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Transport, Relaxation, and Kinetic Processes in Electrolyte Solutions pp 110–134Cite as

The Role of Ion Aggregation and Micelle Formation Kinetics in Diffusional Transport of Binary Solutions

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Part of the book series: Lecture Notes in Chemistry ((LNC,volume 57))

Abstract

This chapter is concerned with binary electrolyte solutions in which diffusion processes and rates of chemical reactions are coupled. The solutes may exist as free ions and ion pairs or higher aggregates with and without inclusion of solvent molecules. The crucial point of the discussion is the influence of the rate constants of chemical reactions on the observable diffusion coefficients, in contrast to the common point of view which treats the influence of diffusion processes on kinetics, e.g., in the kinetics of diffusion limited reactions.

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References

  1. P. Turq, L. Orcil, M. Chemla and J. Barthel, Ber. Bunsenges. Phys. Chem. 85 (1981) 535.

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Authors and Affiliations

  1. Laboratoire d’Electrochimie, Universitè Pierre et Marie Curie, 4 Place Jussieu, 75230, Paris, France

    Pierre Turq & Marius Chemla

  2. Institute of Physical and Theoretical Chemistry, University of Regensburg, Univeritätsstraße 31, 8400, Regensburg, Germany

    Josef M. G. Barthel

Authors
  1. Pierre Turq
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  2. Josef M. G. Barthel
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  3. Marius Chemla
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© 1992 Springer-Verlag Berlin Heidelberg

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Turq, P., Barthel, J.M.G., Chemla, M. (1992). The Role of Ion Aggregation and Micelle Formation Kinetics in Diffusional Transport of Binary Solutions. In: Transport, Relaxation, and Kinetic Processes in Electrolyte Solutions. Lecture Notes in Chemistry, vol 57. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-48755-2_5

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  • DOI: https://doi.org/10.1007/978-3-642-48755-2_5

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-55002-0

  • Online ISBN: 978-3-642-48755-2

  • eBook Packages: Springer Book Archive

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