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A Fourier Transform Ion Cyclotron Resonance Study of Negative Ion-Molecule Reactions of Phenyl Acetate, Phenyl Trifluoroacetate and Acetanilide

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Ion Cyclotron Resonance Spectrometry II

Part of the book series: Lecture Notes in Chemistry ((LNC,volume 31))

Abstract

Recently we have shown by 18O-labelling [1] that in the gas-phase reaction of OH - with methyl phenyl ether (C6H5OCH3) 15% of the phenoxide anions (C6H5O-) are formed via an ipso substitution reaction (1a), whereas the remaining 85% are formed via an SN2 displacement [2] reaction 1b.

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References

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Authors and Affiliations

  1. Laboratory of Organic Chemistry, University of Amsterdam, Nieuwe Achtergracht 129, 1018 Amsterdam, The Netherlands

    J. C. Kleingeld & N. M. M. Nibbering

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  1. J. C. Kleingeld
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  2. N. M. M. Nibbering
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© 1982 Springer-Verlag Berlin Heidelberg

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Kleingeld, J.C., Nibbering, N.M.M. (1982). A Fourier Transform Ion Cyclotron Resonance Study of Negative Ion-Molecule Reactions of Phenyl Acetate, Phenyl Trifluoroacetate and Acetanilide. In: Ion Cyclotron Resonance Spectrometry II. Lecture Notes in Chemistry, vol 31. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-50207-1_11

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  • DOI: https://doi.org/10.1007/978-3-642-50207-1_11

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-11957-9

  • Online ISBN: 978-3-642-50207-1

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