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Solution NMR of Synthetic Polymers

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Special Applications

Part of the book series: NMR Basic Principles and Progress ((NMR,volume 29))

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Abstract

Nuclear Magnetic Resonance (NMR) Spectroscopy is well recognised as the primary technique for the determination of molecular structure of synthetic polymers. In this article the author aims to illustrate how solution-state NMR is used for molecular structural determinations on a wide range of commercially available polymers.

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References

  1. Fisch MH, Dannenberg JJ (1977) Analytical Chemistry 49: 1405

    CAS  Google Scholar 

  2. Paxson JR, Randall JC (1978) Anal. Chem. 50: 1777

    CAS  Google Scholar 

  3. Wehrli FW, Merchand AP, Wehrli S (1988) Interpretation of carbon-13 spectra, Wiley, New York

    Google Scholar 

  4. Derome AE (1987) Modern NMR techniques for chemistry research, Pergamon Press

    Google Scholar 

  5. Abraham RJ, Fisher J, Loftus P (1988) Introduction to nuclear magnetic resonance spectroscopy, Wiley, New York

    Google Scholar 

  6. Randall JC (1977) Polymer sequence determinations-carbon-13 NMR method, Academic Press, New York

    Google Scholar 

  7. Bovey FA (1972) High resolution NMR of macromolecules, Academic Press, New York

    Google Scholar 

  8. Bovey FA (1986) Polymer Engineering & Science, 26: 1419

    CAS  Google Scholar 

  9. Ebdon JR (1984) Macromolecular Chemistry 3: 175

    CAS  Google Scholar 

  10. Simmons WW, Zanger M (1973) The Sadtler guide to the NMR spectra of polymers, Sadtler Research Lab Inc, Philadelphia

    Google Scholar 

  11. Pham QT, Petiaud R, Waton H (1982) Proton & carbon NMR spectra of polymers, Wiley, New York, vol 1

    Google Scholar 

  12. Pham QT, Petiaud R, Waton H (1983) Proton & carbon NMR spectra of polymers, Wiley, New York, vol 2

    Google Scholar 

  13. Pham QT, Petiaud R, Llauro MF, Waton H (1985) Proton & carbon NMR spectra of polymers, Wiley, New York, vol 3

    Google Scholar 

  14. Field LD, Sternhall S (1989) Analytical NMR, Wiley

    Google Scholar 

  15. Müllen K, Pregosin PS (1976) Fourier transform NMR techniques: a practical approach, Academic Press, New York, London

