Skip to main content

Protective Clothing Based on Electrospun Nanofibrous Membranes

  • Chapter
  • First Online:
Electrospun Nanofibers for Energy and Environmental Applications

Part of the book series: Nanostructure Science and Technology ((NST))

Abstract

Recently, researchers have focused on the development of specialized protective clothing used to protect military personnel and emergency responders when they are at risk of exposure to chemical or biological threats such as toxic industrial chemicals or chemical or biological warfare agents. These breathable chemical and biological detoxifying protective fabrics with comparable comfort level containing peculiar membranes provide full barrier protection by absorbing or blocking toxic agents. Nanofibrous membranes, mainly fabricated by electrospinning, have exhibited great potential for many emerging applications including smart protective clothing. They can be considered as one of the safest nanomaterials due to their extremely long length (can be up to hundreds of kilometers) and their ability to be embedded within other media. The new generation of protective fabrics based on electrospun nanofibrous membranes is envisioned not only to absorb or block toxic chemical and biological agents but also to detoxify them to reduce the risk of secondary contamination. The aim of this chapter is to examine the use of electrospun nanofibers for developing protective clothing materials that could provide both good protection performance from various environmental hazards and thermal comfort for the users.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Zhu J, Bahramian Q, Gibson P, Schreuder-Gibson H, Sun G (2012) Chemical and biological decontamination functions of nanofibrous membranes. J Mater Chem 22(17):8532–8540. doi:10.1039/c2jm16605d

    Article  Google Scholar 

  2. Schreuder-Gibson HL, Truong Q, Walker JE, Owens JR, Wander JD, Jones WE (2003) Chemical and biological protection and detection in fabrics for protective clothing. MRS Bull 28(8):574–578. doi:10.1557/mrs2003.168

    Article  Google Scholar 

  3. Yoon B, Lee S (2011) Designing waterproof breathable materials based on electrospun nanofibers and assessing the performance characteristics. Fiber Polym 12(1):57–64. doi:10.1007/s12221-011-0057-9

    Article  Google Scholar 

  4. Ahn HW, Park CH, Chung SE (2011) Waterproof and breathable properties of nanoweb applied clothing. Text Res J 81(14):1438–1447. doi:10.1177/0040517510392462

    Article  Google Scholar 

  5. Lee S, Obendorf SK (2007) Barrier effectiveness and thermal comfort of protective clothing materials. J Text Inst 98(2):87–97. doi:10.1533/joti.2005.0143

    Article  Google Scholar 

  6. Lin DJ, Chang HH, Chen TC, Lee YC, Cheng LP (2006) Formation of porous poly(vinylidene fluoride) membranes with symmetric or asymmetric morphology by immersion precipitation in the water/TEP/PVDF system. Eur Polym J 42(7):1581–1594. doi:10.1016/j.eurpolymj.2006.01.027

    Article  Google Scholar 

  7. Lin T, Wang X (2009) Nano related research in fibres and textiles. Int J Nanotechnol 6(5–6):579–598. doi:10.1504/IJNT.2009.024648

    Article  Google Scholar 

  8. Wang X, Ding B, Yu J, Wang M (2011) Engineering biomimetic superhydrophobic surfaces of electrospun nanomaterials. Nano Today 6(5):510–530. doi:10.1016/j.nantod.2011.08.004

    Article  Google Scholar 

  9. Wang X, Ding B, Sun G, Wang M, Yu J (2013) Electro-spinning/netting: a strategy for the fabrication of three-dimensional polymer nano-fiber/nets. Prog Mater Sci 58(8):1173–1243, http://dx.doi.org/10.1016/j.pmatsci.2013.05.001

    Article  Google Scholar 

  10. Lin J, Wang X, Ding B, Yu J, Sun G, Wang M (2012) Biomimicry via electrospinning. Crit Rev Solid State 37(2):94–114. doi:10.1080/10408436.2011.627096

    Google Scholar 

  11. Ding B, Wang M, Wang X, Yu J, Sun G (2010) Electrospun nanomaterials for ultrasensitive sensors. Mater Today 13(11):16–27, http://dx.doi.org/10.1016/S1369-7021(10)70200-5

    Article  Google Scholar 

  12. Gugliuzza A, Drioli E (2013) A review on membrane engineering for innovation in wearable fabrics and protective textiles. J Membr Sci 446:350–375, http://dx.doi.org/10.1016/j.memsci.2013.07.014

    Article  Google Scholar 

  13. Mukhopadhyay A, Midha VK (2008) A review on designing the waterproof breathable fabrics part i: Fundamental principles and designing aspects of breathable fabrics. J Ind Text 37(3):225–262. doi:10.1177/1528083707082164

