Abstract
Monitoring of usable, explosive, and hazardous materials (gases, heavy metal ions, and organic contaminants) is one of the most important concerns that has attracted growing attention in the past few decades. Numerous sensors have been developed to meet the demands and the pursuit of highly sensitive, selective, reversible, fast response and recovery, cost-effective, and portable sensors which have gained great interest. Electrospun nanofibrous membranes that possess large surface area, high porosity, good interconnected porous structure, and flexibility of surface functionalization are expected to be ideal candidates of substrates to improve the performance of the sensors. More interestingly, the novel two-dimensional nanofiber/net membranes fabricated by electrospinning/netting are demonstrated to have extremely large surface area and unique pore structure, which could further enhance the sensitivity, stability, and response speed of the sensors. In this chapter, we summarize recent progress in the development of electrospun nanofiber-based sensors, describe the design of different types of sensors, and discuss their sensing performances in detail. This chapter might bring further development and evolution of sensors based on electrospun nanofibers for the detection of various analytes.
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References
Noyes PD, McElwee MK, Miller HD, Clark BW, Van Tiem LA, Walcott KC, Erwin KN, Levin ED (2009) The toxicology of climate change: environmental contaminants in a warming world. Environ Int 35(6):971–986. doi:10.1016/j.envint.2009.02.006
Nriagu JO, Pacyna JM (1988) Quantitative assessment of worldwide contamination of air, water and soils by trace-metals. Nature 333(6169):134–139. doi:10.1038/333134a0
Jarup L (2004) Health and environment information systems for exposure and disease mapping, and risk assessment. Environ Health Perspect 112(9):995–997. doi:10.1289/ehp.6736
Onyido I, Norris AR, Buncel E (2004) Biomolecule-mercury interactions: modalities of DNA base-mercury binding mechanisms. Remediation strategies. Chem Rev 104(12):5911–5929. doi:10.1021/cr030443w
Maserti BE, Ferrara R (1991) Mercury in plants, soil and atmosphere near a chlor-alkali complex. Water Air Soil Pollut 56(1):15–20. doi:10.1007/bf00342257
Komarek M, Ettler V, Chrastny V, Mihaljevic M (2008) Lead isotopes in environmental sciences: a review. Environ Int 34(4):562–577. doi:10.1016/j.envint.2007.10.005
Yuan CG, Shi JB, He B, Liu JF, Liang LN, Jiang GB (2004) Speciation of heavy metals in marine sediments from the East China Sea by ICP-MS with sequential extraction. Environ Int 30(6):769–783. doi:10.1016/j.envint.2004.01.001
Mateos R, Espartero JL, Trujillo M, Rios JJ, Leon M, Alcudia F, Cert A (2001) Determination of phenols, flavones, and lignans in virgin olive oils by solid-phase extraction and high-performance liquid chromatography with diode array ultraviolet detection. J Agric Food Chem 49(5):2185–2192. doi:10.1021/jf0013205
Carabias-Martinez R, Rodriguez E, Fernandez ME, Calvo L, Sanchez FJ (2003) Evolution over time of the agricultural pollution of waters in an area of Salamanca and Zamora (Spain). Water Res 37(4):928–938. doi:10.1016/s0043-1354(02)00366-4
Galloway TS, Sanger RC, Smith KL, Fillmann G, Readman JW, Ford TE, Depledge MH (2002) Rapid assessment of marine pollution using multiple biomarkers and chemical immunoassays. Environ Sci Technol 36(10):2219–2226. doi:10.1021/es010300w
Basheer C, Balasubramanian R, Lee HK (2003) Determination of organic micropollutants in rainwater using hollow fiber membrane/liquid-phase microextraction combined with gas chromatography–mass spectrometry. J Chromatogr A 1016(1):11–20. doi:10.1016/s0021-9673(03)01295-0
Sturgeon RE, Willie SN, Berman SS (1985) Preconcentration of selenium and antimony from seawater for determination by graphite-furnace atomic-absorption spectrometry. Anal Chem 57(1):6–9. doi:10.1021/ac00279a006
Kalcher K, Kauffmann JM, Wang J, Svancara I, Vytras K, Neuhold C, Yang Z (1995) Sensors based on carbon-paste in electrochemical analysis – a review with particular emphasis on the period 1990–1993. Electroanalysis 7(1):5–22. doi:10.1002/elan.1140070103
