Abstract
The analysis of all kinds of compounds of food products is highly important to maintain food quality, which means primarily meeting the consumer’s expectations in terms of sensory properties, health, and correct declaration of ingredients and origin. Absence of residues and contaminants, as well as presence of desired ingredients, is highly appreciated by the consumer. From the multitude of analytical methods applied in food analysis, gas chromatography is an important tool with the major reason providing the unique chromatographical resolution making the parallel determination of a bundle of more or less similar compounds possible. Further, better extraction procedures in combination with innovative detection systems are improving more and more the sensitivity for detecting compounds, even at trace level. This chapter illustrates the applicability of gas chromatography in food analysis by discussing selected examples.
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References
Rohn S, Kroh LW (2008) Quality of processed plant food. In: Zude M (ed) Optical monitoring of fresh and processed agricultural crops – basics and applications for a better understanding of non-destructive sensing. CRC, Boca Raton
Huyskens-Keil S, Schreiner M (2003) Quality of fruits and vegetables. J Appl Bot 77:147–151
MoniQA Food Authenticity working group. Food Authenticity – general considerations. http://www.moniqa.org. Accessed 5 Jan 2011
Lu C, Barr DB, Pearson MA, Waller LA (2008) Dietary intake and its contribution to longitudinal organophosphorus pesticide exposure in urban/suburban children. Environ Health Perspect 116:537–542
Anastassiades M, Lehotay SJ, Stajnbaher D, Schenck FJ (2003) Fast and easy multiresidue method employing acetonitrile extraction/partitioning and “dispersive solid-phase extraction” for the determination of pesticide residues in produce. J AOAC Int 86:412–431
Lehotay SJ, Mastovská K, Yun SJ (2005) Evaluation of two fast and easy methods for pesticide residue analysis in fatty food matrixes. J AOAC Int 88:630–638
Wong JW, Hennessy MK, Hayward DG, Krynitsky AJ, Cassias I, Schenck FJ (2007) Analysis of organophosphorus pesticides in dried ground ginseng root by capillary gas chromatography-mass spectrometry and -flame photometric detection. J Agric Food Chem 55:1117–1128
Schenck F, Wong J, Lu C, Li J, Holcomb JR, Mitchell LM (2009) Multiresidue analysis of 102 organophosphorus pesticides in produce at parts-per-billion levels using a modified QuEChERS method and gas chromatography with pulsed flame photometric detection. J AOAC Int 92:561–573
Fernandez-Muino MA, Sancho MT, Muniategui S, Huidobro JF, Simal-Lozano J (1995) Nonacaricide pesticide residues in honey: analytical methods and levels found. J Food Prot 58:1271–1274
Blasco C, Lino CM, Picó Y, Pena A, Font G, Silveira MI (2004) Determination of organochlorine pesticide residues in honey from the central zone of Portugal and the Valencian community of Spain. J Chromatogr A 1049:155–160
Perez-Serradilla JA, Mata-Granados JM, de Castro MDL (2010) Low-level determination of organochlorine pesticides in wines by automatic preconcentration and GC-MS-MS detection. Chromatographia 71:899–905
Portoles T, Sancho JV, Hernandez F, Newton A, Hancock P (2010) Potential of atmospheric pressure chemical ionization source in GC-QTOF MS for pesticide residue analysis. J Mass Spectrom 45:926–936
Chan EY, Griffiths SM, Chan CW (2008) Public-health risks of melamine in milk products. Lancet 372:1444–1445
Brown CA, Jeong KS, Poppenga RH, Puschner B, Miller DM, Ellis AE, Kang KI, Sum S, Cistola AM, Brown SA (2007) Outbreaks of renal failure associated with melamine and cyanuric acid in dogs and cats in 2004 and 2007. J Vet Diagn Invest 19:525–531
Skinner CG, Thomas JD, Osterloh JD (2010) Melamine toxicity. J Med Toxicol 6:50–55
Xu X, Ren Y, Zhu Y, Cai Z, Han J, Huang B, Zhu Y (2009) Direct determination of melamine in dairy products by gas chromatography/mass spectrometry with coupled column separation. Anal Chim Acta 650:39–43
Xu X, Song G, Zhu Y, Zhang J, Zhao Y, Shen H, Cai Z, Han J, Ren Y (2008) Simultaneous determination of two acute poisoning rodenticides tetramine and fluoroacetamide with a coupled column in poisoning cases. J Chromatogr B 876:103–108
Li J, Qi HY, Shi YP (2009) Determination of melamine residues in milk products by zirconia hollow fiber sorptive microextraction and gas chromatography-mass spectrometry. J Chromatogr A 1216:5467–5471
Lijinsky W (1999) N-Nitroso compounds in the diet. Mutat Res 443:129–138
Adam F, Bertoncini F, Brodusch N, Durand E, Thiebaut D, Espinat D, Hennion MC (2007) New benchmark for basic and neutral nitrogen compounds speciation in middle distillates using comprehensive two-dimensional gas chromatography. J Chromatogr A 1148:55–64
Yan X (2006) Unique selective detector for gas chromatography: nitrogen and sulfur chemiluminescence detectors. J Sep Sci 29:1931–1945
Ozel MZ, Gogus F, Yagci S, Hamilton JF, Lewis AC (2010) Determination of volatile nitrosamines in various meat products using comprehensive gas chromatography-nitrogen chemiluminescence detection. Food Chem Toxicol 48:3268–3273
Yurchenko S, Molder U (2006) Volatile N-nitrosamines in various fish products. Food Chem 96:325–333
Grebel JE, Suffet IH (2007) Nitrogen-phosphorus detection and nitrogen chemiluminescence detection of volatile nitrosamines in water matrices: optimization and performance comparison. J Chromatogr A 1175:141–144
International Agency for Research on Cancer (IARC) (1995) Dry cleaning, some chlorinated solvents and other industrial chemicals. Monogr Eval Carcinog Risks Hum 63:3194–3407
Zoller O, Sager F, Reinhard H (2007) Furan in food: headspace method and product survey. Food Addit Contam 24:91–107
Perez-Locas C, Yaylayan VA (2004) Origin and mechanistic pathways of formation of the parent furan-a food toxicant. J Agric Food Chem 52:6830–6836
Jestoi M, Järvinen T, Järvenpää E, Tapanainen H, Virtanen S, Peltonen K (2009) Furan in the baby-food samples purchased from the Finnish markets – determination with SPME-GC-MS. Food Chem 117:522–528
Kim TK, Kim S, Lee KG (2010) Analysis of furan in heat-processed foods consumed in Korea using solid phase microextraction-gas chromatography/mass spectrometry (SPME-GC/MS). Food Chem 123:1328–1333
Senyuva HZ, Gokmen V (2005) Analysis of furan in foods. Is headspace sampling a fit-for-purpose technique? Food Addit Contam 22:1198–1202
Bicchi C, Ruosi MR, Cagliero C, Cordero C, Liberto E, Rubiolo P, Sgorbini B (2011) Quantitative analysis of volatiles from solid matrices of vegetable origin by high concentration capacity headspace techniques: determination of furan in roasted coffee. J Chromatogr A 1218:753–762
Wagner MW (1970) Cyclamate acceptance. Science 168:1605
Takayama S, Renwick AG, Johansson SL, Thorgeirsson UP, Tsutsumi M, Dalgard DW, Sieber SM (2000) Long-term toxicity and carcinogenicity study of cyclamate in nonhuman primates. Toxicol Sci 53:33–39
Hashemi M, Habibi A, Jahanshahi N (2011) Determination of cyclamate in artificial sweeteners and beverages using headspace single-drop microextraction and gas chromatography flame-ionisation detection. Food Chem 124:1258–1263
Suslow T (2000) Postharvest handling of organic crops. ANR Publication 7254, University of California, Oakland
Staples CA, Peterson DR, Parkerton TF, Adams WJ (1997) The environmental fate of phthalate esters: a literature review. Chemosphere 35:667–749
Guo Z, Wang S, Wie D, Wang M, Zhang H, Gai P, Duan J (2010) Development and application of a method for analysis of phthalates in ham sausages by solid-phase extraction and gas chromatography-mass spectrometry. Meat Sci 84:484–490
Heudorf U, Mersch-Sundermann V, Angerer J (2007) Phthalates: toxicology and exposure. Int J Hyg Environ Health 210:623–634
