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Homogeneous Catalysis Promoted by Carbon Dioxide

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Transformation and Utilization of Carbon Dioxide

Part of the book series: Green Chemistry and Sustainable Technology ((GCST))

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Abstract

Supercritical CO2 (scCO2), which is recognized as CO2 heated and pressurized beyond its critical point (T c = 31.06 °C, P c = 7.38 MPa), is considered to be a suitable candidate for the replacement of conventional organic solvents, owing to its unique physical properties, such as abundantly available and cheap, nontoxic and environmentally benign, nonflammable and nonreactive even under oxidative conditions, high gaseous miscibility, effective mass transfer, easily tunable properties with subtle variation of pressure or temperature, weakening of the solvent interactions around the reacting species, and easy separation and recycling. In particular, smart use of dense CO2 would pronouncedly enhance the selectivity of target products and improve catalytic efficiency and lifetime of the catalyst. In this chapter, utilization of scCO2 as innovative and environmentally friendly reaction medium for chemical syntheses and especially for the metal-catalyzed reactions, including hydrogenation (asymmetric hydrogenation, hydrogenation, and hydroboration of styrene), carbonylation (hydroformylation, hydroesterification), C–C forming reaction (Diels–Alder cycloaddition, coupling reaction, olefin metathesis, Aldol reaction, miscellaneous reactions), oxidation reaction (oxidation reaction of alcohols, aldehydes, hydrocarbon and olefins, Baeyer–Villiger reaction), and polymerization (free radical polymerization, cationic polymerization, metal-catalyzed polymerization) is summarized.

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Authors and Affiliations

  1. State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin, 300071, People’s Republic of China

    Ran Ma, Zhen-Feng Diao, Zhen-Zhen Yang & Liang-Nian He

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  1. Ran Ma
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  2. Zhen-Feng Diao
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  1. Department of Chemistry, Institute of Chemical Technology, Mumbai, India

    Bhalchandra M. Bhanage

  2. Division of Chemical Process Engineering, Hokkaido University Faculty of Engineering, Sapporo, Japan

    Masahiko Arai

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Ma, R., Diao, ZF., Yang, ZZ., He, LN. (2014). Homogeneous Catalysis Promoted by Carbon Dioxide. In: Bhanage, B., Arai, M. (eds) Transformation and Utilization of Carbon Dioxide. Green Chemistry and Sustainable Technology. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-44988-8_13

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