Abstract
The usage of municipal solid waste (MSW) is usually hindered by its nonuniformity, high moisture, low energy density, and the occurrence of chlorine in the plastic-impregnated waste. A hydrothermal treatment is developed to convert the MSW into solid fuel by employing a commercial scale system of about 1 ton capacity, applying saturated steam at about 2 MPa for about 60 min holding time. It was shown that the product has better uniformity, higher density, and better drying performance compared to MSW without reducing its heating value. The combustion characteristic of the final product was similar to that of sub-bituminous coal, and capable of reducing the SO2 and NO emissions during co-combustion with coal. Additionally, the product showed that about 80 % of the organic chlorine was converted into inorganic, water-soluble chlorine, and the total chlorine content in the water-washed product was down to 16 %. It was calculated that the required energy for the hydrothermal treatment was 0.8 MJ/kg MSW, lower than conventional RDF production process which needs 1.35 MJ/kg MSW. It can be concluded that the hydrothermal treatment can be employed to convert MSW into a chlorine-free solid fuel suitable for co-combustion with coal.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Ministry of Environment Japan (2010) State of discharge and treatment of municipal solid waste in FY 2008. http://www.env.go.jp/en/headline/headline.php?serial=1333
The Asahi Shimbun (2008 )Coal prices surging due to global demand. Australia Flooding. Accessed 4 March 2008
British Petroleum (BP) (2010) BP statistical review of World energy. http://www.bp.com/statisticalreview/
UNEP (2005) Solid waste management, vol. I, chapter X: types of waste-to-energy systems. http://www.unep.or.jp/ietc/publications/spc/solid_waste_management/index.asp
Plastic Waste Management Institute Japan (2010) Breakdown of total plastic waste. In: Plastic products, plastic waste and resource recovery [2008], PWMI Newsletter No. 39, (2010). http://www2.pwmi.or.jp/siryo/ei/ei_pdf/ei39.pdf (accessed December 2010)
IPCC’s Task Force on National Greenhouse Gas Inventories (2010) MSW composition data by percent-regional defaults. In: 2006 IPCC Guidelines for National Greenhouse Gas Inventories, vol 5: Waste, Chapter 2. Waste generation, composition and management data. http://www.ipcc-nggip.iges.or.jp/public/2006gl/vol5.html. Accessed Dec 2010
IPCC Guidelines for National Greenhouse Gas Inventories (2006) Vol. 5: Waste, Chapter 2. Waste generation, composition and management data. IPCC’s task force on national greenhouse gas inventories, 2010. http://www.ipcc-nggip.iges.or.jp/public/2006gl/vol5.html
European Commission—Directorate General Environment (2003) Refuse derived fuel, current practice and perspective: final report. http://ec.europa.eu/environment/waste/studies/pdf/rdf.pdf. Accessed Dec 2010
Zevenhoven R, Axelsen EP, Hupa M (2002) Pyrolysis of waste-derived fuel containing PVC. Fuel 81:507–510
Ma S, Lu J, Gao J (2002) Study of the low temperature pyrolysis of PVC. Energy Fuels 16:338–342
Miranda R, Yang J, Roy C, Vasile C (1999) Vacuum pyrolysis of PVC. Polym Degrad Stab 64:127–144
Xiao X, Zeng Z, Xiao S (2008) Behavior and products of mechano-chemical dechlorination of polyvinylchloride and poly (vinylidene chloride). J Hazard Mater 151:118–124
Kamo T, Kondo Y, Kodera Y, Sato Y, Kushiyama S (2003) Effects of solvent on degradation of poly(vinyl chloride). Polym Degrad Stab 81:187–196
Sato K, Jian Z, Soon JH, Namioka T, Yoshikawa K, Morohashi Y et al (2004) Studies on fuel conversion of high moisture content biomass using middle pressure steam. In: Proceeding of the thermal engineering conference, pp 259–260
Yoshikawa K (2005) Fuelization and gasification of wet biomass with middle-pressure steam. Eco Ind 10:29–37 (in Japanese)
Muthuraman M, Namioka T, Yoshikawa K (2010) Characteristics of co-combustion and kinetic study on hydrothermally treated municipal solid waste with different rank coals: a thermogravimetric analysis. Appl Energy 87:141–148
Prawisudha P, Namioka T, Yoshikawa K (2012) Coal alternative fuel production from municipal solid wastes employing hydrothermal treatment. Appl Energy 90:298–304
Roditi International Co. Ltd. (2010) Hydrothermal crystal growth—Quartz. http://www.roditi.com/SingleCrystal/Quartz/Hydrothermal_Growth.html. Accessed Dec 2010
Savage PE, Levine RB, Huelsman CM (2010) Hydrothermal processing of biomass. In: Thermochemical conversion of biomass to liquid fuels and chemicals, Ch. 8. RSC Publishing, Cambridge
Cole EL, Hess HV, Guptill FE (2010) Preparation of solid fuel-water slurries. United States Patent No. 4,104,035, http://www.google.com/patents?hl=id&lr=&vid=USPAT4104035&id=c9EuAAAAEBAJ&oi=fnd&dq=hydrothermal+fuel&printsec=abstract#v=onepage&q=hydrothermal%20fuel&f=false. Accessed Dec 2010
Cole EL, Hess HV, Wong J (2010) Upgrading of solid fuels. United States Patent No. 4,047,898, http://www.google.com/patents?hl=id&lr=&vid=USPAT4047898&id=VJU3AAAAEBAJ&oi=fnd&dq=hydrothermal+fuel&printsec=abstract#v=onepage&q=hydrothermal%20fuel&f=false. Accessed Dec 2010
Bobleter O, Niesner R, Röhr M (1976) The hydrothermal degradation of cellulosic matter to sugars and their fermentative conversion to protein. J Appl Polym Sci 20:2083–2093
Goto M, Obuchi R, Hirose T, Sakaki T, Shibata M (2004) Hydrothermal conversion of municipal organic waste into resources. Bioresour Technol 93:279–284
Goudriaan F, Naber JE (2008) HTU diesel from wet waste streams. In: Symposium new biofuels, Berlin 2008. http://www.fnr-server.de/cms35/fileadmin/allgemein/pdf/veranstaltungen/NeueBiokraftstoffe/5_HTU.pdf. Accessed Dec 2010
Brightstar Environmental (2010) Solid Waste & Energy Recycling Facility (SWERF) Technology. http://www.sovereignty.org.uk/features/eco/swerf.html. Accessed Dec 2010
Ompeco (2010) Converter MO Series. http://www.ompeco.com/converter/en_serie_mo.html. Accessed Dec 2010
Endo K, Emori N (2001) Dechlorination of poly(vinyl chloride) without anomalous units under high pressure and at high temperature in water. Polym Degrad Stab 74:113–117
Takeshita Y, Kato K, Takahashi K, Sato Y, Nishi S (2004) Basic study on treatment of waste polyvinyl chloride plastics by hydrothermal decomposition in subcritical and supercritical regions. J Supercrit Fluids 31:185–193
Shanableh A (2000) Production of useful organic matter from sludge using hydrothermal treatment. Water Resour 34:945–951
Wenzhi H, Guangming L, Lingzhao K, Hua W, Juwen H, Jingcheng X (2008) Application of hydrothermal reaction in resource recovery of organic wastes. Resour Convers Recycl 52:691–699
Ishida Y, Kumabe K, Hata K, Tanifuji K, Hasegawa T, Kitagawa K et al (2009) Selective hydrogen generation from real biomass through hydrothermal reaction at relatively low temperatures. Biomass Bioener 33:8–13
Jomaa S, Shanableh A, Khalil W, Trebilco B (2003) Hydrothermal decomposition and oxidation of the organic component of municipal and industrial waste products. Adv Environ Resour 7:647–653
Sato K, Jian Z, Soon JH, Namioka T, Yoshikawa K, Morohashi Y et al (2004) Studies on fuel conversion of high moisture content biomass using middle pressure steam. In: Proceeding of thermal engineering conference, G132
Yoshikawa K (2005) Fuelization and gasification of wet biomass with middle-pressure steam. Eco Ind 10:29–37 (in Japanese)
Funke A, Ziegler F (2010) Hydrothermal carbonization of biomass: A summery and discussion of chemical mechanisms for process engineering. Biofuels Bioprod Bioref 4:160–177
Krammer P, Vogel H (2000) Hydrolysis of esters in subcritical and supercritical water. J Supercrit Fluids 16(3):189–206
Bobleter O (2005) Hydrothermal degradation of polymers derived from plants. Prog Polym Sci 19:797–841
Sakaguchi M, Laursen K, Nakagawa H, Miura K (2008) Hydrothermal upgrading of Loy Yang Brown coal-Effect of upgrading conditions on the characteristics of the products. Fuel Prog Technol 89:391–396