Karton N, Segal E, Omer L, Portnoy M, Satchi R, Shabat D (2011) A unique paradigm for a turn-on near-infrared cyanine-based probe: noninvasive intravital optical imaging of hydrogen peroxide. J Am Chem Soc 133(28):10960–10965. doi:10.1021/ja203145v
Janshoff A, Galla HJ, Steinem C (2000) Piezoelectric mass-sensing devices as biosensors-an alternative to optical biosensors? Angew Chem-Int Ed 39(22):4004–4032. doi:10.1002/1521-3773(20001117)39:22<4004::aid-anie4004>3.0.co;2-2
Khin MM, Nair AS, Babu VJ, Murugan R, Ramakrishna S (2012) A review on nanomaterials for environmental remediation. Energy Environ Sci 5(8):8075–8109. doi:10.1039/c2ee21818f
Zhang LD, Fang M (2010) Nanomaterials in pollution trace detection and environmental improvement. Nano Today 5(2):128–142. doi:10.1016/j.nantod.2010.03.002
Su S, Wu W, Gao J, Lu J, Fan C (2012) Nanomaterials-based sensors for applications in environmental monitoring. J Mater Chem 22(35):18101–18110. doi:10.1039/c2jm33284a
Huang ZM, Zhang YZ, Kotaki M, Ramakrishna S (2003) A review on polymer nanofibers by electrospinning and their applications in nanocomposites. Compos Sci Technol 63(15):2223–2253. doi:10.1016/s0266-3538(03)00178-7
Zhang SG (2003) Fabrication of novel biomaterials through molecular self-assembly. Nat Biotechnol 21(10):1171–1178. doi:10.1038/nbt874
Barnes CP, Sell SA, Boland ED, Simpson DG, Bowlin GL (2007) Nanofiber technology: designing the next generation of tissue engineering scaffolds. Adv Drug Deliv Rev 59(14):1413–1433. doi:10.1016/j.addr.2007.04.022
Teo WE, Ramakrishna S (2006) A review on electrospinning design and nanofibre assemblies. Nanotechnology 17(14):R89–R106. doi:10.1088/0957-4484/17/14/r01
Subbiah T, Bhat GS, Tock RW, Pararneswaran S, Ramkumar SS (2005) Electrospinning of nanofibers. J Appl Polym Sci 96(2):557–569. doi:10.1002/app.21481
Lin J, Wang X, Ding B, Yu J, Sun G, Wang M (2012) Biomimicry via electrospinning. Crit Rev Solid State 37(2):94–114. doi:10.1080/10408436.2011.627096
Ding B, Li C, Miyauchi Y, Kuwaki O, Shiratori S (2006) Formation of novel 2D polymer nanowebs via electrospinning. Nanotechnology 17(15):3685–3691. doi:10.1088/0957-4484/17/15/011
Wang X, Ding B, Sun G, Wang M, Yu J (2013) Electro-spinning/netting: a strategy for the fabrication of three-dimensional polymer nano-fiber/nets. Prog Mater Sci 58(8):1173–1243, doi:http://dx.doi.org/10.1016/j.pmatsci.2013.05.001
Ding B, Wang M, Yu J, Sun G (2009) Gas sensors based on electrospun nanofibers. Sensors 9(3):1609–1624. doi:10.3390/s90301609
Ding B, Wang M, Wang X, Yu J, Sun G (2010) Electrospun nanomaterials for ultrasensitive sensors. Mater Today 13(11):16–27. doi:10.1016/S1369-7021(10)70200-5
Kang E, Kim M, Oh JS, Park DW, Shim SE (2012) Electrospun BMIMPF6/nylon 6,6 nanofiber chemiresistors as organic vapour sensors. Macromol Res 20(4):372–378. doi:10.1007/s13233-012-0043-0
Wang W, Huang H, Li Z, Zhang H, Wang Y, Zheng W, Wang C (2008) Zinc oxide nanofiber gas sensors via electrospinning. J Am Ceram Soc 91(11):3817–3819. doi:10.1111/j.1551-2916.2008.02765.x
Huang JS, Wang DW, Hou HQ, You TY (2008) Electrospun palladium nanoparticle-loaded carbon nanofibers and their electrocatalytic activities towards hydrogen peroxide and NADH. Adv Funct Mater 18(3):441–448. doi:10.1002/adfm.200700729
Ding Y, Liu Y, Parisi J, Zhang L, Lei Y (2011) A novel NiO-Au hybrid nanobelts based sensor for sensitive and selective glucose detection. Biosens Bioelectron 28(1):393–398. doi:10.1016/j.bios.2011.07.054
Jung L, Balakrishnan S, Jaehwa C, Seong J, Jong K (2011) Detection of adulterated gasoline using colorimetric organic microfibers. J Mater Chem 21(8):2648–2655. doi:10.1039/c0jm02287j
Manesh KM, Santhosh P, Gopalan A, Lee KP (2007) Electrospun poly(vinylidene fluoride)/poly(aminophenylboronic acid) composite nanofibrous membrane as a novel glucose sensor. Anal Biochem 360(2):189–195. doi:10.1016/j.ab.2006.09.021
