Abstract
This chapter deals with the structure, properties, and applications of electrospun-based cellulose composites. Extraction methods of cellulosic nanofibers from different sources are discussed in detail. Cellulose has the special advantage of high specific strength and sustainability, which make them ideal candidates for reinforcement in various polymeric matrices. Cellulose nanofibers find application in various fields, including construction, the automobile industry, and soil conservation. Cellulose, an eminent representative of nanomaterial obtained from various natural fibers, can be dissolved in various solvent systems, which are described in detail in this study. Thermoplastic-based electrospun cellulose nanocomposites and their applications are highlighted. This chapter describes current and future applications of electrospun cellulosic nanofibers in various fields.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Abbott A, Bismarck A (2010) Self-reinforced cellulose nanocomposites. Cellulose 17:779. http://link.springer.com/article/10.1007/s10570-010-9427-5
Abdel-Hady F, Alzahrany A, Hamed M (2011) Experimental validation of upward electrospinning process. ISRN Nanotechnol 2011:1
Abdul Khalil HPS, Issam AM, Ahmad Shakri MT, Suriani R, Awang AY (2007) Conventional agro-composites from chemically modified fibers. Ind Crop Prod 26:315
Abdul Khalil HPS, Siti Alwani M, Ridzuan R, Kamarudin H, Khairul A (2008) Chemical composition, morphological characteristics, and cell wall structure of Malaysian oil palm fibers. Polym Plast Technol Eng 47:273
Abdul Khalil HPS, Yusra AFI, Bhat AH, Jawaid M (2010) Cell wall ultrastructure, anatomy, lignin distribution, and chemical composition of Malaysian cultivated kenaf fiber. Ind Crop Prod 31:113
Abdul Khalil HPS, Bhat I, Ireana Yusra AF, Sanusi ZA, Hezri AA (2011) Broad perspective of palm oil for non- food applications for sustainable tomorrow. Nova Science, New York
Abdul Khalil HPS, Bhat AH, Ireana Yusra AF (2012) Green composites from sustainable cellulose nanofibrils: A review. Carbohydr Polym 87:963
Abreu HS, Latorraca JVF, Pereira RPW, Monteiro MBO, Abreu FA, Amparado KF (2009) Supramolecular proposal of lignin in structure and its relation with the wood proprieties. An Acad Bras Cienc 81:137
Adomaviciute E, Milasius R, Levinskas R (2007) The influence of main technological parameters on the diameter of poly (vinyl alcohol)(PVA) nanofibre and morphology of manufactured mat. Mater Sci 13:152
Ago M, Okajima K, Jakes JE, Park S, Rojas OJ (2012) Lignin-based electrospun nanofibers reinforced with cellulose nanocrystals. Biomacromolecules 13, pp 918–926
Ahn Y, Lee SH, Kim HJ, Yang YH, Hong JH, Kim YH, Kim H (2012) Electrospinning of lignocellulosic biomass using ionic liquid. Carbohydr Polym 88:395
Ahn Y, Hu DH, Hong JH, Lee SH, Kim HJ, Kim H (2012) Effect of co-solvent on the spinnability and properties of electrospun cellulose nanofiber. Carbohydr Polym 89:340. http://journals.ohiolink.edu/ejc/article.cgi?issn=01448617&issue=v89i0002&article=340_eocotsapoecn
Aluigi A, Vineis C, Varesano A, Mazzuchetti G, Ferrero F, Tonin C (2008) Structure and properties of keratin/PEO blend nanofibres. Eur Polym J 44:2465
Amiraliyan N, Nouri M, Haghighat Kish M (2009) Electrospinning of silk nanofibers. I. An investigation of nanofiber morphology and process optimization using response surface methodology. Fiber Polym 10:167
Ando T (2009) The electronic properties of graphene and carbon nanotubes. NPG Asia Mater 1:17
Arranz-Andreś J, Blau WJ (2008) Enhanced device performance using different carbon nanotube types in polymer photovoltaic devices. Carbon 46:2067
Asakura T, Yamane T, Nakazawa Y, Kameda T, Ando K (2001) Structure of Bombyx mori silk fibroin before spinning in solid state studied with wide angle x‐ray scattering and 13C cross‐polarization/magic angle spinning NMR. Biopolymers 58:521
Ashammakhi N, Ndreu A, Nikkola L, Wimpenny I, Yang Y (2008) Advancing tissue engineering by using electrospun nanofibers. Regen Med 3:547
Ayaz O, Ucar N, Bahar E, Oksuz M, Ucar M, Onen A, Demir A, Wang Y (2011) Production and analysis of composite nanofiber and heat applied nanofiber. In: International congress of innovative textiles, İstanbul, pp. 20–22
Ayaz O, Ucar N, Bahar E, Ucar O, Oksuz M, Onen A, Ucar M, İşmar E, Demir A (2012) Properties of composite nanofiber produced by single and coaxial nozzle method used for electrospinning technique. WASET 61:345
Ayutsede J, Gandhi M, Sukigara S, Micklus M, Chen HE, Ko F (2005) Regeneration of Bombyx mori silk by electrospinning. Part3: characterization of electrospun nonwoven mat. Polymer 46:1625
Ayutsede J, Gandhi M, Sukigara S, Ye H, Hsu CM, Gogotsi Y, Ko F (2006) Carbon nanotube reinforced Bombyx mori silk nanofibers by the electrospinning process. Biomacromolecules 7:208
Baji A, Mai YW, Wong SC, Abtahi M, Chen P (2010) Electrospinning of polymer nanofibers: effects on oriented morphology, structures and tensile properties. Compos Sci Technol 70:703
Balamurugan R, Sundarrajan S, Ramakrishna S (2011) Recent trends in nanofibrous membranes and their suitability for air and water filtrations. Membranes 1:232
Baley C (2002) Analysis of the flax fibres tensile behaviour and analysis of the tensile stiffness increase. Compos A 33:939
Baumgarten PK (1971) Electrostatic spinning of acrylic microfibers. J Colloid Interface Sci 36:71
Beck-Candanedo S, Roman M, Gray DG (2005) Effect of reaction conditions on the properties and behavior of wood cellulose nanocrystal suspensions. Biomacromolecules 6:1048
Bhardwaj N, Kundu SC (2010) Electrospinning: a fascinating fiber fabrication technique. Biotechnol Adv 28:325
Bjorge D, Daels N, Vrieze SD, Dejans P, Camp TV, Audenaert W, Hogie J, Westbroek P, Clerck KD, Hulle SWHV (2009) Performance assessment of electrospun nanofibers for filter applications. Desalination 249:942
Blascu V (2010) Aramid fibers for technical textiles II. Forms, availability and applications. Bul Inst Polit Iasi t LVI (LX) f.1: 9
Bochek A, Petropavlovsky G, Kallistov O (1993) Dissolution of cellulose and its derivatives in the same solvent, methylmorpholine-N-oxide and the properties of the resulting solutions. Cellul Chem Technol 27:137
Bognitzki M, Czado W, Frese T, Schaper A, Hellwig M, Steinhart M, Greiner A, Wendorff JH (2001) Nanostructured fibers via electrospinning. Adv Mater 13:70
Boss HL, Van Den Oever MJA, Peters OCJJ (2002) Tensile and compressive properties of flax fibres for natural fibre reinforced composites. J Mater Sci 37:1683
Cai ZX, Mo XM, Zhang KH, Fan LP, Yin AL, He CL, Wang HS (2010) Fabrication of chitosan/silk fibroin composite nanofibers for wound-dressing applications. Int J Mol Sci 11:3529
Cao X, Habibi Y, Magalhães WLE, Rojas OJ, Lucia LA (2011) Cellulose nanocrystals-based nanocomposites: fruits of a novel biomass research and teaching platform. Curr Sci 100:1172
Castro C, Gargallo L, Leiva A, Radic D (2005) Interactions in blends containing chitosan with functionalized polymers. J Appl Polym Sci 97:1953
Celebioglu A, Uyar T (2010) Cyclodextrin nanofibers by electrospinning. Chem Commun 46:6903
Charlier JC (2002) Defects in carbon nanotubes. Acc Chem Res 35:1063
Chen L, Bromberg L, Hatton TA, Rutledge GC (2007) Catalytic hydrolysis of p-nitrophenyl acetate by electrospun polyacrylamidoxime nanofibers. Polymer 48:4675
Chen Z, Mo X, Qing F (2007) Electrospinning of collagen–chitosan complex. Mater Lett 61:3490
Chen P, Yun YS, Bak H, Cho SY, Jin HJ (2010) Multiwalled carbon nanotubes-embedded electrospun bacterial cellulose nanofibers. Mol Cryst Liq Cryst 519:169
Chowdhury M, Stylios G (2010) Effect of experimental parameters on the morphology of electrospun Nylon 6 fibres. Int J Basic Appl Sci 10:116
Chronakis IS (2005) Novel nanocomposites and nanoceramics based on polymer nanofibers using electrospinning process–a review. J Mater Process Technol 167:283
Chung S, Moghe AK, Montero GA, Kim SH, King MW (2009) Nanofibrous scaffolds electrospun from elastomeric biodegradable poly (L-lactide-co-ε-caprolactone) copolymer. Biomed Mater 4:1
Cozza ES, Bruzzo V, Carniato F, Marsano E, Monticelli O (2012) On a novel catalytic system based on electrospun nanofibers and M-POSS. Appl Mater Interfaces 4:604
Cui W, Li X, Zhou S, Weng J (2007) Investigation on process parameters of electrospinning system through orthogonal experimental design. J Appl Polym Sci 103:3105
Dahlin RL, Kasper FK, Mikos AG (2011) Polymeric nanofibers in tissue engineering. Tissue Eng Part B Rev 17:349
Dai H (2002) Carbon nanotubes: Synthesis, integration, and properties. Acc Chem Res 35:1035
Dallmeyer I, Ko F, Kadla JF (2010) Electrospinning of technical lignins for the production of fibrous networks. J Wood Chem Technol 30:315
Deng XL, Xu MM, Li D, Sui G, Hu XY, Yang XP (2007) Electrospun PLLA-MWNTs-HA hybrid nanofiber scaffolds and their potential in dental engineering. Key Eng Mater 330–332:393
Desai K, Kit K, Li J, Zivanovic S (2008) Morphological and surface properties of electrospun chitosan nanofibers. Biomacromolecules 9:1000
Ding B, Li C, Hotta Y, Kim J, Kuwaki O, Shiratori S (2006) Conversion of an electrospun nanofibrous cellulose acetate mat from a super-hydrophilic to super-hydrophobic surface. Nanotechnology 17:4332
Ding B, Wang M, Yu J, Sun G (2009) Gas sensors based on electrospun nanofibers. Sensors 9:1609
Dong H, Strawhecker KE, Snyder JF, Orlicki JA, Reiner RS, Rudie AW (2012) Cellulose nanocrystals as a reinforcing material for electrospun poly (methyl methacrylate) fibers: Formation, properties and nanomechanical characterization. Carbohydr Polym 87:2488
Drozin VG (1955) The electrical dispersion of liquids as aerosols. J Colloid Sci 10:158
Du J, Hsieh YL (2009) Cellulose/chitosan hybrid nanofibers from electrospinning of their ester derivatives. Cellulose 16:247
Dufresne A (2008) Polysaccharide nano crystal reinforced nanocomposites. Can J Chem 86:484
Duran N, Lemes AP, Duran M, Freer J, Baeza J (2011) A minireview of cellulose nanocrystals and its potential integration as co-product in bioethanol production. J Chil Chem Soc 56, pp 672–677
El-Hefian EA, Nasef MM, Yahaya AH, Attakhan R (2010) Preparation and characterization of chitosan/agar blends: rheological and thermal studies. J Chil Chem Soc 55, pp 130–136
Evcin A, Kaya DA (2010) Effect of production parameters on the structure and morphology of aluminum titanate nanofibers produced using electrospinning technique. Sci Res Essays 5:3682