    Google Scholar 

  16. Shaw D (1987) Fourier transform NMR spectroscopy, 2nd ed, Elsevier Science, New York

    Google Scholar 

  17. Schafer J, Natusch DFS (1972) Macromolecules 5: 416

    Google Scholar 

  18. Axelson DE, Levy GC, Mandelkern L (1979) Macromolecules 12: 41

    CAS  Google Scholar 

  19. Levy G et al. Lab One NMR 1 program, NMR Inc, 719 East Genessee St, Syracuse, New York 13210

    Google Scholar 

  20. Nardin R, Vincendon M (1986) Macromolecules 19: 2452

    CAS  Google Scholar 

  21. Bruch MD, Bonested JK (1986) Macromolecules 19: 1622

    CAS  Google Scholar 

  22. Bruch MD, Payne WG (1986) Macromolecules 19: 2712

    CAS  Google Scholar 

  23. Crowther MW, Szenverenyi NM, Levy GC (1986) Macromolecules 19: 1333

    CAS  Google Scholar 

  24. Moad G, Rizzardo E, Solomon DH, Johns SR, Willing RI (1986) Macromolecules 19: 2494

    CAS  Google Scholar 

  25. Patt SL, Shoolery JN (1982) J. Mag. Reson., 46: 535

    Google Scholar 

  26. Doddrell DM, Pegg DT, Bendali MR (1982) Chem. Phys. 77: 2745

    Google Scholar 

  27. Heatley F, Luo Y-Z, Ding JF, Mobb RH, Booth C (1988) Macromolecules 21: 2713

    CAS  Google Scholar 

  28. Fox JJ, Martin AE (1940) Proc. Roy. Soc., A175: 208

    Google Scholar 

  29. Cross LH, Richards RB, Willis HA (1950) Discussions Faraday Soc, 9: 235

    Google Scholar 

  30. Willbourn AH (1959) J. Poly Sci., 34: 569

    CAS  Google Scholar 

  31. Cudby MEA, Bunn A (1976) Polymer 17: 345

    CAS  Google Scholar 

  32. Harma T, Suzuki T, Kasaka K (1975) Kobunishi Ronbunshi 32(2): 91

    Google Scholar 

  33. Bovey FA, Schilling FC, McCracken FL, Wagner HL (1976) Macromolecules 9: 363

    Google Scholar 

  34. Nishioka A, Mukai Y, Ouchi M, Imani M (1980) Bunseki Kagaku 29(11): 774

    CAS  Google Scholar 

  35. Randall JC (1978) J. Appl. Polym. Sci., 22: 585

    CAS  Google Scholar 

  36. Usani T, Gotoh Y, Takayama S (1986) Macromolecules 19: 2722

    Google Scholar 

  37. Hay JN, Mills PJ, Ognfanovic R (1986) Polymer 27: 677

    CAS  Google Scholar 

  38. Grant DM, Paul EG (1964) J. Amer. Chem. Soc., 86: 2984

    CAS  Google Scholar 

  39. Lindeman LP, Adams JQ (1971) Anal. Chem., 43: 1245

    CAS  Google Scholar 

  40. Randall JC (1973) J. Polym. Sci. Polym. Phys., Ed. 11: 275

    CAS  Google Scholar 

  41. Heatley F, Salovey R, Bovey FA (1969) Macromolecules 2: 619

    CAS  Google Scholar 

  42. Mitani K, Suzuki T, Matsuo A, Takegami Y (1974) J. Poly. Sci. Polym. Chem. Ed 12: 771

    CAS  Google Scholar 

  43. Stehling FC, Knox JR (1975) Macromolecules 8: 595

    CAS  Google Scholar 

  44. Ferguson RC (1971) Macromolecules 4: 324

    CAS  Google Scholar 

  45. Kakugo M, Miyatake T, Naito Y, Mizunuma K (1988) Macromolecules 21: 314

    CAS  Google Scholar 

  46. Hayashi T, Inoue Y, Chujo R, Asakura T (1988) Polymer 29: 138

    CAS  Google Scholar 

  47. Cheng HN, Lee GH (1987) Macromolecules 20: 436

    CAS  Google Scholar 

  48. Inoue Y, Itabashi Y, Chujo R (1984) Polymer 25: 1640

    CAS  Google Scholar 

  49. Cheng HN (1985) Polym. Bull. (Berlin) 14: 347

    CAS  Google Scholar 

  50. Asahura T, Nichiyama Y, Doi Y (1987) Macromolecules 20: 616

    Google Scholar 

  51. Hashimoto M, Miyaka T, Masuda Y, Ya Mayata F (1987) Nippon Gornu Kyokaishi, 60: 38

    CAS  Google Scholar 

  52. Bunn A, Cudby MEA (1976) Polymer 17: 548

    CAS  Google Scholar 

  53. Randall JC (1978) Macromolecules 11: 592

    CAS  Google Scholar 

  54. Bunn A, Cudby MEA, Randall JC (1980) Polymer 21: 117

    CAS  Google Scholar 

  55. Ray GJ, Johnson PE, Knox JR (1977) Macromolecules 773: 10

    Google Scholar 

  56. Carmen CJ, Wilkes CE (1971) Rubber Chem. Techno 44: 781

    Google Scholar 

  57. Randall JC (1978) Macromolecules 11: 33

    CAS  Google Scholar 