    Article  Google Scholar 

  14. Gibson P, Schreuder-Gibson H, Rivin D (2001) Transport properties of porous membranes based on electrospun nanofibers. Colloid Surf A 187:469–481. doi:10.1016/s0927-7757(01)00616-1

    Article  Google Scholar 

  15. Frenot A, Chronakis IS (2003) Polymer nanofibers assembled by electrospinning. Curr Opin Colloid Interface 8(1):64–75. doi:10.1016/s1359-0294(03)00004-9

    Article  Google Scholar 

  16. Shang TC, Yang F, Wang C (2007) Array of polymeric nanofibers via electrospinning. In: Bai C, Xie S, Zhu X (eds) Nanoscience and technology, Pts 1 and 2, vol 121–123, Solid state phenomena., Trans Tech Publications, Stafa-Zurich, Switzerland, pp 583–586. doi:10.4028/www.scientific.net/SSP.121-123.583

  17. Greiner A, Wendorff JH (2008) Functional self-assembled nanofibers by electrospinning. In: Shimizu T (ed) Self-assembled nanomaterials I: Nanofibers, vol 219, Advances in polymer science., Springer Berlin Heidelberg, pp 107–171. doi:10.1007/12_2008_146

  18. Ding B, Kim CK, Kim HY, Se MK, Park SJ (2004) Titanium dioxide nanofibers prepared by using electrospinning method. Fiber Poly 5(2):105–109. doi:10.1007/bf02902922

    Article  Google Scholar 

  19. Huang ZM, Zhang YZ, Kotaki M, Ramakrishna S (2003) A review on polymer nanofibers by electrospinning and their applications in nanocomposites. Compos Sci Technol 63(15):2223–2253. doi:10.1016/s0266-3538(03)00178-7

    Article  Google Scholar 

  20. Cha DI, Kim KW, Chu GH, Kim HY, Lee KH, Bhattarai N (2006) Mechanical behaviors and characterization of electrospun polysulfone/polyurethane blend nonwovens. Macromol Res 14(3):331–337. doi:10.1007/BF03219090

    Article  Google Scholar 

  21. Pedicini A, Farris RJ (2003) Mechanical behavior of electrospun polyurethane. Polymer 44(22):6857–6862. doi:10.1016/j.polymer.2003.08.040

    Article  Google Scholar 

  22. Yun KK, Chung HP, Jooyoun K, Tae JK (2007) Application of electrospun polyurethane web to breathable water-proof fabrics. Fiber Polym 8(5):564–570. doi:10.1007/bf02875881

    Article  Google Scholar 

  23. Lee S, Obendorf SK (2007) Transport properties of layered fabric systems based on electrospun nanofibers. Fiber Polym 8(5):501–506. doi:10.1007/bf02875872

    Article  Google Scholar 

  24. Lee S, Obendorf SK (2007) Use of electrospun nanofiber web for protective textile materials as barriers to liquid penetration. Text Res J 77(9):696–702. doi:10.1177/0040517507080284

    Article  Google Scholar 

  25. Kimura LSD, Keun Hyung L, Park JC, Ick Soo K (2010) The effect of laundering on the thermal and water transfer properties of mass-produced laminated nanofiber web for use in wear. Text Res J 80(2):99–105. doi:10.1177/0040517508102308

    Article  Google Scholar 

  26. Boram Y, Seungsin L (2011) Designing waterproof breathable materials based on electrospun nanofibers and assessing the performance characteristics. Fiber Poly 12(1):57–64. doi:10.1007/s12221-011-0057-9

    Article  Google Scholar 

  27. Bagherzadeh R, Latifi M, Najar SS, Tehran MA, Gorji M, Kong L (2012) Transport properties of multi-layer fabric based on electrospun nanofiber mats as a breathable barrier textile material. Text Res J 82(1):70–76. doi:10.1177/0040517511420766

    Article  Google Scholar 

  28. Yao C, Li X, Neoh KG, Shi Z, Kang ET (2008) Surface modification and antibacterial activity of electrospun polyurethane fibrous membranes with quaternary ammonium moieties. J Membr Sci 320(1–2):259–267. doi:10.1016/j.memsci.2008.04.012

    Article  Google Scholar 

  29. Wu J, Wang N, Wang L, Dong H, Zhao Y, Jiang L (2012) Unidirectional water-penetration composite fibrous film via electrospinning. Soft Matter 8(22):5996–5999. doi:10.1039/c2sm25514f

