Skip to main content

Excitons and Energy Transfer in Doped Luminescent Molecular Organic Materials

  • Chapter
Organic Electronic Materials

Part of the book series: Springer Series in Materials Science ((SSMATERIALS,volume 41))

Abstract

Excitons are integral to nearly all electronic processes in molecular organic solids. Exciton diffusion is a dominant method of energy transfer; exciton absorption dominates the absorption spectrum; and exciton formation is necessary for luminescence and photoconductivity. Indeed, tracking excitonic processes is the key to understanding the physical behavior of molecular organic semiconductors. In this chapter, we examine excitonic behavior in doped molecular organic thin films, focusing on energy-transfer processes between dissimilar organic molecules.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. C. W. Tang, S.A. VanSlyke, C.H. Chen, J. Appl. Phys. 65, 3610 (1989)

    Article  CAS  Google Scholar 

  2. V. G. Kozlov, V. Bulović, P.E. Burrows, M. Baldo, V.B. Khalfin, G. Parthasarathy, S.R. Forrest, J. Appl. Phys. 84, 4096 (1998)

    Article  CAS  Google Scholar 

  3. S. R. Forrest, Chem. Rev. 97, 1793 (1997)

    Article  CAS  Google Scholar 

  4. M. A. Baldo, D.F. O’Brien, M.E. Thompson, S.R. Forrest, Phys. Rev. B 60, 14422 (1999)

    Article  CAS  Google Scholar 

  5. P. F. Barbara, D.M. Adams, D.B. O’Connor, Annu. Rev. Mat. Sci. 29, 433 (1999)

    Article  CAS  Google Scholar 

  6. J. A. Barltrop, J.D. Coyle, Principles of Photochemistry (John Wiley & Sons, New York 1978)

    Google Scholar 

  7. D. Z. Garbuzov, V. Bulović, P.E. Burrows, S.R. Forrest, Chem. Phys. Lett. 249, 433 (1996)

    Article  CAS  Google Scholar 

  8. B. Pullman (ed.) Environmental Effects on Molecular Structure and Properties, Proceedings of the Eight Jerusalem Symposium on Quantum Chemistry and Biochemistry (D. Reidel Publishing Company, Boston 1976)

