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Poly(vinyl Alcohol)-Cellulose and Nanocellulose Composites

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Handbook of Polymer Nanocomposites. Processing, Performance and Application

Abstract

The development of micro/nanofibers has attracted significant interest in the last few decades due to the unique properties they endow. Cellulose nanocrystals (CNs) are a promising material and have been widely studied over the past two decades. This material is interesting as nanofiller due to its nanoscale dimensions, high specific area, and highly rigid crystalline structure. Poly(vinyl alcohol), PVA, is water soluble, semicrystalline, fully biodegradable, nontoxic, and biocompatible, and therefore, it finds use in a broad applications. PVA-based fibers have been considered as an attractive choice in tissue scaffolding, filtration materials, membranes, optics, protective clothing, enzyme immobilization, drug release, and so on. Preparation and morphological features of PVA–nanocelluloses are discussed in this chapter. Their incorporation in nanocomposite materials including processing methods and properties such as thermal gravimetric analysis (TGA), differential scanning calorimetry (DSC), mechanical performances, dynamic mechanical analysis (DMA), and membrane properties are also presented.

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References

  1. Abe K, Iwamoto S, Yano H (2007) Biomacromolecules 8:3276

    Google Scholar 

  2. Adanur S, Ascioglu B (2007) J Ind Text 36:311

    Google Scholar 

  3. Ahola S, Österberg M, Laine J (2008) Cellulose 15:303

    Google Scholar 

  4. Ahola S, Salmi J, Johansson LS, Laine J, Österberg M (2008) Biomacromolecules 9:1273

    Google Scholar 

  5. Andresen M, Johansson LS, Tanem BS, Stenius P (2006) Cellulose 13:665

    Google Scholar 

  6. Andresen M, Stenius P (2007) J Disper Sci Technol 28:837

    Google Scholar 

  7. Andresen M, Stenstad P, Moretro T, Langsrud S, Syverud K, Johansson LS, Stenius P (2007) Biomacromolecules 8:2149

    Google Scholar 

  8. Araki J, Wada M, Kuga S, Okano T (1998) Colloids Surf A 142:75

    Google Scholar 

  9. Araki J, Wada M, Kuga S (2001) Langmuir 17:21

    Google Scholar 

  10. Aulin C, Varga I, Claesson PM, Wågberg L, Lindström T (2008) Langmuir 24:2509

    Google Scholar 

  11. Bai J, Li Y, Yang S, Du J, Wang S, Zheng J, Wang Y, Yang Q, Chen X, Jing X (2007) Solid State Commun 141:292

    ADS  Google Scholar 

  12. Bhatnagar A, Sain M (2005) J Reinf Plast Compos 24:1259

    Google Scholar 

  13. Bohlmann GM (2005) Handbook of biodegradable polymers: General characteristics, processability, industrial applications and market evolution of biodegradable polymers, Bastioli, C. (ed.). Shawbury, Shrewsbury, Shropshire, UK, Rapra Technology Limited

    Google Scholar 

  14. Bordel D, Outaux JL, Heux L (2006) Langmuir 22:4899

    Google Scholar 

  15. Borsali R, De Souza Lima MM (2004) Macromol Rapid Commun 25:771

    Google Scholar 

  16. Borsali R, Ebeling T, Paillet M, Diat O, Dufresne A, Cavaillé JY, Chanzy H (1999) Langmuir 15:6123

    Google Scholar 

  17. Bruce DM, Hobson RN, Farrent JW, Hepworth DG (2005) Compos Part A Appl Sci Manufact 36:1486

    Google Scholar 

  18. Buchanan BB, Gruissem W, Jones RL (2000) Biochemistry & molecular biology of plants, 1st edn. American society of plant physiology, Cellulose - Wikipedia, the free encyclopedia (en.wikipedia.org/wiki/Cellulose)

    Google Scholar 

  19. Cavaillé JY, Chazeau L, Canova G, Dendievel R, Boutherin B (1999) J Appl Polym Sci 71:1797

    Google Scholar 

  20. Cavaillé JY, Chazeau L, Paillet M (1999) J Polym Sci Part B Polym Phys 37:2151

    ADS  Google Scholar 

  21. Cavaillé JY, Chazeau L, Perez J (2000) J Polym Sci Part B Polym Phys 38:383

    ADS  Google Scholar 

  22. Cavaillé JY, Favier V, Chanzy H (1995) Macromolecules 28:6365

    ADS  Google Scholar 

  23. Cavaillé JY, Ruiz MM, Dufresne A, Gerard JF, Graillat C (2000) Compos Interface 7:117

    Google Scholar 

  24. Chang JH, Jang TG, Ihn KJ, Sur GS (2003) J Appl Polym Sci 90:3204

    Google Scholar 

  25. Chazeau L, Terech P, Cavaillé JY (1999) Macromolecules 32:1872

    ADS  Google Scholar 

  26. Cheng Q, Wang S, Rials TG (2009) Compos Part A 40:218

    Google Scholar 

  27. Cheng Q, Wang SQ, Rials TG, Lee SH (2007) Cellulose 14:593

    Google Scholar 

  28. Cho M-J, Park B-D (2011) J Ind Eng Chem 17:36

    Google Scholar 

  29. Chronakis IS, Frenot A (2003) Curr Opin Colloid Interface Sci 8:64

    Google Scholar 

  30. Çifci C, Kaya A (2010) Desalination 253:175

    Google Scholar 

  31. De Souza Lima MM, Wong JT, Paillet M, Borsali R, Pecora R (2003) Langmuir 19:24

    Google Scholar 

  32. Ding B, Kim H-Y, Lee S-C, Lee D-R, Choi K-J (2002) Fibers Polym 3:73

    Google Scholar 

  33. Ding B, Kim H-Y, Lee S-C, Shao C-L, Lee D-R, Park SJ, Kwag G-B, Choi K-J (2002) J Polym Sci Part B Polym Phys 40:1261

    ADS  Google Scholar 

  34. Ding B, Kimura E, Sato T, Fujita S, Shiratori S (2004) Polymer 45:1895

    Google Scholar 

  35. Gardner DJ, Oporto GS, Mills R, Samir MASA (2008) J Adhes Sci Technol 22:545

    Google Scholar 

  36. Dufresne A, Azizi Samir MAS, Alloin F, Sanchez JY, El Kissi N (2004) Macromolecules 37:1386

    ADS  Google Scholar 

  37. Dufresne A, Garcia de Rodriguez N, Thielemans W (2006) Cellulose 13:261

    Google Scholar 

  38. Dufresne A, Helbert W, Cavaillé JY (1996) Polym Compos 17:604

    Google Scholar 

  39. Dufresne A (2006) J Nanosci Nanotechnol 6:322

    Google Scholar 

  40. Eichhorn SJ, Baillie CA, Zafeiropoulos N, Mwaikambo LY, Ansell MP, Dufresne A, Entwistle KM, Herrera-Franco PJ, Escamilla GC, Groom L, Hugues M, Hill C, Rials TG, Wild PM (2001) J Mater Sci 36:2107