Fang X, Reneker DH (1997) DNA fibers by electrospinning. J Macromol Sci Phys 36:169
Feng H, Li J, Wang L (2010) Preparation of biodegradable flax shive cellulose-based superabsorbent polymer under microwave irradiation. BioResources 5:1484
Fink H-P, Weigel P, Purz H (2001) Structure formation from regenerated cellulose materials from NMMO solutions. Prog Polym Sci 26:1473
Fong H, Chun I, Reneker DH (1999) Beaded nanofibers formed during electrospinning. Polymer 40:4585
Formhals A (1934) US patent no 1,975,504
Freire MG, Teles ARR, Ferreira RAS, Carlos LD, Lopes-da-Silvac JA, Coutinho JAP (2011) Electrospun nanosized cellulose fibers using ionic liquids at room temperature. Green Chem 13:3173
Frenot A, Henriksson MW, Walkenstrom P (2007) Electrospinning of cellulose‐based nanofibers. J Appl Polym Sci 103:1473
Frey MW (2008) Electrospinning cellulose and cellulose derivatives. Polym Rev 48:378
Fukaya Y, Hayashi K, Wadab M, Ohno H (2008) Cellulose dissolution with polar ionic liquids under mild conditions: Required factors for anions. Green Chem 10:44
Gardner DJ, Oporto GS, Mills R, Samir ASA (2008) Adhesion and surface issues in cellulose and nanocellulose. J Adhes Sci Technol 22:545
Geng X, Kwon OH, Jinho Jang J (2005) Electrospinning of chitosan dissolved in concentrated acetic acid solution. Biomaterials 26:5427
Geng HZ, Lee DS, Kim KK, Bae JJ, Lee YH (2008) Ect of carbon nanotube types in fabricating flexible transparent conducting films. J Korean Phys Soc 53:979
George J, Sreekala MS, Thomas S (2001) A review on interface modification and characterization of natural fiber reinforced plastic composites. Polym Eng Sci 41:1471
Gorji M, Jeddi AAA, Gharehaghaji AA (2012) Fabrication and characterization of polyurethane electrospun nanofiber membranes for protective clothing applications. J Appl Polym Sci 125, pp 4135–4141
Greiner A, Wendroff JH (2007) Electrospinning: a fascinating method for the preparation of ultrathin fibers. Angew Chem Int Ed 46:5670
Gupta P, Elkins C, Long TE, Wilkes GL (2005) Electrospinning of linear homopolymers of poly (methyl methacrylate): exploring relationships between fiber formation, viscosity, molecular weight and concentration in a good solvent. Polymer 46:4799
Gururajan G, Sullivan SP, Beebe TP, Chase DB, Rabolt JF (2011) Continuous electrospinning of polymer nanofibers of Nylon-6 using an atomic force microscope tip. Nanoscale 3:3300
Härdelin L, Thunberg J, Perzon E, Westman G, Walkenström P, Gatenholm P (2012) Electrospinning of cellulose nanofibers from ionic liquids: The effect of different cosolvents. J Appl Polym Sci 125, pp 1901–1909
Haghi AK, Akbari M (2007) Trends in electrospinning of natural nanofibers. Phys Stat Sol 204:1830
Han SO, Youk JH, Min KD, Kang YO, Park WH (2008) Electrospinning of cellulose acetate nanofibers using a mixed solvent of acetic acid/water: Effects of solvent composition on the fiber diameter. Mater Lett 62:759
Hansen CM, Bjorkman A (1998) The ultrastructure of wood from a solubility parameter point of view. Holzforschung 52:335
Hardick O, Stevens B, Bracewell DG (2011) Nanofibre fabrication in a temperature and humidity controlled environment for improved fibre consistency. J Mater Sci 46:3890
He JH, Wan YQ, Yu JY (2004) Application of vibration technology to polymer electrospinning. Int J Nonlin Sci Num 5:243
He JH, Wu Y, Pan N (2005) A mathematical model for AC-electrospinning. Int J Nonlin Sci Num 6:243
Herrera MA, Mathew AP, Oksman K (2012) Novel biorefinery: A residue from wood bioethanol production converted into cellulose nanocrystals. In: 6th EEIGM international conference on advanced materials research IOP publishing IOP conference series: materials science and engineering, vol 31, Nancy France
Hohman MM, Shin M, Rutledge G, Brenner MP (2001) Electrospinning and electrically forced jets. I. Stability theory. Phys Fluids 13:2221
Huang ZH, Kang FY, Zheng YP, Yang JB, Liang KM (2002) Adsorption of trace polar methy-ethyl-ketone and non-polar benzene vapors on viscose rayon-based activated carbon fibers. Carbon 40:1363
Huang ZM, Zhang YZ, Kotaki M, Ramakrishna S (2003) A review on polymer nanofibers by electrospinning and their applications in nanocomposites. Compos Sci Technol 63:2223
Huang J, Liu L, Yao J (2011) Electrospinning of Bombyx mori silk fibroin nanofiber mats reinforced by cellulose nanowhiskers. Fiber Polym 12:1002
Hur S, Kim WD (2006) The electrospinning process and mechanical properties of nanofiber mats under vacuum conditions. Key Eng Mater 326–328:393
Ignatova M, Manolova N, Markova N, Rashkov I (2009) Electrospun non-woven nanofibrous hybrid mats based on chitosan and PLA for wound-dressing applications. Macromol Biosci 9:102
Iijima S (1991) Helical microtubules of graphitic carbon. Nature 354:56
Inoue S, Tanaka K, Arisaka F, Kimura S, Ohtomo K, Mizuno S (2000) Silk fibroin of bombyx mori is secreted, assembling a high molecular mass elementary unit consisting of H-chain, L-chain, and P25, with a 6:6:1 molar ratio. J Biol Chem 275:40517
Islam MS, Ashaduzzaman M, Masum SM, Yeum JH (2012) Mechanical and electrical properties: electrospun alginate/carbon nanotube composite nanofiber. Dhaka Univ J Sci 60:125
Jacobs V, Anandjiwala RD, Maaza M (2010) The influence of electrospinning parameters on the structural morphology and diameter of electrospun nanofibers. J Appl Polym Sci 115:3130
Jaeger R, Bergshoef MM, Batlle CMI, Schönherr H, Julius Vancso G (1998) Electrospinning of ultra-thin polymer fibres. Macromol Symp 127:141
Jahn A, Schroder MW, Futing M, Schenzel K, Diepenbrock W (2002) Characterization of alkali treated flax fibres by means of FT Raman spectroscopy and environmental scanning electron microscopy. Spectrochim Acta Part A 58:2271
Jang JH, Castano O, Kim HW (2009) Electrospun materials as potential platforms for bone tissue engineering. Adv Drug Deliv Rev 61:1065
Jawaid M, Abdul Khalil HPS (2011) Cellulosic/synthetic fibre reinforced polymer hybrid composites: A review. Carbohydr Polym 86:1
Jayaraman K, Kotaki M, Zhang Y, Mo X, Ramakrishna S (2004) Recent advances in polymer nanofibers. J Nanosci Nanotechnol 4(1–2):52
Jia YT, Kim HY, Gong J, Lee DR (2006) Electrospun nanofibers of block copolymer of trimethylene carbonate and ε-caprolactone. J Appl Polym Sci 99:1462
Jian F, Tao NH, Tong L, XunGai W (2008) Applications of electrospun nanofibers. Chin Sci Bull 53:2265
Johnson D (1969) US patent 3,447,956 (Eastman Kodak Co)
Kanani AG, Bahrami SH (2010) Review on electrospun nanofibers scaffold and biomedical applications. Trends Biomater ArtRif Org 24:93
Kang MS, Yoon SH, Jin HJ (2006) Preparation of electrospun protein nanofibers with multiwalled carbon nanotubes. Key Eng Mater 326–328:1737
Karmanov AP, Monakov YB (2003) Lignin structural organisation and fractal properties. Russ Chem Rev 72:715
Khan MA, Ganster J, Fink HP (2009) Hybrid composites of jute and man-made cellulose fibers with polypropylene by injection moulding. Compos Part A 40:846
Khenoussi N, Schacher L, Adolphe DC (2012) Nanofiber production: Study and development of electrospinning device. Exp Tech 36:32
Khil MS, Kim HY, Kang YS, Bang HJ, Lee DR, Doo JK (2005) Preparation of electrospun oxidized cellulose mats and theirin vitro degradation behavior. Macromol Res 13:62
Kilic A, Oruc F, Demir A (2007) Effects of polarity on electrospinning process. Text Res J 00:1
Kilpelainen I, Xie H, King A, Granstrom M, Heikkinen S, Argyropoulos DS (2007) Dissolution of wood in ionic liquids. J Agric Food Chem 55:9142
Kim CW, Frey MW, Marquez M, Joo YL (2005) Preparation of submicron‐scale, electrospun cellulose fibers via direct dissolution. J Polym Sci Part B Polym Phys 43:1673
Kim GM, Lach R, Michler GH, Chang YW (2005) The mechanical deformation process of electrospun polymer nanocomposite fibers. Macromol Rapid Commun 26:728
Kim CW, Kim DS, Kang SY, Marquez M, Joo YL (2006) Structural studies of electrospun cellulose nanofibers. Polymer 47:5097
Kirecci A, Özkoc U, Icoglu HI (2012) Determination of optimal production parameters for polyacrylonitrile nanofibers. J Appl Polym Sci 124:4961
Kiselev P, Rosell-Llompart J (2012) Highly aligned electrospun nanofibers by elimination of the whipping motion. J Appl Polym Sci 125:2433
Kosan B, Michels C, Meister F (2008) Dissolution and forming of cellulose with ionic liquids. Cellulose 15:59
Kowalewski TA, Blonski S, Barral S (2005) Experiments and modelling of electrospinning process. Bull Pol Acad Sci Chem Tech Sci 53:385
Kriegel C, Arrechi A, Kit K, McClements DJ, Weiss J (2008) Fabrication, functionalization, and application of electrospun biopolymer nanofibers. Crit Rev Food Sci Nutr 48:775
Kuan CY, Yee-Fung W, Yuen KH, Liong MT (2012) Nanotech: propensity in foods and bioactives. Crit Rew Food Sci 52:55
Kulpinski P (2005) Cellulose nanofibers prepared by the N-methylmorpholine-N-oxide method. J Appl Polym Sci 98:1855–1859
Kumar S, Asce F, Kolay P, Asce M, Malla S, Mishra S (2012) Effect of multiwalled carbon nanotubes on mechanical strength of cement paste. J Mater Civ Eng 24(1):84
Kumbar SG, Nukavarapu SP, James R, Hogan MV, Laurencin CT (2008) Recent patents on electrospun biomedical nanostructures: an overview. Recent Pat Biomed Eng 1:68
Lamy B, Baley C (2000) Stiffness prediction of flax fibers-epoxy composite materials. J Mater Sci Lett 19:979
Larrondo L, Manley SJ (1981) Electrostatic fiber spinning from polymer melts. I. Experimental observations on fiber formation and properties. J Polym Sci Polym Phys Ed 19:921
Laus G, Bentivoglio G, Schottenberger H, Kahlenberg V, Kopacka H, Röder T, Sixta H (2005) Ionic liquids: current developments, potential and drawbacks for industrial applications. Lenzinger Berichte 84:71
Lee S (2009) Developing UV-protective textiles based on electrospun zinc oxide nanocomposite fibers. Fibers Polym 10:295
Lee S, Obendorf SK (2007) Use of electrospun nanofiber web for protective textile materials as barriers to liquid penetration. Text Res J 77:696. http://scholar.google.com/citations?view_op=view_citation&hl=en&user=5W6EtHgAAAAJ&citation_for_view=5W6EtHgAAAAJ:u5HHmVD_uO8C
Lee KH, Kim HY, Bang HJ, Jung YH, Lee SG (2003) The change of bead morphology formed on electrospun polystyrene fibers. Polymer 44:4029
Lee EH, Kim HM, Lim SK, Kim KS, Chin IJ (2009) Electro-active polymer actuator based on aligned cellulose nanofibrous membrane. Mol Cryst Liq Cryst 499:259[581]
Lee KY, Jeong L, Kang YO, Lee SJ, Park WH (2009) Electrospinning of polysaccharides for regenerative medicine. Adv Drug Deliv Rev 61:1020
Lewin M (2006) Handbook of fiber chemistry, 3rd edn. CRC Press, Boca Raton
Li P, Li Y, Ying B, Yang M (2009) Electrospun nanofibers of polymer composite as a promising humidity sensitive material. Sens Actuators B 141:390
Li Q, Zhou J, Zhang L (2009) Structure and properties of the nanocomposite films of chitosan reinforced with cellulose whiskers. J Polym Sci Part B Polym Phys 47:1069
Liao S, Li B, Ma Z, Wei H, Chan C, Ramakrishna S (2006) Biomimetic electrospun nanofibers for tissue regeneration. Biomed Mater 1:R45
Liebert T, Heinze T (2008) Interaction of ionic liquids with polysaccharides. 5. Solvents and reaction media for the modification of cellulose. BioResources 3:576
Lin Y-J, Cai Q, Li L, Li QF, Yang XP, Jin RG (2010) Co‐electrospun composite nanofibers of blends of poly [(amino acid ester) phosphazene] and gelatin. Polym Int 59:610
Lisperguer J, Perez P, Urizar S (2009) Structure and thermal properties of lignins: characterization by infrared spectroscopy and differential scanning calorimetry. J Chil Chem Soc 54:460
Liu H, Hsieh YL (2002) Ultrafine fibrous cellulose membranes from electrospinning of cellulose acetate. J Polym Sci Part B Polym Phys 40:2119
Liu Y, He JH, Yu JY, Zeng HM (2008) Controlling numbers and sizes of beads in electrospun nanofibers. Polym Int 57:632
Liu D, Yuan X, Bhattacharyya D (2012) The effects of cellulose nanowhiskers on electrospun poly (lactic acid) nanofibres. J Mater Sci 47:3159
Lönnberg H, Zhou Q, Brumer H, Teeri TT, Malmstrom E, Hult A (2006) Grafting of cellulose fibers with poly (ε-caprolactone) and poly (L-lactic acid) via ring-opening polymerizations. Biomacromolecules 7:2178
Lu C, Chen P, Li J, Zhang Y (2006) Computer simulation of electrospinning. Part I. Effect of solvent in electrospinning. Polymer 47:915
Lyons J, Li C, Ko F (2004) Melt-electrospinning part I: processing parameters and geometric properties. Polymer 45:7597
Magalhães WLE, Cao X, Lucia LA (2009) Cellulose nanocrystals/cellulose core-in-shell nanocomposite assemblies. Langmuir 25:13250
Magalhãess WLE, Cao X, Ramires MA, Lucia LA (2011) Novel method for inducing the alignment of cellulose nanocrystals-reinforced cellulose nanofibers. Tappi J 10:19
Makar JM, Beaudoin JJ (2003) In: 1st international symposium on nanotechnology in construction, Paisley, Scotland
Marcovich NE, Auad ML, Bellesi NE, Nutt SR, Aranguren MI (2006) Cellulose micro/nanocrystals reinforced polyurethane. J Mater Res 21:870
Marsh KN, Boxall JA, Lichtenthaler R (2004) Room temperature ionic liquids and their mixtures–a review. Fluid Phase Equilib 219:93
Martel R, Schmidt T, Shea HR, Hertel T, Avourisa PH (1998) Single-and multi-wall carbon nanotube field-effect transistors. Appl Phys Lett 73
Martínez-Hernández AL, Velasco-Santos C, Castaño VM (2010) Carbon nanotubes composites: processing, grafting and mechanical and thermal properties. Curr Nanosci 6:12. http://scholar.google.com.mx/citations?view_op=view_citation&hl=en&user=megg-bIAAAAJ&citation_for_view=megg-bIAAAAJ:2osOgNQ5qMEC
Martínez-Sanz M, Olsson RT, Lopez-Rubio A, Lagaron JM (2011) Development of electrospun EVOH fibres reinforced with bacterial cellulose nanowhiskers. Part I: Characterization and method optimization. Cellulose 18:335
Martinová L, Lubasová D (2008) Electrospun chitosan based nanofibers. RJTA 12
Martins A, Reis RL, Neves NM (2008) Electrospinning: processing technique for tissue engineering scaffolding. Int Mater Rev 53:257
Matthews JA, Wnek GE, Simpson DG, Bowlin GL (2002) Electrospinning of collagen nanofibers. Biomacromolecules 3:232
Mazoochi T, Jabbari V (2011) Chitosan nanofibrous scaffold fabricated via electrospinning: The effect of processing parameters on the nanofiber morphology. Int J Polym Anal Charact 16:277. http://65.54.113.26/Publication/57595212/chitosan-nanofibrous-scaffold-fabricated-via-electrospinning-the-effect-of-processing-parameters
Meli L, Miao J, Dordick JS, Linhardt RJ (2010) Electrospinning from room temperature ionic liquids for biopolymer fiber formation. Green Chem 12:1883
Mit-uppatham C, Nithitanakul M, Supaphol P (2004) Ultrafine electrospun polyamide‐6 fibers: effect of solution conditions on morphology and average fiber diameter. Macromol Chem Phys 205:2327
Miyauchi M, Miao J, Simmons TJ, Dordick JS, Linhardt RJ (2011) Lexible electrospun cellulose fibers as an affinity packing material for the separation of bovine serum albumin. J Chromatogr Separat Tech 2:110
Mo XM, Xu CY, Kotaki M, Ramakrishna S (2004) Electrospun P (LLA-CL) nanofiber: a biomimetic extracellular matrix for smooth muscle cell and endothelial cell proliferation. Biomaterials 25:1883
Montano-Leyva B, Rodriguez-Felix F, Torres-Chavez P, Ramirez-Wong B, Lopez-Cervantes J, Sanchez-Machado D (2011) Preparation and characterization of durum wheat (Triticum durum) straw cellulose nanofibers by electrospinning. J Agric Food Chem 59:870
Mora-Pale M, Meli L, Doherty TV, Linhardt RJ, Dordick JS (2011) Room temperature ionic liquids as emerging solvents for the pretreatment of lignocellulosic biomass. Biotechnol Bioeng 108:1229
Nakagaito AN, Iwamoto S, Yano H (2005) Bacterial cellulose: the ultimate nano-scalar cellulose morphology for the production of high-strength composites. Appl Phys A 80:93
Nevell TP, Zeronian SH (1985) Wiley, New York
Niyogi S, Hamon MA, Hu H, Zhao B, Bhowmik R (2002) Chemistry of single-walled carbon nanotubes. Acc Chem Res 35:1105
Nouri N, Ziaei-Rad S (2010) Mechanical property evaluation of carbon nanotube sheets. Trans F: Nanotechnol 17, pp 1600–1625
Ohkawa K, Cha D, Kim H, Nishida A, Yamamoto H (2004) Electrospinning of chitosan. Macromol Rapid Commun 25:1600
Ohkawa K, Hayashi S, Nishida A, Yamamoto H, Ducreux J (2009) Preparaiton of pure cellulose nanofiber via electrospinning. Text Res J 79:1396
Pankonian A, Ounaies Z, Yang C (2011) Electrospinning of cellulose and SWNT-cellulose nano fibers for smart applications. J Mech Sci Technol 25:2631
Park TJ, Jung YJ, Choi SW, Park H, Kim H, Kim E, Lee SH, Kim JH (2011) Native chitosan/cellulose composite fibers from an ionic liquid via electrospinning. Macromol Res 19:213
Peesan M, Rujiravanit R, Supaphol P (2006) Electrospinning of hexanoyl chitosan/polylactide blends. J Biomater Sci Polym Edn 17:547
Peng BL, Dhar N, Liu HL, Tam KC (2011) Chemistry and applications of nanocrystalline cellulose and its derivatives: a nanotechnology perspective. Can J Chem Eng 89:1191
Pham QP, Sharma U, Mikos AG (2006) Electrospinning of polymeric nanofibers for tissue engineering applications: a review. Tissue Eng 12:1197
Phillips DM, Drummy LF, Conrady DG, Fox DM, Naik RR, Stone MO, Trulove PC, Long HCD, Mantz RA (2004) Dissolution and regeneration of bombyx mori silk fibroin using ionic liquids. J Am Chem Soc 126:14350
Pinkert A, Marsh KN, Pang S, Staiger MP (2009) Ionic liquids and their interaction with cellulose. Chem Rev 109:6712
Popa VI, Capraru AM, Grama S, Malutan T (2011) Nanoparticles based on modified lignins with biocide properties. Cellul Chem Technol 45:221
Popov VN (2004) Carbon nanotubes: properties and application. Mater Sci Eng R 43:61
Pouteau C, Dole P, Cathala B, Averous L, Boquillon N (2003) Antioxidant properties of lignin in polypropylene. Polym Degrad Stab 81:9
Qiao B, Ding X, Hou X, Wu S (2011) Study on the electrospun CNTs/polyacrylonitrile based nanofiber composites. J Nanomater 2011, pp 1–7
Qin XH, Wang SY (2006) Filtration properties of electrospinning nanofibers. J Appl Polym Sci 102:1285
Quan SL, Kang SG, Chin IJ (2010) Characterization of cellulose fibers electrospun using ionic liquid. Cellulose 17:223
Ramakrishna S, Fujihara K, Teo WE, Yong T, Ma Z, Ramaseshan R (2006) Electrospun nanofibers: solving global issues. Mater Today 9:40
Rangkupan R, Reneker DH (2003) Electrospinning process of molten polypropylene in vacuum. J Met Mater Miner 12:81
Rayleigh L (1882) On the instability of jets. FRS Philos Mag Ser 5 14:184
Reddy CS, Arinstein A, Avrahami R, Zussman E (2009) Fabrication of thermoset polymer nanofibers by co-electrospinning of uniform core-shell structures. J Mater Chem 19:7198
Remsing RC, Swatloski RP, Rogers RD, Moyna G (2006) Mechanism of cellulose dissolution in the ionic liquid 1-n-butyl-3-methylimidazolium chloride: a 13C and 35/37Cl NMR relaxation study on model systems. Chem Commun 12:1271
Reneker DH, Chun I (1996) Nanometre diameter fibres of polymer, produced by electrospinning. Nanotechnology 7:216
Reneker DH, Yarin AL (2008) Electrospinning jets and polymer nanofibers. Polymer 49:2387
Reneker DH, Yarin AL, Fong H, Koombhongse S (2000) Bending instability of electrically charged liquid jets of polymer solutions in electrospinning. J Appl Phys 87:4531
Rockwood DN, Preda RC, Yücel T, Wang X, Lovett ML, Kaplan DL (2011) Materials fabrication from Bombyx mori silk fibroin. Nat Protoc 6:1612
Rong MZ, Zhang MQ, Liu Y, Yang GC, Zeng HM (2001) The effect of fiber treatment on the mechanical properties of unidirectional sisal-reinforced epoxy composites. Compos Sci Technol 61:1437
Saeed K, Park SY, Lee HJ, Baek JB, Huh WS (2006) Preparation of electrospun nanofibers of carbon nanotube/polycaprolactone nanocomposite. Polymer 47:8019
Sahay R, Kumar PS, Sridhar R, Sundaramurthy J, Venugopal J, Mhaisalkar SG, Ramakrishna S (2012) Electrospun composite nanofibers and their multifaceted applications. J Mater Chem 22:12953
Sajeev US, Anand KA, Menon D, Nair S (2008) Control of nanostructures in PVA, PVA/chitosan blends and PCL through electrospinning. Bull Mater Sci 31:343
Sakurai K, Maegawa T, Takahashi T (2000) Glass transition temperature of chitosan and miscibility of chitosan/poly (N-vinyl pyrrolidone) blends. Polymer 41:7051
Salazar-Valencia PJ, Pérez-Merchancano ST, Bolívar-Marinéz LE (2006) Optical properties in Biopolymers: lignin fragments. Braz J Phys 36, pp 840–843
Saligheh O, Arasteh R, Forouharshad M, Farsani RE (2011) Poly (Butylene Terephthalate)/single wall carbon nanotubes composite nanofibers by electrospinning. J Macromol Sci Phys 50:1031
Salvetat JP, Bonard JM, Thomson NH, Kulik AJ, Forró L, Benoit W, Zuppiroli L (1999) Mechanical properties of carbon nanotubes. Appl Phys A Mater Sci Proc 69:255
Samatham R, Kim KJ (2006) Electric current as a control variable in the electrospinning process. Polym Eng Sci 46:954
Sangsanoh P, Supaphol P (2006) Stability improvement of electrospun chitosan nanofibrous membranes in neutral or weak basic aqueous solutions. Biomacromolecules 7:2710
Schiffman JD, Schauer CL (2007) Cross-linking chitosan nanofibers. Biomacromolecules 8:2665
Schiffman JD, Schauer CL (2008) A review: electrospinning of biopolymer nanofibers and their applications. Polym Rev 48:317
Schueren LVD, Steyaert I, Schoenmaker BD, Clerck KD (2012) Polycaprolactone/chitosan blend nanofibres electrospun from an acetic acid/formic acid solvent system. Carbohydr Polym 88:1221
Seo DK, Jeun JP, Kim HB, Kang PH (2011) Preparation and characterization of the carbon nanofiber mat produced from electrospun PAN/lignin precursors by electron beam irradiation. Rev Adv Mater Sci 28:31
Shi Z, Zang S, Jiang F, Huang L, Lu D, Ma Y, Yang G (2012) In situ nano-assembly of bacterial cellulose–polyaniline composites. RSC Adv 2:1040
Shin YM, Hohman MM, Brenner MP, Rutledge GC (2001) Experimental characterization of electrospinning: the electrically forced jet and instabilities. Polymer 42:9955
Sill TJ, Recum HAV (2008) Electrospinning: applications in drug delivery and tissue engineering. Biomaterials 29:1989
Song R, Xue R, He LH, Liu Y, Xiao OL (2008) The structure and properties of chitosan/polyethylene glycol/silica ternary hybrid organic-inorganic films. Chin J Polym Sci 26:621
Srivastava Y, Marquez M, Thorsen T (2007) Multijet electrospinning of conducting nanofibers from microfluidic manifolds. J Appl Polym Sci 106:3171
Subbiah T, Bhat GS, Tock RW, Parameswaran S, Ramkumar SS (2005) Electrospinning of nanofibers. J Appl Polym Sci 96:557
Sui X, Wagner HD (2009) Tough nanocomposites: the role of carbon nanotube type. Nano Lett 9:1423
Sumin L, Kimura D, Yokoyama A, Lee KH, Park JC, Kim IS (2009) The effect of laundering on the thermal and water transfer properties of mass-produced laminated nanofiber web for use in wear. Text Res J 79:1085
Sun Z, Zussman E, Yarin AL, Wendorff JH, Greiner A (2003) Compound core–shell polymer nanofibers by co‐electrospinning. Adv Mater 15:1929
Supaphol P, Neamnark A, Taepaiboon P, Pavasant P (2012) Effect of degree of acetylation on In vitro biocompatibility of electrospun cellulose acetate-based fibrous matrices. Chiang Mai J Sci 39:209
Suwantong O, Opanasopit P, Ruktanonchai U, Supaphol P (2007) Electrospun cellulose acetate fiber mats containing curcumin and release characteristic of the herbal substance. Polymer 48:7546
Swatloski RP, Spear SK, Holbrey JD, Rogers RD (2002) Dissolution of cellose with ionic liquids. J Am Chem Soc 124:4974
Tan SH, Inai R, Kotaki M, Ramakrishna S (2005) Systematic parameter study for ultra-fine fiber fabrication via electrospinning process. Polymer 46:6128
Tan S, Huang X, Wu B (2007) Some fascinating phenomena in electrospinning processes and applications of electrospun nanofibers. Polym Int 56:1330
Thavasi V, Singh G, Ramakrishna S (2008) Electrospun nanofibers in energy and environmental applications. Energy Environ Sci 1:205
Theron SA, Zussman E, Yarin AL (2004) Experimental investigation of the governing parameters in the electrospinning of polymer solutions. Polymer 45:2017
Theron SA, Yarin AL, Zussman E, Kroll E (2005) Multiple jets in electrospinning: experiment and modeling. Polymer 46:2889
Thompson CJ, Chase GG, Yarin AL, Reneker DH (2007) Effects of parameters on nanofiber diameter determined from electrospinning model. Polymer 48:6913
Unnithan AR, Barakat NAM, Nirmala R, Al-Deyab SS, Kim HY (2012) Novel electrospun nanofiber mats as effective catalysts for water photosplitting. Ceram Int 38, pp 5175–5180
Van De Velde K, Kiekens P (2001) Thermoplastic pultrusion of natural fibre reinforced composites. Compos Struct 54:355
Vasita R, Katti DS (2006) Nanofibers and their applications in tissue engineering. Int J Nanomedicine 1:15
Veleirinho B, Rei MF, Lopes-DA-Silva JA (2008) Solvent and concentration effects on the properties of electrospun poly (ethylene terephthalate) nanofiber mats. J Polym Sci Part B Polym Phys 46:460
Viswanathan G, Murugesan S, Pushparaj V, Nalamasu O, Ajayan PM, Linhardt RJ (2006) Preparation of biopolymer fibers by electrospinning from room temperature ionic liquids. Biomacromolecules 7:415
Vitz J, Erdmenger T, Haenscha C, Schubert US (2009) Extended dissolution studies of cellulose in imidazolium based ionic liquids. Green Chem 11:417
Vrieze SD, Camp TV, Nelvig A, Hagström B, Westbroek P, Clerck KD (2009) The effect of temperature and humidity on electrospinning. J Mater Sci 44:1357
Wan Nadirah WO, Jawaid M, Al Masri A, Abdul Khalil HPS, Suhaily SS, Mohamed AR (2012) Cell wall morphology, chemical and thermal analysis of cultivated pineapple leaf fibres for industrial applications. J Polym Environ 20:404
Wan YQ, Guo Q, Pan N (2004) Thermo-electro-hydrodynamic model for electrospinning process. Int J Nonlin Sci Num 5:5
Wang C, Hsu CH, Lin JH (2006) Scaling laws in electrospinning of polystyrene solutions. Macromolecules 39:7662
Wang C, Yan E, Huang Z, Zhao Q, Xin Y (2007) Fabrication of highly photoluminescent TiO2/PPV hybrid nanoparticle‐polymer fibers by electrospinning. Macromol Rapid Commun 28:205
Wang K, Gu M, Wang JJ, Qin C, Dai L (2012) Functionalized carbon nanotube/polyacrylonitrile composite nanofibers: fabrication and properties. Polym Adv Technol 23:262
Wannatong L, Sirivat A, Supaphol P (2004) Effects of solvents on electrospun polymeric fibers: preliminary study on polystyrene. Polym Int 53:1851
Wei K, Li Y, Kim KO, Nakagawa Y, Kim BS, Abe K, Chen GQ, Kim LS (2011) Fabrication of nano-hydroxyapatite on electrospun silk fibroin nanofiber and their effects in osteoblastic behavior. J Biomed Mater Res A 97A:272
Wendler F, Kosan B, Krieg M, Meister F (2009) Cellulosic shapes from Ionic liquids modified by activated charcoals and nanosilver particles. Lenzinger Ber 87:106
Williamson RE, Burn JE, Hocart CH (2002) Towards the mechanism of cellulose synthesis. Trends Plant Sci 7:461
Wu CS (2005) A comparison of the structure, thermal properties, and biodegradability of polycaprolactone/chitosan and acrylic acid grafted polycaprolactone/chitosan. Polymer 46:147
Xu S, Zhang J, He A, Li J, Zhang H, Han CC (2008) Electrospinning of native cellulose from nonvolatile solvent system. Polymer 49:2911
Yang D, Zhang J, Zhang J, Nie J (2008) Aligned electrospun nanofibers induced by magnetic field. J Appl Polym Sci 110:3368
Yang DJ, Kamienchick I, Youn DY, Rothschild A, Kim ID (2010) Ultrasensitive and highly selective gas sensors based on electrospun SnO2 nanofibers modified by Pd loading. Adv Funct Mater 20:4258
Yang M, Cao K, Sui L, Qi Y, Zhu J, Waas A, Arruda EM, Kieffer J, Thouless MD, Kotov NA (2011) Dispersions of aramid nanofibers: a new nanoscale building block. AcsNano 5:6945
Yao L, Lee C, Kim J (2010) Fabrication of electrospun meta-aramid nanofibers in different solvent systems. Fibers Polym 11:1032. http://www.researchgate.net/publication/241053217_Fabrication_of_electrospun_meta-aramid_nanofibers_in_different_solvent_systems
Yao L, Lee C, Kim J (2011) Electrospun meta-aramid/cellulose acetate and meta-aramid/cellulose composite nanofibers. Fiber Polym 12:197
Yeo L, Friend JR (2006) Electrospinning carbon nanotube polymer composite nanofibers. J Exp Nanosci 1:177
Yun GY, Kim HS, Kim J, Kim K, Yang C (2008) Effect of aligned cellulose film to the performance of electro-active paper actuator. Sens Actuators A 141:530
Zamri MFMA, Zein SHS, Abdullah AZ, Basir NI (2011) Improved electrical conductivity of polyvinyl alcohol/multiwalled carbon nanotube nanofibre composite films with MnO2 as filler synthesised using the electrospinning process. IJET-IJENS 11:20
Zavrel M, Bross D, Funke M, Büchs J, Spiess AC (2009) High-throughput screening for ionic liquids dissolving (ligno-) cellulose. Bioresour Technol 100:2580
Zeleny J (1914) The electrical discharge from liquid points, and a hydrostatic method of measuring the electric intensity at their surfaces. Phys Rev Second Ser 3:69
Zhang M, Li J (2009) Carbon nanotube in different shapes. Mater Today 12, pp 12–18
Zhang H, Qian XM (2010) The Applications of electrospun nanofibers in the medical materials. Adv Mater Res 148–149:1138
Zhang H, Wu J, Zhang J, He JS (2005) 1-Allyl-3-methylimidazolium chloride room temperature ionic liquid: a new and powerful nonderivatizing solvent for cellulose. Macromolecules 38:8272
Zhang H, Wang Z, Zhang Z, Wu J, Zhang J, He J (2007) Regenerated-cellulose/multiwalled-carbon-nanotube composite fibers with enhanced mechanical properties prepared with the ionic liquid 1-allyl-3-methylimidazolium chloride. Adv Mater 19:698
Zhao ML, Sui G, Deng XL, Lu JG, Ryu SK, Yang XP (2006) PLLA/HA electrospin hybrid nanofiber scaffolds: morphology, in vitro degradation and cell culture potential. Adv Mater Res 11–12:243
Zhao T, Wang H, Zhang Y, Wang B, Jiang J (2007) The preparation and characterization of poly(m-phenylene- isophthalamide) fibers using ionic liquids. Int J Mol Sci 8:680
Zhou C, Chu R, Wu R, Wu Q (2011) Electrospun polyethylene oxide/cellulose nanocrystal composite nanofibrous mats with homogeneous and heterogeneous microstructures. Biomacromolecules 12:2617
Zhu S, Wu Y, Chen O, Yu Z, Wang C, Jin S, Dinga Y, Wuc G (2006) Dissolution of cellulose with ionic liquids and its application: a mini-review. Green Chem 8:325
Ziabari M, Mottaghitalab V, Haghi AK (2009) Application of direct tracking method for measuring electrospun nanofiber diameter. Braz J Chem Eng 26:53
Zong X, Kim K, Fang D, Ran S, Hsiao BS, Chu B (2002) Structure and process relationship of electrospun bioabsorbable nanofiber membranes. Polymer 43:4403
Zucchelli A, Focarete ML, Gualandi C, Ramakrishna S (2011) Electrospun nanofibers for enhancing structural performance of composite materials. Polym Adv Technol 22:339
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2015 Springer-Verlag Berlin Heidelberg
About this chapter
Cite this chapter
Abdul Khalil, H.P.S., Davoudpour, Y., Bhat, A.H., Rosamah, E., Tahir, P.M. (2015). Electrospun Cellulose Composite Nanofibers. In: Pandey, J., Takagi, H., Nakagaito, A., Kim, HJ. (eds) Handbook of Polymer Nanocomposites. Processing, Performance and Application. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-45232-1_61
Download citation
DOI: https://doi.org/10.1007/978-3-642-45232-1_61
Published:
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-45231-4
Online ISBN: 978-3-642-45232-1
eBook Packages: Physics and AstronomyPhysics and Astronomy (R0)