Ostrovsky I, Cabala R, Kubinec R, Gorova R, Blasko J, Kubincova J, Rimnacova L, Lorenz W (2011) Determination of phthalate sum in fatty food by gas chromatography. Food Chem 124:392–395
van Hoeck E, de Schaetzen T, Pacquet C, Bolle F, Boxus L, van Loco J (2010) Analysis of benzophenone and 4-methylbenzophenone in breakfast cereals using ultrasonic extraction in combination with gas chromatography-tandem mass spectrometry (GC-MSn). Anal Chim Acta 663:55–59
Anderson WA, Castle L (2003) Benzophenone in cartonboard packaging materials and the factors that influence its migration into food. Food Addit Contam 20:607–618
EFSA Statement (2009) 4-methylbenzophenone found in breakfast cereals. EFSA J RN-243:1
Campone L, Piccinelli AL, Östman C, Rastrelli L (2010) Determination of organophosphorus flame retardants in fish tissues by matrix solid-phase dispersion and gas chromatography. Anal Bioanal Chem 397:799–806
Focant JF, Eppe G, Pirard C, Massart AC, Andre JE, de Pauw E (2002) Levels and congener distributions of PCDDs. PCDFs and non-ortho PCBs in Belgian food stuffs. Assessment of dietary intake. Chemospere 48:167–179
Kivitranta H, Tuomisto JT, Tiomisto J, Tukiainen E, Vartiainen T (2005) Polychlorinated dibenzo-p-dioxins, dibenzofurans, and biphenyls in the general population in Finland. Chemosphere 65:854–869
Hoh E, Lehotay SJ, Pangallo KC, Mastovska K, Ngo HL, Reddy CM, Vetter W (2009) Simultaneous quantitation of multiple classes of organohalogen compounds in fish oils with direct sample introduction comprehensive two-dimensional gas chromatography and time-of-flight mass spectrometry. J Agric Food Chem 57:2653–2660
Lennernas M, Fjellstrom C, Becker W, Giachetti I, Schmitt A, Remaut de Winter A, Kearney M (1997) Influences on food choice perceived to be important by nationally-representative samples of adults in the European Union. Eur J Clin Nutr 51:S8–S15
Ruiz-Rodriguez A, Reglero G, Ibanez E (2010) Recent trends in the advanced analysis of bioactive fatty acids. J Pharm Biomed Anal 51:305–326
Metcalfe LD, Schmitz AA (1961) The rapid preparation of fatty acid esters for gas chromatographic analysis. Anal Chem 33:363–364
Schlenk H, Gellerman JL (1960) Esterification of fatty acids with diazomethane on a small scale. Anal Chem 32:1412–1414
Morrison WR, Smith LM (1964) Preparation of fatty acid methyl esters and dimethylacetals from lipids with boron fluoride-methanol. J Lipid Res 5:600–608
Siang GH, Makahleh A, Saad B, Lim BP (2010) Hollow fiber liquid-phase microextraction co pled with gas chromatography-flame ionization detection for the profiling of fatty acids in vegetable oils. J Chromatogr A 1217:8073–8078
Sinclair HM (1956) Deficiency of essential fatty acids and atherosclerosis, etcetera. Lancet 270:381–383
Nguemeni C, Delplanque B, Rovere C, Simon-Rousseau N, Gandin C, Agnani G, Nahon JL, Heurteaux C, Blondeau N (2010) Dietary supplementation of alpha-linolenic acid in an enriched rapeseed oil diet protects from stroke. Pharmacol Res 61:226–233
Riediger ND, Othman RA, Suh M, Moghadasian MH (2009) A systemic review of the roles of n-3 fatty acids in health and disease. J Am Diet Assoc 109:668–679
Fritsche J, Steinhart H (1998) Amounts of conjugated linoleic acid (CLA) in German foods and evaluation of daily intake. Z Lebensm Unters Forsch 206:77–82
Tanaka K (2005) Occurrence of conjugated linoleic acid in ruminant products and its physiological functions. Anim Sci J 76:291–303
Chilliard Y, Ferlay A, Doreau M (2001) Effect of different types of forages, animal fat, or marine oils in cow’s diet on milk fat secretion and composition, especially conjugated linoleic acid (CLA) and polyunsaturated fatty acids. Livest Prod Sci 70:31–48
Eder K, Ringseis R (2010) Metabolism and actions of conjugated linoleic acids on atherosclerosis-related events in vascular endothelial cells and smooth muscle cells. Mol Nutr Food Res 54:17–36
