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Geochemical Fingerprinting Using LIBS

  • Richard R. HarkEmail author
  • Russell S. Harmon
Chapter
Part of the Springer Series in Optical Sciences book series (SSOS, volume 182)

Abstract

Geochemical fingerprinting is based upon the idea that the chemical composition of a mineral or rock reflects the geological processes associated with its formation. Information about the elemental composition and isotopic ratios has used been used extensively within the geochemical community to differentiate geological samples derived from distinct source reservoirs or having a different post-formation history.

Keywords

Instrumental Neutron Activation Analysis Partial Little Square Discriminant Analysis Laser Ablation Inductively Couple Plasma Mass Spectrometry Volcanogenic Massive Sulfide Partial Little Square Discriminant Analysis Model 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

References

  1. 1.
    J. Hoefs, Eur. J. Mineral. 22, 3 (2010)CrossRefGoogle Scholar
  2. 2.
    B.S. Kamber, Appl. Geochem. 24, 1074 (2009)CrossRefGoogle Scholar
  3. 3.
    B.J. Skinner, P.B. Barton Jr, Annu. Rev. Earth Planet. Sci. 1, 183 (1973)ADSCrossRefGoogle Scholar
  4. 4.
    C. Klein, B. Dutrow, The 23rd Edition of the Manual of Mineral Science (Wiley, Hoboken, 2008)Google Scholar
  5. 5.
    V.M. Goldschmidt, J. Chem. Soc. 0, 655 (1937)Google Scholar
  6. 6.
    A.W. Hofmann, Nature 385, 218 (1997)ADSCrossRefGoogle Scholar
  7. 7.
    P.R. Kyle, D. Seward, Geology 12, 487 (1984)ADSCrossRefGoogle Scholar
  8. 8.
    S.L. de Silva, P.W. Francis, J. Volcanol. Geoth. Res. 37, 133 (1989)ADSCrossRefGoogle Scholar
  9. 9.
    P. Shane, I. Smith, New Zeal. J. Geol. Geop. 43, 569 (2000)CrossRefGoogle Scholar
  10. 10.
    S.L. Donoghue, J. Vallance, I.E.M. Smith, R.B. Stewart, J. Quat. Sci. 22, 395 (2007)CrossRefGoogle Scholar
  11. 11.
    E.L. Tomlinson, T. Thordarson, W. Müller, M. Thirlwall, M.A. Menzies, Chem. Geol. 279, 73 (2010)CrossRefGoogle Scholar
  12. 12.
    J. Pearce, Episodes 19, 120 (1996)Google Scholar
  13. 13.
    J.-H. Yu, X. Xu, S.Y. O’Reilly, W.L. Griffin, M. Zhang, Lithos 67, 77 (2003)ADSCrossRefGoogle Scholar
  14. 14.
    J.W. Goodge, P. Myrow, I.S. Williams, S.A. Bowring, J. Geol. 110, 393 (2002)ADSCrossRefGoogle Scholar
  15. 15.
    B. Schmickler, D.E. Jacob, S.F. Foley, Lithos 75, 173 (2004)ADSCrossRefGoogle Scholar
  16. 16.
    J.J. Gurney, P. Zweistra, J. Geochem. Explor. 53, 293 (1995)CrossRefGoogle Scholar
  17. 17.
    C. Dupuis, G. Beaudoin, Miner. Dep. 46, 319 (2011)CrossRefGoogle Scholar
  18. 18.
    R.J. Parker, K. Nicholson, in Proceedings of the 12th New Zealand Geothermal Workshop, Auckland University, Auckland, 1990Google Scholar
  19. 19.
    J.D. Grigsby, J. Sediment. Res. 62, 331 (1992)Google Scholar
  20. 20.
    P.R. Duller, J.D. Floyd, Geol. Mag. 132, 557 (1995)CrossRefGoogle Scholar
  21. 21.
    E. Martínez-Monasterio, R.W. Duck, W.E. Stephens, J. Walden, Scot. J. Geol. 42, 137 (2006)CrossRefGoogle Scholar
  22. 22.
    R.S. Harmon, K.M. Shughrue, J.J. Remus, M.A. Wise, L.J. East, R.R. Hark, Anal. Bioanal. Chem. 400, 3377 (2011)CrossRefGoogle Scholar
  23. 23.