Wang X, Ding B, Yu J, Si Y, Yang S, Sun G (2011) Electro-netting: fabrication of two-dimensional nano-nets for highly sensitive trimethylamine sensing. Nanoscale 3(3):911–915. doi:10.1039/c0nr00783h
Ding B, Si Y, Wang X, Yu J, Feng L, Sun G (2011) Label-free ultrasensitive colorimetric detection of copper(II) ions utilizing polyaniline/polyamide-6 nano-fiber/net sensor strips. J Mater Chem 21(35):13345–13353. doi:10.1039/c1jm11851j
Bin D, Xianfeng W, Jianyong Y, Moran W (2011) Polyamide 6 composite nano-fiber/net functionalized by polyethyleneimine on quartz crystal microbalance for highly sensitive formaldehyde sensors. J Mater Chem 21(34):12784–12792. doi:10.1039/c1jm11847a
Henry Wohltjen RD (1979) Surface acoustic wave probe for chemical analysis. Anal Chem 51(9):1458–1464. doi:10.1021/ac50045a024
Liu S, Sun H, Nagarajan R, Kumar J, Gu Z, Cho J, Kurup P (2011) Dynamic chemical vapor sensing with nanofibrous film based surface acoustic wave sensors. Sens Actuator A Phys 167(1):8–13. doi:10.1016/j.sna.2011.02.007
Wang X, Ding B, Yu J, Wang M (2011) Highly sensitive humidity sensors based on electro-spinning/netting a polyamide 6 nano-fiber/net modified by polyethyleneimine. J Mater Chem 21(40):16231–16238. doi:10.1039/c1jm13037d
Sun M, Ding B, Yu J (2012) Sensitive metal ion sensors based on fibrous polystyrene membranes modified by polyethyleneimine. RSC Adv 2(4):1373–1378. doi:10.1039/c1ra00673h
Lin Q, Li Y, Yang M (2012) Highly sensitive and ultrafast response surface acoustic wave humidity sensor based on electrospun polyaniline/poly(vinyl butyral) nanofibers. Anal Chim Acta 748:73–80. doi:10.1016/j.aca.2012.08.041
He XL, Arsat R, Sadek AZ, Wlodarski W, Kalantar K, Li JP (2010) Electrospun PVP fibers and gas sensing properties of PVP/36 deg YX LiTaO3 SAW device. Sens Actuator B Chem 145(2):674–679. doi:10.1016/j.snb.2010.01.013
Buttry DA, Ward MD (1992) Measurement of interfacial processes at electrode surfaces with the electrochemical quartz crystal microbalance. Chem Rev 92(6):1355–1379. doi:10.1021/cr00014a006
Yoo HY, Bruckenstein S (2013) A novel quartz crystal microbalance gas sensor based on porous film coatings. A high sensitivity porous poly(methylmethacrylate) water vapor sensor. Anal Chim Acta 785:98–103. doi:10.1016/j.aca.2013.04.052
Vashist SK, Vashist P (2011) Recent advances in quartz crystal microbalance-based sensors. J Sens 2011:571405–571418. doi:10.1155/2011/571405
Wang X, Cui F, Lin J, Ding B, Yu J, Al SS (2012) Functionalized nanoporous TiO2 fibers on quartz crystal microbalance platform for formaldehyde sensor. Sens Actuator B Chem 171–172:658–665. doi:10.1016/j.snb.2012.05.050
Hu W, Chen S, Liu L, Ding B, Wang H (2011) Formaldehyde sensors based on nanofibrous polyethyleneimine/bacterial cellulose membranes coated quartz crystal microbalance. Sens Actuator B Chem 157(2):554–559. doi:10.1016/j.snb.2011.05.021
Wang X, Wang J, Si Y, Ding B, Yu J, Sun G, Luo W, Zheng G (2012) Nanofiber-net-binary structured membranes for highly sensitive detection of trace HCl gas. Nanoscale 4(23):7585–7592. doi:10.1039/c2nr32730a
Wang X, Ding B, Sun M, Yu J, Sun G (2010) Nanofibrous polyethyleneimine membranes as sensitive coatings for quartz crystal microbalance-based formaldehyde sensors. Sens Actuator B Chem 144(1):11–17. doi:10.1016/j.snb.2009.08.023
Sabri YM, Kojima R, Ippolito SJ, Wlodarski W, Kalantar K, Kaner RB, Bhargava SK (2011) QCM based mercury vapor sensor modified with polypyrrole supported palladium. Sens Actuator B Chem 160(1):616–622. doi:10.1016/j.snb.2011.08.038
Pei Z, Ma X, Ding P, Zhang W, Luo Z, Li G (2010) Study of a QCM dimethyl methylphosphonate sensor based on a ZnO-modified nanowire-structured manganese dioxide film. Sensors 10(9):8275–8290. doi:10.3390/s100908275
Kim ID, Rothschild A, Lee BH, Kim DY, Jo SM, Tuller HL (2006) Ultrasensitive chemiresistors based on electrospun TiO2 nanofibers. Nano Lett 6(9):2009–2013. doi:10.1021/nl061197h
Choi SH, Hwang IS, Lee JH, Oh SG, Kim ID (2011) Microstructural control and selective C2H5OH sensing properties of Zn2SnO4 nanofibers prepared by electrospinning. Chem Commun 47(33):9315–9317. doi:10.1039/c1cc10707k
Yoon JW, Choi JK, Lee JH (2012) Design of a highly sensitive and selective C2H5OH sensor using p-type Co3O4 nanofibers. Sens Actuator B Chem 161(1):570–577. doi:10.1016/j.snb.2011.11.002
Wang G, Ji Y, Huang X, Yang X, Gouma PI, Dudley M (2006) Fabrication and characterization of polycrystalline WO3 nanofibers and their application for ammonia sensing. J Phys Chem B 110(47):23777–23782. doi:10.1021/jp0635819
Zhang Y, He X, Li J, Miao Z, Huang F (2008) Fabrication and ethanol-sensing properties of micro gas sensor based on electrospun SnO2 nanofibers. Sens Actuator B Chem 132(1):67–73. doi:10.1016/j.snb.2008.01.006
Leng JY, Xu XJ, Lv N, Fan HT, Zhang T (2011) Synthesis and gas-sensing characteristics of WO3 nanofibers via electrospinning. J Colloid Interface Sci 356(1):54–57. doi:10.1016/j.jcis.2010.11.079
Ruggieri F, Di Camillo D, Lozzi L, Santucci S, De A, Ferri G, Giancaterini L, Cantalini C (2013) Preparation of nitrogen doped TiO2 nanofibers by near field electrospinning (NFES) technique for NO2 sensing. Sens Actuator B Chem 179:107–113. doi:10.1016/j.snb.2012.10.094
Choi SW, Park JY, Kim SS (2011) Dependence of gas sensing properties in ZnO nanofibers on size and crystallinity of nanograins. J Mater Res 26(14):1662–1665. doi:10.1557/jmr.2011.209
Lee HU, Ahn K, Lee SJ, Kim JP, Kim HG, Jeong SY, Cho CR (2011) ZnO nanobarbed fibers: fabrication, sensing NO2 gas, and their sensing mechanism. Appl Phys Lett 98(19). doi:10.1063/1.3590202
Zhang Z, Li X, Wang C, Wei L, Liu Y, Shao C (2009) ZnO hollow nanofibers: fabrication from facile single capillary electrospinning and applications in gas sensors. J Phys Chem C 113(45):19397–19403. doi:10.1021/jp9070373
Tuan N, Park S, Kim JB, Kim TK, Seong GH, Choo J, Kim YS (2011) Polycrystalline tungsten oxide nanofibers for gas-sensing applications. Sens Actuator B Chem 160(1):549–554. doi:10.1016/j.snb.2011.08.028
Qi Q, Zhang T, Liu L, Zheng X (2009) Synthesis and toluene sensing properties of SnO2 nanofibers. Sens Actuator B Chem 137(2):471–475. doi:10.1016/j.snb.2008.11.042
Zheng W, Li Z, Zhang H, Wang W, Wang Y, Wang C (2009) Electrospinning route for α-Fe2O3 ceramic nanofibers and their gas sensing properties. Mater Res Bull 44(6):1432–1436. doi:10.1016/j.materresbull.2008.12.013
Fan HT, Xu XJ, Ma XK, Zhang T (2011) Preparation of LaFeO3 nanofibers by electrospinning for gas sensors with fast response and recovery. Nanotechnology 22(11):115502–115509. doi:10.1088/0957-4484/22/11/115502
Zheng W, Lu X, Wang W, Dong B, Zhang H, Wang Z, Xu X, Wang C (2010) A rapidly responding sensor for methanol based on electrospun In2O3-SnO2 nanofibers. J Am Ceram Soc 93(1):15–17. doi:10.1111/j.1551-2916.2009.03354.x
Song X, Liu L (2009) Characterization of electrospun ZnO-SnO2 nanofibers for ethanol sensor. Sens Actuator A Phys 154(1):175–179. doi:10.1016/j.sna.2009.06.010
Wei S, Zhang Y, Zhou M (2011) Toluene sensing properties of SnO2-ZnO hollow nanofibers fabricated from single capillary electrospinning. Solid State Commun 151(12):895–899. doi:10.1016/j.ssc.2011.03.031
Wang Z, Li Z, Sun J, Zhang H, Wang W, Zheng W, Wang C (2010) Improved hydrogen monitoring properties based on p-NiO/n-SnO2 heterojunction composite nanofibers. J Phys Chem C 114(13):6100–6105. doi:10.1021/jp9100202
Xu L, Zheng R, Liu S, Song J, Chen J, Dong B, Song H (2012) NiO@ZnO heterostructured nanotubes: coelectrospinning fabrication, characterization, and highly enhanced gas sensing properties. Inorg Chem 51(14):7733–7740. doi:10.1021/ic300749a
Liu L, Guo C, Li S, Wang L, Dong Q, Li W (2010) Improved H2 sensing properties of Co-doped SnO2 nanofibers. Sens Actuator B Chem 150(2):806–810. doi:10.1016/j.snb.2010.07.022
Zhang HN, Li ZY, Liu L, Xu XR, Wang ZJ, Wang W, Zheng W, Dong B, Wang C (2010) Enhancement of hydrogen monitoring properties based on Pd–SnO2 composite nanofibers. Sensor Actuator B Chem 147(1):111–115. doi:10.1016/j.snb.2010.01.056
Cho NG, Yang DJ, Jin MJ, Kim HG, Tuller HL, Kim ID (2011) Highly sensitive SnO2 hollow nanofiber-based NO2 gas sensors. Sensor Actuator B Chem 160(1):1468–1472. doi:10.1016/j.snb.2011.07.035
