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Part of the book series: Inorganic Chemistry Concepts ((INORGANIC,volume 13))

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Abstract

We now tie these A nm to a model of a luminescence center. The model of Fig. 1 need not have equal force constants. Figure 15 is drawn accurately for θ = 42°, α uv = 5.886. This set of parameters, seemingly over-particularized, is related to an equal-force-constants case with simple parameters and has roughly the largest deviation from equal force constants that we have found necessary to consider. The case involving this set of parameters will be taken up again in Sect. 9.1, where the two curves of Fig. 15 are seen again as the dotted curves of Fig. 21. In Sect. 9.1, related equal- and unequal-force constants cases are compared.

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© 1991 Springer-Verlag Berlin Heidelberg

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Struck, C.W., Fonger, W.H. (1991). The Luminescence Center: The Single-Configurational-Coordinate Model. In: Understanding Luminescence Spectra and Efficiency Using W p and Related Functions. Inorganic Chemistry Concepts, vol 13. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-48629-6_4

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  • DOI: https://doi.org/10.1007/978-3-642-48629-6_4

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-48631-9

  • Online ISBN: 978-3-642-48629-6

  • eBook Packages: Springer Book Archive

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