    R.R. Hark, J.J. Remus, L.J. East, R.S. Harmon, M.A. Wise, B.M. Tansi, K.M. Shughrue, K.S. Dunsin, C. Liu, Spectrochim. Acta Part B 74–75, 131 (2012)Google Scholar
  24. 24.
    A.I. Fridman, J. Geochem. Explor. 38, 1 (1990)CrossRefGoogle Scholar
  25. 25.
    M.I. Leybourne, E.M. Cameron, Geochem-Explor. Env. A. 10, 99 (2010)CrossRefGoogle Scholar
  26. 26.
    A. Marie, A. Vengosh, Ground Water 39, 240 (2001)CrossRefGoogle Scholar
  27. 27.
    S. Helgen, A. Davis, A. Nicholson, Environ. Forensics 4, 255 (2003)CrossRefGoogle Scholar
  28. 28.
    M.G. Lawrence, A. Greig, K.D. Collerson, B.S. Kamber, Appl. Geochem. 21, 839 (2006)CrossRefGoogle Scholar
  29. 29.
    C. Reimann, M. Birke, Geochemistry of European Bottled Water (Borntraeger Verlagsbuchhandlung, Stuttgart, 2010)Google Scholar
  30. 30.
    D.E. Walling, P.N. Owens, G.J.L. Leeks, Hydrol. Process. 13, 955 (1999)ADSCrossRefGoogle Scholar
  31. 31.
    G.F. Birch, Int. J. Environ. Pollut. 13, 573 (2000)CrossRefGoogle Scholar
  32. 32.
    E. de Miguel, S. Charlesworth, A. Ordóñez, E. Seijas, Sci. Total Environ. 340, 137 (2005)CrossRefGoogle Scholar
  33. 33.
    J. Liu, Y. Saito, X. Kong, H. Wang, L. Zhao, Cont. Shelf Res. 29, 846 (2009)ADSCrossRefGoogle Scholar
  34. 34.
    A.L. Collins, Y. Zhang, D.E. Walling, S.E. Grenfell, P. Smith, Sci. Total Environ. 408, 5461 (2010)CrossRefGoogle Scholar
  35. 35.
    D.R. Muhs, C.A. Bush, K.C. Stewart, T.R. Rowland, R.C. Crittenden, Quat. Res. 33, 157 (1990)CrossRefGoogle Scholar
  36. 36.
    B. Bousquet, G. Travaillé, A. Ismaël, L. Canioni, K.M.-L. Pierrès, E. Brasseur, S. Roy, I.l. Hecho, M. Larregieu, S. Tellier, M. Potin-Gautier, T. Boriachon, P. Wazen, A. Diard, S. Belbèze, Spectrochim. Acta Part B 63, 1085 (2008)Google Scholar
  37. 37.
    T.L. Potter, in Petroleum Contaminated Soils, vol. 3, ed. by P.T. Kostecki, E.J. Calabrese (Lewis Publishers Inc., 1990), pp. 83–92Google Scholar
  38. 38.
    I.R. Kaplan, Y. Galperin, S.-T. Lu, R.-P. Lee, Org. Geochem. 27, 289 (1997)CrossRefGoogle Scholar
  39. 39.
    R.L. Kaufman, H. Dashti, C.S. Kabir, J.M. Pederson, M.S. Moon, R. Quttainah, H. Al-Wael, SPE Reserv. Eval. Eng. 5, 190 (2002)CrossRefGoogle Scholar
  40. 40.
    I. Eide, K. Zahlsen, Energ. Fuel. 19, 964 (2005)CrossRefGoogle Scholar
  41. 41.
    C.A. Redmount, M.E. Morgenstein, J. Archaeol. Sci. 23, 741 (1996)CrossRefGoogle Scholar
  42. 42.
    K.H. Wedepohl, Glass Sci. Tech. 70, 246 (1997)Google Scholar
  43. 43.
    M. Markham, P.A. Floyd, Proc. Ussher 9, 218 (1998)Google Scholar
  44. 44.
    J.D. Greenough, M.P. Gorton, L.M. Mallory-Greenough, Geoarchaeol. 16, 763 (2001)CrossRefGoogle Scholar
  45. 45.
    M.D. Glascock, Acc. Chem. Res. 35, 611 (2002)CrossRefGoogle Scholar
  46. 46.
