Skip to main content
SpringerLink
Log in

A XANES Study of Co(II) in Cobalt Model Compounds and in Some Cobalt-Substituted Enzyme

  • Conference paper
EXAFS and Near Edge Structure

Part of the book series: Springer Series in Chemical Physics ((CHEMICAL,volume 27))

Abstract

In this work the K edge of two tetrahedral, three distorted trigonal bipyramidal and one octahedral Co(II) complex and of the cobalt derivatives of superoxide dismutase, carbonic anhydrase, stellacyanin and alcohol dehydrogenase are investigated and the properties of their X-ray absorption spectra are compared. The X-ray absorption data were taken at the synchrotron Radiation Facility PULS of the Frascati National Laboratories. The Co(II) proteins were prepared as described in [1], Tetrahedral Co(imidazole)2 (acetate)2 and Co(aptsz)2I2 were prepared according to [2,3]; trigonal bipyramidal Co(atsz)2Cl2H2O, Co(atsz)2I2·2H2O and Co(S2PPh2)2C9H7N according to [3]; octahedral Co(bipyridyl)3 perchlorate according to [4].

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 84.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. A. Desideri, F. Comin, L. Morpurgo D. Cocco, L. Calabrese, B. Mondovì, W. Maret, G. Rotilio: Biochim. Biophys. Acta 661, 312 (1981)

    Google Scholar 

  2. A. Dobry-Duclaux, A. May: Bull. Soc. Chim. Biol. 52, 1467 (1970)

    Google Scholar 

  3. C. Bellitto, A.A.G. Tomlinson, C. Furlani, G. De Munno: Inorg. Chim. Acta 28, 269 (1978)

    Article  Google Scholar 

  4. F.H. Burstall, R.S. Nyholm: J. Chem. Soc. 3571 (1952)

    Google Scholar 

  5. R.G. Shulman, Y. Yafet, P. Eisenberger, W.E. Blumberg: Proc. Natl. Acad. Sci. 73, 1384 (1976)

    Article  ADS  Google Scholar 

  6. G. Rotilio: In Metalloproteins, ed. by U. Weser (Thieme, New York 1979) pp. 1–28

    Google Scholar 

  7. H. Eklund, C.I. Branden: J. Biol. Chem. 254, 3458 (1979)

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Dipartimento di Fisica, Università della Calabria, I-87036, Arcavata di Rende, Italy

    A. Desideri

  2. Istituto di Chimica Biologica, Università di Roma, I-00185, Roma, Italy

    G. Rotilio

Authors
  1. A. Desideri
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. G. Rotilio
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. Dipartimento di Fisica, Università di Roma, La Sapienza, P. Aldo Moro 2, I-00185, Roma, Italy

    Antonio Bianconi

  2. Laboratori Nazionali di Frascati, PULS-CNR, P.O. Box 13, I-00044, Frascati, Italy

    Lucia Incoccia

  3. Laboratori Nazionali di Frascati, INFN, P.O. Box 13, I-00044, Frascati, Italy

    Stanislao Stipcich

Rights and permissions

Reprints and permissions

Copyright information

© 1983 Springer-Verlag Berlin Heidelberg

About this paper

Cite this paper

Desideri, A., Rotilio, G. (1983). A XANES Study of Co(II) in Cobalt Model Compounds and in Some Cobalt-Substituted Enzyme. In: Bianconi, A., Incoccia, L., Stipcich, S. (eds) EXAFS and Near Edge Structure. Springer Series in Chemical Physics, vol 27. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-50098-5_77

Download citation

  • DOI: https://doi.org/10.1007/978-3-642-50098-5_77

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-50100-5

  • Online ISBN: 978-3-642-50098-5

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation