Abstract
The zirconium phosphates are the most intensively studied members of a vast class of layer-structured inorganic ion-exchangers with potential end-uses ranging from catalysis to ion transport [I]. Our interest lies in monitoring changes in site availability to transition metal ions after exchange, dehydration, and other treatments, with reference to catalytic applications. An extensive series of materials with first-row transition metal ions is under investigation. For high-loaded (20–100%) materials containing Co(2+) or Ni(2+), there is electronic spectral evidence for coordination number changes as the materials are dehydrated (c.n. 6→4) and the layers subsequently destroyed (c.n. 4→5) [2].
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
Similar content being viewed by others
References
A. Clearfield, “Industrial Uses of Zirconium Phosphate”, Magnesium Elektron Ltd. (U.K.), 1978
L. Alagna, C. Ferragina, A. La Ginestra, and A.A.G. Tomlinson, J.Chem.Soc.Dalton Trans., 1981, 2376
L. Alagna, T. Prosperi, A.A.G. Tomlinson, C. Ferragina, and A. La Ginestra, J.Chem. Soc.Faraday Trans. I, 1982, in press
L. Alagna and A.A.G. Tomlinson, J.Chem.Soc.Faraday Trans. I, 1982, in press
J. Gazo, I.B. Bersuker et al., Coordination Chem.Rev., 1976, 19, 253
K. Klier, J. Hutta, and R. Kellerman, ACS Symposium Ser., 1977, 40, 108
A. Clearfield and G.D. Smith, Inorg.Chem., 1969, 8, 431.
L. Alagna, T. Prosperi, and A.A.G. Tomlinson, unpublished work
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1983 Springer-Verlag Berlin Heidelberg
About this paper
Cite this paper
Alagna, L., Prosperi, T., Tomlinson, A.G. (1983). EXAFS Studies of Metal-Ion Exchanged Layer Structures. In: Bianconi, A., Incoccia, L., Stipcich, S. (eds) EXAFS and Near Edge Structure. Springer Series in Chemical Physics, vol 27. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-50098-5_67
Download citation
DOI: https://doi.org/10.1007/978-3-642-50098-5_67
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-50100-5
Online ISBN: 978-3-642-50098-5
eBook Packages: Springer Book Archive