Abstract
In addition to the thermochromic phenomena observed in solution, numerous changes are also known to occur in the solid state among the transition metal complexes [1, 2]. In this Chapter, we shall first consider some representative examples of irreversible thermochromism. Common reactions of colored complexes will not be treated, since they are, quite naturally, irreversibly thermochromic. Thus, we shall focus our attention on certain reactions of special structural interest, e.g., dehydration reactions, isomerizations and so on, in order to find out some general features of the phenomena. Examples of reversible thermochromism, which are of more specific interest, will then be reviewed.
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Sone, K., Fukuda, Y. (1987). Thermochromism of Transition Metal Complexes in the Solid State. In: Inorganic Thermochromism. Inorganic Chemistry Concepts, vol 10. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-51017-5_6
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DOI: https://doi.org/10.1007/978-3-642-51017-5_6
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