Abstract
Ion cyclotron resonance (ICR) spectroscopy with a pulsed laser volatilization/ ionization source of atomic metal cations has recently been applied to studies of the reactions of gas-phase metal ions with neutral molecules 11,2]. Initial results from this laboratory have included a variety of mechanistic studies [1–4] as well as measurements of gas-phase ligand binding energies for a number of different metal cations [5–9]. These mechanistic and thermodynamic studies yield data which is useful in developing models for understanding molecular interactions.
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References
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The standard enthalpy change for this reaction was calculated from heats of formation given in ref. 20.
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Kappes, M.M., Staley, R.H. (1982). Gas-Phase Atomic Metal Cations. Ligand Binding Energies, Oxidation Chemistry and Catalysis. In: Ion Cyclotron Resonance Spectrometry II. Lecture Notes in Chemistry, vol 31. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-50207-1_5
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DOI: https://doi.org/10.1007/978-3-642-50207-1_5
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