    ADS  Google Scholar 

  41. Erika Adomaviciute RM (2007) Fibres Text East Eur 15:69

    Google Scholar 

  42. Favier V, Canova GR, Cavaillé JY, Chanza H, Dufresne A, Gauthier C (2003) Polym Adv Technol 6:351

    Google Scholar 

  43. Favier V, Cavaillé JY, Canova GR, Chanzy H, Dufresne A, Gauthier C (1995) Polym Adv Technol 6:351

    Google Scholar 

  44. Finch CA (1973) Poly Vinyl alcohol; properties and applications. Wiley Interscience, New York

    Google Scholar 

  45. Fink H-P, Ganster J (2006) Cellulose 13:271

    Google Scholar 

  46. Frenot A, Chronakis IS (2003) Curr Opin Colloid Interface Sci 8:64

    Google Scholar 

  47. Gindl W, Keckes J (2005) Polymer 46:10221

    Google Scholar 

  48. Gray DG, Beck-Candanedo S, Roman M (2005) Biomacromolecules 6:1048

    Google Scholar 

  49. Gray DG, Chen W (2002) Langmuir 18:633

    Google Scholar 

  50. Gray DG, Cranston ED (2006) Sci Technol Adv Mater 7:319

    Google Scholar 

  51. Grunert M, Winter WT (2002) J Polym Environ 10:27

    Google Scholar 

  52. Guerrini LM, de Oliveira MP, Branciforti MC, Custodio TA, Bretas RES (2009) J Appl Polym Sci 112:1680

    Google Scholar 

  53. Hajji P, Favier V, Gauthier C, Vigier G (1996) Polym Compos 17:612

    Google Scholar 

  54. Hanley SJ, Revol J-F, Godbout L, Gray DG (1997) Cellulose 4:209

    Google Scholar 

  55. Hassan CM, Peppas NA (2000) Polym Nanocompos 153:37

    Google Scholar 

  56. Henriksson M, Berglund LA, Isaksson P, Lindström T, Nishino T (2008) Biomacromolecules 9:1579

    Google Scholar 

  57. Henriksson M, Berglund LA (2007) J Appl Polym Sci 106:2817

    Google Scholar 

  58. Henriksson M, Henriksson G, Berglund LA, Lindström T (2007) Eur Polym J 43:3434

    Google Scholar 

  59. Heux L, Bonini C, Cavaillé JY, Linder P, Dewhurst C, Terech P (2002) Langmuir 18:3311

    Google Scholar 

  60. Heux L, Chauve G, Bonini C (2000) Langmuir 16:8210

    Google Scholar 

  61. Heux L, Ljungberg N, Cavaillé JY (2006) Polymer 47:6285

    Google Scholar 

  62. Hon DNS (1994) Cellulose 1:1

    Google Scholar 

  63. Hong KH (2007) Polym Eng Sci 47:43

    Google Scholar 

  64. Huang CC, Lin CK, Lu CT, Lou CW, Chao CY, Lin JH (2009) Fibres Text East Eur 17:34

    Google Scholar 

  65. Huang Y, Wu X, Wang L, Yu H (2005) J Appl Polym Sci 97:1292

    Google Scholar 

  66. Hubbe MA, Rojas OJ, Lucia LA, Sain M (2008) BioResour 3:929

    Google Scholar 

  67. Hult EL, Larsson PT, Iversen T (2001) Polymer 42:3309

    Google Scholar 

  68. Iwamoto S, Nakagaito AN, Yano H (2007) Appl Phys A Mater Sci Process 89:461

    ADS  Google Scholar 

  69. Jeong JS, Moon JS, Jeon SY, Park JH, Alegaonkar PS, Yoo JB (2007) Thin Solid Films 515:5136

    ADS  Google Scholar 

  70. Jeun J-P, Jeon Y-K, Nho Y-C, Kang P-H (2009) J Ind Chem Eng 15:430

    Google Scholar 

  71. Ji HM, Lee HW, Karim MR, Cheong IW, Bae EA, Kim TH, Islam MS, Ji BC, Yeum JH (2009) Colloid Polym Sci 287:751

    Google Scholar 

  72. Jia Z, Li Q, Liu J, Yang Y, Wang L, Guan Z (2008) J Polym Eng 28:87