Cho S, Kim DH, Lee BS, Jung J, Yu WR, Hong SH, Lee S (2012) Ethanol sensors based on ZnO nanotubes with controllable wall thickness via atomic layer deposition an O2 plasma process and an annealing process. Sens Actuator B Chem 162(1):300–306. doi:10.1016/j.snb.2011.12.081
Modafferi V, Panzera G, Donato A, Antonucci PL, Cannilla C, Donato N, Spadaro D, Neri G (2012) Highly sensitive ammonia resistive sensor based on electrospun V2O5 fibers. Sens Actuator B Chem 163(1):61–68. doi:10.1016/j.snb.2012.01.007
Zhang Y, Li J, An G, He X (2010) Highly porous SnO2 fibers by electrospinning and oxygen plasma etching and its ethanol-sensing properties. Sens Actuator B Chem 144(1):43–48. doi:10.1016/j.snb.2009.10.012
Zhang XJ, Qiao GJ (2012) High performance ethanol sensing films fabricated from ZnO and In2O3 nanofibers with a double-layer structure. Appl Surf Sci 258(17):6643–6647, doi:http://dx.doi.org/10.1016/j.apsusc.2012.03.098
Choi SH, Choi SJ, Min BK, Lee WY, Park JS, Kim ID (2013) Facile synthesis of p-type perovskite SrTi0.65Fe0.35O3 nanofibers prepared by electrospinning and their oxygen-sensing properties. Macromol Mater Eng 298(5):521–527. doi:10.1002/mame.201200375
Hwang DK, Kim S, Lee JH, Hwang IS, Kim ID (2011) Phase evolution of perovskite LaNiO3 nanofibers for supercapacitor application and p-type gas sensing properties of LaOCl-NiO composite nanofibers. J Mater Chem 21(6):1959–1965. doi:10.1039/c0jm02256j
Moon J, Park J, Lee S, Zyung T, Kim I (2010) Pd-doped TiO2 nanofiber networks for gas sensor applications. Sensor Actuator B Chem 149(1):301–305. doi:10.1016/j.snb.2010.06.033
Wang W, Li Z, Liu L, Zhang H, Zheng W, Wang Y, Huang H, Wang Z, Wang C (2009) Humidity sensor based on LiCl-doped ZnO electrospun nanofibers. Sens Actuator B Chem 141(2):404–409. doi:10.1016/j.snb.2009.06.029
Wang X, Zhao M, Liu F, Jia J, Li X, Cao L (2013) C2H2 gas sensor based on Ni-doped ZnO electrospun nanofibers. Ceram Int 39(3):2883–2887. doi:10.1016/j.ceramint.2012.09.062
Zhang H, Li Z, Liu L, Wang C, Wei Y, MacDiarmid AG (2009) Mg2+/Na+-doped rutile TiO2 nanofiber mats for high-speed and anti-fogged humidity sensors. Talanta 79(3):953–958. doi:10.1016/j.talanta.2009.05.035
Xu L, Xing R, Song J, Xu W, Song H (2013) ZnO-SnO2 nanotubes surface engineered by Ag nanoparticles: synthesis, characterization, and highly enhanced HCHO gas sensing properties. J Mater Chem C 1(11):2174–2182. doi:10.1039/c3tc00689a
Zhang L, Wang X, Zhao Y, Zhu Z, Fong H (2012) Electrospun carbon nano-felt surface-attached with Pd nanoparticles for hydrogen sensing application. Mater Lett 68:133–136. doi:10.1016/j.matlet.2011.10.064
Li Z, Zhang H, Zheng W, Wang W, Huang H, Wang C, MacDiarmid AG, Wei Y (2008) Highly sensitive and stable humidity nanosensors based on LiCl doped TiO2 electrospun nanofibers. J Am Chem Soc 130(15):5036–5037. doi:10.1021/ja800176s
Casalbore G, Yang MJ, Camaioni N, Mari CM, Li Y, Sun H, Ling M (2000) Investigations on the ion transport mechanism in conducting polymer films. Solid State Ion 131(3–4):311–321. doi:10.1016/s0167-2738(00)00688-3
Lin Q, Li Y, Yang M (2012) Polyaniline nanofiber humidity sensor prepared by electrospinning. Sens Actuator B Chem 161(1):967–972. doi:10.1016/j.snb.2011.11.074
Liu HQ, Kameoka J, Czaplewski DA, Craighead HG (2004) Polymeric nanowire chemical sensor. Nano Lett 4(4):671–675. doi:10.1021/nl049826f
Li P, Li Y, Ying B, Yang M (2009) Electrospun nanofibers of polymer composite as a promising humidity sensitive material. Sens Actuator B Chem 141(2):390–395. doi:10.1016/j.snb.2009.07.006
Wang S, Chao D, Berda EB, Jia X, Yang R, Wang X, Jiang T, Wang C (2013) Fabrication of electroactive oligoaniline functionalized poly(amic acid) nanofibers for application as an ammonia sensor. RSC Adv 3(12):4059–4065. doi:10.1039/c3ra00056g
Aussawasathien D, Sahasithiwat S, Menbangpung L (2008) Electrospun camphorsulfonic acid doped poly(o-toluidine)-polystyrene composite fibers: chemical vapor sensing. Synthetic Met 158(7):259–263. doi:10.1016/j.synthmet.2008.01.007
Haynes AS, Gouma PI (2008) Electrospun conducting polymer-based sensors for advanced pathogen detection. IEEE Sens J 8(5–6):701–705. doi:10.1109/jsen.2008.923039
Rojas R, Pinto NJ (2008) Using electrospinning for the fabrication of rapid response gas sensors based on conducting polymer nanowires. IEEE Sens J 8(5–6):951–953. doi:10.1109/jsen.2008.923932
Pinto NJ, Rivera D, Melendez A, Ramos I, Lim JH, Johnson ATC (2011) Electrical response of electrospun PEDOT-PSSA nanofibers to organic and inorganic gases. Sens Actuator B Chem 156(2):849–853. doi:10.1016/j.snb.2011.02.053
Aussawasathien D, Sahasithiwat S, Menbangpung L, Teerawattananon C (2011) Poly(o-anisidine)-polystyrene composite fibers via electrospinning process: surface morphology and chemical vapor sensing. Sens Actuator B Chem 151(2):341–350. doi:10.1016/j.snb.2010.07.048
Chen D, Lei S, Chen Y (2011) A single polyaniline nanofiber field effect transistor and its gas sensing mechanisms. Sensors 11(7):6509–6516. doi:10.3390/s110706509
Bai H, Zhao L, Lu C, Li C, Shi G (2009) Composite nanofibers of conducting polymers and hydrophobic insulating polymers: preparation and sensing applications. Polymer 50(14):3292–3301. doi:10.1016/j.polymer.2009.04.066
Wang Y, Jia W, Strout T, Schempf A, Zhang H, Li B, Cui J, Lei Y (2009) Ammonia gas sensor using polypyrrole-coated TiO2/ZnO nanofibers. Electroanalysis 21(12):1432–1438. doi:10.1002/elan.200904584
Jaewon C, Eun Joo P, Dong Wha P, Sang Eun S (2010) MWCNT-OH adsorbed electrospun nylon 6,6 nanofibers chemiresistor and their application in low molecular weight alcohol vapours sensing. Synthetic Met 160(23–24):2664–2669. doi:10.1016/j.synthmet.2010.10.022
Eaidkong T, Mungkarndee R, Phollookin C, Tumcharern G, Sukwattanasinitt M, Wacharasindhu S (2012) Polydiacetylene paper-based colorimetric sensor array for vapor phase detection and identification of volatile organic compounds. J Mater Chem 22(13):5970–5977. doi:10.1039/c2jm16273c
Chae SK, Park H, Yoon J, Lee CH, Ahn DJ, Kim JM (2007) Polydiacetylene supramolecules in electrospun microfibers: fabrication, micropatterning, and sensor applications. Adv Mater 19(4):521–524. doi:10.1002/adma.200602012
Wang X, Si Y, Wang J, Ding B, Yu J, Al SS (2012) A facile and highly sensitive colorimetric sensor for the detection of formaldehyde based on electro-spinning/netting nano-fiber/nets. Sens Actuator B Chem 163(1):186–193. doi:10.1016/j.snb.2012.01.033
Yarimaga O, Jaworski J, Yoon B, Kim JM (2012) Polydiacetylenes: supramolecular smart materials with a structural hierarchy for sensing, imaging and display applications. Chem Commun 48(19):2469–2485. doi:10.1039/c2cc17441c
Pumtang S, Siripornnoppakhun W, Sukwattanasinitt M, Ajavakom A (2011) Solvent colorimetric paper-based polydiacetylene sensors from diacetylene lipids. J Colloid Interface Sci 364(2):366–372. doi:10.1016/j.jcis.2011.08.074
Yoon J, Chae SK, Kim JM (2007) Colorimetric sensors for volatile organic compounds (VOCs) based on conjugated polymer-embedded electrospun fibers. J Am Chem Soc 129(11):3038–3039. doi:10.1021/ja067856+
Yoon J, Jung YS, Kim JM (2009) A combinatorial approach for colorimetric differentiation of organic solvents based on conjugated polymer-embedded electrospun fibers. Adv Funct Mater 19(2):209–214. doi:10.1002/adfm.200800963
Poltue T, Rangkupan R, Dubas ST, Dubas L (2011) Nickel(II) ions sensing properties of dimethylglyoxime/poly(caprolactone) electrospun fibers. Mater Lett 65(14):2231–2234. doi:10.1016/j.matlet.2011.04.012
Li Y, Si Y, Wang X, Ding B, Sun G, Zheng G, Luo W, Yu J (2013) Colorimetric sensor strips for lead (II) assay utilizing nanogold probes immobilized polyamide-6/nitrocellulose nano-fibers/nets. Biosens Bioelectron 48:244–250. doi:10.1016/j.bios.2013.03.085
Van der Schueren L, Mollet T, Ceylan Ö, De Clerck K (2010) The development of polyamide 6.6 nanofibres with a pH-sensitive function by electrospinning. Eur Polym J 46(12):2229–2239, doi:http://dx.doi.org/10.1016/j.eurpolymj.2010.09.016
Van der Schueren L, De Meyer T, Steyaert I, Ceylan O, Hemelsoet K, Van Speybroeck V, De Clerck K (2013) Polycaprolactone and polycaprolactone/chitosan nanofibres functionalised with the pH-sensitive dye Nitrazine Yellow. Carbohyd Polym 91(1):284–293. doi:10.1016/j.carbpol.2012.08.003
