Abstract
Nanoparticles with various sizes and shapes produce unique localized surface plasmon resonance bands and exhibit different physical and chemical properties. For instance, catalytic ability, sensitivity to changes in the surrounding medium, and biocompatibility are all dependent on the morphology of nanoparticles. In recent decades, various types of nanostructures have been fabricated to tune plasmon resonance bands, enhance the electromagnetic field around metal nanoparticles, and determine the relationship between the size and shape of nanoparticles and their LSPR band. In this chapter, we discuss the effect of morphology on plasmonic properties and the related applications.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Link S, El-Sayed MA (2000) Shape and size dependence of radiative, non-radiative and photothermal properties of gold nanocrystals. Int Rev Phys Chem 19:409–453
Kelly KL, Coronado E, Zhao LL, Schatz GC (2003) The optical properties of metal nanoparticles: the influence of size, shape, and dielectric environment. J Phys Chem B 107:668–677
Jain PK, Lee KS, El-Sayed IH, El-Sayed MA (2006) Calculated absorption and scattering properties of gold nanoparticles of different size, shape, and composition: applications in biological imaging and biomedicine. J Phys Chem B 110:7238–7248
Gans R (1912) Über die form ultramikroskopischer goldteilchen. Ann Phys 37:881–900
Perez-Juste J, Pastoriza-Santos I, Liz-Marzan LM, Mulvaney P (2005) Gold nanorods: synthesis, characterization and applications. Coord Chem Rev 249:1870–1901
Hu M, Hillyard P, Hartland GV, Kosel T, Perez-Juste J, Mulvaney P (2004) Determination of the elastic constants of gold nanorods produced by seed mediated growth. Nano Lett 4:2493–2497
Gao J, Bender CM, Murphy CJ (2003) Dependence of the gold nanorod aspect ratio on the nature of the directing surfactant in aqueous solution. Langmuir 19:9065–9070
Huang X, El-Sayed IH, Qian W, El-Sayed MA (2006) Cancer cell imaging and photothermal therapy in the near-infrared region by using gold nanorods. J Am Chem Soc 128:2115–2120
Nelayah J, Kociak M, Stéphan O, de Abajo FJG, Tencé M, Henrard L et al (2007) Mapping surface plasmons on a single metallic nanoparticle. Nat Phys 3:348–353
Pedano ML, Li S, Schatz GC, Mirkin CA (2010) Periodic electric field enhancement along gold rods with nanogaps. Angew Chem 122:82–86
Heo CJ, Kim SH, Jang SG, Lee SY, Yang SM (2009) Gold “nanograils” with tunable dipolar multiple plasmon resonances. Adv Mater 21:1726–1731
Wang H, Brandl DW, Le F, Nordlander P, Halas NJ (2006) Nanorice: a hybrid plasmonic nanostructure. Nano Lett 6:827–832
McMahon JM, Wang Y, Sherry LJ, Van Duyne RP, Marks LD, Gray SK et al (2009) Correlating the structure, optical spectra, and electrodynamics of single silver nanocubes. J Phys Chem C 113:2731–2735
Becker J, Schubert O, Sönnichsen C (2007) Gold nanoparticle growth monitored in situ using a novel fast optical single-particle spectroscopy method. Nano Lett 7:1664–1669
Sherry LJ, Chang S-H, Schatz GC, Van Duyne RP, Wiley BJ, Xia Y (2005) Localized surface plasmon resonance spectroscopy of single silver nanocubes. Nano Lett 5:2034–2038
Mahmoud M, El-Sayed M (2011) Time dependence and signs of the shift of the surface plasmon resonance frequency in nanocages elucidate the nanocatalysis mechanism in hollow nanoparticles. Nano Lett 11:946–953
Hu M, Chen J, Marquez M, Xia Y, Hartland GV (2007) Correlated rayleigh scattering spectroscopy and scanning electron microscopy studies of Au-Ag bimetallic nanoboxes and nanocages. J Phys Chem C 111:12558–12565
Jin R, Cao Y, Mirkin CA, Kelly K, Schatz GC, Zheng J (2001) Photoinduced conversion of silver nanospheres to nanoprisms. Science 294:1901–1903
Härtling T, Alaverdyan Y, Wenzel MT, Kullock R, Käll M, Eng LM (2008) Photochemical tuning of plasmon resonances in single gold nanoparticles. J Phys Chem C 112:4920–4924
Haynes CL, Van Duyne RP (2001) Nanosphere lithography: a versatile nanofabrication tool for studies of size-dependent nanoparticle optics. J Phys Chem B 105:5599–5611
Polte J, Ahner TT, Delissen F, Sokolov S, Emmerling F, Thünemann AF et al (2010) Mechanism of gold nanoparticle formation in the classical citrate synthesis method derived from coupled in situ XANES and SAXS evaluation. J Am Chem Soc 132:1296–1301
Qin LX, Li Y, Li DW, Jing C, Chen BQ, Ma W et al (2012) Electrodeposition of single-metal nanoparticles on stable protein 1 membranes: application of plasmonic sensing by single nanoparticles. Angew Chem Int Ed 51:140–144
Jing C, Gu Z, Ying Y-L, Li D-W, Zhang L, Long Y-T (2012) Chrominance to dimension: a real-time method for measuring the size of single gold nanoparticles. Anal Chem 84:4284–4291
Song Y, Nallathamby PD, Huang T, Elsayed-Ali HE, Xu X-HN (2009) Correlation and characterization of three-dimensional morphologically dependent localized surface plasmon resonance spectra of single silver nanoparticles using dark-field optical microscopy and spectroscopy and atomic force microscopy. J Phys Chem C 114:74–81
Mock J, Barbic M, Smith D, Schultz D, Schultz S (2002) Shape effects in plasmon resonance of individual colloidal silver nanoparticles. J Chem Phys 116:6755–6760
Ringe E, Zhang J, Langille MR, Mirkin CA, Marks LD, Van Duyne RP (2012) Correlating the structure and localized surface plasmon resonance of single silver right bipyramids. Nanotechnology 23:444005–444011
Blaber MG, Henry A-I, Bingham JM, Schatz GC, Van Duyne RP (2011) LSPR imaging of silver triangular nanoprisms: correlating scattering with structure using electrodynamics for plasmon lifetime analysis. J Phys Chem C 116:393–403
Ringe E, Langille MR, Sohn K, Zhang J, Huang J, Mirkin CA et al (2012) Plasmon length: a universal parameter to describe size effects in gold nanoparticles. J Phys Chem Lett 3:1479–1483
Huang Y, Kim D-H (2011) Dark-field microscopy studies of polarization-dependent plasmonic resonance of single gold nanorods: rainbow nanoparticles. Nanoscale 3:3228–3232
Nehl CL, Liao H, Hafner JH (2006) Optical properties of star-shaped gold nanoparticles. Nano Lett 6:683–688
Anderson LJ, Payne CM, Zhen Y-R, Nordlander P, Hafner JH (2011) A tunable plasmon resonance in gold nanobelts. Nano Lett 11:5034–5037
Tang ML, Liu N, Dionne JA, Alivisatos AP (2011) Observations of shape-dependent hydrogen uptake trajectories from single nanocrystals. J Am Chem Soc 133:13220–13223
Nehl CL, Grady NK, Goodrich GP, Tam F, Halas NJ, Hafner JH (2004) Scattering spectra of single gold nanoshells. Nano Lett 4:2355–2359
Banholzer MJ, Harris N, Millstone JE, Schatz GC, Mirkin CA (2010) Abnormally large plasmonic shifts in silica-protected gold triangular nanoprisms. J Phys Chem C 114:7521–7526
