    X. Liu, J. J. Lin, D. W. Hwang, X. F. Yang, S. Harich & X. Yang

  2. Department of Chemistry, National Tsing-Hua University, Hischu, Taiwan

    D. W. Hwang

  3. Department of Chemistry, National Taiwan University, Taipei, Taiwan

    X. F. Yang

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  1. X. Liu
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  1. Laboratoire d’Aerothermique, CNRS, 4ter Route des Gardes, 92140, Meudon, France

    Roger Campargue

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Liu, X., Lin, J.J., Hwang, D.W., Yang, X.F., Harich, S., Yang, X. (2001). High Resolution Translational Spectroscopic Studies of Elementary Chemical Processes. In: Campargue, R. (eds) Atomic and Molecular Beams. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-56800-8_37

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  • DOI: https://doi.org/10.1007/978-3-642-56800-8_37

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