Valeur B, Leray I (2000) Design principles of fluorescent molecular sensors for cation recognition. Coord Chem Rev 205(1):3–40. doi:10.1016/s0010-8545(00)00246-0
Wang M, Meng G, Huang Q, Qian Y (2012) Electrospun 1,4-DHAQ-doped cellulose nanofiber films for reusable fluorescence detection of trace Cu2+ and further for Cr3+. Environ Sci Technol 46(1):367–373. doi:10.1021/es202137c
Basabe L, Reinhoudt DN, Crego M (2007) Design of fluorescent materials for chemical sensing. Chem Soc Rev 36(6):993–1017. doi:10.1039/b609548h
Adewuyi S, Ondigo DA, Zugle R, Tshentu Z, Nyokong T, Torto N (2012) A highly selective and sensitive pyridylazo-2-naphthol-poly(acrylic acid) functionalized electrospun nanofiber fluorescence “turn-off” chemosensory system for Ni2+. Anal Method 4(6):1729–1735. doi:10.1039/c2ay25182e
Wang W, Yang Q, Sun L, Wang H, Zhang C, Fei X, Sun M, Li Y (2011) Preparation of fluorescent nanofibrous film as a sensing material and adsorbent for Cu2+ in aqueous solution via copolymerization and electrospinning. J Hazard Mater 194:185–192. doi:10.1016/j.jhazmat.2011.07.083
Wang W, Wang X, Yang Q, Fei X, Sun M, Song Y (2013) A reusable nanofibrous film chemosensor for highly selective and sensitive optical signaling of Cu2+ in aqueous media. Chem Commun 49(42):4833–4835. doi:10.1039/c3cc41317a
Davis BW, Niamnont N, Hare CD, Sukwattanasinitt M, Cheng Q (2010) Nanofibers doped with dendritic fluorophores for protein detection. ACS Appl Mater Interface 2(7):1798–1803. doi:10.1021/am100345g
Long Y, Chen H, Yang Y, Wang H, Yang Y, Li N, Li K, Pei J, Liu F (2009) Electrospun nanofibrous film doped with a conjugated polymer for DNT fluorescence sensor. Macromolecules 42(17):6501–6509. doi:10.1021/ma900756w
Wang XY, Kim YG, Drew C, Ku BC, Kumar J, Samuelson LA (2004) Electrostatic assembly of conjugated polymer thin layers on electrospun nanofibrous membranes for biosensors. Nano Lett 4(2):331–334. doi:10.1021/nl034885z
Silva AP, Fox DB, Huxley AJM, Moody TS (2000) Combining luminescence, coordination and electron transfer for signalling purposes. Coord Chem Rev 205(1):41–57. doi:10.1016/s0010-8545(00)00238-1
Prodi L, Bolletta F, Montalti M, Zaccheroni N (2000) Luminescent chemosensors for transition metal ions. Coord Chem Rev 205(1):59–83. doi:10.1016/s0010-8545(00)00242-3
Keefe MH, Benkstein KD, Hupp JT (2000) Luminescent sensor molecules based on coordinated metals: a review of recent developments. Coord Chem Rev 205(1):201–228. doi:10.1016/s0010-8545(00)00240-x
Demas JN, DeGraff BA, Coleman PB (1999) Oxygen sensors based on luminescence quenching. Anal Chem 71(23):793A–800A. doi:10.1021/ac9908546
Zhou C, Shi Y, Ding X, Li M, Luo J, Lu Z, Xiao D (2013) Development of a fast and sensitive glucose biosensor using iridium complex-doped electrospun optical fibrous membrane. Anal Chem 85(2):1171–1176. doi:10.1021/ac303107d
Wang LY, Xu Y, Lin Z, Zhao N, Xu YH (2011) Electrospinning fabrication and oxygen sensing properties of Cu(I) complex-polystyrene composite microfibrous membranes. J Lumin 131(7):1277–1282. doi:10.1016/j.jlumin.2011.03.017
Kuo CC, Tung YC, Chen WC (2010) Morphology and pH sensing characteristics of new luminescent electrospun fibers prepared from poly(phenylquinoline)-block-polystyrene/polystyrene blends. Macromol Rapid Commun 31(1):65–70. doi:10.1002/marc.200900566
Liu CL, Lin CH, Kuo CC, Lin ST, Chen WC (2011) Conjugated rod-coil block copolymers: synthesis, morphology, photophysical properties, and stimuli-responsive applications. Prog Polym Sci 36(5):603–637. doi:10.1016/j.progpolymsci.2010.07.008
Kind H, Yan HQ, Messer B, Law M, Yang PD (2002) Nanowire ultraviolet photodetectors and optical switches. Adv Mater 14(2):158–160. doi:10.1002/1521-4095(20020116)14:2<158::aid-adma158>3.0.co;2-w
Lin D, Wu H, Zhang W, Li H, Pan W (2009) Enhanced UV photoresponse from heterostructured Ag-ZnO nanowires. Appl Phys Lett 94(17). doi:10.1063/1.3126045
Wu H, Sun Y, Lin D, Zhong R, Zhang C, Pan W (2009) GaN nanofibers based on electrospinning: facile synthesis, controlled assembly, precise doping, and application as high performance UV photodetector. Adv Mater 21(2):227–231. doi:10.1002/adma.200800529