    Google Scholar 

  73. Joo YL, Kim C-W, Frey M, Marquez M (2005) J Polym Sci Part B Polym Phys 43:1673

    ADS  Google Scholar 

  74. Joon Seok Lee KHC, Ghim HD, Kim SS, Chun DH, Kim HY, Lyoo WS (2004) J Appl Polym Sci 93:1638

    Google Scholar 

  75. Jung YH, Kim HY, Lee DR, Park SY, Khil MS (2005) Macromol Res 13:385

    Google Scholar 

  76. Junkasem J, Rujiravanit R, Supaphol P (2006) Nanotechnology 17:4519

    ADS  Google Scholar 

  77. Kim C-W, Kim D-S, Kang S-Y, Marquez M, Joo YL (2006) Polymer 47:5097

    Google Scholar 

  78. Kim G-M, Asran AS, Michler GH, Simon P, Kim J-S (2008) Bioinspir Biomim 3:046003/1

    ADS  Google Scholar 

  79. Kokabi M, Sirousazar M, Hassan ZM (2007) Eur Polym J 43:773

    Google Scholar 

  80. Kong C-S, Lee T-H, Lee K-H, Kim H-S (2009) J Macromol Sci B 48:77

    Google Scholar 

  81. Koski A, Yim K, Shivkumar S (2003) Mater Lett 58:493

    Google Scholar 

  82. Kotov NA, Podsiadlo P, Choi SY, Shim B, Lee J, Cuddihy M (2005) Biomacromolecules 6:2914

    Google Scholar 

  83. Kuga S, Yuan H, Nishiyama Y, Wada M (2006) Biomacromolecules 7:696

    Google Scholar 

  84. Kulpinski P (2005) J Appl Polym Sci 98:1855

    Google Scholar 

  85. Kvien I, Oksman K (2007) Appl Phys A 87:641

    ADS  Google Scholar 

  86. Lange J, Wyser Y (2003) Packag Technol Sci 16:149

    Google Scholar 

  87. Lee HW, Karim MR, Park JH, Bae DG, Oh W, Cheong IW, Yeum JH (2009) Polym Polym Compos 17:47

    Google Scholar 

  88. Lee HW, Karim MR, Park JH, Ghim HD, Choi JH, Kim K, Deng Y, Yeum JH (2009) J Appl Polym Sci 111:132

    Google Scholar 

  89. Leitner J, Hinterstoisser B, Wastyn M, Keckes J, Gindl W (2007) Cellulose 14:419

    Google Scholar 

  90. Li W, Yue J, Liu S (2012) Ultrason Sonochem 19:479

    Google Scholar 

  91. Liu H, Tang C (2007) Polym J 39:65

    MathSciNet  Google Scholar 

  92. Liu R, Yu H, Huang Y (2005) Cellulose 12:25

    Google Scholar 

  93. Matthews S, Fleming K, Gray D, Prasannan S (2000) J Am Chem Soc 122:5224

    Google Scholar 

  94. Medeiros E, Mattoso L, Offeman R, Wood D, Orts WJ (2008) Biobased Mater Bioenergy 2:1

    Google Scholar 

  95. Mi Y, Zhang X, Zhou S, Cheng J, Liu F, Zhu H, Dong X, Jiao Z (2007) Compos Part A 38:2041

    Google Scholar 

  96. Munir MM, Iskandar F, Khairurrijal OK (2009) Rev Sci Instrum 80:026106-3

    ADS  Google Scholar 

  97. Nakagaito AN, Yano H (2004) Appl Phys A 78:547

    ADS  Google Scholar 

  98. Nakagaito AN, Yano H (2005) Appl Phys A 80:155

    ADS  Google Scholar 

  99. Nishiyama M (1997) Chem Fibers Int 47:296

    Google Scholar 

  100. Oksman C, Bondeson D, Mathew A (2006) Cellulose 13:171

    Google Scholar 

  101. Oksman K, Petersson L (2006) Compos Sci Technol 66:2187

    Google Scholar 

  102. Oskman K, Kvien I (2007) Appl Phys A 87:641

    ADS  Google Scholar 

  103. Pääkkö M, Vapaavuori J, Silvennoinen R, Kosonen H, Ankerfors M, Lindström T, Berglund LA, Ikkala O (2008) Soft Matter 4:2492