    L.M. Mallory-Greenough, J. Baker, J.D. Greenough, Can. J. Archaeol. 26 (2002)Google Scholar
  47. 47.
    A. Adriaens, Spectrochim. Acta B 60, 1503 (2005)ADSCrossRefGoogle Scholar
  48. 48.
    R.H. Tykot, Acc. Chem. Res. 35, 618 (2002)CrossRefGoogle Scholar
  49. 49.
    A. Abduriyim, H. Kitawaki, Gems Gemol. 42, 98 (2006)CrossRefGoogle Scholar
  50. 50.
    C.E. McManus, N.J. McMillan, R.S. Harmon, R.C. Whitmore, F.C. DeLucia, A.W. Miziolek, Appl. Opt. 47, 72 (2008)CrossRefGoogle Scholar
  51. 51.
    B. Giussani, D. Monticelli, L. Rampazzi, Anal. Chim. Acta 635, 6 (2009)Google Scholar
  52. 52.
    G.R. Rossman, Elements 5, 159 (2009)CrossRefGoogle Scholar
  53. 53.
    D.C. Alvey, K. Morton, R.S. Harmon, J.L. Gottfried, J.J. Remus, L.M. Collins, M.A. Wise, Appl. Opt. 49, C168 (2010)CrossRefGoogle Scholar
  54. 54.
    J.J. Remus, R.S. Harmon, R.R. Hark, G. Haverstock, D. Baron, I.K. Potter, S.K. Bristol, L.J. East, Appl. Opt. 51, B65 (2012)CrossRefGoogle Scholar
  55. 55.
    G. Rapp, Annu. Rev. Earth Planet. Sci. 15, 97 (1987)ADSCrossRefGoogle Scholar
  56. 56.
    R.S. Harmon, R.E. Russo, R.R. Hark, Spectrochim. Acta A (in press) (2013)Google Scholar
  57. 57.
    B. Naes, S. Umpierrez, S. Ryland, C. Barnett, J. Almirall, Spectrochim. Acta A 63, 1145 (2008)CrossRefGoogle Scholar
  58. 58.
    M.S. Shackley, Obsidian: Geology and Archeology in the North American Southwest (The University of Arizona Press, 2005)Google Scholar
  59. 59.
    R.C. Wiens, S. Maurice, Geol. Soc. Am. Abs. Prog. 44, 190 (2012)Google Scholar
  60. 60.
    R.S. Harmon, J.J. Remus, J. Gottfried, J. Gonzalez, D. Wong, D. Baron, The effects of LIBS laser wavelength on the identification of obsidian artifact provenance. Paper presented at the LIBS 2010, 6th international conference on laser-induced breakdown spectroscopy, Memphis, TN, September 13–17, 2010Google Scholar
  61. 61.
    A. Hrdlička, L. Prokeš, M. Galiová, K. Novotný, A. Vitešníková, T. Helešicová, V. Kanický, Chem. Pap. 67, 546 (2013)CrossRefGoogle Scholar
  62. 62.
    J.L. Gottfried, R.S. Harmon, F.C. De Lucia Jr, A.W. Miziolek, Spectrochim. Acta B 64, 1009 (2009)ADSCrossRefGoogle Scholar
  63. 63.
    R.T. Wainner, R.S. Harmon, A.W. Miziolek, K.L. McNesby, P.D. French, Spectrochim. Acta, Part B 56, 777 (2001)Google Scholar
  64. 64.
    M.Z. Martin, S.D. Wullschleger, C.T. Garten, A.V. Palumbo, Appl. Opt. 42, 2072 (2003)ADSCrossRefGoogle Scholar
  65. 65.
    C. Fabre, M.-C. Boiron, J. Dubessy, A. Moissette, J. Anal. At. Spectrom. 14, 913 (1999)CrossRefGoogle Scholar
  66. 66.
    D.W. Hahn, W.L. Flower, K.R. Hencken, Appl. Spectrosc. 51, 1836 (1997)ADSCrossRefGoogle Scholar
  67. 67.
    T. Kim, C.T. Lin, Y. Yoon, J. Phys. Chem. B. 102, 4284 (1998)CrossRefGoogle Scholar
  68. 68.
    K. Novotný, J. Kaiser, M. Galiová, V. Konečná, J. Novotný, R. Maliona, M. Liška, V. Kanický, V. Otruba, Spectrochim. Acta, Part B 63, 1139 (2008)Google Scholar
  69. 69.
    V. Zorba, X. Mao, R.E. Russo, Spectrochim. Acta, Part B 66, 189 (2011)Google Scholar
  70. 70.
    T. Čtvrtnícková, F.J. Fortes, L.M. Cabalin, J.J. Laserna, Appl. Spectrosc. 61, 719 (2007)ADSCrossRefGoogle Scholar
  71. 71.
    T. Čtvrtnícková, F.J. Fortes, L.M. Cabalin, V. Kanický, J.J. Laserna, Surf. Interface Anal. 41, 714 (2009)CrossRefGoogle Scholar
  72. 72.
    S.K. Sharma, A.K. Misra, P.G. Lucey, R.C. Weins, S.M. Clegg, Spectrochim. Acta, Part B 68, 1036 (2007)Google Scholar
  73. 73.
    F. Hilbk-Kortenbruck, R. Noll, P. Wintjens, H. Falk, C. Becker, Spectrochim. Acta, Part B 56, 933 (2001)Google Scholar
  74. 74.
    S.L. Lui, Y. Godwal, M.T. Taschuk, Y.Y. Tsui, R. Fedosejevs, Anal. Chem. 80, 1995 (2008)CrossRefGoogle Scholar
  75. 75.
    S.K. Sharma, A.K. Misra, P.G. Lucey, R.C.G. Lentz, Spectrochim. Acta, Part A 73, 468 (2009)Google Scholar
  76. 76.
    N.J. McMillan, C.E. McManus, R.S. Harmon, F.C. DeLucia, A.W. Miziolek, Anal. Bioanal. Chem. 385, 263 (2006)CrossRefGoogle Scholar
  77. 77.
    R.S. Harmon, F.C. DeLucia, A.W. Miziolek, K.L. McNesby, R.A. Walters, P.D. French, Geochem.-Explor. Env. A. 5, 21 (2005)Google Scholar
  78. 78.
    A.P.M. Michel, M. Lawrence-Snyder, S.M. Angel, A.D. Chave, Appl. Opt. 46, 2507 (2007)ADSCrossRefGoogle Scholar
  79. 79.
    A.S. Eppler, D.A. Cremers, D.D. Hickmott, A.C. Koskelo, Appl. Spectrosc. 50, 1175 (1996)ADSCrossRefGoogle Scholar
  80. 80.
    S.I. Gornushkin, I.B. Gornushkin, J.M. Anzano, B.W. Smith, J.D. Winefordner, Appl. Spectrosc. 56, 433 (2002)ADSCrossRefGoogle Scholar
  81. 81.
    P. Yaroshchyk, D.L. Death, S.J. Spencer, Appl. Spectrosc. 264, 1335 (2010)ADSCrossRefGoogle Scholar
  82. 82.
    A. Ciucci, M. Corsi, V. Palleschi, S. Ratelli, A. Slavetti, E. Tognoni, Appl. Spectrosc. 53, 960 (1999)ADSCrossRefGoogle Scholar
  83. 83.
    E. Tognoni, G. Cristoforetti, S. Legnaiolia, V. Palleschi, Spectrochim. Acta, Part B 65, 1 (2010)Google Scholar
  84. 84.
    I. Borgia, L.M.F. Burgio, M. Corsi, R. Fantoni, V. Palleschi, A. Salvetti, M.C. Squarcialupi, E. Tognoni, J. Cult. Herit. 1, S281 (2000)CrossRefGoogle Scholar
  85. 85.
    D. Bilajic, M. Corsi, G. Cristoforetti, S. Lehnaioli, V. Palleschi, A. Salvetti, E. Tognoni, Spectrochim. Acta, Part B 57, 339 (2002)Google Scholar
  86. 86.
    F.C. DeLucia Jr, J.L. Gottfried, Mater. Today 14, 274 (2011)CrossRefGoogle Scholar
  87. 87.
    R. Wisbrun, I. Schechter, R. Neissner, H. Schroder, K.L. Kompa, Anal. Chem. 66, 2964 (1994)CrossRefGoogle Scholar
  88. 88.
    J.O. Cáceres, J.T. López, H.H. Telle, A.G. Ureña, Spectrochim. Acta, Part B 56, 831 (2001)Google Scholar
  89. 89.
    R.S. Harmon, J.J. Remus, C. McManus, F.C. DeLucia, J. Gottfried, A.W. Miziolek, Appl. Geochem. 24, 1125 (2009)CrossRefGoogle Scholar
  90. 90.
    J.M. Andrade-Garda, Basic Chemometric Techniques in Atomic Spectroscopy (Royal Society of Chemistry, Cambridge, 2009)CrossRefGoogle Scholar
  91. 91.
    M.Z. Martin, N. Labbé, N. André, S.D. Wullschleger, R.D. Harris, M.H. Ebinger, Soil Sci. Soc. Am. J. 74, 87 (2009)CrossRefGoogle Scholar
  92. 92.
    V. Motto-Ros, A.S. Koujelev, G.R. Osinski, A.E. Dudelzak, J. Europ. Opt. Soc. Rap. Public. 3, 08011 (2008)CrossRefGoogle Scholar
  93. 93.
    E.C. Ferreira, D.M.B.P. Milori, E.J. Ferreira, R.M. DaSilva, L. Martin-Neto, Spectrochim. Acta A 63, 1216 (2008)CrossRefGoogle Scholar
  94. 94.
    J.-B. Sirven, B. Bousquet, L. Canioni, L. Sarger, Anal. Chem. 78, 1462 (2006)CrossRefGoogle Scholar
  95. 95.
    N.J. McMillan, C. Montoya, W.H. Chesner, Appl. Opt. 51, B213 (2012)CrossRefGoogle Scholar
  96. 96.
    J.-B. Sirven, B. Sallé, P. Mauchien, J.-L. Lacour, S. Maurice, G. Manhes, J. Anal. At. Spectrom. 22, 1471 (2007)CrossRefGoogle Scholar
  97. 97.
    J. Remus, K.S. Dunsin, Appl. Opt. 51, B49 (2012)CrossRefGoogle Scholar
  98. 98.
    J.J. Remus, J.L. Gottfried, R.S. Harmon, A. Draucker, D. Baron, R. Yohe, Appl. Opt. 49, 120 (2010)CrossRefGoogle Scholar
  99. 99.
    R.S. Harmon, F.C. DeLucia, C.E. McManus, N.J. McMillan, T.F. Jenkins, M.E. Walsh, A.W. Miziolek, Appl. Geochem. 21, 730 (2006)CrossRefGoogle Scholar
  100. 100.
    N.J. McMillan, R.S. Harmon, F.C. DeLucia, A.W. Miziolek, Spectrochim. Acta, Part B 62, 1528 (2007)Google Scholar
  101. 101.
    T.G.G. Laboratory, Jewellery News Asia, 66 (2006)Google Scholar
  102. 102.
    R.W. Hughes, Austral. Gemmol. 19, 52 (1995)Google Scholar
  103. 103.
    M. Guillong, D. Günther, Spectrochim. Acta A 56, 1219 (2001)CrossRefGoogle Scholar
  104. 104.
    H.A. Hänni, M.S. Krzemnicki, K. L., J.P. Chalain, Z. Dtsch. Gem. Gesell. 53, 79 (2004)Google Scholar
  105. 105.
    M.S. Krzemnicki, H.A. Hänni, R. Walters, Gems Gemol. 40, 314 (2004)CrossRefGoogle Scholar
  106. 106.
    D.B. Hoover, B. Williams, Austral. Gemmol. 23, 146 (2007)Google Scholar
  107. 107.
    J. Gottfried, R.S. Harmon, R.R. Hark, F.C. De Lucia Jr, A.W. Miziolek, Analysis and discrimination of volcanic rocks by benchtop and standoff LIBS. Paper presented at the Joint Meeting of The Geological Society of America, Soil Science Society of America, American Society of Agronomy, Crop Science Society of America, Gulf Coast Association of Geological Societies with the Gulf Coast Section of SEPM, Houston, TXGoogle Scholar
  108. 108.
    S.K. Bristol, R.R. Hark, R.S. Harmon, J.J. Remus, L.J. East, Analysis of historical rocks using laser-induced breakdown spectroscopy (LIBS). Paper presented at the 241st American Chemical Society National Meeting & Exposition, Anaheim, CA, 27–31 March 2011Google Scholar
  109. 109.
    L. Haarklau, L. Johnson, D.L. Wagner, Fingerprints in the Great Basin: The Nellis Air Force Base Regional Obsidian Sourcing Study (U.S. Army Corps of Engineers, Fort Worth District, 2005)Google Scholar
  110. 110.
    R.S. Harmon, J.J. Remus, S.K. Bristol, I.K. Potter, R.R. Hark, L.J. East, Connecting obsidian artifacts with their sources using laser-induced breakdown spectroscopy (LIBS). Paper presented at the 38th Annual Meeting of the Federation of Analytical Chemistry and Spectroscopy Societies (FACSS), Reno, NVGoogle Scholar
  111. 111.
    F. Melcher, M.A. Sitnikova, T. Graupner, N. Martin, T. Oberthür, F. Henjes-Kunst, E. Gäbler, A. Gerdes, H. Brätz, D.W. Davis, S. Dewaele, SGA News 23, 6 (2008)Google Scholar
  112. 112.
    C. Savu-Krohn, G. Rantitsch, P. Auer, F. Melcher, T. Graupner, Nat. Resour. Res. 20, 177 (2011)CrossRefGoogle Scholar
  113. 113.
    H.-E. Gäbler, F. Melcher, T. Graupner, A. Bahr, M.A. Sitnikova, F. Henjes-Kunst, T. Oberthür, H. Brätz, A. Gerdes, Geostan. Geolanal. Res. 35, 431 (2011)CrossRefGoogle Scholar
  114. 114.
    K.M. Shughrue, K.S. Dunsin, M.A. Wise, J.J. Remus, L.J. East, J. Gonzalez, R.R. Hark, R.S. Harmon, LIBS analysis of columbite-tantalite: A real-time technique for the analysis of conflict minerals in the field? Paper presented at the 3rd North American Symposium on Laser-induced Breakdown Spectroscopy, Clearwater Beach, FL, 18–20 July 2011Google Scholar
  115. 115.
    B.M. Tansi, R.R. Hark, L.J. East, J.J. Remus, R.S. Harmon, M.A. Wise, Laser-induced breakdown spectroscopy (LIBS) for geochemical fingerprinting of columbite-tantalite sources. Paper presented at the 243rd American Chemical Society National Meeting & Exposition, San Diego, CA, 25–29 March 2012Google Scholar
  116. 116.
    IndexMundi, Tin Monthly Price—US Dollars per Metric Ton. http://www.indexmundi.com/commodities/?commodity=tin&months=360. Accessed 20 May 2013
  117. 117.
    I.K. Potter, B.M. Tansi, K. Hilferding, R.R. Hark, J.J. Remus, M.A. Wise, R.S. Harmon, L.J. East, Determination of source location of the “conflict mineral” cassiterite using laser-induced breakdown spectroscopy (LIBS). Paper presented at the 243rd American Chemical Society National Meeting & Exposition, San Diego, CA, 25–29 March 2012Google Scholar
  118. 118.
    C.H. Aurand, Chem. Eng. News 90, 36 (2012)Google Scholar
  119. 119.
    H.-E. Gabler, S. Rehder, A. Bahr, F. Melcher, S. Goldmann, J. Anal. Atomic Spectrom (2013)Google Scholar
  120. 120.
    . M.J.C. Pontes, J. Cortez, R.K.H. Galvão, C. Pasquini, M.C.U. Araújo, R.M. Coelho, M.K. Chiba, M.F.d. Abreu, B.E. Madari, Anal. Chim. Acta 642, 12 (2009)Google Scholar
  121. 121.
    S. Jantzi, J.R. Almirall, Anal. Bioanal. Chem. 400, 3341 (2011)CrossRefGoogle Scholar
  122. 122.
    M. Gaft, E. Dvir, H. Modiano, U. Schone, Spectrochim. Acta, Part B 63, 1177 (2008)Google Scholar
  123. 123.
    W. Yin, L. Zhang, L. Dong, W. Ma, S. Jia, Appl. Spectrosc. 63, 865 (2009)ADSCrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2014

Authors and Affiliations

  1. 1.Department of ChemistryJuniata CollegeHuntingdonUSA
  2. 2.Department of Marine, Earth and Atmospheric SciencesNorth Carolina State UniversityRaleighUSA

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