Moon S, Kim Y, Oh Y, Lee H, Kim HC, Lee K et al (2012) Grating-based surface plasmon resonance detection of core-shell nanoparticle mediated DNA hybridization. Biosens Bioelectron 32:141–147
Srnová-Šloufová I, Vlčková B, Bastl Z, Hasslett TL (2004) Bimetallic (Ag) Au nanoparticles prepared by the seed growth method: two-dimensional assembling, characterization by energy dispersive X-ray analysis, X-ray photoelectron spectroscopy, and surface enhanced Raman spectroscopy, and proposed mechanism of growth. Langmuir 20:3407–3415
Wu Y, Jiang P, Jiang M, Wang T-W, Guo C-F, Xie S-S et al (2009) The shape evolution of gold seeds and gold@ silver core–shell nanostructures. Nanotechnology 20:305602–305612
Shore MS, Wang J, Johnston-Peck AC, Oldenburg AL, Tracy JB (2011) Synthesis of Au (Core)/Ag (Shell) nanoparticles and their conversion to AuAg alloy nanoparticles. Small 7:230–234
Deng J, Du J, Wang Y, Tu Y, Di J (2011) Synthesis of ultrathin silver shell on gold core for reducing substrate effect of LSPR sensor. Electrochem Commun 13:1517–1520
Xiong B, Zhou R, Hao J, Jia Y, He Y, Yeung ES (2013) Highly sensitive sulphide mapping in live cells by kinetic spectral analysis of single Au–Ag core-shell nanoparticles. Nat Commun 4:1708–1717
Park S-J, Duncan TV, Sanchez-Gaytan BL, Park S-J (2008) Bifunctional nanostructures composed of fluorescent core and metal shell subdomains with controllable geometry. J Phys Chem C 112:11205–11210
Raschke G, Brogl S, Susha A, Rogach A, Klar T, Feldmann J et al (2004) Gold nanoshells improve single nanoparticle molecular sensors. Nano Lett 4:1853–1857
Averitt R, Sarkar D, Halas N (1997) Plasmon resonance shifts of Au-coated Au2S nanoshells: insight into multicomponent nanoparticle growth. Phys Rev Lett 78:4217–4220
Hien Pham TT, Cao C, Sim SJ (2008) Application of citrate-stabilized gold-coated ferric oxide composite nanoparticles for biological separations. J Magn Magn Mater 320:2049–2055
Peng S, Lei C, Ren Y, Cook RE, Sun Y (2011) Plasmonic/magnetic bifunctional nanoparticles. Angew Chem Int Ed 50:3158–3163
Xu Z, Hou Y, Sun S (2007) Magnetic core/shell Fe3O4/Au and Fe3O4/Au/Ag nanoparticles with tunable plasmonic properties. J Am Chem Soc 129:8698–8699
Zhang L, Li Y, Li DW, Jing C, Chen X, Lv M et al (2011) Single gold nanoparticles as real-time optical probes for the detection of NADH-dependent intracellular metabolic enzymatic pathways. Angew Chem 123:6921–6924
Zheng X, Liu Q, Jing C, Li Y, Li D, Luo W et al (2011) Catalytic gold nanoparticles for nanoplasmonic detection of DNA hybridization. Angew Chem 123:12200–12204
Liu Q, Jing C, Zheng X, Gu Z, Li D, Li D-W et al (2012) Nanoplasmonic detection of adenosine triphosphate by aptamer regulated self-catalytic growth of single gold nanoparticles. Chem Commun 48:9574–9576
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
Copyright information
© 2014 The Author(s)
About this chapter
Cite this chapter
Long, YT., Jing, C. (2014). Morphology- and Composition-Modulated Sensing. In: Localized Surface Plasmon Resonance Based Nanobiosensors. SpringerBriefs in Molecular Science. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-54795-9_4
Download citation
DOI: https://doi.org/10.1007/978-3-642-54795-9_4
Published:
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-54794-2
Online ISBN: 978-3-642-54795-9
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)