  58. Okada T, Hashimoto, Ikushige T (1980) Nippon Kagaku Kaishi 1: 74

    Google Scholar 

  59. Wu TK, Ovenall DW, Reddy GS (1974) J. Polym. Sci. Polym. Phys. Ed. 12: 901

    CAS  Google Scholar 

  60. Ketels H, Beulen J, Van der Velden G (1988) Macromolecules 21: 2032

    CAS  Google Scholar 

  61. Zambelli A, Gatti G (1978) Macromolecules 11: 485

    CAS  Google Scholar 

  62. Harwood HJ (1968) J. Polym. Sci. Part C, 25: 37

    Google Scholar 

  63. Allen PEM, Fisher MC (1985) Eur. Poly. J., 21: 201

    CAS  Google Scholar 

  64. Ferguson RC, Ovenall DW (1985) Polym. Prep. (Amer. Chem. Soc. Dev. Polym. Chem.), 26: 182

    CAS  Google Scholar 

  65. Bandermann F, Speikamp HD (1985) Makromol, Chem. Rapid Commun., 6: 335

    CAS  Google Scholar 

  66. Kricheldorf HR, Schwartz M (1983) Makromol Chemie 184: 475

    CAS  Google Scholar 

  67. Hvilsted S, Jorgensen NU (1983) Polymer Bulletin 10: 236

    CAS  Google Scholar 

  68. Kricheldorf HR (1978) Makromol Chemie 179: 2133

    CAS  Google Scholar 

  69. Newmark RA (1980) J. Poly. Sci. Poly. Chem. Ed. 18: 559

    CAS  Google Scholar 

  70. Russell GA, Henrichs PM, Hewitt JM, Grashol HR, Sandu MA (1981) Macromolecules 14: 1764

    CAS  Google Scholar 

  71. Kricheldorf HR, Droscher M, Hull WE (1981) Polymer Bulletin 4: 547

    CAS  Google Scholar 

  72. Kricheldorf HR, Hull WE (1978) Poly. Sci. Polym. Chem. Ed. 16: 2253

    CAS  Google Scholar 

  73. Kricheldorf HR, Hull WE (1977) J. Macromol. Sci. Chem. Al 1(12): 2281

    Google Scholar 

  74. Kricheldorf HR, Muhilhaupt R (1977) Angew Makromol Chem., 65: 169

    CAS  Google Scholar 

  75. Tran N-M, Djodeyre E, Carriere FJ, Sekiguchi E (1980) Makromol Chem. Rapid Commun., 1: 507

    CAS  Google Scholar 

  76. Kricheldorf HR, Schilling G (1976) Makromol Chemie 177: 607

    CAS  Google Scholar 

  77. Schilling G, Kricheldorf HR (1975) Makromol Chemie 176: 3341

    CAS  Google Scholar 

  78. Kricheldorf HR, Schilling G (1978) Makromol Chemie 179: 2267

    Google Scholar 

  79. Kricheldorf HR (1978) Proceedings of Eur. Conf. on NMR of Macromolecules

    Google Scholar 

  80. Kricheldorf HR, Leppert E, Schilling G (1975) Makromol Chemie 176: 1629

    CAS  Google Scholar 

  81. Kricheldorf HR, Kaschig J (1978) J. Eur. Polym. J., 14: 923

    CAS  Google Scholar 

  82. Kricheldorf HR, Mülhaust R (1980) J. Macromol Sci. Chem., A14(7): 977

    CAS  Google Scholar 

  83. Cudby MEA, Feasey RG, Jennings BE, Jones MEB, Rose JB (1965) Polymer 6: 589

    CAS  Google Scholar 

  84. Ger. Offen. (1978) 2803873, 1978 Chem. Abst. 1978, 89, 147398g

    Google Scholar 

  85. Attwood TE, Dawson PC, Freeman JL, Hoy LRJ, Rose JB, Staniland PA (1981) Polymer 22: 1096

    CAS  Google Scholar 

  86. Lyle GD, Senger JS, Chen DH, Kilic S, Wu SD, Moherty DK, McGrath JE (1989) Polymer 30: 978

    CAS  Google Scholar 

  87. Bunn A (1988) Brit. Polym. J., 20: 307

    CAS  Google Scholar 

  88. Abraham RJ, Haworth IS, Bunn A, Hearmon RA (1988) Polymer 27: 1110

    Google Scholar 

  89. Abraham RJ, Bunn A, Haworth IS, Hearmon RA (1989) Polymer 30: 1969

    CAS  Google Scholar 

  90. Abraham RJ, Bunn A, Haworth IS, Hearmon RA (1990) Polymer 31: 728

    CAS  Google Scholar 

  91. Attwood TE, Newton AB, Rose JB (1972) Br. Polym. J. 4: 391

    CAS  Google Scholar 

  92. Heatley F (personal communication)

    Google Scholar 

  93. Starnes WH, Schilling FC, Abbas KB, Cais RE, Bovey FA (1979) Macromolecules 12: 556

    CAS  Google Scholar 

  94. Starnes WH, Schilling FC, Abbas KB, Cais RE, Bovey FA (1979) Polym. Prepr., Am. Chem. Soc, Div. Polym. Chem. 20: 653

    Google Scholar 

  95. Starnes WH, Schilling FC, Plitz IM, Cais RE, Freed DJ, Bovey FA (1980) Preprints, 3rd International Symp. on PVC, Cleveland

