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Thermochromism of Transition Metal Complexes in the Solid State

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Inorganic Thermochromism

Part of the book series: Inorganic Chemistry Concepts ((INORGANIC,volume 10))

Abstract

In addition to the thermochromic phenomena observed in solution, numerous changes are also known to occur in the solid state among the transition metal complexes [1, 2]. In this Chapter, we shall first consider some representative examples of irreversible thermochromism. Common reactions of colored complexes will not be treated, since they are, quite naturally, irreversibly thermochromic. Thus, we shall focus our attention on certain reactions of special structural interest, e.g., dehydration reactions, isomerizations and so on, in order to find out some general features of the phenomena. Examples of reversible thermochromism, which are of more specific interest, will then be reviewed.

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Sone, K., Fukuda, Y. (1987). Thermochromism of Transition Metal Complexes in the Solid State. In: Inorganic Thermochromism. Inorganic Chemistry Concepts, vol 10. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-51017-5_6

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  • DOI: https://doi.org/10.1007/978-3-642-51017-5_6

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-51019-9

  • Online ISBN: 978-3-642-51017-5

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