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Determination of Atomic Masses by Microwave Methods

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Part of the book series: Encyclopedia of Physics / Handbuch der Physik ((PHYSIK 8,volume 8 / 38 / 1))

Abstract

The development of microwave techniques in the last decade has resulted in another tool for the accurate determination of atomic masses. The characteristic rotational frequencies of molecules lie in the microwave region (electromagnetic spectrum from about 1 to 300 mm in wavelength) and comprise the bulk of the microwave spectra of gases. By measuring the frequency shift which occurs in the pure rotational absorption spectrum of a molecule when another isotope is substituted for one of the atoms, accurate information about the relative masses of the isotopes can be obtained.

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Bibliography

Microwave spectroscopy

  1. Townes , C. H., and A. Schawlow: Microwave Spectroscopy. New York: McGraw Hill 1955 — This excellent book is the most complete and detailed treatment to be found of both the theoretical and experimental aspects of the microwave spectroscopy of gases. Parts of chapters 1, 2, 3 and 8 contain accounts and information dealing with microwave mass determinations.

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Molecular spectra

  1. Herzberg, G.: Spectra of Diatomic Molecules. New York: Van Nostrand Co. Inc. 1950.

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  2. Herzberg, G.: Infrared and Raman Spectra. New York: Van Nostrand Co. Inc. 1945. — Polyatomic molecules.

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Nuclear mass compilations

  1. “Mass Differences — A compilation of experimental atomic mass differences from/5-decay, reaction energies, microwave data, alpha decay and mass doublets”. Rev. Mod. Phys. 26, 327 (1954).

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  2. Wapstra, A. H.: Isotopic Masses, Physica, Haag 21, 367 (1955). — Part I contains a computation of isotopic masses for A < 34 obtained from nuclear reaction data. Part II contains a computation of masses for A = 33 to A =202 using data from all the techniques of mass determination. (See also Wapstra’s preceding article in this volume.)

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S. Flügge

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© 1958 Springer-Verlag OHG. Berlin · Göttingen · Heidelberg

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Geschwind, S. (1958). Determination of Atomic Masses by Microwave Methods. In: Flügge, S. (eds) External Properties of Atomic Nuclei / Äussere Eigenschaften der Atomkerne. Encyclopedia of Physics / Handbuch der Physik, vol 8 / 38 / 1. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-45901-6_2

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  • DOI: https://doi.org/10.1007/978-3-642-45901-6_2

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-45902-3

  • Online ISBN: 978-3-642-45901-6

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