    Article  Google Scholar 

  30. Ge J, Si Y, Fu F, Wang J, Yang J, Cui L, Ding B, Yu J, Sun G (2013) Amphiphobic fluorinated polyurethane composite microfibrous membranes with robust waterproof and breathable performances. RSC Adv 3(7):2248–2255. doi:10.1039/c2ra22111j

    Article  Google Scholar 

  31. Wang J, Raza A, Si Y, Cui L, Ge J, Ding B, Yu J (2012) Synthesis of superamphiphobic breathable membranes utilizing SiO2 nanoparticles decorated fluorinated polyurethane nanofibers. Nanoscale 4(23):7549–7556

    Article  Google Scholar 

  32. Han HR, Chung SE, Park CH (2013) Shape memory and breathable waterproof properties of polyurethane nanowebs. Text Res J 83(1):76–82. doi:10.1177/0040517512450757

    Article  Google Scholar 

  33. Wilusz E, Truong OT, Rivin D, Kendrick CE (1997) Development of selectively permeable membranes for chemical protective clothing. Abstr Pap Am Chem S 214:341, PMSE

    Google Scholar 

  34. Gibson PW, Schreuder-Gibson HL, Rivin D (1999) Electrospun fiber mats: transport properties. Aiche J 45(1):190–195. doi:10.1002/aic.690450116

    Article  Google Scholar 

  35. Seungsin L, Kay Obendorf S (2006) Developing protective textile materials as barriers to liquid penetration using melt-electrospinning. J Appl Polym Sci 102(4):3430–3437. doi:10.1002/app.24258

    Article  Google Scholar 

  36. Ramaseshan R, Sundarrajan S, Liu Y, Barhate RS, Lala NL, Ramakrishna S (2006) Functionalized polymer nanofibre membranes for protection from chemical warfare stimulants. Nanotechnology 17(12):2947–2953. doi:10.1088/0957-4484/17/12/021

    Article  Google Scholar 

  37. Ramaseshan R, Ramakrishna S (2007) Zinc titanate nanofibers for the detoxification of chemical warfare simulants. J Am Ceram Soc 90(6):1836–1842. doi:10.1111/j.1551-2916.2007.01633.x

    Article  Google Scholar 

  38. Bromberg L, Schreuder-Gibson H, Creasy WR, McGarvey DJ, Fry RA, Hatton TA (2009) Degradation of chemical warfare agents by reactive polymers. Ind Eng Chem Res 48(3):1650–1659. doi:10.1021/ie801150y

    Article  Google Scholar 

  39. Chen L, Bromberg L, Schreuder-Gibson H, Walker J, Hatton TA, Rutledge GC (2009) Chemical protection fabrics via surface oximation of electrospun polyacrylonitrile fiber mats. J Mater Chem 19(16):2432–2438. doi:10.1039/b818639a

    Article  Google Scholar 

  40. Ogawa T, Ding B, Sone Y, Shiratori S (2007) Super-hydrophobic surfaces of layer-by-layer structured film-coated electrospun nanofibrous membranes. Nanotechnology 18(16). doi:10.1088/0957-4484/18/16/165607

  41. Lee JA, Krogman KC, Ma M, Hill RM, Hammond PT, Rutledge GC (2009) Highly reactive multilayer-assembled TiO2 coating on electrospun polymer nanofibers. Adv Mater 21(12):1252. doi:10.1002/adma.200802458

    Article  Google Scholar 

  42. Krogman KC, Lowery JL, Zacharia NS, Rutledge GC, Hammond PT (2009) Spraying asymmetry into functional membranes layer-by-layer. Nat Mater 8(6):512–518. doi:10.1038/nmat2430

    Article  Google Scholar 

  43. Faccini M, Vaquero C, Amantia D (2012) Development of protective clothing against nanoparticle based on electrospun nanofibers. J Nanomater 2012:1–9. doi:10.1155/2012/892894

    Article  Google Scholar 

  44. Yang YC, Baker JA, Ward JR (1992) Decontamination of chemical warfare agents. Chem Rev 92(8):1729–1743. doi:10.1021/cr00016a003

    Article  Google Scholar 

  45. Chen L, Bromberg L, Lee JA, Zhang H, Schreuder-Gibson H, Gibson P, Walker J, Hammond PT, Hatton TA, Rutledge GC (2010) Multifunctional electrospun fabrics via layer-by-layer electrostatic assembly for chemical and biological protection. Chem Mater 22(4):1429–1436. doi:10.1021/cm902834a