    ADS  Google Scholar 

  104. Paiva MC, Zhou B, Fernando KAS, Lin Y, Kennedy JM, Sun Y-P (2004) Carbon 42:2849

    Google Scholar 

  105. Paradossi G, Cavalieri F, Chiessi E (2003) J Mater Sci Mater Med 14:687

    Google Scholar 

  106. Peng Z, Kong LX, Li SD (2005) Synthetic Met 152:25

    Google Scholar 

  107. Peng Z, Kong LX, Li SD (2005) Synthetic Met 152:321

    Google Scholar 

  108. Peng Z, Kong LX (2007) Polym Degrad Stabil 926:1061

    Google Scholar 

  109. Peresin MS, Habibi Y, Zoppe JO, Pawlak JJ, Rojas OJ (2010) Biomacromolecules 11:674

    Google Scholar 

  110. Ramaraj B (2007) J Appl Polym Sci 103:909

    Google Scholar 

  111. Ranby BG (1952) Tappi 35:53

    Google Scholar 

  112. Ristolainen N, Heikkila P, Harlin A, Seppala J (2006) Macromol Mater Eng 291:114

    Google Scholar 

  113. Samir MASA, Alloin F, Dufresne A (2005) Biomacromolecules 6:612

    Google Scholar 

  114. Samir MASA, Dufresne A, Alloin F, Paillet M (2004) Macromolecules 37:4313

    ADS  Google Scholar 

  115. Schmedlen R, Masters K, West J (2002) Biomaterials 23:4325

    Google Scholar 

  116. Shao C, Kim H-Y, Gong J, Ding B, Lee D-R, Park S-J (2003) Mater Lett 57:1579

    Google Scholar 

  117. Siró I, Plackett D (2010) Cellulose 17:459

    Google Scholar 

  118. Sjoström E (1993) Wood chemistry fundamentals and applications. Academic, New York

    Google Scholar 

  119. Skaar C (1988) Wood–Water Relations, New York, NY: Springer Verlag (Springer Series in Wood Science)

    Google Scholar 

  120. Son WK, Youk JH, Lee TS, Park WH (2005) Mater Lett 59:1571

    Google Scholar 

  121. Stenstad P, Andresen M, Tanem BS, Stenius P (2008) Cellulose 15:35

    Google Scholar 

  122. Strawhecker KE, Manias E (2000) Chem Mater 12:2943

    Google Scholar 

  123. Sugiyama J, Chanzy H, Maret G (1992) Macromolecules 25:4232

    ADS  Google Scholar 

  124. Svagan AJ, Samir MASA, Berglund LA (2008) Adv Mater 20:1263

    Google Scholar 

  125. Svagan AJ, Samir MASA, Berglund LA (2007) Biomacromolecules 8:2556

    Google Scholar 

  126. Syverud K, Stenius P (2009) Cellulose 16:75

    Google Scholar 

  127. Tsai Y-C, Huang J-D (2006) Electrochem Commun 8:956

    Google Scholar 

  128. Turbak AF, Snyder FW, Sandberg KR (1983) J Appl Polym Sci Appl Polym Symp 37:815

    Google Scholar 

  129. Vignon MR, Habibi Y, Chanzy H (2006) Cellulose 13:679

    Google Scholar 

  130. Virtanen T, Maunu SL, Tamminen T, Hortfing B, Liitia T (2008) Carbohydr Polym 73:156

    Google Scholar 

  131. Walkenstrom P, Frenot A, Henriksson MW (2007) J Appl Polym Sci 103:1473

    Google Scholar 

  132. Wan W, Campbell G, Zhang Z, Hui A, Boughner D (2002) J Biomed Mater Res 63:854

    Google Scholar 

  133. Wang H, Fang P, Chen Z, Wang S (2007) Appl Surf Sci 253:8495

    ADS  Google Scholar 

  134. Wang Y, Wang Y, Yan D (2003) Polym Prep 44:1102

    Google Scholar 

  135. Werner O, Persson L, Nolte M, Fery A, WÃ¥gberg L (2008) Soft Matter 4:1158

    ADS  Google Scholar 

  136. Wong KKH, Zinke-Allmang M, Hutter JL, Hrapovic S, Luong JHT, Wan W (2009) Carbon 47:2571

    Google Scholar 

  137. Xia Y, Li D (2004) Adv Mater 16:1151

    Google Scholar 

  138. Yoshiharu N, Paul L, Henri C (2002) J Am Chem Soc 124:9074

    Google Scholar 

  139. Yoshiharu N, Shigenori K, Masahisa W, Takeshi O (1997) Macromolecules 30:6395

    ADS  Google Scholar 

  140. Yu H, Liu R, Shen D, Jiang Y, Huang Y (2005) Polymer 46:5689

    Google Scholar 

  141. Yu YH, Lin CY, Yeh JM, Lin WH (2003) Polymer 44:3553

    Google Scholar 

  142. Zhang C, Yuan X, Wu L, Han Y, Sheng J (2005) Eur Polym J 41:423–432

    Google Scholar 

  143. Zimmermann T, Pohler E, Geiger T (2004) Adv Eng Mater 6:754

    Google Scholar 

  144. Zoppe JO, Peresin MS, Habibi Y, Venditti RA, Rojas OJ (2009) ACS Appl Mater Interfaces 1:1996

    Google Scholar 

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Authors and Affiliations

  1. Cellulose and Paper Department, National Research Center, El-Tahrir St., Dokki, Giza, Egypt

    Maha M. Ibrahim & Waleed K. El-Zawawy

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  1. Maha M. Ibrahim
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  2. Waleed K. El-Zawawy
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Correspondence to Maha M. Ibrahim .

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Editors and Affiliations

  1. University of Petroleum and Energy Studies (UPES), Dehradun, India

    Jitendra K. Pandey

  2. Advanced Materials Division, Institute of Technology and Science, The University of Tokushima, Tokushima, Japan

    Hitoshi Takagi

  3. Dept. of Mechanical Engineering, Graduate School of Engineering, The University of Tokushima, Tokushima, Japan

    Antonio Norio Nakagaito

  4. College of Agriculture and Life Sciences, Seoul National University, Seoul, Korea, Republic of (South Korea)

    Hyun-Joong Kim

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Ibrahim, M.M., El-Zawawy, W.K. (2015). Poly(vinyl Alcohol)-Cellulose and Nanocellulose Composites. In: Pandey, J., Takagi, H., Nakagaito, A., Kim, HJ. (eds) Handbook of Polymer Nanocomposites. Processing, Performance and Application. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-45232-1_77

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