Yuliansyah T, Jirajima Y, Kumagai S, Sasaki K (2010) Production of solid biofuel from agriculture wastes of the palm oil industry by hydrothermal treatment. Waste Biomass Valor 1:395–405
Hammerschimidt N, Boukis E, Hauer U, Galla E, Dinjus B, Hitzmann T, Larsen S, Nygaard D (2011) Catalytic conversion of waste biomass by hydrothermal treatment. Fuel 90:555–562
Nonaka M, Hirajima T, Sasaki K (2011) Upgrading of low rank coal and woody biomass mixture by hydrothermal treatment. Fuel 90:2578–2584
Luo SY, Xiao B, Ho ZQ (2009) An experimental study on a novel shredder for municipal solid waste (MSW). Int J Hydrogen Energy 34(3):1270–2272
Luo S, Xiao B, Xiao L (2010) A novel shredder for municipal solid waste (MSW): influence of feed moisture on breakage performance. Bioresour Technol 101:6256–6258
ASTM Standard D388-99 (1999) Standard classification of coals by rank
European Commission—Directorate General Environment (2003) Refuse derived fuel, current practice and perspective: final report. http://ec.europa.eu/environment/waste/studies/pdf/rdf.pdf. Accessed Dec 2010
Ryu C, Yang YB, Khor A, Yates NE, Sharifi VN, Swithenbank J (2006) Effect of fuel properties on biomass combustion: Part I. Experiments—fuel type, equivalence ratio and particle size. Fuel 85(7–8):1039–1046
Muthuraman M, Namioka T, Yoshikawa K (2009) A comparison of co-combustion characteristics of coal with wood and hydrothermally treated municipal solid waste. Bioresour Technol. doi:10.1016/j.biortech.2009.11.060
Muthuraman M, Namioka T, Yoshikawa K (2010) Characteristics of co-combustion and kinetic study on hydrothermally treated municipal solid waste with different rank coals: a thermogravimetric analysis. Appl Energy 87:141–148
Chen Y, Mori S (1995) Estimating the combustibility of various coals by TG-DTA. Energy Fuels 9:71–74
Khan AA, de Jong W, Spliethoff H (2005) Biomass combustion in fluidized bed boiler. Bioenergy for Wood Industry, Jyväskylä, Finland, pp 365–370
Werther J, Saenger M, Hartge E-U, Ogada T, Siagi Z (2000) Combustion of agricultural residues. Prog Energy Combust Sci 26(1):1–27
Löffler Gerhard, Wargadalam Verina J, Winter Franz (2002) Catalytic effect of biomass ash on CO, CH4 and HCN oxidation under fluidised bed combustor conditions. Fuel 81(6):711–717
Lu Y, Hippinen I, Jahkola A (1995) Control of NOx and N2O in pressurized fluidized-bed combustion. Fuel Energy Abstracts 36(3):216
Khan AA, de Jong W, Jansens PJ, Spliethoff H (2009) Biomass combustion in fluidized bed boilers: potential problems and remedies. Fuel Process Technol 90(1):21–50
Amand LE, Leckner B (1991) Influence of fuel on the emission of nitrogen-oxides (NO and N2O) from an 8-MWth fluidized-bed boiler. Combust Flame 84(1–2):181–196
Hwang IH, Matsuto T, Tanaka N (2006) Water-soluble characteristics of chlorine in char derived from municipal solid wastes. Waste Manag 26:571–579
Caputo AC, Pelagagge PM (2002) RDF production plants I: Design and costs. Appl Therm Eng 22:423–437
Sikka P Energy from MSW: RDF pelletization—A pilot Indian plant
Moyers CG, Baldwin GW (1999) Psychrometry, evaporative cooling, and solids drying. In: Perry’s chemical engineer’s handbook, 7th edn, Section 12. McGraw-Hill, New York
Glasser L (2004) Water, ordinary water substance. J Chem Educ 81:414–418
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2014 Springer-Verlag Berlin Heidelberg
About this chapter
Cite this chapter
Yoshikawa, K., Prawisudha, P. (2014). Hydrothermal Treatment of Municipal Solid Waste for Producing Solid Fuel. In: Jin, F. (eds) Application of Hydrothermal Reactions to Biomass Conversion. Green Chemistry and Sustainable Technology. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-54458-3_14
Download citation
DOI: https://doi.org/10.1007/978-3-642-54458-3_14
Published:
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-54457-6
Online ISBN: 978-3-642-54458-3
eBook Packages: EnergyEnergy (R0)