Sottero B, Gamba P, Gargiulo S, Leonarduzzi G, Poli G (2009) Cholesterol oxidation products and disease: an emerging topic of interest in medicinal chemistry. Curr Med Chem 16:685–705
Yen TY, Inbaraj BS, Chien JT, Chen BH (2010) Gas chromatography-mass spectrometry determination of conjugated linoleic acids and cholesterol oxides and their stability in a model system. Anal Biochem 400:130–138
Kroll J, Rohn S, Rawel HM (2003) Secondary plant metabolites as functional constituents of foods. Dt Lebensm Rundsch 99:259–270
Robards K, Antolovich M (1997) Analytical chemistry of fruit bioflavonoids – a review. Analyst 122:11R–34R
Luck G, Liao H, Murray NJ, Grimmer HR, Warminski EE, Williamson MP, Lilley TH, Haslam E (1994) Polyphenols, astringency and proline-rich proteins. Phytochemistry 37:357–371
Halliwell B (1996) Oxidative stress, nutrition and health. Experimental strategies for optimization of nutritional antioxidant intake in humans. Free Radic Res 25:57–74
Scalbert A, Manach C, Morand C, Remesy C, Jimenez L (2005) Dietary polyphenols and the prevention of diseases. Crit Rev Food Sci Nutr 45:287–306
Saito Y, Jinno K (2003) Miniaturized sample preparation combined with liquid phase separations. J Chromatogr A 1000:53–67
Vinas P, Martinez-Castillo N, Campillo N, Hernandez-Córdoba M (2011) Directly suspended droplet microextraction with in injection-port derivatization coupled to gas chromatography-mass spectrometry for the analysis of polyphenols in herbal infusions, fruits and functional foods. J Chromatogr A 1218:639–646
Gao X, Williams SJ, Woodman OL, Marriott PJ (2010) Comprehensive two-dimensional gas chromatography, retention indices and time-of-flight mass spectra of flavonoids and chalcones. J Chromatogr A 1217:8317–8326
Cole RA (1976) Isothiocyanates, nitriles and thiocyanates as products of autolysis of glucosinolates in Cruciferae. Phytochemistry 15:759–762
Verkerk R, Schreiner M, Krumbein A, Ciska E, Holst B, Rowland I, De Schrijver R, Hansen M, Gerhäuser C, Mithen R, Dekker M (2009) Glucosinolates in Brassica vegetables: the influence of the food supply chain on intake, bioavailability and human health. Mol Nutr Food Res 53:S219
Underhill EW, Kirkland DF (1971) Gas chromatography of trimethylsilyl derivatives of glucosinolates. J Chromatogr A 57:47–54
Shen L, Su G, Wang X, Du O, Wang K (2010) Endogenous and exogenous enzymolysis of vegetable-sourced glucosinolates and influencing factors. Food Chem 119:987–994
Spencer GF, Daxenbichler ME (1980) Gas chromatography-mass spectrometry of nitriles, isothiocyanates and oxazolidinethiones derived from cruciferous glucosinolates. J Sci Food Agric 31:359–367
Slater GP, Manville JF (1993) Analysis of thiocyanates and isothiocyanates by ammonia chemical ionization gas chromatography-mass spectrometry and gas chromatography-Fourier transform infrared spectroscopy. J Chromatogr A 648:433–443
Luykx DMAM, van Ruth SM (2008) An overview of analytical methods for determining the geographical origin of food products. Food Chem 107:897–911
White JW, Doner LW (1978) Mass spectrometric detection of high-fructose corn syrup in honey by use of 13C/12C ratio: collaborative study. J Assoc Off Anal Chem 61:746–750
Woodbury SE, Evershed RP, Rossell JB (1998) δ13C analyses of vegetable oil fatty acid components, determined by gas chromatography-combustion isotope ratio mass spectrometry, after saponification or regiospecific hydrolysis. J Chromatogr A 805:249–257
Meier-Augenstein W (2002) Stable isotope analysis of fatty acids by gas chromatography-isotope ratio mass spectrometry. Anal Chim Acta 465:63–79
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Rohn, S. (2014). Gas Chromatography in Food Analysis. In: Dettmer-Wilde, K., Engewald, W. (eds) Practical Gas Chromatography. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-54640-2_21
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DOI: https://doi.org/10.1007/978-3-642-54640-2_21
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