Abstract
Alkyltetracarbonylcobalt derivatives, RCo(CO)4, have been prepared by the reaction of sodium tetracarbonylcobaltate with alkyl halides in polar solvents and by decarboxylation of acyltetracarbonylcobalt, RCOCo(CO)4, by a thermal or vacuum treatment. Ethyltetracarbonylcobalt was obtained by treating sodium tetracarbonylcobaltate with triethyloxonium tetrafluoroborate. Perfluoroalkyltetracarbonylcobalt derivatives resulted from the reaction of perfluoroacyl halides or perfluorocarboxylic anhydrides with lithium tetracarbonylcobaltate and with dicobalt octacarbonyl, respectively. Tetrafluoroethylenebis(tetracarbonylcobalt) was prepared through the reaction of tetrafluoroethylene with dicobalt octacarbonyl.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1966 Springer Science+Business Media New York
About this chapter
Cite this chapter
Dub, M. (1966). Cobalt Compounds. In: Dub, M. (eds) Compounds of Transition Metals. Organometallic Compounds, vol 1. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-52101-0_17
Download citation
DOI: https://doi.org/10.1007/978-3-642-52101-0_17
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-52103-4
Online ISBN: 978-3-642-52101-0
eBook Packages: Springer Book Archive