    Article  Google Scholar 

  46. Lala NL, Ramaseshan R, Li B, Sundarrajan S, Barhate RS, Liu YJ, Ramakrishna S (2007) Fabrication of nanofibers with antimicrobial functionality used as filters: protection against bacterial contaminants. Biotechnol Bioeng 97(6):1357–1365. doi:10.1002/bit.21351

    Article  Google Scholar 

  47. Fu GD, Yao F, Li Z, Li X (2008) Solvent-resistant antibacterial microfibers of self-quaternized block copolymers from atom transfer radical polymerization and electrospinning. J Mater Chem 18(8):859–867. doi:10.1039/b716127a

    Article  Google Scholar 

  48. Chen L, Bromberg L, Hatton TA, Rutledge GC (2008) Electrospun cellulose acetate fibers containing chlorhexidine as a bactericide. Polymer 49(5):1266–1275. doi:10.1016/j.polymer.2008.01.003

    Article  Google Scholar 

  49. Fan L, Du Y, Zhang B, Yang J, Zhou J, Kennedy JF (2006) Preparation and properties of alginate/carboxyrnethyl chitosan blend fibers. Carbohyd Polym 65(4):447–452. doi:10.1016/j.carbpol.2006.01.031

    Article  Google Scholar 

  50. Lu HF, Fei B, Xin JH, Wang RH, Li L (2006) Fabrication of UV-blocking nanohybrid coating via miniemulsion polymerization. J Colloid Interf Sci 300(1):111–116. doi:10.1016/j.jcis.2006.03.059

    Article  Google Scholar 

  51. Tragoonwichian S, O’Rear EA, Yanumet N (2008) Broad ultraviolet protection by copolymerization of 2-3-(2H-benzotriazol-2-yl)-4-hydroxyphenyl ethyl methacrylate and 2-hydroxy-4-acryloyloxybenzophenone on cotton via admicellar polymerization. J Appl Polym Sci 108(6):4004–4013. doi:10.1002/app.28049

    Article  Google Scholar 

  52. Broasca G, Borcia G, Dumitrascu N, Vrinceanu N (2013) Characterization of ZnO coated polyester fabrics for UV protection. Appl Surf Sci 279:272–278. doi:10.1016/j.apsusc.2013.04.084

    Article  Google Scholar 

  53. Wang RH, Xin JH, Tao XM (2005) UV-Blocking property of dumbbell-shaped ZnO crystallites on cotton fabrics. Inorg Chem 44(11):3926–3930. doi:10.1021/ic0503176

    Article  Google Scholar 

  54. Wu DY, Long MC, Zhou JY, Cai WM, Zhu XH, Chen C, Wu YH (2009) Synthesis and characterization of self-cleaning cotton fabrics modified by TiO2 through a facile approach. Surf Coat Technol 203(24):3728–3733. doi:10.1016/j.surfcoat.2009.06.008

    Article  Google Scholar 

  55. Wu ZB, Gu ZL, Zhao WR, Wang HQ (2007) Photocatalytic oxidation of gaseous benzene over nanosized TiO2 prepared by solvothermal method. Chin Sci Bull 52(22):3061–3067. doi:10.1007/s11434-007-0456-x

    Article  Google Scholar 

  56. Seungsin L (2009) Developing UV-protective textiles based on electrospun zinc oxide nanocomposite fibers. Fiber Polym 10(3):295–301. doi:10.1007/s12221-009-0295-2

    Article  Google Scholar 

  57. Li C, Shu S, Chen R, Chen B, Dong W (2013) Functionalization of electrospun nanofibers of natural cotton cellulose by cerium dioxide nanoparticles for ultraviolet protection. J Appl Polym Sci 130(3):1524–1529. doi:10.1002/app.39264

    Article  Google Scholar 

Download references

Acknowledgments

This work is supported by the National Basic Research Program of China (973 Program, 2011CB606103, and 2012CB525005), the National Natural Science Foundation of China (No. 51322304, 51173022, U1232116, and 51273038), the Shanghai Nano Special Projects (11 nm0502900), the Shanghai Committee of Science and Technology (No. 12JC1400101), the Huo Yingdong Foundation (131070), and the Program for New Century Talents of the University in China.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Bin Ding .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2014 Springer-Verlag Berlin Heidelberg

About this chapter

Cite this chapter

Raza, A., Li, Y., Sheng, J., Yu, J., Ding, B. (2014). Protective Clothing Based on Electrospun Nanofibrous Membranes. In: Ding, B., Yu, J. (eds) Electrospun Nanofibers for Energy and Environmental Applications. Nanostructure Science and Technology. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-54160-5_14

Download citation

Publish with us

Policies and ethics