Lai C, Wang X, Zhao Y, Fong H, Zhu Z (2013) Effects of humidity on the ultraviolet nanosensors of aligned electrospun ZnO nanofibers. RSC Adv 3(18):6640–6645. doi:10.1039/c3ra23420g
Anitha S, Brabu B, Rajesh KP, Natarajan TS (2013) Fabrication of UV sensor based on electrospun composite fibers. Mater Lett 92:417–420. doi:10.1016/j.matlet.2012.11.005
Li Y, Gong J, He G, Deng Y (2012) Enhancement of photoresponse and UV-assisted gas sensing with Au decorated ZnO nanofibers. Mater Chem Phys 134(2–3):1172–1178. doi:10.1016/j.matchemphys.2012.04.014
Zhu ZT, Zhang LF, Howe JY, Liao YL, Speidel JT, Smith S, Fong H (2009) Aligned electrospun ZnO nanofibers for simple and sensitive ultraviolet nanosensors. Chem Commun 18:2568–2570. doi:10.1039/b901426h
Garrido JA, Monroy E, Izpura I, Munoz E (1998) Photoconductive gain modelling of GaN photoconductors. Semicond Sci Technol 13(6):563–568. doi:10.1088/0268-1242/13/6/005
Avnir D, Braun S, Lev O, Ottolenghi M (1994) Enzymes and other proteins entrapped in sol–gel materials. Chem Mater 6(10):1605–1614. doi:10.1021/cm00046a008
Im JS, Kim JG, Bae TS, Yu HR, Lee YS (2011) Surface modification of electrospun spherical activated carbon for a high-performance biosensor electrode. Sens Actuator B Chem 158(1):151–158. doi:10.1016/j.snb.2011.05.058
Scampicchio M, Arecchi A, Lawrence NS, Mannino S (2010) Nylon nanofibrous membrane for mediated glucose biosensing. Sens Actuator B Chem 145(1):394–397. doi:10.1016/j.snb.2009.12.042
Wilson R, Turner APF (1992) Glucose-oxidase-an ideal enzyme. Biosens Bioelectron 7(3):165–185. doi:10.1016/0956-5663(92)87013-f
Im JS, Yun J, Kim JG, Bae TS, Lee YS (2012) The effects of carbon nanotube addition and oxyfluorination on the glucose-sensing capabilities of glucose oxidase-coated carbon fiber electrodes. Appl Surf Sci 258(7):2219–2225. doi:10.1016/j.apsusc.2011.08.017
Ren G, Xu X, Liu Q, Cheng J, Yuan X, Wu L, Wan Y (2006) Electrospun poly(vinyl alcohol)/glucose oxidase biocomposite membranes for biosensor applications. React Funct Polym 66(12):1559–1564. doi:10.1016/j.reactfunctpolym.2006.05.005
Liu G, Zheng B, Jiang Y, Cai Y, Du J, Yuan H, Xiao D (2012) Improvement of sensitive CuO NFs-ITO nonenzymatic glucose sensor based on in situ electrospun fiber. Talanta 101:24–31. doi:10.1016/j.talanta.2012.08.040
Liu Y, Teng H, Hou H, You T (2009) Nonenzymatic glucose sensor based on renewable electrospun Ni nanoparticle-loaded carbon nanofiber paste electrode. Biosens Bioelectron 24(11):3329–3334. doi:10.1016/j.bios.2009.04.032
Xiao Y, Ju HX, Chen HY (1999) Hydrogen peroxide sensor based on horseradish peroxidase-labeled Au colloids immobilized on gold electrode surface by cysteamine monolayer. Anal Chim Acta 391(1):73–82. doi:10.1016/s0003-2670(99)00196-8
Mao X, Simeon F, Rutledge GC, Hatton TA (2013) Electrospun carbon nanofiber webs with controlled density of states for sensor applications. Adv Mater 25(9):1309–1314. doi:10.1002/adma.201203045
Ouyang Z, Li J, Wang J, Li Q, Ni T, Zhang X, Wang H, Li Q, Su Z, Wei G (2013) Fabrication, characterization and sensor application of electrospun polyurethane nanofibers filled with carbon nanotubes and silver nanoparticles. J Mater Chem B 1(18):2415–2424. doi:10.1039/c3tb20316f
Acknowledgement
This work is supported by the National Natural Science Foundation of China (No. 51173022 and 51273038), the Shanghai Nano Special Projects (11nm0502900), the Shanghai Committee of Science and Technology (No. 12JC1400101), the Huo Yingdong Foundation (131070), the Program for New Century Talents of the University in China, and the Fundamental Research Funds for the Central Universities.
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Wang, X., Li, Y., Ding, B. (2014). Electrospun Nanofiber-Based Sensors. In: Ding, B., Yu, J. (eds) Electrospun Nanofibers for Energy and Environmental Applications. Nanostructure Science and Technology. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-54160-5_11
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