    Google Scholar 

  96. Starnes WH (1981) Development in polymer degradation, 3, S. 135

    Google Scholar 

  97. Starnes WH, Schilling FC, Plitz IM, Cais RE, Bovey FA (1981) Polym. Bull. 4: 555

    CAS  Google Scholar 

  98. Starnes WH (1985) Pure & Appl. Chem., 57: 1001

    CAS  Google Scholar 

  99. Bovey FA (1962) J. Poly. Sci. 62: 197

    CAS  Google Scholar 

  100. Ishigura K, Watanabe S, Tabata Y, Oshima K (1980) Macromolecules 13: 1630

    Google Scholar 

  101. Katritzky AR, Smith A, Weiss DE (1974) J. Chem. Soc. Perkin Trans., 2: 1547

    Google Scholar 

  102. Harwood HJ, Ritchey WN (1965) J. Poly. Sci. B., 3: 419

    CAS  Google Scholar 

  103. Kale LT, O’Driscoll KF, Dinan FJ, Uebel JJ (1986) J. Poly. Sci. Polym. Chem. Ed. 24: 3145

    CAS  Google Scholar 

  104. Brar AS, Kapur GS (1988) Polymer Journal 20: 371

    CAS  Google Scholar 

  105. Hirai H, Koinuma H, Tanabe T, Tacheuchi K (1979) J. Poly. Sci. Poly. Chem. Ed. 17: 1339

    CAS  Google Scholar 

  106. Koinuma H, Tanabe T, Hirai H (1981) Macromolecules 14: 883

    CAS  Google Scholar 

  107. Llauro MF, Pichot C, Ramitez W, Guillot J (1986) Poly. Mater. Sci. Eng. 54: 61

    Google Scholar 

  108. Llauro-Darricardes MF, Pichot C, Guillo J, Rios GL, Gruz EMA, Guzman CC (1986) Polymer 27: 889

    Google Scholar 

  109. Wilson CW, Santee ER (1965) J. Poly. Sci. Pt. C, 8: 97

    Google Scholar 

  110. Pianca M, Bonardelli P, Tato M, Cirillo G, Moggi G (1987) Polymer 28: 224

    CAS  Google Scholar 

  111. Weigert FJ (1971) Org. Magn. Resonance 3(3): 373

    CAS  Google Scholar 

  112. Ishigure K, Ohashi H, Tabata Y, Oshima K (1977) Macromolecules 10: 567

    CAS  Google Scholar 

  113. Braeme EG (1974) Nucl. Magn. Resn. Spectrosc. Nucl. other than protons, Wiley, New York

    Google Scholar 

  114. Ishigure K (1976) Buneski Kiki 14: 610

    CAS  Google Scholar 

  115. Devaux J, Daoust D, Legras R, Dereppe JM, Nield E (1989) Polymer 30: 161

    CAS  Google Scholar 

  116. Williams DAR, Dyke R, Malcomsen S, Massey S (1983) J. Cell. Plast., 19: 121

    CAS  Google Scholar 

  117. Noshiro M, Jitsuigiri Y, Shigeyuki K, Tadishi S, In: Ashida K, Frisch KC (eds) International progress in urethanes, vol 5 (in press)

    Google Scholar 

  118. Sauer W, Kimmer W (1980) Plaste kautsch 27: 188

    CAS  Google Scholar 

  119. Pillon LZ, Utracki LA (1984) Polymer Eng. & Science 24: 1300

    CAS  Google Scholar 

  120. Devaux J, Godard P, Mercier JP (1982) J. Poly. Sci., Polymer Phys. Ed. 20: 1875

    CAS  Google Scholar 

  121. Devaux J, Godard P, Mercier JP, Toillaux R, Dereppe JM (1982) J. Poly. Sci. Polymer Phys. Ed. 20: 1881

    CAS  Google Scholar 

  122. Devaux J, Godard P, Mercier JP (1982) J. Poly. Sci. Polymer Phys. Ed. 20: 1895

    CAS  Google Scholar 

  123. Godard P, Dekoninck JM, Devlesaver V, Devaux J (1986) J. Sci. Part A, Polymer Chemistry 24: 3301

    CAS  Google Scholar 

  124. Godard P, Dekoninck JM, Develsaver V, Devaux J (1986) J. Poly. Sci. Part A, Polymer Chemistry 24: 3315

    CAS  Google Scholar 

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© 1993 Springer-Verlag Berlin Heidelberg

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Bunn, A. (1993). Solution NMR of Synthetic Polymers. In: Pfeifer, H., Barker, P. (eds) Special Applications. NMR Basic Principles and Progress, vol 29. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-50046-6_3

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  • DOI: https://doi.org/10.1007/978-3-642-50046-6_3

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