    Google Scholar 

  9. C. Reichardt, Solvents and Solvent Effects in Organic Chemistry (VCH Verlagsgesellschaft mbH, Weinheim 1988)

    Google Scholar 

  10. V. Bulović, R. S. Deshpande, S. R. Forrest, Chem. Phys. Lett. 308, 317 (1999)

    Article  Google Scholar 

  11. M. Pope, C.E. Swenberg, Electronic Processes in Organic Crystals (Oxford University Press, Oxford 1982)

    Google Scholar 

  12. G. H. Wannier, Phys. Rev. 52, 191 (1937)

    Article  CAS  Google Scholar 

  13. N. F. Mott, Trans. Faraday. Soc. 34, 500 (1938)

    Article  CAS  Google Scholar 

  14. J. Frenkel, Phys. Rev. 37, 17 (1931); 37,1276 (1931)

    Article  CAS  Google Scholar 

  15. Z. Shen, S.R. Forrest, Phys. Rev. B 55, 10578 (1997)

    Article  CAS  Google Scholar 

  16. E. A. Silinsh, V. Ćápek, Organic Molecular Crystals (American Institute of Physics, New York 1994)

    Google Scholar 

  17. T. Forster, In: Modem Quantum Chemistry, Part 2, ed. by O. Sinanoglu (Academic Press, 1965)

    Google Scholar 

  18. D. L. Dexter, J. Chem. Phys. 21, 838 (1953)

    Article  Google Scholar 

  19. A. A. Lamola, Photochem. Photobiol. 8, 601 (1968)

    Article  CAS  Google Scholar 

  20. G. L. Closs, M.D. Johnson, J.R. Miller, P. Piotrowiak, J. Am. Chem. Soc. 111,3751 (1989)

    Article  CAS  Google Scholar 

  21. K. C. Kao, W. Hwang, Electrical Transport in Solids (Pergamon Press, Oxford 1981)

    Google Scholar 

  22. C. Adachi, T. Tsutsui, S. Saito, Optoelect. Devices Technol. 6, 25 (1991)

    CAS  Google Scholar 

  23. V. Bulović, PhD thesis, Princeton University (1998)

    Google Scholar 

  24. C. W. Tang, S.A. VanSlyke, Appl. Phys. Lett. 51, 913 (1987)

    Article  CAS  Google Scholar 

  25. M. Stolka, J.F. Janus, D.M. Pai, J. Phys. Chem. 88, 4707 (1984)

    Article  CAS  Google Scholar 

  26. R. G. Kepler, P.M. Beeson, S.J. Jacobs, R.A. Anderson, M.B. Sinclair, V.S. Valencia, P.A. Cahill, Appl. Phys. Lett. 66, 3618 (1995)

    Article  CAS  Google Scholar 

  27. L-B. Lin, S.A. Jenekhe, R.H. Young, P.M. Borsenberger, Appl. Phys. Lett. 70, 2052 (1997)

    Article  CAS  Google Scholar 

  28. J. Kalinowski, G. Giro, P.D. Marco, N. Camaioni, V. Fattori, Chem. Phys. Lett. 265, 607 (1997)

    Article  CAS  Google Scholar 

  29. V. Bulović, V.B. Khalfin, G. Gu, P.E. Burrows, S.R. Forrest, Phys. Rev. B 58, 3730 (1998)

    Article  Google Scholar 

  30. C. W. Tang, Society for Information Display, International Symposium, Digest Tech. Pap. 27, 181 (1996)

    Google Scholar 

  31. V. Bulović, A. Shoustikov, M.A. Baldo, E. Bose, V.G. Kozlov, M.E. Thompson, S.R. Forrest, Chem. Phys. Lett. 287, 455 (1998)

    Article  Google Scholar 

  32. M. A. Baldo, D.F. O’Brien, Y. You, A. Shoustikov, S. Sibley, M.E. Thompson, S.R. Forrest, Nature 395, 151 (1998)

    Google Scholar 

  33. M. Berggren, A. Dodabalapur, R.E. Slusher, Z. Bao, Nature 389, 466 (1997)

    Article  CAS  Google Scholar 

  34. R. S. Deshpande, V. Bulović, S.R. Forrest, Appl. Phys. Lett. 75, 888 (1999)

    Article  CAS  Google Scholar 

  35. R. H. Jordan, A. Dodabalapur, M. Strukelj, T.M. Miller, Appl. Phys. Lett. 68, 1192 (1996)

    Article  CAS  Google Scholar 

  36. J. Kido, W. Ikeda, M. Kimura, K. Nagai, Jpn. J. Appl. Phys. Part 2 35, L394 (1996)

    Google Scholar 

  37. M. Granström, O. Inganas, Appl. Phys. Lett. 68, 147 (1996)

    Article  Google Scholar 

  38. S. Tasch, E. J. W. List, O. Ekström, W. Graupner, G. Leising, P. Schlichting, U. Rohr, Y. Geerts, U. Scherf, K. MÜllen, Appl. Phys. Lett. 71, 2883 (1997)

    Article  CAS  Google Scholar 

  39. J. Kido, H. Shionoya, K. Nagai, Appl. Phys. Lett. 67, 2281 (1995)

    Article  CAS  Google Scholar 

  40. T. Christ, A. Greiner, R. Sander, V. Stiimpfien, J. Wendorff, Adv. Mat. 9, 219 (1997)

    Article  CAS  Google Scholar 

  41. J. Kido, M. Kimura, K. Nagai, Science 267, 1332 (1995)

    Article  CAS  Google Scholar 

  42. P.E. Burrows, S.R. Forrest, Appl. Phys. Lett. 64, 2285 (1993)

    Article  Google Scholar 

  43. D. F. O’Brien, M.A. Baldo, M.E. Thompson, S.R Forrest, Appl. Phys. Lett. 74, 442 (1999)

    Article  CAS  Google Scholar 

  44. M. M. Martin, P. Plaza, Y.H. Meyer, Chem. Phys. 192, 367 (1995)

    Article  CAS  Google Scholar 

  45. W. P. Anderson, T.R Cundari, R.S. Drago, M.C. Zerner, Inorg. Chem. 29, 1 (1990)

    Article  CAS  Google Scholar 

  46. J. Kalinowski, W. Stampor, P. Di Marco, V. Fattori, Chem. Phys. 182, 341 (1994)

    Article  CAS  Google Scholar 

  47. Y. Kijima, N. Asai, S. Tamura (eds.) Proc. of the Mat. Res. Soc., Spring’ 98 Meeting, paper G2.1, San Francisco, California (April 13–17, 1998)

    Google Scholar 

  48. P. M. Borsenberger, J.J. Fitzgerald, J. Phys. Chem. 97,4815 (1993)

    Article  CAS  Google Scholar 

  49. H. Schmidbaur, J. Lettenbauer, D.L. Wilkinson, G. Muller, O. Kumberger, Z. Naturforsch. B 46, 901 (1991)

    CAS  Google Scholar 

  50. J. Kido, Y. Iizumi, Appl. Phys. Lett. 73, 2721 (1998)

    Article  CAS  Google Scholar 

  51. M. A. Baldo, S. Lamansky, P.E. Burrows, M.E. Thompson, S.R. Forrest, Appl. Phys. Lett. 75, 4 (1999)

    Article  CAS  Google Scholar 

  52. M. A. Baldo, M.E. Thompson, S.R. Forrest, Pure Appl. Chem. (2000)

    Google Scholar 

  53. A. Mills, A. Lepre, Anal. Chem. 69, 4653 (1997)

    Article  CAS  Google Scholar 

  54. G. Ponterini, N. Serpone, M.A. Bergkamp, T.L. Netzel, J. Am. Chem. Soc. 105, 4639 (1983)

    Article  CAS  Google Scholar 

  55. D. B. Papkovski, Sensors and Actuators B 29, 213 (1995)

    Article  Google Scholar 

  56. V. Cleave, G. Yahioglu, P. Le Barny, R.H. Friend, N. Tessler, Adv. Mat. 11, 285 (1999)

    Article  CAS  Google Scholar 

  57. M. A. Baldo, S.R. Forrest, Phys. Rev. B 62, 10958 (2000)

    Article  CAS  Google Scholar 

  58. M. Klessinger, J. Michl, Excited states and photochemistry of organic molecules (VCH Publishers, New York 1995)

    Google Scholar 

  59. N. J. Turro, Modem Molecular Photochemistry (University Science Books, Mill Valley 1991)

    Google Scholar 

  60. M. A. Baldo, C. Adachi, S.R. Forrest, Phys. Rev. B 62, 10967 (2000)

    Article  CAS  Google Scholar 

  61. C. Adachi, M.A. Baldo, M.E. Thompson, S.R. Forrest, unpublished

    Google Scholar 

  62. R. Ballardini, G. Varani, M.T. Indelli, F. Scandola, Inorg. Chem. 25, 3858 (1986)

    Article  CAS  Google Scholar 

  63. V. L. Ermolaev, E.B. Sveshnikova, Dokl. Akad. Nauk. SSSR 149, 1295 (1963)

    CAS  Google Scholar 

  64. T. Tsutsui, S. Saito, In: Intrinsically Conducting Polymers: An Emerging Technology, ed. by M. Aldissi (Kluwer Academic, Dordrecht 1993) pp. 123

    Chapter  Google Scholar 

  65. L. J. Rothberg, A.J. Lovinger, J. Mat. Res. 11,3174 (1996)

    Article  CAS  Google Scholar 

  66. T. Förster, Discuss. Faraday Soc. 27, 7 (1959)

    Article  Google Scholar 

  67. M. A. Baldo, M.E. Thompson, S.R. Forrest, Nature 403, 750 (2000)

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2001 Springer-Verlag Berlin Heidelberg

About this chapter

Cite this chapter

Bulović, V., Baldo, M.A., Forrest, S.R. (2001). Excitons and Energy Transfer in Doped Luminescent Molecular Organic Materials. In: Farchioni, R., Grosso, G. (eds) Organic Electronic Materials. Springer Series in Materials Science, vol 41. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-56425-3_11

Download citation

  • DOI: https://doi.org/10.1007/978-3-642-56425-3_11

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-63085-9

  • Online ISBN: 978-3-642-56425-3

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics